The diploma thesis deals with the reading level of pupils in the third year, who in the first year learned to read by different methods. The thesis is divided into theoretical and research parts. The theoretical part deals with the characteristics of pupils at the younger school age, the development of reading skills, the teaching of early reading by the analytical-synthetic, genetic and Sfumato methods. Furthermore, it defines reading literacy, and refers to international research surveys, types and qualities of reading, diagnosis of reading, reading defects and their correction. The research part focuses on the diagnosis of the reading performance of pupils in the 3rd grade of primary school. The reading results are evaluated according to the criteria based on the theoretical part of the thesis.

Les investigations présentées dans ce mémoire de doctorat portent sur la synthèse d’antennes à éléments parasites à polarisation circulaire. Une stratégie de conception rapide et efficace est développée et mise en oeuvre pour synthétiser des diagrammes de rayonnement à multiples objectifs. Des éléments parasites peuvent ainsi être associés à d’autres antennes pour en améliorer les performances. Deux antennes ont été imaginées. Un premier démonstrateur d’AEP directive à polarisation circulaire et à bande élargie a été conçu. Ce démonstrateur qui se compose de l’association de 18 dipôles parasites avec une antenne spirale logarithmique a été fabriqué et mesuré. Un second prototype d’AEP a été inventé dans le cadre d’un projet spatiale «Antenne Isoflux Bande-X pour nano-satellite». L’antenne compacte a été développée pour supporter les débits de transmission des futures missions des plateformes Nano-Satellite « Cube-Sat ». Ce prototype associe une antenne patch avec une distribution de 12 dipôles parasites pour réaliser une couverture Isoflux en polarisation circulaire. Cette antenne a été mesurée sur sa plateforme d’accueil. / The investigations presented in this thesis propose the synthesis of circularly polarized antennas with parasitic elements. An innovative and effective strategy is developed and implemented to synthesize a multi-objective radiation patterns. Parasitic elements can also be associated with other antennas to improve the performances. Two antennas were suggested. The first one represents a wide band circularly polarized directive antenna with parasitic elements. This demonstrator consists of the combination of 18 parasitic dipoles with a logarithmic spiral antenna; this antenna was manufactured and measured. The second antenna is a part of a space project « Isoflux X-Band antenna for Nano-Satellite». This compact antenna has been developed to support transmission rates for future mission.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / In this work the single-step/single-phase synthesis of hybrid organic-inorganic core-shell gold nanoparticles (AuNPs), facilitated by amino-functionalized amphiphilic block copolymers that simultaneously play the roles of reductant and stabilizer, was investigated in this study. Experiments were devised with emphasis on the pH-responsive poly(ethylene oxide)-b-poly(2,3-dihydroxypropyl methacrylate)-b-poly[2-(diisopropylamino)ethyl methacrylate] triblock copolymer, which allows direct chemical cross-linking of the micellar structures to be performed. The polymer structure-reactivity relationship associated with the AuNP formation was established using a set of six structurally related macromolecules. AuNP formation was dependent on the aqueous dissociation equilibrium involving tertiary amino groups, the Au(III) speciation, and electrochemical redox potentials. The effects of these parameters on the synthesis of AuNPs change as the solution pH is increased from pH 3.5 (molecularly dissolved polymer chains; no AuNP formation) to 6.8 or higher (polymer chains self-assembled into spherical micelles; stable gold sols are produced), and Au(III) reduction potentials shift toward the cathodic region whilst the oxidation potential of deprotonated amino groups decreases. Sigmoidal nanoparticle growth kinetics was observed in all cases after a characteristic induction period. Stable, well-defined, uniform polymer-coated gold colloids with localized surface plasmon resonance centered at 530 nm can be conveniently produced in one-pot, two-reactant, no work-up reactions when the stoichiometry is [N]/[Au] = 3.5 - 25.0. / Neste trabalho a síntese em única fase/etapa de nanopartículas de ouro híbridas orgânico-inorgânicas do tipo casca núcleo (AuNPs) facilitadas por copolímeros em bloco anfifílicos funcionalizados com grupos aminos e que simultaneamente atuam como agente redutor e estabilizante foi investigada. Os experimentos foram realizados com ênfase nas respostas frente ao pH do copolímero tribloco poli(óxido de etileno)-b-poli(metacrilato de 2,3-diidroxipropila)-b-poli(metacrilato de 2-(diisopropilamino)etila) e que permite a química direta de reticulação das estruturas micelares. A relação entre estrutura e reatividade do copolímero associada à formação das AuNPs foi estabelecida usando uma série de seis macromoléculas semelhantes aos blocos constituintes do copolímero. A formação das AuNPs é dependente do equilíbrio de dissociação envolvendo grupos aminos terciários, espécies de Au(III) e também do potencial eletroquímico redox. Os efeitos desses parâmetros levam a formação de AuNPs quando da mudança de pH de 3,5 (cadeias poliméricas dissolvidas não formam AuNPs) para pH 6,8 ou maior (polímero auto-organizado em micelas esféricas coloides estáveis de ouro são produzidos), e quando o potencial de redução dos íons Au(III) mudam para a região catódica e o potencial de oxidação dos grupos aminos desprotonados presentes no copolímero diminui. A cinética de crescimentos das AuNPs apresentou em todos os casos perfil sigmoidal após o período de indução característicos da síntese. Coloides de ouro estáveis, bem definidos e estabilizados pelo copolímero com ressonância plasmônica de superfície centrado em cerca de 530 nm foram produzidos em etapa única, dois reagentes, sem reações paralelas na estequiometria [N]/[Au(III)] entre 3,5 e 25.

The master's thesis is devoted to establish optimal parameters produced composites of iron oxide and carbon (FeOx/C) through the physicochemical study of the samples obtained for further use as anode materials of lithium-ion batteries (LIA). This interdisciplinary work was made in the laboratory of chemistry of compounds of rare-earth elements of the The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences as well as with the use of the equipment of the Ural Center for Shared Use «Modern nanotechnologies» of Ural Federal University named after the first President of Russia B. N. Yeltsin. / Магистерская диссертация посвящена установлению оптимальных параметров получения композитов из оксида железа и углерода (FeOx/C) посредством физико-химического исследования полученных образцов для дальнейшего использования в качестве анодных материалов литий-ионных аккумуляторов (ЛИА). Данная работа носит междисциплинарный характер и была выполнена в лаборатории химии соединений редкоземельных элементов ИХТТ УрО РАН, а также с использованием оборудования УЦКП «Современные нанотехнологии» УрФУ им. Б. Н. Ельцина.

This thesis deals with specific learning disabilities on the first level of primary education. The theoretical part is devoted to the definition of the basic concepts, to the etiology of the occurrence of specific learning disabilities and to the classification of their manifestation. It draws up the possibilities of the diagnostics and of the follow-up re-education. It describes the possibilities of educating students with disabilities at basic schools or individually. The practical part of this thesis focuses on exploring the issue of specific learning disabilities on the first level of primary education, namely, in the third and fourth grade. Three case reports whose results most visibly pointed to a problem are also present here.

The diploma thesis deals with teaching elementary reading in our territory. The theoretical part focuses on reading from the past till present. It analyzes methods, that were taught in our territory during the past, and shows their benefits for current methods of teaching elementary reading. It also presents current methods of teaching reading and their methodology. The research part is focused on comparing analytical-synthesis method and genetic method of reading from the viewpoint of reading comprehension, accuracy, fluency and reading speed.