Velocity tomography is a noninvasive technique that can image the interior of a rock structure. To apply tomography to rock specimens, a propagation wave, which acts as a probe, is used. The propagation wave propagates from a source until it reaches a sensor on the surface of the rock specimen. Tomograms can then be generated from the velocity distribution within the rock structure. Areas of higher velocity are typically representative of higher stress concentrations, whereas areas of low velocity can be areas of fracturing. The variation of velocity tomography described in this thesis uses acoustic emissions as sources for the propagation wave. Acoustic emission sources provide advantages over mechanical sources, since the acoustic emission source is generated by the rock as a result of deformation and fracturing. Velocity tomography of rock structures in the field has numerous applications and advantages. Velocity tomography can be used to monitor rock structures surrounding tunnels and underground openings such as mines. To monitor the rock structure, velocity tomography is used to determine areas of higher stress concentration that may be precursors to rock failure. However, velocity tomography must first be used in a laboratory environment to determine failure in rock samples before being applied to the field. The research presented includes the unconfined compression strength testing of 19 Berea sandstone samples. These samples were loaded to failure and during the experiment the acoustic emission events within the samples were monitored using a commercial acquisition system manufactured by Engineering Seismology Group (ESG) Canada. Source location software, also produced by ESG, was used for the location of the acoustic emission events. Ray inversions were performed on the data from the experiments to generate tomograms. The tomograms generated display the p-wave velocity distribution imaged within the Berea sandstone samples with the ultimate goal of being able to predict rock failure. Based on the experiments discussed in this thesis it can be inferred that velocity tomography is a useful tool for imaging the inside of the Berea sandstone samples. Precursors of rock failure could not be determined in this early stage of research. However, the tomograms do image the p-wave velocity distribution and do show a gradual progression of the p-wave velocity from the initial velocity model to higher velocities. Results of these 19 experiments do provide reasonable confidence in the method and warrant pursuit of further research to refine and improve this method of monitoring velocity tomography. / Master of Science

Clay stabilizers are means to prevent fines migration and clay swelling, which are caused by the contact of formation with low salinity or high pH brines at high temperature. Previous clay stabilizers including: Al and Zr compounds and cationic polymers have several drawbacks. Al and Zr compounds can be removed by acids. Cationic polymers can cause formation damage in some cases. Quaternary amine-based chemicals have been used for many years as clay stabilizer, however, environmental profile of some has limited their use. There is a need to develop new clay stabilizers that can work following acid treatment and are environmentally acceptable. Laboratory studies were conducted on newly developed Al/Zr-based compound (Stabilizer A) to determine the optimum conditions for field application. Zeta potential was used to determine surface charge of different types of clays; and to optimize clay stabilizer concentration. Coreflood experiments were conducted on Berea and Bandera sandstone cores to assess the effectiveness of the new compound at high temperature, and determine the impact of acids on its performance. Also the effectiveness of this stabilizer was investigated at high pH medium and in low permeability cores. Inductively Coupled Plasma was used to measure the concentrations of e key cations in the core flood effluent. Three different commercial clay stabilizers (zirconium oxychloride, choline chloride and tetramethyl ammonium chloride) were also tested to validate the new chemical. The new clay stabilizer was very effective in mitigating fines migration. Zeta potential indicated that the isoelectric point at which complete shields of surface charge of clay particles was achieved at a stabilizer concentration of 0.2 wt%. Coreflood tests showed that this new chemical was effective, and unlike previous Al-based and Zr-based stabilizers (hydroxy aluminum and zirconium oxychloride solutions), it did not dissolve in acids and worked very well up to 300oF. Stabilizer A proved to be better than the three commercial stabilizers. Stabilizer A worked effectively at the high pH and no reduction in permeability was noticed after NaOH injection, unlike the other stabilizers. In addition, Stabilizer A is an inorganic-based fluid, environmentally friendly, in contrast to Quaternary amine chemicals.

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The fundamental forces of adhesion are responsible for the spreading of fluids such as crude oil/brine on the reservoir rock surface. These physico-chemical interactions determine the surface energetics of a reservoir and thus their wetting phenomena. Inverse Gas Chromatography is introduced to characterize the surface energy of carbonates (calcite and dolomite) and sandstones (Ottawa sand and Berea sandstone). The behavior of the polar and non-polar interaction forces was investigated at varying water coverage and at different temperatures. The results indicated that in general as the water coverage increased, the Lifshitz-van der Waals component of surface energy decreased to nearly that of the bulk water, while the acid-base component also showed a decreasing trend. The Lifshitz-van der Waals component of surface energy always decreased with increase in temperature, while the acid-base properties mostly increased with temperature with the exception of calcite. / text

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