Stellar atmospheres constitute excellent environments to study the chemical evolution of our Galaxy. The chemical composition of these atmospheres reflects the composition of the gas from where these stars were born. As the Galaxy evolves, the composition of the gas changes from being primordial (Big-Bang nucleosynthesis) to being enriched in heavy elements (stellar and interstellar nucleosynthesis). The abundances of fragile chemical elements can be affected by stellar mixing processes. Precise lithium, beryllium and oxygen abundance determinations in old stars are presented in this thesis. These determinations are based on the analysis of the observed spectra of a sample of thirteen metal-poor subgiant stars. According to stellar mixing theories, these stars are in a stellar evolutionary stage in which mixing by convection is expected. Abundances of fragile elements like lithium and beryllium are thus expected to be affected by such mixing processes. As a consequence of this, the abundances of these elements are discussed in a dilution context. Lithium and beryllium abundances are compared with the abundances of stars with similar characteristics but in a less evolved stellar phase so that mixing processes have not acted yet. As expected, our abundances seem to be depleted following reasonably well the standard predictions. Stellar abundances of oxygen should give an estimate of the oxygen contribution of core-collapse supernovae to the interstellar medium. However, there is poor agreement among the abundances determined from different atomic or molecular indicators in general. Abundances coming from three different indicators are compared in this thesis. The abundances determined from the O I infrared triplet lines at 777.1-5 nm give the poorest agreement among the three indicators. The abundances based on OH ultraviolet lines around 310 nm are lower for the subgiants in comparison with previous studies of main-sequence stars, becoming even lower than values based on the O I forbidden line at 630.03 nm. Still the most reliable indicator appears to be the O I forbidden line which suggests a plateau-like or only slowly increasing [O/Fe] towards lower [Fe/H]. In addition, the line formation of the Be II ultraviolet resonance lines at 313.0-1 nm, commonly used for abundance determinations purposes, is investigated under non-local thermodynamic equilibrium. We find that the common assumption of local thermodynamic equilibrium typically gives systematic errors of about 0.1 dex.

The information about the chemical compositions of stars is encoded in their spectra. Accurate determinations of these compositions are crucial for our understanding of stellar nucleosynthesis and Galactic chemical evolution. The determination of elemental abundances in stars requires models for the stellar atmospheres and the processes of line formation. Nearly all spectroscopic analyses of late-type stars carried out today are based on one-dimensional (1D), hydrostatic model atmospheres and on the assumption of local thermodynamic equilibrium (LTE). This approach can lead to large systematic errors in the predicted stellar atmospheric structures and line-strengths, and, hence, in the derived stellar abundances. In this thesis, examples of departures from LTE and from hydrostatic equilibrium are explored. The effects of background line opacities (line-blocking) due to atomic lines on the statistical equilibrium of Fe are investigated in late-type stars. Accounting for this line opacity is important at solar metallicity, where line-blocking significantly reduces the rates of radiatively induced ionizations of Fe. On the contrary, the effects of line-blocking in metal-poor stars are insignificant. In metal-poor stars, the dominant uncertainty in the statistical equilibrium of Fe is the treatment of inelastic H+Fe collisions. Substantial departures of Fe abundances from LTE are found at low metallicities: about 0.3 dex with efficient H+Fe collisions and about 0.5 dex without. The impact of three-dimensional (3D) hydrodynamical model atmospheres on line formation in red giant stars is also investigated. Inhomogeneities and correlated velocity fields in 3D models and differences between the mean 3D stratifications and corresponding 1D model atmospheres can significantly affect the predicted line strengths and derived abundances, in particular at very low metallicities. In LTE, the differences between 3D and 1D abundances of C, N, and O derived from CH, NH, and OH weak low-excitation lines are in the range -0.5 dex to -1.0 dex at [Fe/H]=-3. Large negative corrections (about -0.8 dex) are also found in LTE for weak low-excitation neutral Fe lines. We also investigate the impact of 3D hydrodynamical model stellar atmospheres on the determination of elemental abundances in the carbon-rich, hyper iron-poor stars HE 0107-5240 and HE 1327-2326. The lower temperatures of the line-forming regions of the 3D models compared with 1D models cause changes in the predicted spectral line strengths. In particular we find the 3D abundances of C, N, and O to be lower by about -0.8 dex (or more) than estimated from a 1D analysis. The 3D abundance of Fe is decreased but only by -0.2 dex. Departures from LTE for Fe might actually be very large for these stars and dominate over the effects due to granulation.

I developed a spectrum synthesis method to investigate the physical properties of hot OB main sequence (MS) stars, which are often rapid rotators. The code realistically simulates the surface conditions of rapidly rotating stars, considering the rotationally-deformed stellar shape and gravity darkening effect. Comparing the synthesized absorption line profiles with the observed spectra of the member stars of 19 young Galactic clusters, I determined the projected rotational velocities of 496 stars. The average surface temperature and gravity for most of these objects were then derived from H$\gamma$ line fits. The polar gravity of each star was estimated as a good indicator of the evolutionary status of the star. The derived parameters show that massive rotators spin down during their MS phase. The He abundance data (measured by fitting the He I lines) also favor the theoretical prediction that rotationally-induced mixing can gradually enrich the surface helium abundance through the MS phase. A quicker spin-down is evident in the lower mass star group where a large portion of helium peculiar stars are found. This correlation implies that strong stellar magnetic fields may exist on the surface of these lower mass stars. The same method is also applied to interferometric observations from the CHARA Array of a nearby rapid rotator, Regulus. By combining results from spectroscopic and interferometric analysis, the shape, space orientation, mass, and surface temperature distribution of Regulus are firmly determined. This analysis provides the first evidence of the gravity darkening phenomenon among stars that are not components of an eclipsing binary system. The surprisingly high luminosity determined for Regulus appears to agree with the theoretical prediction that rapid rotator can become more luminous as rotationally-induced mixing brings fresh hydrogen down to the core. Finally I present an extension of the model that simulates the shape, velocity, and temperature variations of a star experiencing nonradial pulsation. I simulated and analyzed the line profile variations in the spectra of $\epsilon$ Per, a B0.7~III star with strong evidence of nonradial pulsation (NRP). A comparison of the model simulations and observations indicates that the pulsations of $\epsilon$ Per have a corresponding local temperature variation that is out of phase with the radial oscillation (a non-adiabatic phase lag).

<p>Ispitivana je zavisnost brzine fronta udarnih talasa u T-cevi od vi&scaron;e parametara. Izvr&scaron;eno je povezivanje ICCD kamere sa spektrometrom. Ispitane su karakteristike celokupnog sistema i izvr&scaron;ena je njegova optimizacija i kalibracija. Izmerene su &Scaron;tarkove polu&scaron;irine 45 spektralnih linija OII, 13 spektralnih linija Si II i 14 spektralnih linija Si III. Dobijene vrednosti su upoređene sa vrednostima koje se mogu naći u literature, kao i sa teorijskim vrednostima. Urađena je detaljna analiza rezultata iz ovog rada kao i svih dostupnih prethodno dobijenih eksperimentalnih podataka.</p> / <p>The dependence of shock front velocity on different parameters was examined. The ICCD camera was mounted on the spectrometer. The characteristics of the whole system were examined and the system was optimized and calibrated. The Stark halfwidths of 45 O II spectral lines, 13 Si II spectral lines and 14 Si III spectral lines were measured. The obtained values were compared with the data available in the literature, as well as with theoretical values. A detailed analysis of both the experimental results given in this dissertation and previously published experimental data was done.</p>

A radiation code based on method of lines (MOL) solution of discrete ordinates method (DOM) for the prediction of radiative heat transfer in nongray absorbing-emitting media was developed by incorporation of two different gas spectral radiative property models, namely wide band correlated-k (WBCK) and spectral line-based weighted sum of gray gases (SLW) models. Predictive accuracy and computational efficiency of the developed code were assessed by applying it to the predictions of source term distributions and net wall radiative heat fluxes in several one- and two-dimensional test problems including isothermal/non-isothermal and homogeneous/non-homogeneous media of water vapor, carbon dioxide or mixture of both, and benchmarking its steady-state predictions against line-by-line (LBL) solutions and measurements available in the literature. In order to demonstrate the improvements brought about by these two spectral models over and above the ones obtained by gray gas approximation, predictions obtained by these spectral models were also compared with those of gray gas model. Comparisons reveal that MOL solution of DOM with SLW model produces the most accurate results for radiative heat fluxes and source terms at the expense of computation time when compared with MOL solution of DOM with WBCK and gray gas models. In an attempt to gain an insight into the conditions under which the source term predictions obtained with gray gas model produce acceptable accuracy for engineering applications when compared with those of gas spectral radiative property models, a parametric study was also performed. Comparisons reveal reasonable agreement for problems containing low concentration of absorbing-emitting media at low temperatures. Overall evaluation of the performance of the radiation code developed in this study points out that it provides accurate solutions with SLW model and can be used with confidence in conjunction with computational fluid dynamics (CFD) codes based on the same approach.

High-resolution molecular spectroscopy has been used to study acetylene line parameters and emission spectra of hydrogen cyanide. All acetylene spectra were recorded in our laboratory at the University of Lethbridge using a 3-channel tuneable diode laser spectrometer. N2-broadened line widths and N2-pressure induced line shifts have been measured for transitions in the v1+v3 band of acetylene at seven temperatures in the range 213–333K to obtain the temperature dependences of broadening and shift coefficients. The Voigt and hard-collision line profile models were used to retrieve the line parameters. The line-broadening and line-shift coefficients as well as their temperature-dependent parameters have been also evaluated theoretically, in the frame work of a semi-classical approach based on an exponential representation of the scattering operator, an intermolecular potential composed of electrostatic quadrupole–quadrupole and pairwise atom–atom interactions as well as on exact trajectories driven by an effective isotropic potential. The experimental results for both N2-broadening and shifting show good agreement with the theoretical results. We have studied the line intensities of the 1νl20←0νl20 band system from the HCN emission spectrum. The infrared emission spectrum of H12C14N was measured at the Justus-Liebig University, Giessen, Germany. The emission spectrum was analyzed with the spectrum analysis software Symath running using Mathematica as a platform. This approach allowed us to retrieve information on band intensity parameters. / viii, 112 leaves : ill. ; 29 cm

Les protoétoiles de masse intermédiaire (IM) (2 ≤ M* ≤ 8 Msun) sont le lien entre les étoiles de faible et haute masse car elles couvrent également un intervalle intermédiaire de luminosités, de densités et de températures [Fuente et al., 2012]. Même si les « IM-YSOs » jouent un rôle important dans l'étude de la formation des étoiles, on a très peu de connaissances sur la formation et l'évolution des premières étapes des protoétoiles de masse intermédiaire. Les études systématiques spectrales sont un outil puissant pour caractériser la composition chimique d'un objet astrophysique, et la seule façon d'obtenir un recensement complet des espèces chimiques. Une étude spectrale fournit également des lignes multiples de la même molécule, donnant la possibilité d'une analyse multifréquences ainsi que d'une modélisation. En outre, grâce aux profils des raies, nous pouvons obtenir des informations sur la cinématique, et identifier les structures au long de la ligne de vue, en tant que sources multiples, des jets ou des cavités, par exemple, [Caux et al., 2011]. Les phénomènes d'éjection (jets, des vents et des « outflows » bipolaires moléculaires), sont une phase inhérente au processus de formation d'étoiles observées dans les YSOs de toutes masses dans des longueurs d'onde millimétriques. Cependant, il n'y a pas d'études systématiques dans l'intervalle de masse intermédiaire comme dans le cas des protoétoiles de faible et haute masse. Compte tenu de l'absence d'une étude systématique de la partie mm/submillimétrique dans le spectre des protoétoiles de masse intermédiaire, au cours de ma thèse, j'ai mené une étude systématique spectrale vers la protoétoile de masse intermédiaire de classe 0 Cep E et de son « outflow » moléculaire. / Intermediate-mass (IM) protostars (2 ≤ M∗ ≤8 Msun) are the link between low and the high mass stars as they cover also an intermediate range of luminosities, densities and temperatures [Fuente et al., 2012]. Even though the IM-YSOs are important in the study of star formation, very little is known about the formation and first evolutionary stages of IM protostars. Unbiased spectral surveys are a powerful tool to characterize the chemical composition of an astrophysical object, and the only way to obtain a complete census of the chemical species. A spectral survey provides also multiple lines from the same molecule, giving the possibility of a multi-frequency analysis and modeling. Also, through line profiles, we can obtain kinematic information, and identify structures along the line of sight, as multiple sources, outflows, jets or cavities, e.g. [Caux et al., 2011]. The outflow phenomena (jets, winds and bipolar molecular outflows), are an inherent phase in the process of star formation observed in YSOs of all range of masses at millimeter wavelengths. However, there are not systematic studies in IM range as in the case of of low- and high-mass protostars. Given the lack of a systematic study of the mm/submm spectrum of IM protostars, during my thesis I carried out an unbiased spectral survey towards IM Class 0 Cep E protostar and its molecular outflow.