Ziel der Arbeit ist es, ein genaueres Prozessverständnis zur Abflussbildung an Hängen auf der Basis der räumlichen Verbreitung periglazialer Deckschichten zu erhalten. Das Untersuchungsgebiet ist ein 6 ha großes, forstlich bewirtschaftetes Quelleinzugsgebiet im Osterzgebirge. Das anstehende Gestein ist Gneis. Der oberflächennahe Untergrund ist aus zwei- und dreigliedrigen Deckschichten zusammengesetzt. Auf der Punkt-, Hang- und Kleineinzugsgebietsskala werden hydrometrische, hydrochemische und geoelektrische Methoden sowie Färbeversuche eingesetzt, um auf die dominierenden Abflussbildungsprozesse schließen zu können. Aus der Synthese der Teilergebnisse werden drei typische Prozessabläufe in Abhängigkeit von der Gebietsvorfeuchte abgeleitet. Diese verdeutlichen, dass bei geringer Vorfeuchte Sättigungsoberflächenabfluss im Quellsumpf vorherrscht, bei mittlerer bis hoher Vorfeuchte dagegen Zwischenabfluss der dominierende Abflussprozess ist. Die Abflusswirksamkeit der Niederschläge steigt zudem mit zunehmender Vorfeuchte nichtlinear an. Es wird herausgestellt, dass die hydraulisch anisotropen Eigenschaften der Basislage entscheidend die oberflächennahen Fließwege des Wassers beeinflussen. Sie besitzt durch ihre hohe Lagerungsdichte einerseits vertikal wasserstauende Eigenschaften. Andererseits kann Wasser, begünstigt durch das dominant sandige Substrat und das hangparallel eingeregelte Bodenskelett innerhalb der Schicht bevorzugt lateral geleitet werden. Die gewonnenen Erkenntnisse verdeutlichen die Bedeutung der Eigenschaften der periglazialen Deckschichten für die Abflussbildung an Mittelgebirgshängen. / The aim of this study is to contribute to the understanding of runoff processes on slopes based on the spatial distribution of periglacial cover beds. The study area is a 6 ha large forested spring catchment in the Eastern Ore Mountains, Saxony. Bedrock is gneiss overlain by periglacial cover beds comprising two or three layers. On plot, hillslope and small-catchment scales hydrometrical, hydrochemical and geoelectrical methods as well as tracer experiments are used to determine the constitutive runoff processes. From the synthesis of partial results, three pre-moisture controlled process cycles are derived. With low pre-moisture, saturation overland flow dominates in the spring bog. In contrast, with medium or high pre-moisture interflow occurs. Besides, with rising pre-moisture runoff coefficients increase in a non-linear manner. It is emphasised that the hydraulic anisotropic structure of the Basal Layer is the major control factor for subsurface water-flow paths. On the one hand, this layer acts as an aquitard for seeping water because of its high bulk density. On the other hand, water within the layer is able to flow laterally because of the sandy texture and the coarse clasts oriented parallel to the slope. These findings highlight the importance of relic periglacial cover beds for runoff generation in subdued mountains.

From the Proceedings of the 1971 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 22-23, 1971, Tempe, Arizona / A study was made to determine how the evaporation rate from a bare Adelanto loam soil in Phoenix changes with season and with time since the last irrigation. The evaporation rates were determined by precision lysimeters in a bare field, with measurements being taken in every month of the year for at least a week after irrigation. The data exhibited a cosine-shaped curve, with a maximum evaporation rate of about 5 mm/day in summer and a minimum rate of about 2 mm/day in winter. By the seventh day, seasonal effects virtually disappear, and the evaporation rate is the same in both summer and winter, being about 2 mm/day after the 7th day and about 0.75 mm/day after the 21st day. It is generally accepted that soil dries in 3 stages, and the transition between the 1st and 2nd stages occurs when atmospheric conditions are no longer critical. In previous laboratory studies of soil drying, with constant atmospheric conditions, stage 1 was easily distinguished from stage II, and these results correlated closely with the equations of Gardner and Hillel. The individual drying curves of this field study were qualitatively different from the laboratory studies and did not confirm the predictions of the equations, suggesting that diurnal variations in temperature and other meteorological parameters have caused the difference.

From the Proceedings of the 1975 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 11-12, 1975, Tempe, Arizona / Space-time variability in the hydrologic characteristics of four major soil series represented in the Silverbell validation site was investigated by sampling the infiltration characteristics, at randomly selected locations, under several vegetative covers within each series. The experimental data was the time distribution of infiltration which, for each sampled location, was fitted by least squares to the Philip's infiltration equation. The parameters of this equation have physical interpretation and therefore were used as measures of the infiltration characteristics. Analysis of variance was used to investigate the spatial variability in the parameters. The mean values of the parameters for selected soil-vegetation combinations were used to simulate runoff due to a rainfall event over a desert catchment "containing" the given combination. Statistical tests show that there is no significant difference among the infiltration parameters of all the soil-vegetation combinations. However, the statistically insignificant variations in the parameters produce significant variations in simulated runoff volumes indicating the sensitivity of the runoff generating process to infiltration characteristics vis-a-vis the hydrologic properties of the soils.

From the Proceedings of the 1975 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 11-12, 1975, Tempe, Arizona / Evaporation of water from bare soils is an important consideration in the scheduling of many farming operations in both irrigated and dryland agriculture. Accurate predictions of bare soil evaporation can serve as the basis for decisions to increase the acreage planted with a given crop. An alternative is presented to previous approaches to bare soil evaporation estimation by empirically correlating the ratio of daily totals of actual to potential evaporation and the amplitude of the diurnal surface soil temperature wave. Since evaporation is directly related to the surface soil water pressure, the soil thermal inertia technique might be capable of prescribing relative bare soil evaporation rates which, combined with potential evaporation calculations, could allow determination of actual evaporation rates over the entire range of soil drying.

From the Proceedings of the 1978 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 14-15, 1978, Flagstaff, Arizona / The equations of Darcy, Kostiakov, Ostashev, Philip, and four modified Philip equations were evaluated for use in predicting and controlling rainwater infiltration and rainfall excess in crop and rangelands. These eight equations were least- square fitted to data from ring, border-irrigation, closed-top, and sprinkling infiltrometers. Kostiakov's equation satisfied the evaluation criteria better than the other seven equations. The parameters of Kostiakov's equation were physically interpreted by relating their magnitudes to some physical, biological, and hydraulic characteristics of the infiltration system. These characteristics included several infiltration abatement and augmentation processes and factors that are controlled at the soil surface by land management practices. The eight equations were also fitted to rainfall data to permit calculating runoff from small surface areas about the size of a typical crop plant. Comparison of the regression curves for infiltration and rainfall suggested that land management practices that appropriately alter the soil surface will permit wide-range control of infiltration, runoff, and erosion; and thereby achieve conservation and more efficient use of soil and water resources for crop production. The most important soil surface conditions affecting infiltration were microroughness, macroporosity, plant litter, and effective surface head.

From the Proceedings of the 1978 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 14-15, 1978, Flagstaff, Arizona / Described is a microroughness meter developed to obtain numerous and accurate measurements of rangeland surface microroughness and characteristics. The meter, which consists of four basic parts: (1) meter base and pin guide, (2) pin lifting support bar and lifting mechanism, (3) 100 vertically moving pins, and (4) stripchart support guide and winding mechanism, was designed to measure soil surface evaluations and characteristics of a 1m2 plot. Performance tests on multi-plot sprinkler infiltrometer studies conducted on the Santa Rita Experimental Range in southeastern Arizona indicated that the meter was accurate and relatively precise in repeating soil surface roughness measurements but was not precise in defining the theoretical characteristics of constructed surfaces. It was concluded, however, that these errors in precision were insignificant and due partly to surface geometry construction errors and that the meter is a convenient, quick, simple and accurate means of measuring surface roughness in studies requiring many plots and data points.

No description available.

No description available.

Ongoing concerns about the efficient and sustainable utilisation of South Africa’s water resources have resulted in much interest regarding the water use of different land uses within a catchment. Research has been focussed on water use by different dryland vegetation, in particular commercial forestry which has been declared a Stream Flow Reduction Activity for which a water use license is required for production. Consequently, concerns about the water use of other dryland crops have lead to a need to quantify water use by other land uses, particularly sugarcane. In this document, previous research focussed on water use by sugarcane is reviewed and summarised, together with an experiment where an energy balance approach has been used to quantify water consumption in the form of total evaporation for an area of sugarcane production in the KwaZulu-Natal Midlands with an assessment of the seasonal variability of this water consumption for a period of 1 year. The study was performed using a Large Aperture Scintillometer to measure sensible heat flux, whilst all other energy balance components, as well as rainfall, soil moisture and other climatic data were obtained using standard methods. Total evaporation was estimated from latent heat flux which was derived as a residual of the energy balance. Total evaporation varies over the year with substantially higher values occurring in summer in response to high energy and water availability. Over the year, the crop used approximately 630mm of water which equates to 53% of rainfall at the site. The two main factors affecting the seasonal variability of water use by sugarcane are net radiation and soil moisture content. In the wetter months when soil moisture is readily available, net radiation limits total evaporation. In the drier months, soil moisture is not as readily available, and limits total evaporation. Air temperature and relative humidity proved to also be important considerations in their effect on total evaporation. The total evaporation estimates obtained could be compared to a baseline (grassland) and used in simulations for a better understanding of the stream flow reduction potential of sugarcane and the seasonal variability thereof. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2006.

Löslighet och transport av sällsynta jordartsmetaller i Källfallsfältets gruvsandsmagasin Hugo de Campos Pereira Syftet med detta arbete har varit att kartlägga vilka mekanismer som styr lösligheten av sällsynta jordartsmetaller (eng. rare earth elements, REE) i sulfidhaltig anrikningssand vid den föredetta gruvan Källfallsfältet i Västmanland. För syftet har markvatten- och grundvattenprovtagning utförts, tillsammans med laktester och geokemisk modellering med Visual MINTEQ ver. 3.0. Resultaten visade att sulfidvittring är den främsta processen som styr pH i anrikningssanden, och därmed också indirekt REEs löslighet. Däremot är sulfidvittring ingen källa till REE i sig då ämnena inte föreligger sulfidbundna, något som oxiderat tillgänglighetstest NT ENVIR 006 visade. Istället går REE ut i lösning i anrikningssanden genom vittring av lättvittrade silikatmineral. Vanligtvis betraktas metall bunden i silikatform inte som geokemiskt aktiv. Jämförelser mellan laktester med olika jämviktstid visade att en kinetisk (tidsberoende) faktor föreligger, kopplad till nämnda silikatvittring, som påverkar pH och således också metallöslighet vid laktester på anrikningssanden. Vid jämförelse mellan laktester och halter i anrikningssandens mark- och grundvatten bör denna därmed vägas in. Det pH-statiska laktestet SIS-CEN/TS 14997 visade begränsad möjlighet att undersöka kinetik med anledning av att det utförs under förhållandevis kort tid, 48 timmar. REE- och Cu-halter vid syratitrering (de behandlingar med lägst syratillsatser) och enstegslakning (SIS-CEN ISO/TS 21268-2:2010) visade god, respektive förhållandevis god, överensstämmelse med uppmätta markvattenhalter. Detta visade att syratitrering och enstegslakning är laktest som är tillämpbara, respektive förhållandevis väl tillämpbara, för att uppskatta markvattenhalter i anrikningssanden. Specieringsmodellering med Visual MINTEQ ver. 3.0 visade att pH och DOC är de viktigaste parametrarna som styr REEs speciering i anrikningssandens mark-, grund och ytvatten. Samtliga REE bildar starka komplex med löst organiskt material, men koncentrationerna av DOC var generellt sett låga. I sura sulfatrika mark-, grund och ytvatten domineras specieringen av lösta sulfatkomplex, huvudsakligen (REE)SO4+, följt av fria hydratiserade joner som näst vanligaste förekomstform. Dessa resultat överensstämmer väl med tidigare modelleringsstudier av REEs speciering i sura sulfatrika vatten resulterande från gruvavfall. Med bakgrund av detta och av att REEs ekotoxicitet verkar överensstämma med den fria jon-modellen (eng. free ion model) förväntas REE uppvisa högre toxicitet vid låga pH-värden. / Solubility and transport of rare earth elements in the mine tailings of Källfallsfältet Hugo de Campos Pereira The mechanisms which govern the solubility of rare earth elements (REEs) in sulfide-containing tailings at the former mine site of Källfallsfältet (Västmanland, Sweden) were studied by the means of soil water and ground water sampling, leaching tests and geochemical modeling using Visual MINTEQ ver. 3.0. The results showed that weathering of sulfides is the primary process governing pH in the tailings, and thus also REE solubility. However, weathering of sulfides is no source for REE in itself since the elements are not bound in sulfides, which the oxidized availability test NT ENVIR 006 showed. Instead REE are released into solution by weathering of easily weathered silicates. Usually, metal bound in silicate form is not considered geochemically active. A kinetic (time dependent) factor, associated with the weathering of silicates, was found to affect pH and thus also metal solubility in leaching tests performed on the tailings. The standardized pH static leaching test (SIS-CEN/TS 14997) showed limitations in observing kinetic effects because of its relatively short equilibration time (48 h). Thus, in future studies with similar materials, leaching test kinetics should be taken into account when comparing leached concentrations with field measured concentrations. Acid titration and one step batch test (SIS-CEN ISO/TS 21268-2:2010) proved to be applicable and relatively well applicable to the tailings, respectively, in order to estimate soil solution concentrations. Speciation calculations using Visual MINTEQ ver. 3.0 showed that pH and DOC concentration are the most important factors which affect REE speciation in soil solution, ground water and surface water associated with the tailings. In acid sulfate rich solutions, low in DOC, speciation is dominated by sulfate complexes, mainly (REE)SO4+, followed by free dissolved ions as the second most common form. These results are in accordance with previous modeling studies of REE speciation in acid sulfate rich waters resulting from tailings. This, together with previous results showing that REE ecotoxicity seems to follow the free ion model, implies that the toxicity of the elements is expected to increase with decreasing pH value.