A produção de álcool combustível vem aumentando a cada ano devido à necessidade de substituir as fontes de combustíveis fósseis, que é finita, e por outro lado o álcool que é uma fonte de energia renovável. Porém, a produção deste combustível gera uma grande quantidade de resíduos, sendo a vinhaça o que chama mais atenção, pelo seu alto valor como fertilizante e, principalmente, pela quantidade expressiva de potássio. O íon potássio, por se tratar de um cátion monovalente tem a característica de promover a dispersão das partículas de argila, assim como o sódio, provocando um entupimento dos poros do solo e diminuindo a sua permeabilidade, o que pode resultar em encharcamento e aumentar o escoamento superficial. Para avaliar este efeito dispersivo da aplicação de vinhaça no solo foram implementados dois experimentos: O Experimento I teve o objetivo de avaliar o efeito de diferentes doses de vinhaça na condutividade hidráulica do solo saturado e o Experimento II avaliou diferentes doses de aplicação de vinhaça no escoamento superficial. No Experimento I foram utilizadas colunas de PVC preenchidas com 3 tipos de solos (Latossolo Vermelho-Escuro LVE, Latossolo Roxo LR e Nitossolo Vermelho Eutrófico NVE), nas quais foram aplicadas quatro doses de vinhaça (0, 150, 300 e 450 m3 ha-1), em um delineamento inteiramente casualizado em esquema fatorial 3x4 com três repetições. Neste experimento, utilizou-se um permeâmetro de carga constante para obtenção da condutividade hidráulica do solo saturado. No segundo experimento, montou-se uma estrutura na área pertencente ao Departamento de Engenharia Rural (ESALQ/USP) para avaliação de escoamento superficial em um Nitossolo Vermelho Eutrófico. O delineamento experimental adotado neste experimento foi blocos ao acaso num esquema fatorial 3x3 com três blocos, sendo: 3 variedades de cana-de-açúcar (IAC87-3396, SP81-3250 e RB86-7515) e 3 doses de vinhaça (150, 300 e 450 m3 ha-1). Os parâmetros avaliados foram a perda de água e de solo, perda do potássio e de sólidos dissolvidos totais (SDT). Diante dos resultados obtidos, observou-se que no solo LVE com o aumento das doses de vinhaça diminuiu-se os valores de condutividade hidráulica do solo saturado e para os solos LR e NVE os valores deste parâmetro aumentaram com o acréscimo das doses. Em relação ao escoamento superficial não houve efeito significativo para os fatores em estudo, demonstrando que as doses não contribuíram para o aumento do escoamento superficial como se era suposto. / The production of alcohol used as fuel is increasing every year due to the need to replace the sources of fossil fuels, which is finite, and on the other hand alcohol is a renewable energy source. But the production of this fuel generates large quantities of waste and the vinasse draws most attention by its high value as fertilizer, primarily by the amount of potassium. The potassium ion due to a monovalent feature is to promote the dispersion of the clay particles as well as sodium, clogged the pores of the soil by decreasing the permeability, may cause flooding and increase runoff. For evaluating the dispersive effect of vinasse on the soil were implemented two experiments: Experiment I aimed to evaluate the effect of different doses of vinasse in saturated hydraulic conductivity, and Experiment II, which evaluated different doses of vinasse in runoff. In Experiment I were used PVC columns filled with 3 kinds of soils (Dark Red Latosol - LVE, Dusky Red Latosol- LR and Rhodic Kandiustalf - NVE), and applied four doses of vinasse (0, 150, 300 and 450 m3 ha -1), in a completely randomized design in a 3x4 factorial design with three replications. In this experiment we used a constant load permeameter to obtain the hydraulic conductivity of saturated soil. In the second experiment was mounted in a structure belonging to the Department of Rural Engineering (ESALQ / USP) for evaluation of runoff in a Rhodic Kandiustalf. The experimental design used in this experiment was a randomized block design in a 3x3 factorial with three blocks, and these factors were: 3 varieties of sugarcane (IAC87-3396, SP81-3250 and RB86-7515) and 3 doses of vinasse (150 , 300 and 450 m3 ha-1). The parameteres evaluated were the loss of water and soil, loss of potassium and total dissolved solids (TDS). Results obtained showed that the soil LVE with increasing doses of vinasse also decreased the values of hydraulic conductivity, and for the LR soil and NVE values of this parameter increased with increased doses. In the runoff no significant effect on the factors under study, showing that the doses did not contribute to the increase in runoff as was supposed.

Aggregate stability and aggregate size distribution on soil surface that is impacted by rain drops affect soil erosion yet little is known about less weathered coarse textured soils. The objectives of the current study were to determine (i) the aggregate stability and associated aggregate fraction size distribution and (ii) the impact of the initial aggregate size on the aggregate stability and the resulting sediment fraction size distribution following rain drop impact in some quartz dominated coarse textured soils in the Eastern Cape Province. Soil samples for this experiment were collected from 14 ecotopes on the surface with a natural slope between 7.5 to 11% and at the depth between 0 to 0.2 m in the Eastern Cape Province. In each ecotope, twenty-five different spots were sampled using a spade at depth 0 to 0.2 m in other to eradicate biasness and ensure homogeneity. Thereafter, the soil samples were mixed to make a composite sample. The composited soil samples were then placed in rigid containers and taken to the soil science laboratory of the University of Fort Hare, Alice Campus where analyses were carried out. The soil properties were determined by passing the < 5 mm soil sample through a 2 mm sieve. The total Na, Ca and Mg contents in the soil samples were also determined using the wet digestion with sulphuric acid method. The total Soil organic matter content (SOM) was determined by the process known as weight loss on ignition. Thereafter, the fraction size distribution and aggregate stability was done by passing < 5 mm soil samples through a 3 mm sieve. The obtained calibrated aggregates between 3 and 5 mm were oven dried at 40o C. Thereafter, five gram (5g) of oven dried calibrated aggregates was immersed in a 50 mL deionized water in a 250 mL beaker for 10 minutes. The soil material left was transferred to a 0.053 mm sieve already immersed in ethanol and moved five times in the ethanol to separate < 0.053 mm from > 0.053 mm fragments. The remaining > 0.053 mm was re-immersed in ethanol and further oven dried at 40o C for 5 minutes. Thereafter, the > 0.053 mm fraction was transferred from 0.053 mm sieve, oven dried at 40o C, dry sieved using Digital Electromagnetic Shaker on a six column of sieves: 2 mm, 1 mm, 0.5 mm, 0.25 mm, 0.106 mm, and 0.053 mm. The aggregate stability was determined using the resulting size distribution in seven classes by calculating the mean weight diameter (MWD, mm). The soils were very stable, moderately stable or unstable. The presence of smectite and cultivation as opposed to pasture lowered aggregate stability. The studied soils showed three different aggregate size distributions. Unstable soils were dominated by 0.106 – 0.25 mm aggregate size and showed a positively skewed aggregate fraction size distribution. Aggregates finer than 0.106 mm were limited because of the coarse nature of the soil texture. Moderately stable soils broke down to both micro aggregates, 0.106 – 0.25 mm and macro aggregates, 2 – 5 mm giving a bimodal distribution. The aggregate size distribution in the very stable soils was dominated by the aggregate fraction size 2 – 5 mm and a negatively skewed aggregate fraction size distribution. The smaller the initial aggregate size the higher was the aggregate stability but the reverse was true for splash erosion. It was thought that the short 5 minutes duration of the rainfall might not have been enough to cause a total breakdown of the aggregates. Alternatively, ecotopes that were dominated by primary soil minerals such as quartz showed different breakdown behaviour compared to those containing secondary minerals such as kaolinite or smectite.

In southeastern Florida, the majority of drinking water comes from the Biscayne aquifer. This aquifer is comprised of heterogeneous limestones, sandstones, sand, shell and clayey sand with zones of very high permeability. Visualizing the spatial variations in lithology, porosity and permeability of heterogeneous aquifers, like the Biscayne, can be difficult using traditional methods of investigation. Using the Roxar IRAP RMS software multi-layered 3D conceptual geomodels of the lithology, cyclostratigraphy and porosity were created in a portion of the Biscayne aquifer. The models were built using published data from borehole geophysical measurements, core samples, and thin sections. Spatial relations between lithology, cyclostratigraphy, porosity, and preferential flow zones were compared and contrasted to better understand how these geologic features were inter-related. The models show local areas of differing porosity within and cross-cutting different cycles and lithologies. Porosity in the Biscayne aquifer study area follows a hierarchy attributed to lithofacies with a pattern of increasing porosity for the high frequency cycles. This modeling improves understanding of the distribution and interconnectedness of preferential flow zones, and is thus an invaluable tool for future studies of groundwater flow and groundwater contamination in the Biscayne aquifer. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection

[Truncated abstract] Self-filtration is here defined as particle detachment and re-deposition causing re-arrangement of the particles and therefore pore space which affects water flow in soil by decreasing hydraulic conductivity. This is of particular important in soils which are susceptible to structural breakdown. The objective of this thesis was to examine the dynamics of the self-filtration process in sodic sandy soils as affected by ionic strength and soil solution composition. The temporal changes of hydraulic conductivity and the elution of fine particles from soil columns were used as the main criteria to assess selffiltration. Two porous media exhibiting significantly different structural cohesion were examined, one a loamy sand (Balkuling soil) from agricultural land use and the second a mining residue from mineral sands operations . . . The effects of the composition of mixed calcium (Ca) and sodium (Na) ions in solution (sodium adsorption ratio (SAR)) on the exchange behaviour and saturated hydraulic conductivity were examined by carrying out batch binary exchange and saturated column transport experiments. A strong preference for Ca2+ ions in the exchange complex was observed for both soils. Generally K/Ko was found to decrease with increasing sodium adsorption ratio with the more structured Balkuling soil maintaining K/Ko for SARs 3 and 5 at an electrolyte concentration of 100 mmol/L. However measurements at the critical threshold and turbidity concentrations at a SAR of 15 revealed structural breakdown of the pore matrix system attributed to various extents of slaking, swelling, dispersion and decreases of pore radii as a result of selffiltration during leaching. These experiments illustrate the wide range of complex interactions involving clay mineralogy, solution composition and structural factors which can influence the extent of mobilization, transport and re-deposition of colloidal particles during the leaching process in soil profiles.

This project attempted to combine digital data sets to define and map geologic features in the Sparta and Montpelier quadrangles of Chickasaw and Clay counties in northeastern Mississippi. LANDSAT TM, digital elevation, and soil permeability data was used in conjunction with reference data for the Sparta quadrangle to build a computer model. Variables used in the model were: geology, slope, soil permeability, vegetation indices, the first three bands of a tasseled cap transformation, and drainage frequency. The data used was LANDSAT TM 30 meter imagery, digital elevation models, also at 30 meter resolution, Penn State STASGO soils data, and the existing map of the Sparta quadrangle. The purpose of this project was to use digital data to remotely map geologic features through heavy vegetation using a computer model. While the results of this project were not completely successful, the methods used show some potential for future application.

The current interest in conservation agriculture (CA) technologies is a result of the need to reduce excessive land degradation in most crop producing areas as well as to enhance sustainable food production. Cover crops that are usually grown under CA to provide soil cover, may offer secondary benefits, depending on the farming system. The concept of growing cover crops is a relatively new phenomenon to smallholder farmers. Production of large biomass yields and weed suppression from cover crops were major challenges affecting success and uptake of CA technologies by smallholder irrigation farmers. Coupled with this, low soil fertility limit maize productivity and reduce water use efficiency on smallholder irrigation schemes in what is largely a water strained agro-ecology in South Africa. While cover cropping can increase maize productivity, benefits of different types of mulch are not well understood, leading to challenges in selecting the most appropriate cover crop species to grow in the Eastern Cape Province (EC) of South Africa (SA) which has a warm temperate climate. With respect to any new technology, smallholder farmers are more interested in the economic benefits. Cover crops have been defined as leguminous or non-leguminous plants used for ground cover in various temporal and special configurations used in crop or animal production systems. The purpose of these cover crops is to improve on or more of the following: soil erosion, availability and cycling of N, P, K, Ca and other nutrients, soil moisture and water infiltration, and weed or pest control (Eilitta et al., 2004).. Improvement of animal or human diet may be additional goals. This definition accommodates diverse systems which may include intercrop and sole-cropping systems. In the Eastern Cape Province of South Africa, a government initiative has promoted the growing of winter cover crops in smallholder irrigation schemes (Allwood, 2006). In other parts of Africa, legume food crops have been simultaneously grown with cereal staples to improve both soil cover and human diet (Eilitta et al., 2004). Winter experiments were undertaken in 2007 and 2008 to evaluate biomass accumulation, C and N uptake, weed suppression and response to fertilization. Winter cover crops planted included; oats (Avena sativa), grazing vetch (Vicia dasycarpa), faba bean (Vicia faba), forage peas (Pisum sativum) and lupin (Lupinus angustifolius). After cover crops were terminated, the effects of residues on weeds, fertility, moisture conservation and maize productivity were undertaken in the 2007/08 and 2008/09 summer seasons. Field studies were also done in the 2007/08 and 2008/09 summer seasons to investigate effects of strip intercropping patterns (3:2; 4:2; and 6:2 patterns) of maize (cv. PAN 6479) with mucuna (Mucuna pruriens) or sunnhemp (Crotalaria juncea) on maize productivity and summer cover crop biomass production. In a separate experiment effects of relay intercropping sunnhemp, mucuna and sorghum (Sorghum bicolor) on biomass accumulation and maize productivity were investigated. Decomposition, N and P release from both winter cover crops and summer cover crops were also assessed in laboratory incubation experiments. Oats, grazing vetch and forage peas cover crops produced mean dry mass of 13873 kg/ha, 8945.5 kg/ha and 11073 kg/ha, respectively, while lupin had the lowest dry mass of 1226 kg/ha over the two seasons. Oats responded to fertilization while, there was little or no response from the other winter cover crops. Oats and grazing vetch also reduced weed density by 90 % and 80 % respectively while lupin only reduced weed density by 23 % in relation to the control plots. Nitrogen uptake was 254 kg N/ha for oats while it was 346 kg N /ha for grazing vetch. In the subsequent summer season, grazing vetch and forage pea residues significantly (P < 0.01) improved soil inorganic N. Oat and grazing vetch residues significantly (P < 0.05) reduced weed dry masss and weed species diversity compared to plots with lupin residues and the control. Lack of maize fertilization tended to reduce maize yields but not for maize grown on grazing vetch residues. From an economic perspective, grazing vetch resulted in the highest returns. Decomposition of winter cover crops was much faster for grazing vetch followed by forage peas and lastly oats. Oats had 40 % ash free dry mass remaining after 124 days while grazing vetch and forage peas had 7 % and 16 % respectively. Maximum net mineralized N and P were greater for grazing vetch (84.8 mg N/kg; 3.6 mg P/kg) compared to forage peas (66.3 mg N/kg; 2.7 mg P/ha) and oats (13.7 mg N/kg; 2.8 mg P/kg). In the strip intercropping trials, sunnhemp achieved the highest biomass yield of 4576 kg/ha in the 3:2 pattern while mucuna achieved 1897 kg/ha for the same strip pattern. The 3:2 strip intercropping pattern slightly depressed yields, however, yield reduction was more pronounced in the first season where water stress was experienced. Growing maize on previous cover crop strips failed to increase maize productivity probably due to weed growth during the fallow reducing mineral N in these strips. Decomposition was faster in sunnhemp leaves and mucuna compared to sunnhemp stems. Sunnhemp stems had about 65 % of ash free dry mass remaining after the end of the experiment at 132 days while just over 10 % of mucuna and sunnhemp leaves still remained. Mucuna mineralized 60 mg N/kg and 3.2 mg P/kg and sunnhemp mineralized 45 mg N/kg and 3.5 mg P/kg. Relay intercropping did not significantly (P > 0.05) affect maize biomass and grain yield. Sorghum experienced the largest drop in biomass when relay-intercropped with maize. Mucuna resulted in the highest N uptake (271 kg N/ha) in sole cropping while sorghum had the lowest (88 kg N/ha). Grazing vetch results in high biomass yields with minimal fertilizer application in a warm-temperate climate. Grazing vetch mulch is also the most cost effective mulch for better early weed control, improving soil mineral N status, water conservation and ultimately enhanced maize productivity in smallholder irrigation maize-based systems. The 3:2 pattern maximizes summer cover crop biomass yields compared to the 6:2 and 4:2 patterns. However, the 3:2 pattern may slightly depress yields in a water stressed environment. Relay intercropping mucuna, sunnhemp and sorghum into a maize crop at 42 days after maize sowing has no effect on maize productivity while cover crop biomass yields are low. Having a long winter fallow period after maize harvesting, a common practice in the study area, reduces the positive impact of legume cover crops on soil mineral N. Results suggest that winter cover crops may result in weed control, soil fertility and maize yield improvement benefits while a long fallow period may cancel-out these benefits for summer cover crops. Grazing vetch is a cost effective cover crop that produces high maize yields with minimal fertilizer input. Maize growing on oat mulch requires more fertilizer application than crops growing on grazing vetch mulch. Conservation agriculture systems in which summer cover crops are grown alongside the maize crop with a long winter fallow period do not produce the intended CA benefits.