Due to the recent changes in the economy of Kentucky tobacco production, some producers are seeking an alternative crop that will provide similar economic gains to tobacco without needing more acreage. Tomatoes are an existing crop in Kentucky that have been declining in acreage over the last five years. There is evidence to suggest that, through niche and local marketing, tomatoes may be able to fill the void left by tobacco. However, there is concern among producers that they will lose yield and/or quality if they switch to one of these niche production systems or cultivars. A two year study at Western Kentucky University compared the yield and quality of three tomato cultivars, two heirlooms and one hybrid, under organic and conventional management techniques to see if producers concerns are valid. The heirloom cultivars used were 'Cherokee Purple' (CP) and 'Mr. Stripey', (MS) the hybrid cultivar was 'Crista' (CR). The study was a split block design, with four randomized replications within each block. Plants were grown under black plastic mulch, with drip irrigation under the mulch. Plants were harvested weekly throughout the season and data were collected on individual fruit weight, size, grade and the number of fruit produced per plant. Production and quality were compared between management techniques for each cultivar, and the cultivars were compared to each other under individual management techniques. When comparing organic and conventional management practices, CP produced significantly (p<.05) larger, heavier, and higher quality fruit under organic practices and showed no significant differences in fruit number in 2008. MS and CR showed no significant differences between production systems for fruit weight or size, CR produced significantly higher quality fruit under conventional treatment and MS produced significantly more fruit per plant in 2008. In 2009, CP did not produce enough fruit under organic management to allow statistical comparison between management systems. MS however did not show any significant differences between management systems for any of the traits studied. CR produced significantly larger fruit under organic management, but no other differences were observed. When comparing cultivars in 2008, CP and CR produced fruit of similar weight but significantly heavier than MS under both production systems. CP produced the largest fruit under organic management, with CR following and MS producing the smallest fruit. Under conventional management, CP and CR produced fruit of similar size and both were larger than MS. MS produced the highest quality fruit under organic management, and CR produced the nicest grade under conventional management. No differences were seen for number of fruit per plant between cultivars under organic management, while MS produced the most fruit per plant under conventional management. In 2009 CP did not produce enough fruit to be statistically compared to the other cultivars under organic management. MS and CR produced fruit of similar weight under both organic and conventional management, while CP produced the greatest weight under conventional management. CR produced larger fruit than MS under organic management, while under conventional management CP and CR were of similar size as were CR and MS, but CP was significantly larger than MS. No significant differences were found between cultivars for fruit grade or number of fruit per plant under either management system in 2009.

This study was conducted to obtain landscape- and regional-scale estimates of N₂O emissions for a representative part of the Black soil zone of Saskatchewan. A 4318-km² study region was stratified based on soil texture and land use. At the regional scale, soil texture was the proxy variable used to represent the differences in soil moisture regimes and soil fertility, whereas land use was the surrogate variable used to reflect the differences in N and C cycling. Soil landscapes were selected to cover the range of soil texture and land use characteristics in the study region. At the landscape level, shoulder and footslope complexes were used as the spatial sampling units to cover the range of topographical and soil characteristics within the landscape. At the landform complex level, soil moisture (as assessed by volumetric moisture content and water-filled pore space) was the most important factor controlling N₂O emission. At the landscape scale, soil moisture was, in turn, influenced by topography, and on the seasonal scale it was affected by climatic factor(s) (e.g., precipitation). The annual N₂O emissions were calculated as the sum of the spring and the summer to fall fluxes. The spring emission was estimated by interpolating the N₂O fluxes measured on discrete sampling days, whereas the summer to fall emission was estimated by establishing regression models that related N₂O fluxes to water-filled pore space. Regional estimates of N₂O emissions were obtained using the GIS database of soil texture and land use types. The average annual fluxes for fertilized cropped, fallow, pasture, and forest areas, weighted by their areal extent in the different textural areas of the study region, were 2.01, 0.12, 0.04, and 0.02 kg N₂O-N ha^-1 yr^-1 respectively. The weighted-average annual fluxes for the medium- to fine-textured and sandy-textured areas were 1.31 and 0.04 kg N₂O-N ha^-1 yr$\sp{-1},$ respectively. For the study region, the weighted-average annual flux was 0.90 kg N₂O-N ha^-1 yr$\sp{-1}.$

No description available.

Agronomic practices, including tillage, crop rotation and N fertilization, have been developed to efficiently manage soil N dynamics and crop N nutrition. These practices can affect soil organic carbon (SOC) and soil total nitrogen (STN) sequestration, and consequently influence soil nitrogen mineralization (SNM) and crop N nutrition. However, little research has been systematically and simultaneously conducted to examine the effect of agronomic management on (1) SOC and STN stocks; (2) SNM; and (3) crop N nutrition. Burley tobacco (Nicotiana tobacum L.) is a N demanding crop and subject to inefficiency in N fertilization. Moreover, conservation tillage and rotation have been integrated into traditionally tillage intensive tobacco cropping systems. Thus, a tobacco tillage and rotation study was used to test how agronomic practices can affect N dynamics and crop N status in a series of sequential experiments. Firstly, different tobacco production systems were utilized to investigate the effects of tillage and rotation on soil aggregate stabilization and associated SOM sequestration. No-tillage and rotation management enhanced SOC and STN stocks, mainly by increasing the proportion of macroaggregates and SOC and STN concentrations. Secondly, a series of studies were conducted on SNM, including: (1) comparison of laboratory and in situ resin-core methods in estimating SNM; (2) evaluation of the influence of N fertilizer application on SNM; and (3) comparison of chemical indices for predicting SNM across management treatments over time. Laboratory method had different results relative to in situ method due to sample pretreatments. Fertilizer N application had a priming effect on SNM, but priming depended on both the N fertilizer rate and the background SOM level. The effect of rotation/tillage treatments on SNM was stable across years and SOC appeared to be the best indicator of SNM among other soil carbon and N estimates. Thirdly, a N fertilizer study for different tillage systems was conducted in 2012 and 2013. Crop parameters and plant available N (PAN) were collected to investigate the impact of tillage on tobacco production. Crop parameters showed that no-tillage can result in N deficiency in dry years. Similar PAN for both tillage methods suggested N deficiency in no-till tobacco was due to the crop’s lower N uptake capacity. In 2014, tobacco root analysis confirmed that no-tillage can result in less root exploration of the soil volume than conventional tillage.

A greenhouse study was carried out to investigate the effectiveness of soil-applied silicon (Si) with that of foliar applications for sorghum growth. Silicon sources were soil-applied as calmasil (calcium silicate) at two rates (4 and 8t/ha) and foliar applied Si including pure K-silicate, K-humate and K-fulvate (all three foliar treatments at rates of 300 and 600 ppm). Another treatment included soil applied calmasil plus low rate of foliar applied K-humate. The soils used for the greenhouse trial were Cartref, Glenrosa, Nomanci and Fernwood. Results indicated that application of calcium silicate to the soil before planting increased sorghum yield and Si uptake in three of the four soils. Silicon uptake from different experimental treatments followed the order: Calmasil 8t/ha > calmasil 4t/ha ~ calmasil + 300 ppm K-humate> K-humate = K-fulvate = pure-K silicate = control. Foliar sprays were ineffective at increasing yield, Si content of the plant tissues or Si uptake. The concentrations of exchangeable Ca, Mg as well as soil pH were significantly increased by calmasil treatments. Extractable AI concentrations were also reduced due to the Iiming effect of calcium silicate and also possibly formation of insoluble aluminosilicates. The yield response to applied calmasil seemed to be primarily related to its Iiming effect and reductions in extractable AI in the Cartref, Glenrosa and Nomanci soils. The dry matter yield was highest in Fernwood and lowest in Cartref soil. However, there was no significant yield response to calmasil in Fernwood soil which had an initial pH of 5.8 and insignificant extractable AI concentrations. Therefore application of calcium silicate had no significant effect on extractable AI concentration in this soil. Yield response to calmasil may also have been partly due to direct positive effects of applied Si on crop growth through mechanisms such as increased photosynthetic rate and reduced transpiration rate, Addition of calmasil increased the concentrations of Si in the plant tissues and reduced those of N, P and Kin Nomanci and Fernwood soils respectively. This indicates that nutrient interactions were occurring in the plant. It was concluded that foliar-application is not an effective way of applying Si to a Siresponsive crop such as sorghum when growing in soils low in extractable soil Si. This is because Si is accumulated in plant tissues in similar amounts to macronutrients. It was also concluded that in future, studies of crop response to applied Si should include the use of non-Iiming source of Si (e.g. silicic acid) so as to separate a liming effect of calcium silicate from effect of applied Si. In a laboratory study, the effects of applied silicic acid, calcium silicate and calcium hydroxide on levels of extractable P in two Si-deficient soils were investigated. Two soils (Fernwood and Nomanci soils) were treated with two rates of P and three soil amendments (calcium silicate, calcium hydroxide and silicic acid) and incubated for six weeks at room temperature. Phosphorus was extracted using Truog, AMBIC and resin methods, and levels of exchangeable and solution AI and extractable and solution Si were also measured. Application of calcium silicate and calcium hydroxide increased soil pH in both soils while silicic acid additions had no significant effect compared with the control. The pH increase was much greater in the Fernwood than Nomanci soil because of the low buffering capacity of the sandy Fernwood soil. Exchangeable AI and concentrations of monomeric and total AI in soil solution generally followed the order: control ~ silicic acid> calcium silicate> calcium hydroxide. The lowering of soluble AI concentrations in the silicic acid treatments was attributed to formation of insoluble aluminosilicate compounds while that in the calcium silicate and calcium hydroxide treatments was attributed to their Iiming effects causing a rise in pH. Concentrations of Si in soil solution were lower in the calcium hydroxide than the control treatment suggesting the solubility of Si decreased with increased pH. Additions of both Si sources increased Si concentrations in solution and the effect was more marked for the calcium silicate treatment. This was attributed to formation of insoluble aluminosilicates in the silicic acid treatment. Concentrations of H2S04extractable Si with treatment did not closely follow the same trends as those for Si concentrations in soil solution. That is, levels of extractable Si were very much higher in the calcium silicate than silicic acid treatment in both soils. In addition, concentrations of extractable Si in the calcium hydroxide treatment were similar to control in the Nomanci soil, while for the Fernwood soil, concentrations in the calcium hydroxide treatment were exceptionally high. It was suggested that liming with calcium silicate or calcium hydroxide had rendered some Si-containing compounds in the soil acid-extractable and that the nature of acid-extractable Si fraction need further study in future. The quantities of P extracted from the two soils by the various extractants followed the order: Truog> AMBle> resin. The greatest increase in extractable P induced by additions of P was recorded for Truog P and the least for resin P. The effects of Iiming (addition of calcium silicate or calcium hydroxide) on extractable P levels differed depending on the soil and extractant used with increase, decrease or no effect being recorded. Such results confirm the complexity of lime and P interactions which occur in acid soils. Additions of silicic acid had no effect on levels of extractable P, compared to control. It was suggested that the reason for this was that phosphate is adsorbed to AI and Fe oxide surfaces much more strongly than silicate. As a result, additions of Si are ineffective at increasing extractable P levels. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2006.

Water treatment residues (WTRs) are the by-product from the production of potable water. They consist mainly of the precipitated hydrous oxides of the treatment chemicals, and materials removed from the raw water. This study investigated the range of treatment processes and residues produced in South Africa, and two WTRs were selected for testing on selected soils and mine materials. A questionnaire was developed and sent to water treatment authorities across South Africa. Information on the treatment chemicals, dosages, volumes and current disposal practices, and a sample of WTR from each treatment plant were requested. Eleven, of 21 authorities, returned completed questionnaires, representing 37 water treatment facilities. Organic polymers were the most commonly used treatment chemical, with most plants also using lime. Other less frequently used chemicals and additives were Alz(S04)3.14I-hO, Fe2(S04)3, FeC!), sodium aluminate, activated silica, activated charcoal, CO2 and bentonite. Information given regarding residue thickening and disposal was poor. Samples from Rand Water, Umgeni Water (Midmar), Midvaal Water Company, Amatola Water and Cape Metropolitan Council (Faure) were received or collected. An additional sample from Faure was also received, representing a change in the treatment process. These samples were analysed for a range of chemical and physical characteristics. These analyses showed that the WTRs had the potential to supply some plant nutrients (Ca, Mg, Fe, S) but that metal toxicity may be a problem, in particular Mn in the Faure WTR, and that P adsorption may be severe. The samples selected to test the potential for land disposal were from Rand Water and Faure. A pot experiment tested the growth of Eragrostis tefJ, Cenchrus ciliaris and Digitaria eriantha in mixtures of Rand WTR and material from a coal mine i.e., a sandy soil material, spoil material and coal combustion ash, at rates of 0, 50, 100, 200 and 400 g kg" with a uniform fertiliser treatment applied to all mixtures. The grass was harvested on three occasions and the mean total yield (dry mass) determined, as well as nutrient uptake. The pots were leached after each harvest and the pH and electrical conductivity determined. The soil, spoil and ash were characterised and pH, EC and water retention characteristics of the mixtures determined. Growth of the grasses in the ash treatments was poor and these were terminated. Eragrostis tefJ grown in the soil showed a decrease in mean total yield with increasing WTR application rate, but yield was good up to the 200 g kg" treatment at the first harvest, declining substantially by the second harvest. In general C. ciliaris and D. eriantha grown in the soil showed a decrease in mean total yield for all harvests with increasing WTR application. The yield of E. /ejJ, grown in the spoil, increased up to 100 g kg,l WTR addition, but decreased thereafter. Digitaria eriantha showed a decrease in yield, and C. ciliaris an increase, with increasing WTR application rate , but for all treatments the differences were non-significant. The pH and EC of the leachates generally increased with increasing WTR addition. The concentration of nutrients in the grasses did not indicate any deficiencies or toxicities. As the growth of grass was poor in the ash treatments, another pot experiment was established to test the growth of two creeping grass species grown in the Rand WTR as a cover over the ash material. Cynodon dactylon and Stenotaphrum secundatum were grown in 20, 40 and 60 mm layers of Rand WTR, with and without a fertiliser treatment. Both species performed best in the 60 mm layer with fertiliser, and C. dactylon performed better than S. secundatum. The former species was more tolerant of the high pH, but both have potential as cover vegetation on the ash dumps when these are covered with Rand WTR. A further glasshouse study investigated the effect of Faure WTR mixed with a nutrient poor sandy soil on the nutrient uptake and seed yield of common dry beans (Phaseolus vulgaris). The WTR was added to the soil at 0, 50, 100, 200 and 400 g kg" each with five levels of fertiliser (0, 25, 50, 100 (recommended optimum) and 150 %). Bean pods were harvested once the plants had senesced. The number of pods and mass and number of seeds per treatment were determined. The seeds were analysed for nutrient uptake. Interveinal chlorosis and necrotic lesions were evident on cotylendonous and new leaves in the WTR treated soils, the severity of the symptoms increasing with increasing rate of WTR. Additional pots were established at the 400 g kg" rate (without fertiliser) and leaf material collected for chemical analysis. This showed that Mn toxicity was the cause, with leaf concentrations about 12 times the recommended 100 mg kg" upper limit. However, mass of bean seed was highest in the 400 g kg" Faure WTR treatment with 150 % fertiliser. Nutrient translocation to the seed seemed to be relatively consistent regardless of treatment, with little accumulation ofMn. The data collected illustrated the range of conditions and types of WTRs produced in South Africa, and that in some instances these residues have favourable characteristics for land application. The use of the Rand WTR showed that it could be applied to the spoil medium at relatively high concentrations without severely negatively impacting on grass growth, but more caution should be used when applying this material to the soil medium. While the grass did not grow in the ash treatments, it would seem that with suitable species the Rand WTR could be beneficially applied to ash material as a cover layer. The use of the Faure WTR on a sandy soil seemed to potentially improve the yield of the indicator crop, but caution should be exercised due to the possibility of Mn toxicity. The use of additional fertiliser would seem to be essential. Further research would require that field scale investigation of both WTRs be conducted, as well as further studies of applicat ion rates and techniques in laboratory and glasshouse investigations. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2003.

The effects of irrigation-induced salinity and/or sodicity on sugarcane yield, and two growth parameters, namely stalk height and number of nodes per stalk , were investigated on a sugarcane estate in the Zimbabwean lowveld. The effects of soil salinity and/or sodicity on the size, activity and metabolic efficiency of the soil microbial community was also studied. Furrow-irrigated fields which had a gradient in soil salinity and/or sodicity which increased from the upper to lower ends of the fields were selected for this study. This gradient was recognized by decreasing sugarcane growth down from the upper to the lower ends and the appearance of salt on the soil surface at the lower ends of fields. Sugarcane growth was classified as either dead, poor, satisfactory or good; and soil samples (0-0 .15 m, 0.15-0 .3 m, 0.3-0 .6 m and 0.6-0.9 m) were taken from each of these areas. Soils from under adjacent areas of undisturbed veld were also sampled. Sugarcane growth and yields in micro-plots of the various areas of the fields were measured. Foliar samples of sugarcane were taken at 22 weeks of age and analysed for nutrient content. Soil salinity and sodicity were quantified by measuring pH(water), electrical conductivity (ECe) and cation content of saturation paste extracts and the exchangeable cation content. From this information, the sodium adsorption ratio (SARe)and exchangeable sodium percentage (ESP) were also calculated. The calcareous, vertic soils in the study area under undisturbed veld were found to have high pH values (8 to 9.5), very high exchangeable Ca and Mg concentrations and there was evidence of accumulation of soluble salts in the surface 0.15 m. Under sugarcane production, irrigation induced salinity and sodicity had developed. Under poor and dead sugarcane, high values for ECe, SARe, and ESP were generally encountered in the surface 0-0 .3 m of the profile. In addition, the pH values under sugarcane were often between 9 and 10 particularly in profiles where sugarcane grew poorly or had died. As expected, pH was positively related to ESP and SARe, but negatively related to ECe. Measurements of aggregate stability by wet sieving, the Emerson dispersion test and the Loveday dispersion score all showed that soils from the study sited tended to disperse and that dispersion was most apparent where high ESP and SARe values occurred in association with elevated pH values and relatively low ECe values. These measurements confirmed observations at the sites of low infiltration rates and restricted drainage particularly on the lower ends of fields where sugarcane had died. In addition to the above measurements it was also observed that there was a rise in the watertable under furrow irrigation and that the watertable was nearest to the surface at the lower ends of the fields. In some cases the watertable was observed to be only 0.2 to 0.3 m from the surface. Thus, death of roots due to anaerobic conditions could be occurring to a greater extent at the lower ends of the fields. Another consequence of the high watertable was that these vertic soils were observed to remain in a permanently swollen state. This limits air and water movement in the soil profile as such soils need to be allowed to dry out and crack regularly so that macroporosity can be restored. Sugarcane yield, stalk height and number of nodes per stalk were not significantly related to ECe. Sugarcane yields were, however, significantly correlated with ESP and pH while stalk height and number of nodes were negatively correlated with ESP, SARe and pH. These results suggested that sodicity was a more limiting factor for sugarcane growth than salinity. Foliar analysis of leaf tissue did not reveal substantial differences in macro- or micro-nutrient content between good and poorly-growing sugarcane. It was concluded that the gradient of decreasing sugarcane growth down the furrow-irrigated fields, with crop death at the lower ends, was the result of a combination of factors. That is, the watertable had risen due to over-irrigation and it was nearer the surface at the lower ends of the fields. Due to capillary rise of salts, this resulted in sodic and sometimes saline-sodic conditions in the surface soil. These conditions could limit plant growth through ion toxicities, plant water stress and inhibition of root growth and function and physiological processes. These would be induced by the high pH and high salt, Na and HC03- concentrations in soil solution. Poor physical conditions associated with sodicity and the continually swollen state of the soils presumably limited infiltration and aeration in the surface soil, and probably restricted root growth. In addition, it is likely that the high watertable limited effective crop rooting depth to about 0.2 m at the lower ends of the fields. The net result was that sugarcane died at the lower ends. A negative effect of soil salinity and/or sodicity was also observed on the soil microbial population. Significant negative correlations were obtained with ECe SARe and ESP with microbial biomass C and microbial activity (as measured by FDA hydrolytic activity or arginine ammonification rate). The activity of enzymes involved in C (P-glucosidase), P (phosphatase) and S (arylsulfatase) mineralization and potential nitrogen mineralization (as determined by aerobic incubation) were also negatively correlated with these factors, with the exception of arylsulfatase activity and ESP. All the above mentioned microbial population measures were also positively correlated with soil organic C content, besides potential nitrogen mineralization. The metabolic quotient, which provides an indication of stress and efficiency of the microbial community, increased considerably with increasing salinity and sodicity and decreased with soil organic C. Thus, increasing salinity and/or sodicity resulted in a smaller, more stressed, less efficient microbial community, while the turnover rate and cycling of C, N, P and S also decreased. It was concluded that salt affected soil not only causes a decline in sugarcane yield through raising the concentration of soluble salts in soil solution, but also has a detrimental effect on microbial activity and on mineralization of soil organic C, N, Sand P. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2001.

Pasture-based dairy farming is the major land use in the Tsitsikamma region of the Eastern Cape. Permanent kikuyu grass (Pennisetum clandestinum) dominates pastures in the region. Kikuyu pastures do not, however, provide adequate year-round quality feed for dairy cows. This has led to the use of annually sown pastures with perennial ryegrass (Lolium perenne) to provide winter forage. Soil degradation under this management has, however, become recognised as a major limitation. Soil quality and degradation under annual and permanent pasture in the region were evaluated in three separate studies. These were (i) an investigation of the extent of loss of soil organic matter and related soil microbial properties and aggregate stability under annual pastures, (ii) a comparison of soil physical properties under annual and permanent pastures and (iii) a survey of the nutrient status of soils and pasture herbage in the region. In the first study, four commercial dairy farms, situated on sites which represented the three main soil groups in the region were sampled, were taken from under permanent kikuyu pastures, annual ryegrass pastures and undisturbed native vegetation nearby. In comparison with undisturbed, native vegetation, soils under both annually cultivated and permanent pasture had gained soil organic matter on the sandy, low rainfall eastern end of the Tsitsikamma. By contrast, at the higher rainfall, finer-textured, western end, where the native vegetation consists of coastal forest, there was a loss of soil organic matter under both types of pasture. Despite this, soil organic C content was lower under annual ryegrass than permanent kikuyu pasture at all the sites reflecting the degrading effect of annual cultivation on soil organic matter. As a consequence, labile, K(2)S0(4) - extractable C, microbial biomass C, basal respiration, arginine ammonification, flourescein diacetate hydrolysis rates and aggregate stability were all less under annual ryegrass than permanent kikuyu pastures at all the sites. The effects of annual ryegrass and permanent kikuyu pastures on soil physical properties and root length density were compared with those of undisturbed native vegetation on the four experimental sites. Root density and the depth of rooting were much less under annual ryegrass than under kikuyu pastures or native vegetation. There was no consistent effect of improved pastures or pasture type on bulk density and total porosity or penetrometer resistance, although annual pasture soils generally had higher bulk densities and lower total porosities than those under native vegetation. There was a tendency for smaller saturated hydraulic conductivity and air permeability under ryegrass than kikuyu pastures, regardless of whether total porosity was higher or lower under ryegrass. This was attributed to annual cultivation and subsequent natural consolidation causing a decrease in pore continuity under ryegrass pastures. Penetrometer resistance values confirmed the presence of subsoil compacted layers at two annual ryegrass pasture sites. At one such site, subsoil tillage was effective in reducing penetrometer resistance and bulk density, increasing pore continuity (as evaluated by hydraulic conductivity and air permeability) and greatly increasing root density and rooting depth. The nutrient status of soil and herbage from annual ryegrass and permanent kikuyu pastures sampled from 40 dairy farms in the Tsitsikamma region were evaluated. Along with the decreased organic matter content, there was a decrease in soil pH and a loss of exchangeable cations under annual pastures. Large concentrations of extractable P and sometimes exchangeable K were measured in soils under both ryegrass and kikuyu pastures and it was concluded that the rates of applied P, and sometimes K, were often excessive (particularly under kikuyu). Various nutritional problems were also identified. These included the need for Ca supplementation, particularly under kikuyu, due to the low herbage Ca concentrations. The low Ca : P ratio measured in annual ryegrass pastures, and more particularly in kikuyu herbage, highlighted the low Ca content of herbage and also the tendency of kikuyu grass to accumulate large concentrations of P. The large K concentrations and high K : Ca +Mg ratios identified in pasture herbage suggest the potential for animal nutritional problems such as hypomagnesaemia. It was concluded that although kikuyu is an excellent pasture in terms of dry matter production it tends to be deficient in Ca (and sometimes Na) and can contain prohibitively high K levels, which are likely to induce Mg deficiencies in grazing animals. The micronutrient concentrations in herbage were generally adequate, although copper concentrations tended to be low suggesting that fertilizer applications and/or feed supplementation is required. It was concluded that annual conventional tillage results in a substantial loss of soil organic matter, soil microbial activity and aggregate stability under annual ryegrass pastures when compared to those under permanent kikuyu grass. This loss of soil organic matter can result in natural consolidation of the soil in the cultivated layer and exasperated through treading by the grazing cows. The annual cultivation can also lead to the formation of a subsoil compacted layer. Nonetheless, compaction can also occur under permanent pasture presumably due to treading damage. Careful management to avoid treading damage to pastures should be practised. In order to protect the organic matter status of annual pastures, direct drilling of such pastures should be seriously considered. In some cases, annual fertilizer P rates (and to lesser extent those of K) could be reduced considerably since the levels accumulated in the soils are excessive. / Thesis (M.Sc.Agric.)-University of Natal, Pietermaritzburg, 2002.

Water treatment residues (WTRs) are the by-product from the production of potable water. They consist mainly of the precipitated hydrous oxides of the treatment chemicals, and materials removed from the raw water. This study investigated the range of treatment processes and residues produced in South Africa, and two WTRs were selected for testing on selected soils and mine materials. A questionnaire was developed and sent to water treatment authorities across South Africa. Information on the treatment chemicals, dosages, volumes and current disposal practices, and a sample of WTR from each treatment plant were requested. Eleven, of 21 authorities, returned completed questionnaires, representing 37 water treatment facilities. Organic polymers were the most commonly used treatment chemical, with most plants also using lime. Other less frequently used chemicals and additives were A12(SO4)3.14H2O, Fe2(SO4)3, FeC1), sodium aluminate, activated silica, activated charcoal, CO2 and bentonite. Information given regarding residue thickening and disposal was poor. Samples from Rand Water, Umgeni Water (Midmar), Midvaal Water Company, Amatola Water and Cape Metropolitan Council (Faure) were received or collected. An additional sample from Faure was also received, representing a change in the treatment process. These samples were analysed for a range of chemical and physical characteristics. These analyses showed that the WTRs had the potential to supply some plant nutrients (Ca, Mg, Fe, S) but that metal toxicity may be a problem, in particular Mn in the Faure WTR, and that P adsorption may be severe. The samples selected to test the potential for land disposal were from Rand Water and Faure. A pot experiment tested the growth of Eragrostis teff, Cenchrus ciliaris and Digitaria eriantha in mixtures of Rand WTR and material from a coal mine i.e., a sandy soil material, spoil material and coal combustion ash, at rates of 0, 50, 100, 200 and 400 g kg-1 with a uniform fertiliser treatment applied to all mixtures. The grass was harvested on three occasions and the mean total yield (dry mass) determined, as well as nutrient uptake. The pots were leached after each harvest and the pH and electrical conductivity determined. The soil, spoil and ash were characterised and pH, EC and water retention characteristics of the mixtures determined. Growth of the grasses in the ash treatments was poor and these were terminated. Eragrostis teff grown in the soil showed a decrease in mean total yield with increasing WTR application rate, but yield was good up to the 200 g kg-1 treatment at the first harvest, declining substantially by the second harvest. In general C. ciliaris and D. eriantha grown in the soil showed a decrease in mean total yield for all harvests with increasing WTR application. The yield of E. teff, grown in the spoil, increased up to 100 g kg-1 WTR addition, but decreased thereafter. Digitaria eriantha showed a decrease in yield, and C.ciliaris an increase, with increasing WTR application rate, but for all treatments the differences were non-significant. The pH and EC of the leachates generally increased with increasing WTR addition. The concentration of nutrients in the grasses did not indicate any deficiencies or toxicities. As the growth of grass was poor in the ash treatments, another pot experiment was established to test the growth of two creeping grass species grown in the Rand WTR as a cover over the ash material. Cynodon dactylon and Stenotaphrum secundatum were grown in 20, 40 and 60 mm layers of Rand WTR, with and without a fertiliser treatment. Both species performed best in the 60 mm layer with fertiliser, and C. dactylon performed better than S. secundatum. The former species was more tolerant of the high pH, but both have potential as cover vegetation on the ash dumps when these are covered with Rand WTR. A further glasshouse study investigated the effect of Faure WTR mixed with a nutrient poor sandy soil on the nutrient uptake and seed yield of common dry beans (Phaseolus vulgaris). The WTR was added to the soil at 0, 50, 100, 200 and 400 g kg-1 each with five levels of fertiliser (0, 25, 50, 100 (recommended optimum) and 150 %). Bean pods were harvested once the plants had senesced. The number of pods and mass and number of seeds per treatment were determined. The seeds were analysed for nutrient uptake. Interveinal chlorosis and necrotic lesions were evident on cotylendonous and new leaves in the WTR treated soils, the severity of the symptoms increasing with increasing rate of WTR. Additional pots were established at the 400 g kg-1 rate (without fertiliser) and leaf material collected for chemical analysis. This showed that Mn toxicity was the cause, with leaf concentrations about 12 times the recommended 100 mg kg-1 upper limit. However, mass of bean seed was highest in the 400 g kg-1 Faure WTR treatment with 150 % fertiliser. Nutrient translocation to the seed seemed to be relatively consistent regardless of treatment, with little accumulation of Mn. The data collected illustrated the range of conditions and types of WTRs produced in South Africa, and that in some instances these residues have favourable characteristics for land application. The use of the Rand WTR showed that it could be applied to the spoil medium at relatively high concentrations without severely negatively impacting on grass growth, but that more caution should be used when applying this material to the soil medium. While the grass did not grow in the ash treatments, it would seem that with suitable species the Rand WTR could be beneficially applied to ash material as a cover layer. The use of the Faure WTR on a sandy soil seemed to potentially improve the yield of the indicator crop, but caution should be exercised due to the possibility of Mn toxicity. The use of additional fertiliser would seem to be essential. Further research would require that field scale investigation of both WTRs be conducted, as well as further studies of application rates and techniques in laboratory and glasshouse investigations. / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2003.

No abstract available. / Thesis (Ph.D.)-University of Natal, Pietermaritzburg, 1970.