O objetivo deste trabalho é avaliar a incorporação de uma fração cuja fração granulométrica é menor que 2mm do resíduo do Shredder proveniente de uma indústria siderúrgica ao processo de fabricação de blocos cerâmicos estruturais de uma fábrica de cerâmica vermelha. As variáveis analisadas foram: dimensões, propriedades de resistência à compressão, absorção de água e quanto às questões ambientais pela análise de lixiviação e solubilização segundo a NBR 10.004 (ABNT, 2004). Foi realizado processamento do resíduo do Shredder em uma fração menor que 2mm e realizada a incorporação de uma dosagem de 10% e 20% deste material no processo industrial de uma cerâmica de produção de blocos estruturais. Foram avaliadas as propriedades de qualidade e quanto às questões ambientais. Analisando os resultados constatou-se que tanto o bloco cerâmico padrão quanto aos protótipos contendo 10% e 20% de resíduo atendem os limites normativos para resistência à compressão e para absorção de água. Na análise dimensional, somente o protótipo contendo 10% de resíduo atende todos os parâmetros quanto os requisitos normativos.Pelas análises de lixiviado e solubilizado, concluiu-se que tanto o bloco cerâmico estrutural padrão quanto ao protótipo contendo 20% de resíduo são classificados como Classe II A- não inerte. É possível afirmar que a fração menor que 2mm do resíduo do Shredder pode ser utilizada junto à massa cerâmica como matéria-prima para fabricação de blocos cerâmicos estruturais. / The goal of this work is to evaluate the incorporation of a fraction smaller than 2 mm of the Shredder Residue from a steel industry into a manufacturing process of structural bricks in a red ceramic factory. Evaluate the quality of results as the compressive strength properties, water absorption and environmental issues as leaching and solubilization analysis according to NBR 10.004 (ABNT, 2004). The Shredder Residue in a fraction smaller than 2mm was incorporated in dosages of 10% and 20% with the clay in the industrial process of a ceramic which produces structural blocks. The quality properties and the environmental issues were analyzed and the results was that both brick pattern block and the prototypes containing 10% and 20% residue meet regulatory limits for compressive strength and water absorption. The analysis of leached and solubilized concluded that both the brick pattern and the prototype containing 20% of waste are classified as Class II A – non inert residue. It is possible to say that the fraction smaller than 2mm of Automotive Shredder Residue can be used with the clay as raw material for the manufacture of structural ceramic blocks.

O objetivo deste trabalho é avaliar a incorporação de uma fração cuja fração granulométrica é menor que 2mm do resíduo do Shredder proveniente de uma indústria siderúrgica ao processo de fabricação de blocos cerâmicos estruturais de uma fábrica de cerâmica vermelha. As variáveis analisadas foram: dimensões, propriedades de resistência à compressão, absorção de água e quanto às questões ambientais pela análise de lixiviação e solubilização segundo a NBR 10.004 (ABNT, 2004). Foi realizado processamento do resíduo do Shredder em uma fração menor que 2mm e realizada a incorporação de uma dosagem de 10% e 20% deste material no processo industrial de uma cerâmica de produção de blocos estruturais. Foram avaliadas as propriedades de qualidade e quanto às questões ambientais. Analisando os resultados constatou-se que tanto o bloco cerâmico padrão quanto aos protótipos contendo 10% e 20% de resíduo atendem os limites normativos para resistência à compressão e para absorção de água. Na análise dimensional, somente o protótipo contendo 10% de resíduo atende todos os parâmetros quanto os requisitos normativos.Pelas análises de lixiviado e solubilizado, concluiu-se que tanto o bloco cerâmico estrutural padrão quanto ao protótipo contendo 20% de resíduo são classificados como Classe II A- não inerte. É possível afirmar que a fração menor que 2mm do resíduo do Shredder pode ser utilizada junto à massa cerâmica como matéria-prima para fabricação de blocos cerâmicos estruturais. / The goal of this work is to evaluate the incorporation of a fraction smaller than 2 mm of the Shredder Residue from a steel industry into a manufacturing process of structural bricks in a red ceramic factory. Evaluate the quality of results as the compressive strength properties, water absorption and environmental issues as leaching and solubilization analysis according to NBR 10.004 (ABNT, 2004). The Shredder Residue in a fraction smaller than 2mm was incorporated in dosages of 10% and 20% with the clay in the industrial process of a ceramic which produces structural blocks. The quality properties and the environmental issues were analyzed and the results was that both brick pattern block and the prototypes containing 10% and 20% residue meet regulatory limits for compressive strength and water absorption. The analysis of leached and solubilized concluded that both the brick pattern and the prototype containing 20% of waste are classified as Class II A – non inert residue. It is possible to say that the fraction smaller than 2mm of Automotive Shredder Residue can be used with the clay as raw material for the manufacture of structural ceramic blocks.

O objetivo deste trabalho é avaliar a incorporação de uma fração cuja fração granulométrica é menor que 2mm do resíduo do Shredder proveniente de uma indústria siderúrgica ao processo de fabricação de blocos cerâmicos estruturais de uma fábrica de cerâmica vermelha. As variáveis analisadas foram: dimensões, propriedades de resistência à compressão, absorção de água e quanto às questões ambientais pela análise de lixiviação e solubilização segundo a NBR 10.004 (ABNT, 2004). Foi realizado processamento do resíduo do Shredder em uma fração menor que 2mm e realizada a incorporação de uma dosagem de 10% e 20% deste material no processo industrial de uma cerâmica de produção de blocos estruturais. Foram avaliadas as propriedades de qualidade e quanto às questões ambientais. Analisando os resultados constatou-se que tanto o bloco cerâmico padrão quanto aos protótipos contendo 10% e 20% de resíduo atendem os limites normativos para resistência à compressão e para absorção de água. Na análise dimensional, somente o protótipo contendo 10% de resíduo atende todos os parâmetros quanto os requisitos normativos.Pelas análises de lixiviado e solubilizado, concluiu-se que tanto o bloco cerâmico estrutural padrão quanto ao protótipo contendo 20% de resíduo são classificados como Classe II A- não inerte. É possível afirmar que a fração menor que 2mm do resíduo do Shredder pode ser utilizada junto à massa cerâmica como matéria-prima para fabricação de blocos cerâmicos estruturais. / The goal of this work is to evaluate the incorporation of a fraction smaller than 2 mm of the Shredder Residue from a steel industry into a manufacturing process of structural bricks in a red ceramic factory. Evaluate the quality of results as the compressive strength properties, water absorption and environmental issues as leaching and solubilization analysis according to NBR 10.004 (ABNT, 2004). The Shredder Residue in a fraction smaller than 2mm was incorporated in dosages of 10% and 20% with the clay in the industrial process of a ceramic which produces structural blocks. The quality properties and the environmental issues were analyzed and the results was that both brick pattern block and the prototypes containing 10% and 20% residue meet regulatory limits for compressive strength and water absorption. The analysis of leached and solubilized concluded that both the brick pattern and the prototype containing 20% of waste are classified as Class II A – non inert residue. It is possible to say that the fraction smaller than 2mm of Automotive Shredder Residue can be used with the clay as raw material for the manufacture of structural ceramic blocks.

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With exponential global population growth occurring and associated environmentally destructive consumption of natural resources, alternative materials that are fast growing and sustainable are being sought out to satisfy human needs. One material that is fast growing and sustainable that can be used to meet most basic needs of humans (i.e. shelter, food, tools) is the plant bamboo, of the grass family Poaceae. Bamboo was used in the past by native peoples who lived in the environment where bamboo natively grows (all continents except Europe and Antarctica) with proven success for uses such as shelter, piping, tools, wells, food, fencing, baskets and much more. These practices were mostly abandoned and deemed obsolete due to the introduction of long lasting ‘modern’ building materials of steel and concrete which gained popularity in the 1800s. Now, in the current century with much advancement in science, technology, and education, humanity is reconsidering many practices and returning to more ancient practices and ways that are better for human health, the environment, and overall sustainability. These environmental considerations are drivers of this research, which focuses on how to use bamboo for engineering applications. First, in order to use a material for engineering and design applications, a material must be destructively tested to attain material property values. Therefore, a critical examination of the bamboo mechanical property values published literature was performed. It was found that although many scientists all over the world have been working on mechanical property testing of bamboo, their results have been published in different journals, in different languages, and had not yet been aggregated and compared. This led to the first study in this work that analyzed mechanical property data from 43 bamboo peer-reviewed publications written in English, Spanish, and Portuguese (the three main languages in which bamboo literature is published). This study focused on aggregating mechanical property values, establishing a range of values for each property as well as an average, and correlating the difference in property values to bamboo variables stated in bamboo literature (age, bamboo species, density, moisture content, post-harvest treatment, and testing standard employed). The five mechanical properties reviewed were: shear strength, compressive strength, tensile strength, bending strength / modulus of rupture (MOR), and modulus of elasticity (MOE) and their average values were 9 MPa, 52 MPa, 159 MPa, 120 MPa, and 16 GPa, respectively. Although a thorough graphical set of analyses were performed attempting to correlate the difference in mechanical property values to the previously listed variables, and only main variables found to influence strength values were moisture content and specific testing standard employed. The results of the high range of mechanical property values with no variable with which to separate the results to lower the range, led to the second part of the research. It incorporated the high range of values reported in the literature but was able to establish safety factors and reduction factors alongside corresponding failure rates. This work allows for a designer to use bamboo culms choosing a failure rate he/she deems appropriate for structural bamboo construction. The analyses in this work were performed using Allowable Stress Design (ASD) and Load and Resistance Factor Design (LRFD) equations applied to bamboo as well as Monte Carlo statistical analyses for verification. The raw data and statistically analyzed data of 25 publications were used for this analysis, yielding 3806 strength test values (shear strength, compressive strength, bending strength / modulus of rupture, and tensile strength). Shear strength safety factors ranged from 1.38-3.58 for failure ratios from 1:6-1:25000; compressive strength from 1.30-2.79; bending strength from 1.43-4.03; tensile strength from 1.66-7.43. No singular safety factor is suggested for design as that is due to the judgment of the designer of what failure ratio he/she deems appropriate for the specific application. Although many compression tests have been performed on bamboo, there are no known tests which destructively test bamboo after an extended period of time after harvesting (more than ~3 months). This experiment conducted a field experiment to test the functionality of using bamboo for the application of installing bamboo wells to provide groundwater. The bamboo tested in the third part of the study was of two species, Dendrocalamus giganteus and Dendrocalamus asper half of which were 1) air-dried in a laboratory for 3.5 years and the other half of which was 2) inserted in the ground as bamboo wells. The bamboo culms (or poles) had been separately treated in three different ways right after cutting: 1/3 with a borax and boric acid solution (most conventional treatment in the industry), 1/3 with coconut oil (experimental treatment in the literature), and 1/3 air-dried, a non-treated control. Bamboo wells are said to be used in ancient times as well as in more recent applications in the 1990s in India by small scale farmers. The publication of bamboo well studies have been very few and nearly no scientific analyses had been performed on them. Therefore, six bamboo wells were assembled and installed at the University of South Florida Geopark, the first of their kind in the U.S. These wells were half of species D. giganteus and half of species D. asper and also treated individually using the three different treatments described above. The wells were monitored for pH and presence of leached boron for a 3.5-year monitoring period and then removed. Upon removal, the bamboo well casings were examined for molds present as well as by mechanical compression testing to assess degradation in comparison to each other (of different treatments) and to air-dried control samples maintained in the laboratory for 3.5 years. The mold fc. Acrodictys was observed to cover the entire inner portion of the bamboo (inner diameter), from the surface level up to the water table. The lab air-dried control samples had compression strength and compressive modulus of elasticity values correlating to those found in the literature, 44-90 MPa (72 MPa average) and 15-31 GPa, respectively. Removed well samples exhibited compressive strengths and compressive modulus of elasticity values of 22-61 MPa (39 MPa average) and 7-25 GPa, respectively. This study revealed that bamboo wells were feasible and although their compressive strengths lowered by around a half after being in the ground for 3.5 years, their compressive strength and compressive modulus of elasticity values were still in the range of bamboo tested in the literature.

Almost all research on biorefinery concepts are based on chemical pulping processes and ways of utilising lignin, hemicelluloses and extractives as well as a part of the remaining cellulose for production of nano materials in order to create more valuable products than today. Within the Forest as a Resource (FORE) research program at FSCN we are utilising the whole chain of unit processes from forestry to final products as paper and board, where the pulping process research focus on high yield process as TMP and CTMP. As these process solutions are preserving or only slightly changing the properties of the original wood polymers and extractives, the idea is to find high value adding products designed by nature. From an economic perspective, the production of nanocellulose from a chemical pulp is quite expensive as the pulp has to be either enzymatically (e.g. mono-component endoglucanase) pre-treated or chemically oxidised using the TEMPO (2,2,6,6 - tetramethyl-piperidine-1-oxil) - mediated oxidation method in order to make it possible to disrupt the fibres by means of homogenisation. In high yield pulping processes such as in TMP and CTMP, the idea with this study was to investigate the possibility to use fractions of low quality materials from fines fractions for the production of nano-ligno-cellulose (NLC). The integration of a NLC unit process in a high yield pulping production line has a potential to become a future way to improve the quality level of traditional products such as paper and board grades. The intention of this research work was that, by using this concept, a knowledge base can be created so that it becomes possible to develop a low-cost production method for its implementation. In order to study the potential of this concept, treatment of thermo-mechanical pulp (TMP) fines fractions were studied by means of homogenisation It seems possible to homogenise fine particles of thermo-mechanical pulp (1% w/v) to NLC. A correspond fines fraction from bleached kraft pulp (BKP) was tested as a reference at 0.5% w/v concentration. The objective presented in this work was to develop a methodology for producing mechanical pulp based NLC from fines fractions and to utilise this material as strength additives in paper and board grades. Laboratory sheets of CTMP and BKP, with addition of their respective NLC, were made in a Rapid Köthen sheet former. It was found that handsheets of pulp fibres blended with NLC improved the z-strength and other important mechanical properties for similar sheet densities. The characterisation of the particle size distribution of NLC is both important and challenging and the crill methodology developed at Innventia (former STFI) already during the 1980s was tested to see if it would be both fast and reliable enough. The crill measurement technique is based on the optical responses of a micro/nano particle suspension at two wavelengths of light; UV and IR. The crill value of TMP and CTMP based nano-ligno-cellulose were measured as a function of the homogenisation time. Results showed that the crill value of both TMP-NLC and CTMP-NLC correlated with the homogenisation time.

This thesis deals with processing of nanocellulose originating from pulps, with focus on mechanical pulp fibres and fines fractions. The nanocellulose materials produced within this research project were tested for different purposes ranging from strength additives in paper and paperboard products, via composite films to foam materials. TAPPI (Technical Association of Pulp &amp; Paper Industry) has recently suggested a standard terminology and nomenclature for nanocellulose materials (see paper I). In spite of that we have decided to use the terms nano-ligno-cellulose (NLC), microfibrillated cellulose (MFC), nanofibrillated cellulose (NFC) and nanocellulose (NC) in this thesis . It is well-known that mainly chemical pulps are used as starting material in nanocellulose production. However, chemical pulps as bleached sulphite and bleached kraft are quite expensive. One more cost-effective alternative can be to use fibres or fines fractions from thermo-mechanical pulp (TMP) and chemi-thermomechanical pulp (CTMP).   In paper II-IV, fractionation has been used to obtain fines fractions that can easily be mechanically treated using homogenisation. The idea with this study was to investigate the possibility to use fractions of low quality materials from fines fractions for the production of nanocellulose. The integration of a nanocellulose unit process in a high-yield pulping production line has a potential to become a future way to improve the quality level of traditional products such as paper and paperboard grades.   Paper III describes how to utilise the crill measurement technique as a tool for qualitative estimation of the amount of micro- and nano-material produced in a certain process. The crill values of TMP- and CTMP-based nanocelluloses were measured as a function of the homogenisation time. Results showed that the crill values of both TMP-NLC and CTMP-NLC correlated with the homogenisation time. In Paper V pretreating methods, hydrogen peroxide and TEMPO are evaluated. Crill measurement showed that hydrogen peroxide pretreatment (1% and 4%) and mechanical treatment time did not improve fibrillation efficiency as much as expected. However, for TEMPO-oxidised nanocelluloses, the crill value significantly increased with both the TEMPO chemical treatment and mechanical treatment time. In paper V-VII TEMPO-mediated oxidation systems (TEMPO/NaBr/NaClO) are applied to these fibres (CTMP and Sulphite pulp) in order to swell them so that it becomes easy to disrupt the fibres into nanofibres with mechanical treatment.   The demand for paperboard and other packaging materials are steadily increasing. Paper strength properties are crucial when the paperboard is to withstand high load. A solution that are investigated in papers IV and VI, is to use MFC as an alternative paper strength additive in papermaking. However, if one wish to target extremely higher strength improvement results, particularly for packaging paperboards, then it would be fair to use MFC or cationic starch (CS). In paper VI CS or TEMPO-based MFC was used to improve the strength properties of CTMP-based paperboard products. Results here indicate significant strength improvement with the use of different levels of CS (i.e., 20 and 10 kg t–1) and 5% MFC. The strengthening impact of 5% MFC was approximately equal to that of 10 kg t–1 of CS.   In paper VII, NFC and nanographite (NG) was used when producing composite films with enhanced sheet-resistance and mechanical properties. The films produced being quite stable, flexible, and bendable. Realising this concept of NFC-NG composite film would create new possibilities for technological advancement in the area of high-yield pulp technology.  Finally, in paper VIII, a new processing method for nanocellulose is introduced  where an organic acid (i.e., formic acid) is used. This eco-friendly approach has shown to be successful, a nanocellulose with a uniform size distribution has been produced. / <p>Vid tidpunkten för disputationen var följande delarbeten opublicerade: delarbete 5 och 7 inskickade, delarbete 6 och 8 manuskript.</p><p>At the time of the doctoral defence the following papers were unpublished: paper 5 and 7 submitted, paper 6 and 8 manuscripts.</p>

Magistro darbe tiriama paprastosios eglės vidinio puvinio įtaka medienos savybėms . Darbo objektas – eglės mediena, kuri buvo paimta iš VĮ Prienų miškų urėdijos 15 kv 25 skl., 49 kv 15 skl., Veisėjų 3 kv 7 skl., Šilutės 2 kv 7skl., 11 kv 12 skl., 19 kv 6 skl., 33 kv 3 skl., 147 kv 4 skl. Darbo tikslas – ištirti paprastosios eglės vidinio puvinio įtaką medienos tankio ir stiprio savybėms. Darbo metodai – tirtuose eglės bareliuose visi medžiai buvo patikrinti prietaisu „ARBOTOM“, kuris matuoja garso sklidimo greitį medienoje ir pateikia erdvinį garso greičio stiebe vaizdą. Garsas sveikoje ir puvinio pažeistoje medienoje sklinda skirtingu greičiu. Vėliau atsitiktiniu būdu iš visų medžių, kuriuose prietaisas parodė vidinį puvinį, buvo atrinkti ir nupjauti medžiai. Radus puvinį buvo paimta kelminė atpjova 50 cm ilgio tolesniems tyrimams. Ruošiant bandinius, iš atpjovų buvo išpjauta centrinė (einanti išilgai per šerdį) 60 mm storio išpjova, kuri supjaustyta į sluoksnius. Medienos fizinės ir mechaninės savybės nustatytos LAMMC Miškų instituto medienos laboratorijoje ir slėnio „Nemunas“ medienos naudojimo, kokybės ir apdirbimo technologijų laboratorijoje. Vykdant medienos stipruminių savybių bandymus, naudota 5 tonų galios bandymų mašina P – 5. Duomenų sisteminimas ir jų analizė atlikta, naudojant statistinių duomenų tvarkymo paketą Microsoft Excell. Darbo rezultatai: atlikus tyrimus nustatyta, kad Prienų urėdijos eglės branduolio puvinio įtaką medienos tankiui, išryškėjo, jog... [toliau žr. visą tekstą] / In this master thesis was researched internal rot of Norway spruce (Picea abies) and its impact to woods characteristics. The object of this work: wood of Norway spruce (Picea abies), which was taken from Prienai state-owned forest enterprise (therefore SOFE) 15 quarter 25 plot, 49 quarter 15plot,Veisiejai SOFE 3 quarter 7 plot, Šilutė SOFE 2quarter 7plot, 11 quarter 12plot, 19 quarter 6 plot, 33 quarter 3plot, 147 quarter 4 plot. The aim of this work is to research the inner rot influence of picea abies to wood density and strength properties. The methods: all spruce in research area were checked with device called “ARBOTROM”, which measures sound speed in wood and shows spatial sound speed view in a steam. Sound in healthy and rot wood differs. Randomly were selected and cut down all trees, which according to the device had an inner rot. After the rot was found a 50cm length tree stump sample was taken for the further research. During preparation of samples there was prepared the central 60 mm thick cutoff (lengthways the core) and shredded to layers. Physical and mechanical wood properties were defined in LRCAF Forest Institute for timber laboratory and in “Nemunas” valley, timber quality and technology lab. For a wood strength property testing was used 5 ton test machine P-5. All data was systematized and analyzed by using Microsoft Excel. Results: after researching Norway spruce kernel rot effect to wood density, was discovered, that wood samples with inner rot from... [to full text]

L’objectif principal de la thèse a été d’étudier les propriétés de résistance des matériaux nanoporeux par des approches théoriques et numériques. Dans le contexte des méthodes d’homogénéisation, des critères de résistance macroscopiques ont été établis par des approches analytiques à l’homogénéisation non-linéaire et à l’analyse limite. Les critères de résistance ainsi obtenus permettent de tenir en compte les effets de taille, tout en améliorant les formulations déjà existantes.
 En outre, dans le but de servir de référence pour la calibration et/ou la validation des modèles analytiques, des simulations numériques basées sur la dynamique moléculaire ont été conduites, en se référant à des monocristaux d’aluminium contenant des nanopores sphériques, sous des conditions multiaxiales de vitesse de déformation. Par rapport aux simulations actuellement disponibles dans la littérature, les résultats obtenus ont clairement établi que les surfaces de résistance sont significativement influencées par les trois invariants isotropes de contrainte.
 Finalement, dans le but de mettre à profit les indications fournies par les simulations numériques, le cas d’un matériau nanoporeux constitué d’une matrice ductile sensible aux trois invariants isotropes a été étudié par une approche par l’analyse limite, en prenant en compte une formulation modifiée du critère de résistance de bigoni. La solution exacte du problème a été établie dans le cas d’un chargement isotrope. A partir des résultats ainsi obtenus, une approche d’analyse limite cinématique a été mise en place, et permet de fournir des estimations des propriétés de résistance macroscopiques sous chargements axisymétriques. / The main objectif of the thesis consisted in investigating strength properties of nanoporous materials by means of theoretical and numerical approaches. In the framework of homogenization methods, novel macroscopic strength criteria have been established via a non-linear homogenization procedure and a kinematic limit-analysis approach. Resulting yield functions allowed to take into account void-size effects on nanoporous materials strength properties, thereby resulting in a strong enhancement of available estimates. Furthermore, aiming to funish effective benchmarking evidence for the calibration and/or the assessment of theoretical models, molecular-dynamics based computations have been carried out on in-silico single crystals embedding spherical nanovoids, simulation domains undergoing multiaxial strain-rate boundary conditions. With respect to available numerical studies, proposed results clearly showed the influence of all the three isotropic stress invariants on computed material strength surfaces. Finally, with the aim to account for physical indications coming from numerical simulations, a ductile nanoporous material with a general isotropic plastic matrix has been investigated via a limit analysis approach, by referring to a modified version of the bigoni strength criterion. The limit state of a hollow-sphere model undergoing isotropic loadings has been exactly determined. Correspondigly, a novel strength criterion has been analytically established in the case of axysimmetric boundary conditions.

The Czech deep repository development programme resulted in identification of several localities with favourable geological conditions. The Czech concept of a deep repository construction targets on crystalline host rocks. The dissertation focuses on combined petrographic and physico-mechanical properties (rebound hardness, uniaxial and triaxial compressive strength, indirect tensile strength) of crystalline rocks (durbachite, ganulite) from the most favoured localities – Horka near Velké Meziříčí and Kraví hora near Dolní Rožínka.