This dissertation is a compilation of four separate studies under the umbrella of the Chemical Abundance of Stars in the Halo (CASH) Project. The overall goal of the CASH project is to gain a better understanding of the events and processes that occurred during the early universe that shaped the composition of the stars that we observe today. In order to do so, we have conducted a comprehensive study of the abundances of the oldest observable stars. These stars have preserved the chemical signature of the material from which they formed in their atmospheres. The old, metal-poor stars that make up the stellar halo thus provide a means to study the history of the universe. We will discuss the motivation for the project in Chapter 1, introducing the field of metal-poor halo stars and providing background about the processes that have contributed to the chemical make up of the stars. The first generation of stars that created much of the material from which these stars formed are discussed, along with the low-mass evolved stars that synthesized additional elements in their interiors that are also observed in metal-poor stars today. Utilizing so-called ``snapshot'' spectra obtained with the High Resolution Spectrograph on the Hobby-Eberly Telescope at McDonald Observatory, we provide abundances for 262 stars over the sample. In Chapter 2, we present Robospect, a new code to automatically measure and deblend line equivalent widths for both absorption and emission spectra. We used this code to calculate equivalent width measurements, which provide the foundation of the analysis, from our spectra. We test the accuracy of these measurements against simulated spectra as well as manual equivalent width measurements of five stellar spectra over a range of signal-to-noise values and a set of long slit emission spectra. We find that Robospect accurately matches both the synthetic and manual measurements, with scatter consistent with the expectations based on the data quality and the results of Cayrel (1988). In Chapter 3, we present a comprehensive abundance analysis of 20 elements for 16 new low-metallicity stars from the CASH project. The abundances have been derived from both Hobby-Eberly Telescope High Resolution Spectrograph snapshot spectra (R ~15,000) and corresponding high-resolution (R~35,000) Magellan MIKE spectra. The stars span a metallicity range from [Fe/H] from -2.9 to -3.9, including four new stars with [Fe/H]<-3.7. These pilot sample stars are the most metal-poor ([Fe/H]≲-3.0) of the brightest stars included in CASH and are used to calibrate a newly-developed, automated stellar parameter and abundance determination pipeline. This code is used for the entire CASH snapshot sample. We find that the pipeline results are statistically identical for snapshot spectra when compared to a traditional, manual analysis from a high-resolution spectrum. We find four stars to be carbon-enhanced metal-poor (CEMP) stars, confirming the trend of increasing [C/Fe] abundance ratios with decreasing metallicity. Two of these objects can be classified as CEMP-no stars, adding to the growing number of these objects at [Fe/H]<-3. We also find four neutron-capture enhanced stars in the sample, one of which has [Eu/Fe] of 0.8 with clear r-process signatures. In Chapter 4, we present stellar parameters and abundances for the full CASH sample of 263 metal-poor halo star candidates derived from snapshot spectra obtained with the High Resolution Spectrograph on the Hobby-Eberly Telescope at McDonald Observatory. We determine abundance statistics and trends for 16 elements over the full sample. We identify astrophysically-interesting stars that merit further investigation, including carbon-enhanced metal-poor stars, neutron-capture element enhanced stars, and extremely metal-poor stars. We note one Li giant with a unique abundance pattern. In Chapter~5 we present a detailed abundance analysis of 23 elements for a newly discovered carbon-enhanced metal-poor (CEMP) star, HE 0414-0343, from the CASH sample. Its spectroscopic stellar parameters are T_eff=4863 ,K, log g=1.25, ξ=20 km/s, and [Fe/H]=-2.24. Radial velocity measurements covering seven years indicate HE 0414-0343 to be a binary. HE 0414-0343 has [C/Fe]=1.44 and is strongly enhanced in neutron-capture elements but its abundances cannot be reproduced by a solar-type s-process pattern alone. It could be classified as ``CEMP-r/s'' star but we find that no r-process component is required as explanation of this and other similar stars classified as ``CEMP-s'' and ``CEMP-r/s'' stars. Rather, based on comparisons with AGB star nucleosynthesis models, we suggest a new physically-motivated classification scheme, especially for the still poorly-understood ``CEMP-r/s'' stars. Importantly, it reflects the continuous transition between these so-far distinctly treated subgroups: CEMP-sA, CEMP-sB, and CEMP-sC. The [Y/Ba] ratio parameterizes the classification and can thus be used to classify any future such stars. Possible causes for the transition include the number of thermal pulses the AGB companion underwent and the effect of different AGB star masses on their nucleosynthetic yields. We then speculate that higher AGB masses may explain ``CEMP-r/s'' or now CEMP-sB and CEMP-sC stars, whereas less massive AGB stars would account for ``CEMP-s'' or CEMP-sA stars. Based on a limited set of AGB models, we suggest the abundance signature of HE~0414$-$0343 to have come from a >1.3 M_⊙ mass AGB star and a late-time mass transfer, thereby making it a CEMP-sC star. Finally, in Chapter 6, we summarize our results and provide future directions for the project. / text

The chemical fingerprints of old, metal-poor stars can be used to unravel the events of the newborn Universe and help us understand the properties of the first stars and star clusters. The study of nearby stars to infer properties in the distant past is often referred to as Galactic archaeology. However, the chemical composition of stars cannot be observed directly, but must be inferred by means of spectroscopic modelling. Traditionally, this modelling utilises one-dimensional (1D) stellar atmospheres in hydrostatic and local thermodynamic equilibrium (LTE). Today, we know that departures from LTE (known as NLTE), and differences between 1D model atmospheres and their hydrodynamical three-dimensional (3D) counterparts, become increasingly severe at lower metallicity. The development of NLTE modelling of spectral line formation in 3D atmospheres is still in its infancy, but constitutes a remarkable step forward that has been made possible by parallelised codes and supercomputers. The central theme of this thesis is the application of NLTE analyses to metal-poor stars, to help usher the field of Galactic archaeology forward with important consequences for the nature of the first stellar generations. I present a theoretical NLTE study of aluminium, where I validate the analysis using a set of bright standard stars and provide calculated NLTE effects for a large parameter space. I perform 3D NLTE calculations for the solar spectrum to better constrain the zero-point of the cosmic abundance scale, and find excellent agreement with the meteoritic aluminium abundance. I also present NLTE analyses of metal-poor stars in the globular clusters NGC 6397 and M4. While globular cluster stars were long expected to form from a chemically homogeneous medium, star-to-star abundance variations of light elements indicate multiple epochs of star formation. Massive first-generation stars polluted the interstellar medium from which later generations formed, and I use the observed abundance variations to deduce the properties of the polluting stars. Among the heavier elements, I uncover evolutionary abundance variations that match predictions of stellar evolution models with atomic diffusion. The results indicate that the chemical abundance ratios of unevolved metal-poor stars are affected by gravitational settling, with a bias of the order 25-50 %, increasing towards lower metallicity. This atmospheric depletion mechanism is a probable explanation to why the stellar abundances of lithium fall short of the predictions from standard Big Bang nucleosynthesis. Finally, I apply a 3D NLTE abundance analysis to the red giant SMSS 0313-6708, which is the most iron-deficient star known. The chemical abundance pattern of this star indicates that it formed from gas affected only by Big Bang nucleosynthesis and a single faint supernova. Comparison of the inferred abundance pattern to theoretical predictions leads to constraints on the explosion mechanism and the mass of the metal-free progenitor star.

We report the peculiar chemical abundance patterns of 11 atypical Milky Way (MW) field red giant stars observed by the Apache Point Observatory Galactic Evolution Experiment (APOGEE). These atypical giants exhibit strong Al and N enhancements accompanied by C and Mg depletions, strikingly similar to those observed in the so-called second-generation (SG) stars of globular clusters (GCs). Remarkably, we find low Mg abundances ([Mg/Fe]. < 0.0) together with strong Al and N overabundances in the majority (5/7) of the metal-rich ([Fe/H] greater than or similar to-1.0) sample stars, which is at odds with actual observations of SG stars in Galactic GCs of similar metallicities. This chemical pattern is unique and unprecedented among MW stars, posing urgent questions about its origin. These atypical stars could be former SG stars of dissolved GCs formed with intrinsically lower abundances of Mg and enriched Al (subsequently self-polluted by massive AGB stars) or the result of exotic binary systems. We speculate that the stars Mg-deficiency as well as the orbital properties suggest that they could have an extragalactic origin. This discovery should guide future dedicated spectroscopic searches of atypical stellar chemical patterns in our Galaxy, a fundamental step forward to understanding the Galactic formation and evolution.

The K2 mission is targeting large numbers of nearby (d < 100 pc) GKM dwarfs selected from the SUPERBLINK proper motion survey (mu > 40 mas yr(-1), V < 20). Additionally, the mission is targeting low-mass, high proper motion stars associated with the local (d < 500 pc) Galactic halo population also selected from SUPERBLINK. K2 campaigns 0 through 8 monitored a total of 26,518 of these cool main-sequence stars. We used the auto-correlation function to search for fast rotators by identifying short-period photometric modulations in the K2 light curves. We identified 481 candidate fast rotators with rotation periods < 4 days that show light-curve modulations consistent with starspots. Their kinematics show low average transverse velocities, suggesting that they are part of the young disk population. A subset (13) of the fast rotators is found among those targets with colors and kinematics consistent with the local Galactic halo population and may represent stars spun up by tidal interactions in close binary systems. We further demonstrate that the M dwarf fast rotators selected from the K2 light curves are significantly more likely to have UV excess and discuss the potential of the K2 mission to identify new nearby young GKM dwarfs on the basis of their fast rotation rates. Finally, we discuss the possible use of local halo stars as fiducial, non-variable sources in the Kepler fields.

As part of a large investigation with Hubble Space Telescope to study the faintest stars within the globular cluster omega Centauri, in this work we present early results on the multiplicity of its main sequence (MS) stars, based on deep optical and near-infrared observations. By using appropriate colour-magnitude diagrams, we have identified, for the first time, the two main stellar Populations I and II along the entire MS, from the turn-off towards the hydrogen-burning limit. We have compared the observations with suitable synthetic spectra of MS stars and conclude that the two main sequences (MSs) are consistent with stellar populations with different metallicity, helium and light-element abundance. Specifically, MS-I corresponds to a metal-poor stellar population ([Fe/H] similar to -1.7) with Y similar to 0.25 and [O/Fe] similar to 0.30. The MS-II hosts helium-rich (Y similar to 0.37-0.40) stars with metallicity ranging from [Fe/H] similar to -1.7 to -1.4. Below the MS knee (m(F160W) similar to 19.5), our photometry reveals that each of the two main MSs hosts stellar subpopulations with different oxygen abundances, with very O-poor stars ([O/Fe] similar to -0.5) populating the MS-II. Such a complexity has never been observed in previous studies of M-dwarfs in globular clusters. A few months before the launch of the James Webb Space Telescope, these results demonstrate the power of optical and near-infrared photometry in the study of multiple stellar populations in globular clusters.

Globular clusters are tracers of the formation and evolution of their host galaxies. Kinematics, chemical abundances, age and position of the clusters allows tracing interactions between Milky Way and surrounding galaxies and outlines their chemical enrichment history. In this thesis we analyse mid-resolution spectra of about 800 red giant stars in 51 Galactic globular clusters. It is the first time that [Fe/H] and [Mg/Fe] derived in a consistent way are published for such a huge sample of globular clusters, almost 1/3 of the total number of catalogued clusters. Our metallicities are showed to be more precise than previous works based on mid-resolution spectroscopy. A turnover at [Fe/H] ~ -1.0 is found in the plot [Fe/H] vs. [Mg/Fe] for bulge and halo, although bulge seems to have a more metal-rich turnover, i.e, bulge has more efficient formation than the halo. Comparing the abundances with age the timescale for SNIa to start to become important is 1Gyr. [Fe/H] vs. age corroborates the different star formation efficiency of bulge and halo while [Mg/Fe] does not follow that. Halo was formed in mini halos or dwarf galaxies, and two multiple population clusters had their origin analysed to check it. M 22 seems to have been formed in the Milky Way while NGC 5824 possibly was originated in a dwarf galaxy, although our results are inconclusive for NGC 5824. The Galactic bulge seems to have been formed fast i.e., probably the oldest globular cluster is there. In fact HP 1 has a bluer horizontal branch than expected for its metallicity and we interpret that as an age effect. We determine its distance using light curves of variable stars in order to constrain future age determinations via colour-magnitude diagram. Finally, we investigate interaction between Milky Way and its neighbour galaxy SMC. We find that some star clusters are being stripped out of the SMC main body, which is consistent with tidal stripping scenario for the interaction between the galaxies, instead of ram pressure that would only affect gas. / Aglomerados globulares são traçadores da formação e evolução de suas galáxias. Cinemática, abundâncias químicas, idades e posições dos aglomerados permitem traçar interações entre Via Láctea e galáxias vizinhas e suas histórias de enriquecimento químico. Nesta tese analisamos espectros de média resolução de mais de 800 estrelas gigantes vermelhas em 51 aglomerados globulares Galácticos. É a primeira vez que [Fe/H] and [Mg/Fe] determinados de modo consistente são publicados para uma amostra desse porte, ~1/3 dos objetos catalogados. Nossas metalicidades são mais precisas que trabalhos anteriores similares. Uma quebra em [Fe/H] ~ -1.0 é encontrada no gráfico [Fe/H] vs. [Mg/Fe] para o bojo e halo, embora bojo parece ter uma quebra em [Fe/H] maior, i.e, bojo tem formaçãao mais eficiente que o halo. Comparando abundâncias com idade, a escala de tempo para SNIa ficar importante é 1Gano. [Fe/H] vs. idade corrobora diferentes eficiências de formação do bojo e halo, mas [Mg/Fe] vs. idade não mostra isso. O halo foi formado em mini halos ou galáxias anãs, e dois aglomerados com dispersão em [Fe/H] tiveram suas origens analisadas. M 22 parece ter sido formado na Via Láctea e NGC 5824 possivelmente foi originado em uma galáxia anã, embora os resultados são inconclusivos para NGC 5824. O bojo parece ter sido formado rapidamente e deve possuir o aglomerado mais velho. De fato, HP 1 tem um ramo horizontal mais azul que o esperado para sua metalicidade e vemos isso como um efeito da idade. Determinamos sua distância usando curvas de luz de RR Lyrae de maneira a restringir futuras determinações de idade via diagrama cor-magnitude. Finalmente, investigamos a interação entre Via Láctea e sua galáxia vizinha SMC. Encontramos aglomerados sendo removidos do corpo central da SMC, consistente com cenário de remoção por força de maré para a interação entre as galáxias, em vez de ``ram pressure\'\' que afeta só gás.

Globular clusters are tracers of the formation and evolution of their host galaxies. Kinematics, chemical abundances, age and position of the clusters allows tracing interactions between Milky Way and surrounding galaxies and outlines their chemical enrichment history. In this thesis we analyse mid-resolution spectra of about 800 red giant stars in 51 Galactic globular clusters. It is the first time that [Fe/H] and [Mg/Fe] derived in a consistent way are published for such a huge sample of globular clusters, almost 1/3 of the total number of catalogued clusters. Our metallicities are showed to be more precise than previous works based on mid-resolution spectroscopy. A turnover at [Fe/H] ~ -1.0 is found in the plot [Fe/H] vs. [Mg/Fe] for bulge and halo, although bulge seems to have a more metal-rich turnover, i.e, bulge has more efficient formation than the halo. Comparing the abundances with age the timescale for SNIa to start to become important is 1Gyr. [Fe/H] vs. age corroborates the different star formation efficiency of bulge and halo while [Mg/Fe] does not follow that. Halo was formed in mini halos or dwarf galaxies, and two multiple population clusters had their origin analysed to check it. M 22 seems to have been formed in the Milky Way while NGC 5824 possibly was originated in a dwarf galaxy, although our results are inconclusive for NGC 5824. The Galactic bulge seems to have been formed fast i.e., probably the oldest globular cluster is there. In fact HP 1 has a bluer horizontal branch than expected for its metallicity and we interpret that as an age effect. We determine its distance using light curves of variable stars in order to constrain future age determinations via colour-magnitude diagram. Finally, we investigate interaction between Milky Way and its neighbour galaxy SMC. We find that some star clusters are being stripped out of the SMC main body, which is consistent with tidal stripping scenario for the interaction between the galaxies, instead of ram pressure that would only affect gas. / Aglomerados globulares são traçadores da formação e evolução de suas galáxias. Cinemática, abundâncias químicas, idades e posições dos aglomerados permitem traçar interações entre Via Láctea e galáxias vizinhas e suas histórias de enriquecimento químico. Nesta tese analisamos espectros de média resolução de mais de 800 estrelas gigantes vermelhas em 51 aglomerados globulares Galácticos. É a primeira vez que [Fe/H] and [Mg/Fe] determinados de modo consistente são publicados para uma amostra desse porte, ~1/3 dos objetos catalogados. Nossas metalicidades são mais precisas que trabalhos anteriores similares. Uma quebra em [Fe/H] ~ -1.0 é encontrada no gráfico [Fe/H] vs. [Mg/Fe] para o bojo e halo, embora bojo parece ter uma quebra em [Fe/H] maior, i.e, bojo tem formaçãao mais eficiente que o halo. Comparando abundâncias com idade, a escala de tempo para SNIa ficar importante é 1Gano. [Fe/H] vs. idade corrobora diferentes eficiências de formação do bojo e halo, mas [Mg/Fe] vs. idade não mostra isso. O halo foi formado em mini halos ou galáxias anãs, e dois aglomerados com dispersão em [Fe/H] tiveram suas origens analisadas. M 22 parece ter sido formado na Via Láctea e NGC 5824 possivelmente foi originado em uma galáxia anã, embora os resultados são inconclusivos para NGC 5824. O bojo parece ter sido formado rapidamente e deve possuir o aglomerado mais velho. De fato, HP 1 tem um ramo horizontal mais azul que o esperado para sua metalicidade e vemos isso como um efeito da idade. Determinamos sua distância usando curvas de luz de RR Lyrae de maneira a restringir futuras determinações de idade via diagrama cor-magnitude. Finalmente, investigamos a interação entre Via Láctea e sua galáxia vizinha SMC. Encontramos aglomerados sendo removidos do corpo central da SMC, consistente com cenário de remoção por força de maré para a interação entre as galáxias, em vez de ``ram pressure\'\' que afeta só gás.