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Computer-aided studies on luminescence spectroscopy in pharmaceutical analysisClark, Brian John January 1985 (has links)
No description available.
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Thin-Film Polymer Nanocomposites Composed of Two-Dimensional Plasmonic Nanoparticles and GrapheneKhan, Assad Ullah 26 July 2019 (has links)
Plasmonic polymer nanocomposites contain plasmonic nanoparticles that are dispersed within a polymer. The polymer matrix strongly influences the optical properties of plasmonic nanoparticles. It is imperative to understand the interaction between plasmonic nanoparticles and polymers so that one can develop functional devices using nanocomposites. The utilization of plasmonic nanoparticles as fillers has great potential to transform critical nanotechnologies where light management is crucial, such as refractive index based nanosensors, optical coatings, and light actuated devices. Despite the great potential, effective integration of plasmonic nanoparticles with polymers remains challenging. This dissertation presents i) the effects of dielectric media on the optical properties of plasmonic nanoparticles, ii) the sensing of polymer brush formation on nanoparticles, iii) the fabrication of plasmonic nanocomposite thin-films with controlled optical properties, and iv) the development of electrically conductive membranes for electrostatic speakers.
The optical response of plasmonic nanoparticles (referred to as wavelength of localized surface plasmon resonance, λLSPR) is sensitive to changes in refractive index of the medium. The sensitivity (S) plays a critical role in determining the performance of nanoparticles in sensing applications. In this dissertation, I have conducted a systematic study on the sensitivity of plasmonic nanoparticles as a function of various parameters: shape, size, composition, initial plasmonic resonance wavelength, cross-sectional area, and aspect ratio. Among the parameters investigated, aspect ratio (R) is determined to be the key parameter that controls S, following an empirical equation, S = 46.87 R + 109.37. This relationship provides a guideline for selecting fillers in plasmonic polymer nanocomposites, and it predicts the final effect of plasmonic nanoparticles on the optical properties of polymer nanocomposites.
Plasmonic nanoparticles are employed to probe polymer grafting on the surfaces of metal nanoparticles. Using ultraviolet-visible (UV-vis) spectroscopy, I have demonstrated the quantification of polymer grafting density on the surface of plasmonic nanoparticles. The λLSPR of plasmonic nanoparticles red-shifts as the polymer concentration near the nanoparticle surface increases. I have investigated the formation of polymer brush by grafting the nanoparticles with thiolated polyethylene glycol (PEG-SH) and revealed the three–regime kinetics in situ. Importantly, this study suggests that a latent regime arises due to fast polymer adsorption and prolonged chain rearrangement on nanoparticle surfaces. When the polymer chains rearrange and chemically tether to the surface, they contract and allow more polymer chains to graft onto the particle surface until saturation. This analytical method provides a new surface probing technique for polymer brush analysis, complementary to conventional methods such as quartz crystal microbalance, atomic force microscope, and microcantilivers.
Commercial tinted glass employs expensive metalized films to reduce light transmittance but has limited spectral selectivity. To reduce the cost of metalized films and to improve the spectral selectivity, I have employed plasmonic nanoparticles in polymers to fabricate spectral-selective tinted films. First, I have synthesized two-dimensional (2D) plasmonic silver nanoparticles (AgNPs) using multi-step growth. The nanoparticles have a tunable plasmon resonance and provide spectral selectivity. The multi-step growth forgoes polymeric ligands such as poly(vinylpyrrolidone) (PVP) and solely relies on a small molecule sodium citrate. Briefly, small citrate-capped Ag seeds are first grown into small 2D AgNPs. The small 2D AgNPs are then used to grow large 2D AgNPs via multiple growth steps. The PVP-free method allows for fast synthesis of 2D AgNPs with large sizes and tunable plasmon resonance across the visible and NIR region. The 2D AgNPs are integrated with polymers to produce thin-film plasmonic nanocomposites. By controlling the planar orientation of the 2D AgNPs through layer-by-layer assembly, the polymer nancomposites have achieved reduced light transmittance and enhanced reflectance across the visible and NIR range. In contrast to conventional polymer nanocomposites where the AgNPs are randomly oriented, the thin-film polymer nanocomposites exhibit excellent control over nanoparticle density and hence the optical properties, that is, tunable light transmittance and reflectance across the visible and NIR.
Lastly, graphene is used to prepare conductive free-standing polymer thin-films. Graphene, an ultralight weight 2D material with excellent electrical and mechanical properties, has potential for use in thin-film composites essential for photovoltaics, electrostatic speakers, sensors, and touch displays. Current graphene-based composite films contain graphene flakes randomly mixed in a polymer matrix and usually possess poor mechanical and electrical properties. In this dissertation, I have developed thin-film nanocomposites comprised of chemical vapor deposited (CVD) graphene and high-performance polyetherimide (PI). The CVD-grown graphene is polycrystalline, and it cannot be used as a free-standing film. By enforcing the polycrystalline graphene with a thin layer of PI, I have prepared free-standing thin-film composites with a high aspect ratio of 105. Mechanical and electrical property characterization reveals a Young's modulus of 3.33 GPa and a resistance of 200 - 500 Ω across the membrane. A typical spring constant of the membrane is ~387 N/m. Dynamic electromechanical actuation shows that the membrane vibrates at various input frequencies. The polymer/graphene film has excellent acoustic properties, and when used as a speaker membrane, it reduces the electrical power consumption by a factor of 10-100 over the frequency range of 600–10,000 Hz. / Doctor of Philosophy / Nanomaterials such as plasmonic nanoparticles and graphene have optical, electrical, and mechanical properties that are important for light filters, sensors, printing, photovoltaics, touch screens, speakers, and biomedical devices. To fully employ the nanomaterials, a support such as polymer is often required. However, when the nanomaterials and polymers are combined, their optical, electrical, and mechanical properties drastically change. Therefore, it is imperative to understand the interactions between nanomaterials and polymers, as well as the resulting properties. Towards this goal, I have studied the sensitivity of plasmonic nanoparticles in a dielectric media and then utilized the sensitivity to investigate polymer brush formation on nanoparticle surfaces. In addition, I have investigated the integration of plasmonic nanoparticles and graphene with polymers to develop thin-film nanocomposites for window coatings and audio speakers, respectively.
Plasmonic nanoparticles can detect trace amounts of chemicals, biomolecules, toxics, warfare agents, and environmental pollutants. Sensitivity is the key criterion that determines the performance of nanoparticles for such applications. Firstly, I have conducted a detailed and comprehensive study of the plasmonic sensitivity as a function of various nanoparticle parameters including shape, size, composition, cross-sectional area, initial plasmonic resonance wavelength, and aspect ratio. I have found that the sensitivity scaled linearly with aspect ratio. The strong dependence of sensitivity on aspect ratio provides insight into designing effective plasmonic sensors. Based on the sensitivity study, I have used plasmonic nanoparticles as sensors to probe and understand the mechanism of polymer brush formation in situ. When the concentration of polymer increases on the nanoparticle surfaces, the optical response of the nanoparticle changes. Through functionalizing the plasmonic nanoparticles with polymers, I have confirmed the three different regimes of polymer brush formation.
Plasmonic nanoparticles resonating in the visible and near infrared have a great potential in designing polymer nanocomposites for window coatings. Among different exotic shapes, two-dimensional nanoplates are the most important as their optical properties can be easily tuned across a wide range of wavelengths. However, most of the current methods require polymers, long hours of reaction time, and multiple purification steps. I have developed a new multi-step strategy to synthesize Ag nanoplates which absorb in the range of 500–1660 nm. Utilizing the plasmonic nanoparticles, the spectral-selective plasmonic nanocomposites comprised of polymers and planarly oriented Ag nanoparticles of judiciously selected sizes and compositions were prepared. The plasmonic polymer nanocomposites spectral-selectively reflect, scatter, and filter light of any desired wavelength. The nanocomposites will impact on the tinted glass in modern energy-efficient buildings.
The outstanding electrical and mechanical properties of graphene have stirred a large volume of research in the last 15 years. Most graphene-based technologies focus on graphene at the nano or micro scale. To further the practicality of graphene in large devices like audio speakers, large areas and thin films are needed to reduce energy consumption. Graphene on its own cannot be used over large areas due to the inherent defects arising during the growth. Here I present results on combining suspended sheets of single layer graphene with a mechanically strong polymer thin film. The acoustic properties of speakers made of polymer/graphene thin films are similar to those of conventional electrodynamic speakers in modern cellphones. The energy consumption, however, reduces sharply by a factor of 10-100 for the polymer/graphene based speakers. This sharp decrease in energy is attributed to the lightweight, flexibility, and excellent electrical conductivity. Apart from speakers, the membrane designed here also has huge potential in other devices like touch panels, capacitive sensors, and photovoltaics.
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Spectrally selective AlXOY/Pt/AlXOY solar absorber coatings for high temprature solar-thermal applicationsNuru, Zebib Yenus January 2014 (has links)
Philosophiae Doctor - PhD / The limited supply of fossil hydrocarbon resources and the negative impact of CO2 emission on the global environment dictate the increasing usage of renewable energy sources. Concentrating solar power (CSP) systems are the most likely candidate for providing the majority of the renewable energy. For efficient photo-thermal conversion, these systems require spectrally selective solar absorber surfaces with high solar absorbance in the solar spectrum region and low thermal emittance in the infrared region. In this thesis, a spectrally selective AlxOy/Pt/AlxOy multilayer solar absorber was designed and deposited onto copper substrate using electron beam evaporation at room temperature. The employment of ellipsometric measurements and optical simulation was proposed as an effective method to optimize and deposit the multilayer solar absorber coatings. The optical constants measured using spectroscopic ellipsometry, showed that both AlxOy layers, which used in the coatings,
were dielectric in nature and the Pt layer was semi-transparent. The optimized multilayer coatings exhibited high solar absorptance ~ 0.94±0.01 and low thermal emittance ~ 0.06 ± 0.01 at 82oC.The structural and optical properties of the coatings were investigated. It was found that the stratification of the coatings consists of a semitransparent middle Pt layer sandwiched between two layers of AlxOy. The top and bottom AlxOy layers were nonstoichiometric with no crystalline phases present. The Pt layer is in the fcc crystalline phase with a broad size distribution and spheroidal shape in and between the rims of AlxOy. The surface roughness of the stack was found to be comparable to the inter-particle distance. To study the thermal stability of the multilayer solar absorber coatings, the samples were annealed at different temperatures for different duration in air. The results showed changes in morphology, structure, composition, and optical properties depend on both temperature and
duration of annealing. The XRD pattern showed that the intensity of Pt decreased with
increasing annealing temperature and therefore, disappeared at high temperature. With
increasing annealing temperature, an increase in the size of Pt particles was observed from SEM. The AlxOy/Pt/AlxOy multilayer solar absorber coatings deposited onto Cu substrate were found to be thermally stable up to 500oC in air for 2 h with good spectral selectivity of 0.951/0.09. At 600oC and 700oC, the spectral selectivity decreased to 0.92/0.10 and 0.846/0.11 respectively, which is attributed to the diffusion of Cu and formation of CuO and Cu2O phases. Long term thermal stability study showed that the coatings were thermally stable in air up to 450oC for 24 h. To elucidate the degradation mechanism beyond 500oC, HI-ERDA has been used to study depth-dependent atomic concentration profiles. These measurements revealed
outward diffusion of the copper substrate towards the surface and therefore, the decrease in the constituents of the coating. Hence, to prevent copper from diffusing towards the coatings, a thin Tantalum (Ta) layer was deposited between the base AlxOy layer and the copper substrate.The effect of a thin Ta layer on the thermal stability of AlxOy/Pt/AlxOy multilayer solar absorber coatings was investigated. The Cu/Ta/AlxOy/Pt/AlxOy multilayer solar absorber coatings were found to be thermally stable up to 700oC in air for 2 h with good spectral selectivity of 0.937/0.10. At 800oC, the spectral selectivity decreased to 0.870/0.12, which is attributed to the diffusion of Cu and formation of CuO phase. The formation of CuO phase was confirmed by XRD, EDS and Raman spectroscopy. Long term thermal stability study showed that the coatings were thermally stable in air up to 550oC for 24 h. Therefore, the Cu/Ta/AlxOy/Pt/AlxOy spectrally selective solar absorber coatings can be used for high
temperature solar-thermal applications.
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Novel 1-D and 2-D Carbon Nanostructures Based Absorbers for Photothermal ApplicationsSelvakumar, N January 2016 (has links) (PDF)
Solar thermal energy is emerging as an important source of renewable energy for meeting the ever-increasing energy requirements of the world. Solar selective coatings are known to enhance the efficiency of the photo thermal energy conversion. An ideal solar selective coating has zero reflectance in the solar spectrum region (i.e., 0.3-2.5 µm) and 100% reflectance in the infrared (IR) region (i.e. 2.5-50 µm). In this thesis, novel carbon nanotubes (CNT) and graphene based absorbers have been developed for photo thermal applications. Carbon nanotubes have good optical properties (i.e., α and ε close to 1), high aspect ratios (> 150), high surface area (470 m2/g) and high thermal conductivity (> 3000 W/mK), which enable rapid heat transfer from the CNTs to the substrates. Similarly, graphene also exhibits high transmittance (97%), low reflectance, high thermal conductivity (5000 W/mK) and high oxidation resistance behaviour. The major drawback of using CNTs for photothermal applications is that it exhibits poor spectral selectivity (i.e., α/ε = 1). In other words, it acts as a blackbody absorber. On the other hand, graphene exhibits poor intrinsic absorption behaviour (α - 2.3%) in a broad wavelength range (UV-Near IR).
The main objective of the present study is to develop CNT and graphene based absorbers for photothermal conversion applications. The growth of CNT and graphene was carried out using chemical vapour deposition and sputtering techniques. An absorber-reflector tandem concept was used to develop the CNT based tandem absorber (Ti/Al2O3/Co/CNT). The transition from blackbody absorber to solar selective absorber was achieved by varying the CNT thicknesses and by using a suitable underlying absorber (Ti/Al2O3). A simple multilayer heat mirror concept was used to develop the graphene based multilayer absorber (SiO2/graphene/Cu/graphene). The transition from high transmitance to high absorptance was achieved by varying the Cu thickness. The refractive indices and the extinction coefficients of Ti/Al2O3, AlTiO and graphene samples were determined by the phase-modulated spectroscopic ellipsometric technique. Finally, the optical properties (i.e., absorptance and the emittance) of the CNT and graphene based absorbers were investigated.
Chapter 1 gives a brief introduction about solar thermal energy, spectrally selective coating and photothermal conversion. The different types of absorbers used to achieve the spectral selectivity have also been discussed shortly. A brief description about the carbon-based materials/allotropes and their properties are outlined. The properties of carbon nanotubes and graphene which are the 1-D and 2-D allotropes of carbon, respectively are tabulated. A detailed literature survey was carried out in order to identify the potential candidates for the photothermal conversion applications. The objectives and the scope of the thesis are also discussed in this chapter.
Chapter 2 discusses the deposition and characterization techniques used for the growth and the study of 1-D and 2-D carbon nanostructures. Atmospheric pressure chemical vapour deposition (CVD) and hot filament CVD techniques were used to grow CNT and graphene, respectively. The magnetron sputtering technique was used for the growth of ‘Ti’, ‘Al2O3’ and Co layers which were needed to grow the CNT based tandem absorber on stainless steel (SS) substrates. The important characterization techniques used to examine various properties of the 1-D and 2-D carbon nanostructures include: X-ray diffraction, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), phase modulated ellipsometry, UV-VIS-NIR spectrophotometer, Fourier-infrared spectroscopy (FTIR), micro-Raman spectroscopy and solar spectrum reflectometer and emissometer.
Chapter 3 describes the design and development of Ti/Al2O3 coating for the growth of CNT-based tandem absorber on SS substrates. The power densities of the aluminum and titanium targets and the oxygen flow rates were optimized to deposit the Ti/Al2O3 coatings. The optimized Ti/Al2O3 coating with a Co catalyst on top was used as an underlying substrate to grow the CNT-based tandem absorber at 800°C in Ar+H2 atmosphere (i.e., CNT/Co/Al2O3/Ti/SS). The formation of aluminum titanium oxide (AlTiO) was observed during the CNT growth process and this layer enhances the optical properties of the CNT based tandem absorber. The optical constants of Ti, Al2O3 and AlTiO coatings were measured using phase modulated spectroscopic ellipsometry in the wavelength range of 300-900 nm. The experimentally measured ellipsometric parameters have been fitted with the simulated spectra using the Tauc-Lorentz model for generating the dispersion of the optical constants of the Al2O3 and the AlTiO layers. The Ti and Al2O3 layer thicknesses play a major role in the design of the CNT based tandem absorber with good optical properties.
Chapter 4 describes the synthesis and characterization of the CNT based tandem absorber (Ti/AlTiO/CoO/CNTs) deposited on SS substrates. CNTs at different thicknesses were grown on Ti/AlTiO/CoO coated SS substrates using atmospheric CVD at various growth durations. The transition from blackbody absorber to solar selective absorber was achieved by varying the thicknesses of the CNTs and by suitably designing the bottom tandem absorber. At thicknesses > 10 µm, the CNT forest acts as near-perfect blackbody absorber, whereas, at thicknesses ≤ 0.36 µm, the IR reflectance of the coating increases (i.e., ε = 0.20) with slight decrease in the absorptance (i.e., α = 0.95). A spectral selectivity (α/ε) of 4.75 has been achieved for the 0.36 µm-thick CNTs grown on SS/Ti/AlTiO/CoO tandem absorber.
Chapter 5 discusses the growth of graphene on polycrystalline copper (Cu) foils (1 cm × 1 cm) using hot filament CVD. The roles of the process parameters such as gas flow rates (methane and hydrogen), growth temperatures (filament and substrate) and durations on the growth of graphene were studied. The process parameters were also optimized to grow monolayer, bilayer and multilayer graphene in a controlled manner and the growth mechanism was deduced from the experimental results. The presence of graphene on Cu foils was confirmed using XPS, micro-Raman spectroscopy, FESEM and TEM techniques. The FESEM data clearly confirmed that graphene starts nucleating as hexagonal islands which later evolves into dendritic lobe shaped islands with an increase in the supersaturation. The TEM data substantiated further the growth of monolayer, bilayer and multilayer graphene. The intensity of 2D and G peak ratio (i.e., I2D/IG = 2) confirmed the presence of the monolayer graphene and the absence of the ‘D’ peak in the Raman spectrum indicated the high purity of graphene grown on Cu foils. The results show that the polycrystalline morphology of the copper foil has negligible effect on the growth of monolayer graphene.
In Chapter 6, the design and development of graphene/Cu/graphene multilayer absorber and the study of its optical properties are discussed. The multilayer graphene grown on Cu foils has been transferred on quartz and SiO2 substrates in order to fabricate the graphene/Cu/graphene multilayer absorber. The sputtering technique was used to deposit copper on top of graphene/quartz substrates. The uniformity of the transferred multilayer graphene films was confirmed using Raman mapping. A simple multilayer heat mirror concept was used to develop the graphene/Cu/graphene absorber on quartz substrates and the transition from high transmittance to high absorptance was achieved. In order to further enhance the absorption, the graphene/Cu/graphene multilayer coating was fabricated on SiO2 substrates. The thickness of the Cu layer plays a major role in creating destructive interference, which results in high absorptance and low emittance. A high specular absorptance of 0.91 and emittance of 0.22 was achieved for the SiO2 graphene/Cu/graphene multilayer absorber. The specular reflectance of the multilayer absorber coatings was measured using the universal reflectance accessory of the UV-VIS-NIR spectrophotometer.
Chapter 7 summarizes the major findings of the present investigation and also suggests future aspects for experimentation and analysis. The results obtained from the present work clearly indicate that both CNT and graphene based absorbers can be used as potential candidates for photothermal applications. In particular, the CNT based tandem absorber can be used for high temperature solar thermal applications and the graphene based multilayer absorber finds applications in the area of photodetectors and optical broadband modulators.
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Absorbeur solaire volumique haute température à propriétés optiques contrôlées / High Temperature Volumetric Solar Absorber with Controlled Optical PropertiesMey, Sébastien 09 May 2016 (has links)
La production d’électricité par voie solaire apparait comme la solution la plus prometteuse pour l’avenir, tant en termes de coûts que de pollution. Cependant, afin d’atteindre le niveau de technologie requis pour envisager l’implémentation de telles centrales à grande échelle, plusieurs verrous technologiques et scientifiques sont encore à lever.Dans cette optique, les récepteurs/absorbeurs volumiques pourraient permettre d’atteindre de plus hautes températures que les récepteurs surfaciques (technologie actuellement utilisée dans les tours solaires à concentration), permettant l’usage de cycles thermodynamiques à haute rendement, tels que les cycles Brayton. Via le projet ANR-OPTISOL, la thèse présentée ici veut répondre en partie à ces problématiques par l’étude des absorbeurs solaires volumiques :- Une étude expérimentale des mousses céramiques utilisées comme absorbeur solaire volumique haute température a été menée au laboratoire CNRS-PROMES (UPR 8521). Une expérience a été conçue afin de tester des échantillons de 5cm de diamètre soumis au flux solaire concentré en conditions quasi-1D au foyer d’un four solaire à axe vertical ;- Un code de calcul des transferts thermiques couplés en milieu poreux a été développé utilisant l’hypothèse de « milieu homogène équivalent », puis validé sur les campagnes expérimentales ;- Finalement, un algorithme d’optimisation par essaim de particules a été utilisé afin de déterminer les propriétés géométriques optimales de mousses céramiques maximisant l’efficacité de conversion thermosolaire. / Solar-to-electricity power plants appear to be the most promises way for large electricity production in the future, in terms of costs as well as environmental impacts. Thus, reaching the required technology level still requires research and innovations in order to implement such power plants at large scale.In this context, volumetric solar receivers/absorbers could allow us to reach higher temperatures in comparison to surface receivers (actual concentrating solar power technology used in solar towers), leading to high efficiency thermodynamical cycles such as Brayton cycles. With the ANR-OPTISOL project, this thesis tends to give new answers on volumetric solar absorbers using ceramic foams:- Experimental studies of open pores ceramic foams used as high temperature volumetric solar absorber have been conducted at CNRS-PROMES laboratory (UPR 8521), with designed of a dedicated experiment for 5cm diameter samples operating under quasi-1D conditions submitted to concentrated solar power at the focal point of a vertical axis solar furnace;- A numerical code has been developed in order to solve coupled heat transfers in porous medium using the “equivalent homogeneous medium” hypothesis, then validated on the experimental campaigns;- Finally, an optimization algorithm has been used (“particle swarm optimization”) aiming the identification of the optimal geometrical characteristics maximizing the solar-to-thermal efficiency of ceramic foams.
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