We have developed a probe to measure specific heat of Gd-doped PbMo(_6)S(_8), at low temperatures in high magnetic fields up to 12.5 T using a heat pulse method and an a.c. technique. Comparison between these heat capacity measurements and transport measurements provides critical complimentary information about fundamental thermodynamic properties and granularity m superconductors. We have used a tiny, robust, highly sensitive and broadly field independent Cemox thermometer (CX-1030), eliminating the use of bulky gas thermometry or capacitance thermometry. The diameter of the probe is 20 min which facilitates use in our 17 T high field magnet and in free-standing cryostats. Experiments include accurate measurement of temperature oscillations of 10(^-6)K. The measurements and analysis of the data were made fully computer controlled. Measurements on Cu and NbTi demonstrate we achieved an accuracy of ±0.2 K in temperature and a typical accuracy of -10% m the specific heat values quoted. Gd-doped Lead Chevrel phase material Pb(_1-x)Gd(_x)Mo(_6)S(_8) has been fabricated in a controlled environment using simple sintering methods and a Hot Isostatic Press (HIP) operating at pressures up to 2000 atmospheres. Cp has been measured and the properties of the materials including B(_c2)(T) have been determined. HIP processing improves the materials, increasing Tc ~ 15 K and B(_c2)(0) ~ 60 T. These values are amongst the best reported values for the Chevrel phase materials to date. I am personally responsible for taking all the data and its analysis. The modification of the probe were also undertaken by me. The fabrication of the samples was not my work

A ferromagnetic particle with single domain, at some kinds of applied field (at some angle or strangth), the particle's free energy would be two state model. The rate of barrier crossing could be solve by Fokker-Planck equation .And use master equation to find out the Total rate between two potential well. In this thysis, we use the upper method to simulate particle's magnetic moment under time varying magnetic field at fixed angle or fixed magnetic applied rotate the particle. In numerical method, we use the back Euler method to prevent the divergence of the calculation.

A differential, membrane-based nanocalorimeter has been designed and constructed for thermal studies of mesoscopic samples at low temperatures. The calorimeter is intended for sample masses from mg to sub-μg and a broad temperature range from above room temperature down to the sub-K region. It allows concurrent use of ac steady state and relaxation methods. Effort was spent to achieve good absolute accuracy to enable investigations of the electronic contribution to the heat capacity of superconductors. The calorimeter consists of a pair of cells, each of which is a stack of heaters and thermometer in the center of a silicon nitride membrane, in total giving a background heat capacity less than 100 nJ/K at 300 K, decreasing to 10 pJ/K at 1 K. The device has several distinctive features: i) The resistive thermometer, made of a GeAu alloy, displays a high sensitivity, dlnR/dlnT ≈ −1 over the entire temperature range. ii) The sample is placed in direct contact with the thermometer, which is allowed to self-heat. The thermometer can thus be operated at high dc current to increase the resolution. iii) Data are acquired with a set of eight synchronized lock-in amplifiers measuring dc, 1st and 2nd harmonic signals of heaters and thermometer. iv) Absolute accuracy is achieved via a novel variable-frequency fixed-phase technique in which the measurement frequency is automatically adjusted during ac-calorimetry measurements to account for the temperature variation of the sample specific heat and the device thermal conductance. The properties of the empty cell and the effect of the thermal link between sample and cell were analytically studied. Practical expressions for describing the frequency dependence of heat capacity, thermal conductance, and temperature oscillation amplitude of the system were formulated. Comparisons with measurements and numerical simulations show excellent agreement. Calibration procedures are simple, but care should be taken to minimize thermal radiation effects. The experimental setup is operated with self-regulation of heater powers and thermometer bias, including compensation to zero the differential dc signal. As a result its high resolution and compact format, the calorimeter is well suited for studies of phase transitions and phase diagrams as well as electronic specific heat. The performance of the device is demonstrated by a study of the superconducting state of a small lead crystal. / En differentiell, membran-baserad nanocalorimeter har designats och tillverkats för termiska studier av mesoskopiska prover vid låg temperatur. Kalorimetern är avsedd för provmassor från mg till sub-μg och ett brett temperaturområde från över rumstemperatur till under 1 K. Den tillåter samtidig användning av både ac steady state och relaxations-metod. Fokus har lagts på att uppnå en god absolut noggrannhet för att möjliggöra studier av det elektroniska bidraget till värmekapaciteten hos supraledare. Kalorimetern består av två celler, var och en uppbyggd som en stack med värmeelement och termometer i mitten av ett kiselnitrid-membran, med en total bakgrundsvärmekapacitet på mindre än 100 nJ/K vid 300 K, minskande till 10 pJ/K vid 1 K. Kalorimetern har flera särdrag: i) Den resistiva termometern, gjord av en GeAu legering, visar en hög känslighet, dlnR/dlnT ≈ −1 över hela temperaturområdet. ii) Provet placeras i direkt kontakt med termometern, som tillåts att självvärma. Termometern kan alltså användas vid hög dc ström för att öka upplösningen. iii) Mätningarna genomförs med en uppsättning av åtta synkroniserade lock-in förstärkare, som mäter dc, grundfrekvens och 1:a övertonen hos värme-element och termometer. iv) Absolut noggrannhet uppnås genom en ny variabel-frekvens konstant-fas teknik där mätfrekvensen justeras automatiskt under ac-kalorimetrimätningar för att kompensera temperaturberoendet hos provets specifika värmekapacitet och kalorimetercellens värmeledningsförmåga. Egenskaperna hos den tomma cellen och inverkan av den termiska länken mellan prov och cell studerades analytiskt. Praktiska uttryck för att beskriva frekvens beroendet hos systemets värmekapacitet, värmeledningsförmåga, och temperaturoscillationer har formulerats. Jämförelser mellan mätningar och numeriska simuleringar visar mycket bra överensstämmelse. Kalibreringsförfarandet är enkelt, men försiktighet bör vidtas för att minimera värmestrålningseffekter. Experimentuppställningen drivs med självreglering av värmare och termometer, inklusive kompensation för att nollställa den differentiella dc signalen. Som en följd av dess höga upplösning och kompakta format är kalorimetern väl lämpad för studier av fasövergångar och fasdiagram såväl som det elektroniska specifika värmet. Kalorimeterns prestanda demonstreras genom en studie av det supraledande tillståndet hos en liten blykristall. / At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 5: Accepted.

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O Jateamento com granalha (shot peening, em inglês) é um processo de fabricação amplamente utilizado em indústrias mecânicas, automotivas, navais, aeronáuticas e outras indústrias metalúrgicas. O objetivo principal é induzir tensões residuais de compressão para melhorar a vida à fadiga das peças e estruturas. A modelagem e simulação do processo são muito difíceis, pois envolvem a consideração de muitos e complexos aspectos. Este trabalho propõe um método de modelagem tridimensional utilizando o método dos elementos finitos para a simulação numérica desse processo assim como a sua influência na propagação de trinca, considerando efeitos pouco estudados, como o amolecimento do material devido ao aumento da temperatura na peça durante os impactos, ao comportamento elasto-plástico das granalhas e a rugosidade da peça tratada nos parâmetros da trinca. A modelagem proposta para simular o processo de jateamento com granalhas inclui: (i) análise dinâmica explícita, (ii) modelagem tridimensional, (iii) cálculo da velocidade real das granalhas, (iv) modelo de contato com coeficientes de atrito estático e dinâmico entre as áreas em contato, (v) o modelo constitutivo de Johnson-Cook para o comportamento do material alvo, (vi) um comportamento elasto-plástico multilinear para as granalhas, (vii) a consideração da cobertura real de uma área dada da superfície jateada, (viii) a consideração do aumento da temperatura no material durante o processo e (ix) o relaxamento de tensões residuais devido a este aumento de temperatura. As simulações numérico-computacionais para investigar a influência do processo em fenômenos, tais como fadiga e propagação de trinca, necessitou uma nova abordagem para a incorporação das tensões residuais num modelo de elementos finitos. Além disso, foram realizados vários ensaios quase-estáticos e dinâmicos para a determinação dos parâmetros do modelo constitutivo de Johnson-Cook para o aço AISI 5160. Para a avaliação das metodologias propostas, as tensões residuais foram introduzidas e avaliadas em uma mola parabólica automotiva, sendo que as tensões residuais foram avaliadas através da técnica de difração de raios-X, a intensidade e a cobertura do processo de jateamento com granalha na mola foram avaliadas com Lupa e rugosímetro. Também, dados experimentais de ensaios de fadiga relatados na literatura, realizados em corpos de prova tipo CT foram utilizados. A modelagem numérica do processo de jateamento com granalha desenvolvida neste trabalho consegue prever com sucesso os perfis das tensões residuais, com valores bem próximos aos obtidos experimentalmente. A investigação numérica do efeito do processo na vida à fadiga e fratura das peças comprovou a sua influência nos parâmetros de propagação de trinca nas regiões afetadas pelo processo, ocasionando um amplo aumento da vida à fadiga, e confirmou o relaxamento das tensões residuais devido aos ciclos de carregamento conforme as observações experimentais na literatura. / Shot peening is a manufacturing process widely used in the mechanical, automotive, marine, aeronautical and other metallurgical industries. The main purpose is to induce residual compression stresses to improve fatigue life. The modeling and simulation of the process are very difficult as they involve the consideration of many and complex aspects. This work proposes a three-dimensional modelling method using the finite element method for the numerical simulation of this process as well as its influence on crack propagation, considering little studied effects such as softening of the material due to the increase in temperature in the part during impacts , the elastic-plastic behavior of the shot and the roughness of the treated part in the crack parameters. The proposed modelling approach to simulate the shot peening process includes: (i) explicit dynamic analysis, (ii) three-dimensional modeling, (iii) calculation of the real velocity of the shot, (iv) contact model with static and dynamic friction coefficients between the contact areas, (v) the Johnson-Cook constitutive model for target material behavior, (vi) a multilinear elasto-plastic behavior for the shot, (vii) consideration of real coverage in a given area of the peened surface, (viii) consideration of temperature increase in the material during the process and (ix) relaxation of residual stresses due to this rise in temperature. Numerical-computational simulations to investigate the influence of the shot peening process on phenomena, such as fatigue and crack propagation, required a new approach for the incorporation of residual stress in a finite element model. In addition, several quasi-static and dynamic tests were carried out to determine the parameters of the constitutive Johnson-Cook model for AISI 5160 steel. To assess the proposed methodologies, the residual stresses were introduced and evaluated in an automotive parabolic spring, with the residual stresses being evaluated by the X-ray diffraction technique, the intensity and coverage of the shot peening process for the spring were evaluated with magnifying glass and roughness gauge. Also, fatigue tests available in the literature, carried out on types of CT specimens, were used. The numerical modeling of the shot peening process developed in this work can successfully predict the residual stress profiles, with values close to those obtained experimentally. The numerical investigation of the effect of the process in the fatigue life and fracture of the pieces proved its influence in the parameters of crack propagation in the regions affected by the process, causing a wide increase of the fatigue life, and confirmed the relaxation of the residual stresses due to the cycles loading according to experimental observations in the literature.

DESCRIPTION DES PHENOMENES CITES DANS LES TYPES DE TRANSISTORS SUIVANTS: TRANSISTOR VMOS, TRANSISTOR UMOS, TRANSISTOR HEXFET

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