For an offshore platform structure applied to wave-energy conversion system, in order to catch the maximum waves to generate more powers, similar to wind-energy power generators, a range of angles for the devices normal to the propagating direction of incident waves is required, particularly when the power converting system has directional preference. In this study, an electro-magnetic wave energy conversion device was developed and tested in a single-mooring offshore platform system. In order to find the best design parameters for the electro-magnetic generators system in various wave periods a water-tank experiment was designed and performed. During the experimental study, both wave parameters and dimensional related parameter of the generator were under investigation. It was found in this study that the newly developed wave conversion system can work well under certain periods and height of waves. The relationships between the parameter were presented into figures.

For an offshore platform structure applied to wave-energy conversion system, in order to catch the maximum waves to generate more powers, similar to wind-energy power generators, a range of angles for the devices normal to the propagating direction of incident waves is required, particularly when the power converting system has directional preference. That is one essential reason why a single mooring offshore platform system is so important in the development of an offshore wave-energy conversion system. The single mooring-system would allow the offshore wave-energy conversion system to turn freely in accordance to the action of strong directions of propagating waves and in this way, most energy induced from the incident waves can be caught and converted into reusable powers. The aims of this study are firstly, based on previous studies to further modify a single moored offshore platform system that may subject to less wave forces in the sea and, secondly, to verify the efficiency of single-moored system by carrying out an experimental testing on a simple single-moored floating platform system in the water tank.

Changes in external forcing having traditionally been the main area of interest in trying to understand paleo-depositional environments in sedimentary systems; however, autogenic variability has been rising in importance, while autogenic behavior has been thought of as a “noise” generator. Recently, autogenic variability has been rising in attention because decoupling allogenic signatures (externally driven) from the stratigraphic record requires robust understanding of autogenic variations (internally generated). This study aims to quantitatively measure autogenic processes under a range of flux conditions and to show that autogenic processes generate distinct signatures rather than random noise. We present data from a matrix of nine different tank experiments in order to systematically evaluate the effects of sediment flux and water discharge variations on the autogenic timescale of fluvial sediment storage and release processes and the implications of this data to the stratigraphic record. The sediment flux tow ater discharge ratio and the absolute values of these two discharges control the autogenic timescale. Variations in sediment supply yield two competing effects on the autogenic timescale. The primary sediment flux control causes a reduction in the autogenic timescale as an increase in sediment supply yields an increased rate of filling the “fluvial envelope” (the space between the maximum and minimum fluvial slopes obtained during storage and release events). In contrast, the secondary sediment flux control increases the size of the fluvial envelope and works against the primary sediment flux control. Increasing the water discharge increases the autogenic timescale by widening the fluvial envelope during the organization of the fluvial system and more importantly, diminishes the functionality of the secondary sediment control. A competition exists between these factors, causing a non-linear range of autogenic timescales for a given sediment flux to water discharge ratio. In the nine experiments here, as the ratio decreases, the secondary effects of variations in sediment supply are suppressed by the relatively high water discharge, and the timescale is more predictable using the primary sediment control. As the ratio increases, the secondary effects from sediment supply are enhanced by a poorly organized fluvial system, and the timescale converges to a narrow range. This suggests significant implications for autogenic sediment delivery and stratigraphic development in a wide range of discharge conditions in field cases. / text

This research is about the development of a photocatalytic reactor design, Honeycomb, for in-situ groundwater remediation. Photocatalysis, typically a pseudo first order advanced oxidation process, is initiated via the illumination of UVA light on the catalyst, i.e. titanium dioxide (TiO2). In the presence of oxygen, highly reactive oxidising agents are generated such as superoxide (O2-), hydroxyl (OH.-) radicals, and holes (hvb+) on the catalyst surface which can oxidise a wide range of organic compounds. The target contaminant is methyl tert butyl ether (MTBE), a popular gasoline additive in the past three decades, which gives the water an unpleasant taste and odour at 20 μg L-1, making it undrinkable. This research consists of three major parts, i.e. (i) establishing a suitable catalyst immobilisation procedure, (ii) characterisation and evaluation of reactor models and (iii) scale up studies in a sand tank. TiO2 does not attach well onto many surfaces. Therefore, the first step was to determine a suitable immobilisation procedure by preparing TiO2 films using several potential procedures and testing them under the same conditions, at small scale. The coatings were evaluated in terms of photocatalytic activity and adhesion. The photocatalytic activity of the coatings was tested using methylene blue dye (MB), which is a photocatalytic indicator. A hybrid coating, which comprises a sol gel solution enriched with Aeroxide TiO2 P25 powder, on woven fibreglass exhibited the best adhesion and photocatalytic activity among samples evaluated. Thus, it was used to produce immobilised catalyst for this research. Consequently, the immobilisation procedure was scaled up to synthesize TiO2 coatings for the potential photocatalytic reactor design. The photocatalytic activity of the coatings produced from the scaled up immobilisation procedure were reasonably comparable to that produced at small scale. Due to the UVA irradiation and mass transfer limitations, photocatalytic reactors are typically compact in order to maximise their efficiency to accommodate high flows, particularly in water and wastewater treatment. In the case of groundwater, however, the treatment area can span up to meters in width and depth. Groundwater flow is significantly lower than that of water treatment, as the reactor design does not need to be compact. Considering both factors, a photocatalytic reactor design of hexagonal cross-section (Honeycomb) was proposed, in which the structures can be arranged adjacent to each other forming a honeycomb. A model was constructed and tested in a 4 L column (cylindrical) reactor, using the MB test to characterise the reactor performance and operating conditions. This was followed by a hydraulic performance study, which encompasses single and double pass flow studies. The single pass flow study involves the photocatalytic oxidation (PCO) of MB and MTBE, while the double pass flow study was focused on the PCO of MTBE only. The double pass can simulate two serially connected reactors. Single pass flow studies found that the critical hydraulic residence time (HRT) for the PCO of MB and MTBE is approximately 1 day, achieving up to 84 % MTBE removal. Critical HRT refers to the minimum average duration for a batch of contaminant remaining in the reactor in order to maintain the potential efficiency of the reactor. Double pass studies showed the reactor can achieve up to 95 % MTBE removal in 48 hours, and that reactor performance in the field of serially connected reactors can be estimated by sequential order of single pass removal efficiency. In groundwater, there are likely to be other impurities present and the effects of groundwater constituents on the reactor efficiency were studied. The MTBE PCO rate is affected by the presence of organic compounds and dissolved ions mainly due to the competition for hydroxyl radicals and the deactivation of catalyst surface via adsorption of the more strongly adsorbed organic molecules and ions. Despite the presence of organic compounds and dissolved ions, the reactor achieved about 80 % MTBE removal in 48 hours. A double pass flow study showed that the overall efficiency of the photocatalytic reactor in the field can be estimated via sequential order of its efficiency in a single pass flow study using the actual groundwater sample in the laboratory. A sand tank was designed for the simulation of the clean up of an MTBE plume from a point source leakage using the 200 mm i.d. Honeycomb I prototype. Honeycomb I achieved up to 88.1 % MTBE removal when the contaminated groundwater flowed through (single pass) at 14.6 cm d-1. The critical HRT for Honeycomb I was also approximately 1 day, similar to that in the column reactor. The response of MTBE removal efficiency towards flow obtained in the column reactor and sand tank was generic, indicating that the reactor efficiency can be obtained via testing of the model in the column reactor. The presence of toluene, ethylbenzene and o-xylene (TEo-X) decreased the MTBE removal efficiency in both the sand tank and column reactor. The same set of catalyst and 15 W Philips Cleo UVA fluorescent lamp was operated for a total of about 582 h (24 d) out of the cumulative 1039 h (43 d) sand tank experiments, achieving an overall MTBE removal efficiency of about 76.2 %. The experiments in the column reactor and sand tank exhibited the reliability of the immobilised catalyst produced in this research. This research demonstrates the potential of Honeycomb for in-situ groundwater remediation and also proposes its fabrication and installation options in the field.

Submitted by Morgana Andrade (morgana.andrade@ufes.br) on 2016-03-22T17:05:04Z No. of bitstreams: 2 license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) Pedro Henrique Bonfim Pantoja.pdf: 1965227 bytes, checksum: c6e11a3e91300bad3c95be08b469415f (MD5) / Approved for entry into archive by Patricia Barros (patricia.barros@ufes.br) on 2016-03-23T14:21:49Z (GMT) No. of bitstreams: 2 license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) Pedro Henrique Bonfim Pantoja.pdf: 1965227 bytes, checksum: c6e11a3e91300bad3c95be08b469415f (MD5) / Made available in DSpace on 2016-03-23T14:21:49Z (GMT). No. of bitstreams: 2 license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) Pedro Henrique Bonfim Pantoja.pdf: 1965227 bytes, checksum: c6e11a3e91300bad3c95be08b469415f (MD5) / Neste trabalho, apresenta­se uma solução para equação de difusão­advecção considerando o  termo  contragradiente  que  é um termo  adicional. Esse termo  adicional  contém informações  sobre a assimetria, escala de tempo Lagrangeana e velocidade turbulenta vertical. A solução  da equação foi obtida pela utilização da técnica de Transformada de Laplace, considerando a  Camada  Limite  Planetária  (CLP)  como  um  sistema  de  multicamadas.  Os  parâmetros  turbulentos foram derivados da teoria de difusão estatística de Taylor, combinada com a teoria  da similaridade. Assim, são apresentadas simulações para diferentes valores de assimetria, o  que  propiciou  a  obtenção  de  uma  concentração  de  contaminantes  em  diferentes  alturas,  em  uma  camada  limite  convectiva.  A  avaliação  do  desempenho  do  modelo,  considerando  a  assimetria  no  processo  de  dispersão  de  poluentes  atmosféricos, foi realizada  através  de  um  experimento  de  tanque  convectivo  tradicional.  Nesse  experimento,  o  termo  contragradiente  influenciou a concentração de poluentes para uma camada limite convectiva. Entretanto, com  as  parametrizações  utilizadas,  o  modelo  não  conseguiu  captar  de  forma  eficiente  o  comportamento da concentração em pontos mais distantes da fonte. / In this paper presents a solution to the advection­diffusion equation considering the term is an  additional  term  countergradient.  This  additional  term  contains  information  asymmetry,  Lagrangian  time  scale  and  vertical  turbulent  velocity.  The  solution  of  the  equation  was  obtained  by  using  the  technique  of  Laplace  transform,  considering  the  planetary  boundary  layer (PBL)  as  a multilayer system. The  turbulent  parameters were  derived from statistical  distribution  theory  Taylor,  combined  with  the  theory  of similarity.  Hence,  Simulations  for  different  values  of  asymmetry, which  allowed to  obtain  a  concentration  of  contaminants  at  different  heights  in  a  convective  boundary  layer  is  displayed.  The  evaluation  of  model  performance,  considering  the  asymmetry  in  the  dispersion  of  air  pollutants  process  was  conducted  through  an  experiment  of  traditional  convective  tank.  In  this  experiment,  the  countergradient  influenced  the  concentration  of  pollutants  in  a  convective  boundary  layer.  However, with the parameterizations used, the model failed to capture efficiently the behavior  of concentration at points further away from the source.

The terminations and the joints are the basic accessories of the power cables. Power cables require electrical stress control when terminated. Since there are different types of terminations, the analysis should be done to choose the proper method for electric field control problem at the terminations. Throughout this study two different types of termination methods are investigated by using the finite element analysis program (ANSYS): Stress Controlled Termination Model with Deflector and Stress Control Tube (SCT). The results are compared with those obtained for a cable without stress control model termination. The numerical calculations are also compared with the measurements obtained by an experimental model: the electrolytic tank model.

The main objective of wave energy converters (WECs) is to ensure reliable electricity production at a competitive cost. Two challenges to achieving this are ensuring an efficient energy conversion and offshore survivability.         This thesis work is structured in three different sections: Control and maximum power optimization, forces and dynamics analysis in extreme wave conditions, and statistical modeling of extreme loads in reliability analysis.        The need for prediction and future knowledge of waves and wave forces is essential due to the non-causality of the optimal velocity relation for wave energy converters. Using generic concepts and modes of motion, the sensitivity of the prediction horizon to various parameters encountered in a real system is elaborated. The results show that through a realistic assumption of the dissipative losses, only a few seconds to about half a wave cycle is sufficient to predict the required future knowledge for the aim of maximizing the power absorption.          The results of a 1:30 scaled wave tank experiment are used to assess the line force and dynamic behaviour of a WEC during extreme wave events. Within the comparison of different wave type representations, i.e. irregular, regular and focused waves, of the same sea state, the results show that not all the wave types deliver the same maximum line forces. As a strategy of mitigating the line forces during extreme wave events, changing the power take-off (PTO) damping may be employed. With consideration of the whole PTO range, the results indicate an optimum damping value for each sea state in which the smallest maximum line force is obtained. Although wave breaking slamming and end-stop spring compression lead to high peak line forces, it is possible that they level out due to the overtopping effect. Waves with a long wavelength result in large surge motion and consequently higher and more damaging forces.         On the investigation of reliability assessment of the wave energy converter systems, computing the return period of the extreme forces is crucial. Using force measurement force data gathered at the west coast of Sweden, the extreme forces are statistically modelled with the peak-over-threshold method. Then, the return level of the extreme forces over 20 years for the calm season of the year is computed.