Στις ηλεκτρικές μηχανές η θερμική ανάλυση είναι εξίσου σημαντική με την ηλεκτρομαγνητική ανάλυση, διότι η θέρμανση μίας μηχανής είναι αυτή που τελικά οριοθετεί την ονομαστική ισχύ της. Ακριβής θερμική μοντελοποίηση της μηχανής απαιτείται για την επίτευξη υψηλής απόδοσης, την ορθή σχεδίαση, την επιλογή των υλικών και του τρόπου ψύξης και τη βελτιστοποίηση κόστους. Στόχος της παρούσας διπλωματικής εργασίας είναι η μελέτη των απωλειών, ο υπολογισμός της παραγόμενης θερμότητας και η εύρεση της κατανομής θερμοκρασίας στο εσωτερικό ενός ασύγχρονου κινητήρα στη μόνιμη κατάσταση λειτουργίας του με τη μέθοδο των πεπερασμένων στοιχείων. / Thermal analysis of electrical machines is as important as electromagnetic analysis, since the machine heating actually determines the nominal power of the machine. Accurate thermal modelling is necessary in order to achieve high performance, proper design, cost optimization and selection of the most suitable materials and cooling method. The goal of this project is the study of power losses and the calculation of the produced heat and temperature distribution inside an induction motor, which operates at steady state, using the finite element method.

The elemental composition of the samples of modern and archaeological ceramics was determined using the energy dispersive X-ray analysis, flame atomic absorption spectrometry, titrimetric and spectrophotometric analysis methods. It has been shown that the qualitative and quantitative composition of all the samples is different. It has been established that silicon and aluminium are the main elements in all the samples. SiO2 accounts for 46–60 % of the composition of the ceramics, Al2O3 – for some 17–33%. The amounts of Fe, Na, Mg, K, Ca and Ti discovered in the samples are several times lesser. EDX analysis can successfully be used in determining the main elements whose amounts exceed 0.5% of the overall elemental composition. In order to determine the exact composition of ceramics one has to employ the FAAS analysis method. To determine in a credible manner the amount of aluminium in ceramics, one can use the titrimetric method, and the amount of silicon and titanium – spectrophotometric methods. Upon examination of the modern and archaeological ceramics by diffraction analysis it has been established that the main phase of all the samples is the same – quartz SiO2, however their phase composition varies. In different samples the following phases have been discovered: calcite, dolomite, kaolinite, albite, microcline, muscovite, mullite, hematite, rutile, diopside, corundum, titanite, and sodium anorthite. Being aware of the phase composition, it has been established that the... [to full text] / Šioje daktaro disertacijoje pirmoje dalyje nustatyta šiuolaikinės, o antroje dalyje – archeologinės keramikos gaminių elementinė ir fazinė sudėtis, bei ištirta morfologija. Šiuolaikinės ir archeologinės keramikos pavyzdžių elementinė sudėtis nustatyta Rentgeno spindulių dispersinės analizės (EDX), liepsnos atominės absorbcinės spektrometrijos (LAAS), titrimetrinės ir spektrofotometrinės analizės metodais. Parodyta, kad visų keraminių pavyzdžių kokybinė bei kiekybinė sudėtis yra skirtinga Nustatyta, kad visuose keramikos mėginiuose pagrindiniai elementai yra silicis ir aliuminis. SiO2 sudaro 46 – 60% keramikos sudėties, Al2O3 – apie 17 – 33%. Fe, Na, Mg, K, Ca ir Ti mėginiuose rasta kelis kartus mažiau. EDX analizė gali būti sėkmingai naudojama nustatant pagrindinius elementus, kurių kiekiai viršija 0,5 % bendros elementinės sudėties. Norint nustatyti tikslią keramikos sudėtį ir pėdsakinius elementus reikia naudoti LAAS analizės metodą. Aliuminio kiekį keramikoje patikimai galima nustatyti titrimetriniu, o silicio ir titano kiekį – spektrofotometriniais metodais. Ištyrus šiuolaikę ir archeologinę keramiką Rentgeno spindulių difrakcine analize (XRD), nustatyta, kad visų keramikų pagrindinė fazė yra vienoda – silicio dioksidas SiO2, tačiau jų bendra fazinė sudėtis skiriasi. Skirtinguose kermikos pavyzdžiuose buvo aptikos šios fazės: kvarcas, dolomitas, kaolinas, albitas, mikroklinas, muskovitas, mulitas, hematitas, rutilas, diopsidas, korundas, titanitas, natrio anortitas... [toliau žr. visą tekstą]

Relative densities and heat capacity ratios have been measured for selected aqueous systems. These measurements have been used to calculate apparent molar volumes and heat capacities. Densities of aqueous sodium bromide have been measured from 374 to 522 K and 10.00 to 30.00 MPa using a recently developed high temperature and pressure vibrating tube densimeter. These data have been used to test the utility of an automated high temperature and pressure densimetric data analysis program. Apparent molar volumes and heat capacities of several aqueous rare earth sulphate systems at 298.15 K and 0.10 MPa have been reported, and discussed in terms of ionic contributions. Single ion partial molar volumes and heat capacities for aqueous trivalent rare earth species have been estimated in a review of apparent molar data from the literature and through the use of semi-empirical Debye-Huckel equation. These singles ion properties have subsequently been used to estimate the single ion properties of the monosulphate and disulphate rare earth complex species. Rigorous relaxation calculations are presented in a discussion of apparent molar heat capacities, where relaxation contributions are shown to be negative. Apparent molar volumes and densities for aqueous L-histidine, L-phenylalanine, L-tyrosine, L-tryptophan, and L-dopa have been used to estimate reported partial molar properties have been added to several reported properites for other amino acids and peptides to construct an additivity scheme that utilises the revised Helgeson, Kirkham, and Flowers (HKF) equations of state for neutral organic species. A volumetric study of aqueous glycine, L-serine, and glyclylglycine has been conducted at temperatures from 298 K to 423 K and pressures from 0.10 to 30.00 MPa. These data have been used to evaluate HKF coefficients in a discussion of peptide stability at elevated temperatures and pressures. / xvii, 220 leaves : ill. ; 28 cm.

This thesis was concerned with the proof of concept for mid-grade, 250-500oC, industrial waste heat recovery using a thermally regenerative electrochemical system. Proposed thermally regenerative electrochemical systems are limited to high operating temperatures (> 900oC) and suffer from poor conversion efficiencies (< 20%). As such, a single chamber design that is free of moving parts was presented in this work. The concept for this novel regenerative system relies on gravity and a liquid medium to convey dissolved sodium hydride in a hydride-borohydride solution from cold to hot regions in a continuous circuit. Such a liquid transport medium could allow for operation below 500oC while stabilizing the hydride from thermal decomposition. Investigations on this system were carried out using a custom pressure differential thermal analyzer that was able to operate above temperatures of 700oC and pressures of 2.2MPa. The results of the experiments provided valuable information concerning the phase diagrams of various hydride-borohydride mixtures. The eutectic composition of the NaH-KBH4 system was found to be 43 mole% NaH. The corresponding eutectic temperature (503oC) was determined using the differential cooling curves. Appreciable NaH decomposition was noticed in mixtures above 59.0 mole% NaH. Mixtures up to 42.5 mole% KH in KBH4 were also investigated. The eutectic composition of the KH-KBH4 binary system was determined by extrapolating the liquidus curve to intersect the solidus curve. The KH-KBH4 eutectic temperature was found to be 390oC at 66 mole% KH. The experimental work successfully demonstrates that thermally unstable hydrides can be obtained in the liquid phase below their melting points, under moderate pressures, when mixed with alkali borohydrides. This significantly lowers the achievable operating temperature of the thermally regenerative electrochemical systems currently proposed. The use of the single chamber design with a hydride-borohydride liquid medium offers numerous advantages including: reduced maintenance, reduced operating temperature, reduced system weight, reduced parasitic losses, increased voltage, and increased reliability. The viability for mid-grade industrial waste heat recovery requires construction of a prototype which optimizes power outputs and explores the hydrodynamic transport of material. / Thesis (Master, Mining Engineering) -- Queen's University, 2009-09-24 14:33:22.627

The Loop Heat Pipe (LHP) is a passive, two-phase heat transfer device used, most commonly, for thermal management of aerospace and aeronautical electronic equipment. A unique feature is a porous wick which generates the necessary capillary action required to maintain circulation between the heat source and the heat exchanger. What differentiates LHP devices from traditional heat pipes, which also work through the use of a wick structure, is the constrained locality of the wick, placed solely in the evaporator, which leaves the remainder of the piping throughout the device as hollow. This provides the LHP with a number of advantages, such as the ability to transport heat over long distances, operate in adverse gravitational positions and to tolerate numerous bends in the transport lines. It is also self-priming due to the use of a compensation chamber which passively provides the wick with constant liquid access. These advantages make LHPs popular in aerospace and aeronautical applications, but there is growing interest in their deployment for terrestrial thermal management systems. This research had two aims. Firstly, to create and validate a robust mathematical model of the steady-state operation of an LHP for terrestrial high heat flux electronics. Secondly, to construct an experimental LHP, including a sintered porous wick, which could be used to validate the model and demonstrate the aforementioned heat exchange and gravity resistant characteristics. The porous wick was sintered with properties of 60% porosity, 6.77x10-13 m2 permeability and an average pore radius of 1μm. Ammonia was the chosen working fluid and the LHP functioned as expected during horizontal testing, albeit at higher temperatures than anticipated. For safety reasons the experimental LHP could not be operated past 18 bar, which translated into a maximum saturated vapour temperature of 45°C. The heat load range extended to 60 W, 50 W and 110 W for horizontal, gravity-adverse and gravity-assisted operation respectively. Because of certain simplifying assumptions in the model, the experimental results deviated somewhat from predicted values at low heat loads. Model accuracy improved as the heat load increased. The experimental LHP behaved as expected for 5° and 10° gravity-assisted and gravity-adverse conditions, as well as for transport line variation, in which performance was assessed while the total tubing length was increased from 2.5 m to 4 m. Overall, the construction of the LHP, particularly of the porous wick, its operation and the modeling of the constant conductance mode of operation proved to be successful. The variable conductance mode of operation was not accurately modeled, nor was expected behaviour in the elevation testing encountered, although the reasons for these results are suggested. / Thesis (M.Sc.Eng.)-University of KwaZulu-Natal, Durban, 2013.

In the past decades, a great variety of model fitting and model free (isoconversional) methods have been developed for extracting kinetic parameters for solid state reactions from thermally stimulated experimental data (TGA, DSC, DTA etc.). However, these methods have met with significant controversies about their methodologies. Firstly, model-fitting methods have been strongly criticized because almost any reaction mechanism can be used to fit the experimental data satisfactorily with drastic variations of the kinetic parameters, and no good criterion exists to tell which mechanism is the best choice. Secondly, previous model free methods originated from the isoconversional principle, which is often called the basic assumption; previous studies comparing the accuracy of model free methods have not paid attention to the influence of the principle on model free methods and, therefore, their conclusions are problematic. This work gives, firstly, a critical study of previous methods for evaluating kinetic parameters of solid state reactions and a critical analysis of the isoconversional principle of model free methods. Then an analysis is given of the invariant kinetic parameters method and recommends an incremental version of it. Based on the incremental method and model free method, a comprehensive method is proposed that predicts the degree of the dependences of activation energy on heating programs, and obtains reliable kinetic parameters. In addition, this work also compares the accuracy of previous methods and gives recommendations to apply them to kinetic studies.

For semiconductor processors temperature increases leakage current, which in turn in- creases the temperature of the processor. This increase in heat is seen by other parts of the processor since heat is diffusive across a processor die. In this way, cores are thermally coupled to one another such that when the temperature of one core increases, the temperatures of all cores on the same die can also increase. This increase in temperature and power consumption is not accompanied by any increase in performance. Cores on a chip can also be performance coupled to one another since cores can share data between them. These interactions between cores present new challenges to microarchitects who seek to optimize the energy consumption of a chip multiprocessor (CMP) comprised of multiple symmetric or asymmetric processing cores. This thesis seeks to understand and model the impact of thermal coupling effects between adjacent cores in a chip multiprocessor starting with measurements with a commercial multi-core processor. The hypothesis is that the thermal coupling of compute cores will be influenced by the adjacent core’s performance characteristics. Specifically, we expect thermal coupling is related to the nature of the workloads, e.g. compute intensive workloads will increase coupling over memory intensive workloads. However, we find that simpler parameters such as frequency of operation have more impact on coupling behaviors than the workload behaviors such as memory intensity or instruction retirement rates. A model is developed to capture thermal coupling effects and enable schemes to mitigate its impact.

A series of AlSi9Mg alloys were prepared and tested to reveal the effect of addition sequence and timing of grain refiner and eutectic modifier. AlSr10 master alloy was used as an modification reagent, and also for grain refiner AlTi5B master alloy was used. The depression at the eutectic temperature due to the addition of modifier and decrease in the amount of undercooling at the liquidus due to the presence of grain refiner were examined by the cooling curves which were obtained by the Alu-Therm instrument, which is the aluminum thermal analyzer of the Heraeus Electro-Nite. The alloys that were both modified and grain refined were subsequently poured as tensile test specimen shapes in permanent die casting mould for four times at 60 minutes time intervals, meanwhile thermal analysis of the alloys were also made. In this work the effect of grain refinement and modification agent, also the determination of the optimum time to pour after adding these agents were studied by aluminum thermal analyzer. The parameters obtained from this analyzer are compared with the microstructures / to see the effect of these agents on mechanical properties, hardness, tensile strength and percent elongation values were investigated. In this study the possibility of predicting the mechanical properties prior to casting by thermal analysis method was examined by regression analysis method. By this method relationship between thermal analysis parameters and mechanical properties was established.

This work presents the novel applications of heated AFM tip in nanolithography. Different strategies were investigated for patterning materials using heated AFM tip. New materials were developed for these new nanolithography methods. Simulation and modeling work was done to further understand the heat transfer and chemical reactions involved in the thermal writing process. The selective thermal decomposition of polymer was the first thermal patterning method we¡¯ve investigated. A couple of different sacrificial polymers were used as the writing materials. Among these materials, the cross-linked amorphous polycarbonate (CPC-IV) was the best material for this application. The effect of cross-linking density on the performance of the material was investigated. A novel 3D thermal writing technology was developed by using cross-linked polymer as the writing material. A combined method utilizing the heated cantilever probe to pattern a polymer masking layer that can serve as a template for area selective atomic layer deposition techniques was developed. Another thermal probe nanolithography method, thermal probe top surface imaging, was also developed. In this method, the heated AFM tip was used to generate functional groups on the polymer surface, and ALD was used to selectively deposit TiO2 on the surface where contains those functional groups. A new poly (hydroxyl styrene) based copolymer was developed for this method. We also investigated self assembly monolayers (SAMs) as the thermal writing material. Two different SAMs were investigated. One the APTES and the other one is THP-MPTES. We demonstrated that the APTES can be patterned using thermal AFM probe, and other materials can be selectively deposited on the patterned APTES SAMs. Thermal AFM probe was used to selectively generate thiol groups from THP-MPTES SAMs, and then use these thiol groups to guide the deposition AuNPs. Some simulation and modeling works were also done to further understand these processes. FemLab was used to analyze the heat transfer in the thermal cantilever and between the heated tip and substrate. Based on kinetics of polymer thermal decomposition, we built a simple model for the selective thermal decomposition nanolithography. The experimental results can be very well fitted by this model.

We conduct a comprehensive and systematic study of the Fermi-Pasta-Ulam (FPU) model using both equilibrium and non-equilibrium molecular dynamics simulations, with the aim being to explain the cause of the anomalous energy-transport behaviour in the model. In the equilibrium scenario, our motivation stems from the lack of a complete understanding of the effects of initial conditions on the energy dissipation among Fourier modes. We also critically reconsider the ????probes' that had been widely used to quantitatively describe the types of energy sharing in a system, and then decide on a preferred choice to be used in our equilibrium study. We establish, from strong numerical evidence, that there exists a critical energy density of approximately 0:1, above which the energy dissipation among the modes becomes independent of initial conditions and system parameters, and that the full equipartition of mode energy is never attained in the FPU model. We report, for the first time, the violation of particle positions in the FPU model at high energies, where the particles are found to pass through one another. In the non-equilibrium scenario, we critically review the Nos???Se-Hoover algorithm thermostatting method largely used by other works, and identify its weaknesses. We also review some other alternative methods and decide on the most appropriate one to be implemented throughout our work. We confirm the divergence of the thermal conductivity of the FPU model as the chain length increases, and that kfpu [symbol] No.41, in agreement with other works. Our study further shows that there exists an upper limit of the anharmonicity in the FPU model, and that any attempt to increase the strength of this anharmonicity will not succeed. We also introduce elastic collisions into the original FPU model and find that the Modified model (FPUC) still exhibits anomalous thermal conductivity. We conclude that a one-dimensional FPU-type model with ????only' nearest-neighbour interaction, regardless of being soft or hard, does not exhibit a finite thermal conductivity as the system size increases, due to the non-chaotic nature of its microscopic dynamics, the origin of which we are unable to account for. Finally, we briefly outline possible research directions.