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This thesis examines the prediction of opposed flow flame spread in the Fire Dynamics Simulator version 4 (FDS4) Computational Fluid Dynamics (CFD) model by adapting the Lateral Ignition Flame Transport (LIFT) test procedure. It should be noted that FDS4 was all that was available at the time of the analysis despite FDS5 is now available for beta testing. This research follows on from previous work where LIFT experiments were conducted for various New Zealand timber and timber based products; those materials include Beech, Macrocarpa, Radiata Pine, Rimu, Hardboard, Medium Density Fibreboard (MDF), Melteca faced MDF, Plywood and Particle Board. The objective of this research is to investigate the accuracy of flame spread modelling in FDS4; where the prediction of opposed flow flame spread parameters from FDS4 were directly compared with the experimental results that were obtained experimentally. The standardised procedure for determining the material ignition and flame spread properties was followed and applied to simulate the LIFT test. The LIFT test apparatus was set up in FDS4 with a domain size of 0.9 x 0.3 x 0.3 metres in the x, y and z directions respectively. From the heat flux distribution along the calibration specimen, it indicated that calibration of the LIFT apparatus can be executed in FDS4 where the percentage error is within 1.2%. This report also provides the thermal transport properties (i.e. thermal conductivity and specific heat capacity) of the tested New Zealand timber and timber based products. These were determined using a transient plane source technique and subsequently these properties were entered as the surface identifications in FDS4. The ignition tests were not performed as part of the simulated LIFT test since a direct comparison with the results was required to give a more meaningful assessment. For this reason, the ignition parameters that were obtained from the previous experiments were employed to carry out the flame spread test. Due to the concept of a preheat time required by the standard test method and FDS4 being not able to preheat specimens, the temperature immediately after the preheat time was calculated and implemented for the specimens. The heat transfer problem was solved using an explicit method; where specimens were divided into 11 different nodes. Different scenarios were investigated to see the effect that the selected combustion model has on modelling flame spread. The two analytical models tested were (1) thermoplastic fuels and (2) charring fuels model. Furthermore, the flame spread was visualised using either the Mixture Fraction or the HRRPUV model in Smokeview; where the rate of flame spread for each specimen was obtained. And lastly, three different absorption coefficients (0.6, 0.7 and 0.8) for each specimen were examined; this parameter contributed significantly to the rate of flame spread as it determines the amount of heat flux being absorbed by the specimen during the time of preheating. A study of the grid size was also performed to investigate the accuracy of the FDS4 simulations with the grid size selected. It has been found that increasing the size of the grid cell does not greatly affect the flame spread results. Moisture content and heat of vaporisation input variables were also examined. From the flame spread data, moisture content does not have a significant role in modelling flame spread. However, it was indicated that the heat of vaporisation has an effect on the output of the flame spread parameters. It was determined from the sensitivity analysis that the most appropriate solid boundary condition to be used in predicting the flame spread would be thermoplastic fuels model with an absorption coefficient of 0.8. By using this scenario as the basis, the plot of the arrival time against the distance along the specimen exhibits a similar trend of flame spread with the experimental results at first, but later on, the extinction of flame front actually occurred at a much earlier stage than the experimental results showed. In general, the analyses showed that FDS4 cannot perform the LIFT test where the prediction of flame heating parameter and minimum heat flux for spread were out by more than 20% shown by the direct comparison between experimental results. However, the prediction of minimum heat flux required for ignition seems to agree with the experimental results where the percentage error is within 20%.

Ionic liquids (ILs) are liquid organic salts at room temperature which are composed of only ions (cations and anions). Ionic liquids are regarded as “novel solvents” and have been gaining attention as alternatives to volatile molecular organic solvents. Ionic liquids have outstanding properties, such as negligible vapor pressure (no or limited evaporation or volatilization), low melting point, thermal stability, and ionic conductivity. They can be used in efficient and clean energy production and storage. The synthesis of the low-cost and performance-effective ionic liquids using inexpensive raw materials is presented and characterized. Characterization was done using Thermogravimetric Analysis (TGA), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Differential Thermometry (DSC-TGA). Cost effective ionic liquids were synthesized and characterized and then compared to commercially available ionic liquids. Results for newly synthesized ionic liquids suggest that these cost effective ionic liquids were electroconductive and thermally stable when compared to the raw materials used for synthesis of ionic liquids. The thermal stability of these ionic liquids was less, however, when compared to the regular higher cost ionic liquids. FTIR characterization also provided secondary evidence on expected functional groups of newly synthesized ionic liquids. Viscosity of the syntehsized ionic liquids was higher when comapred to the commercially avaialable ionic liquids.

The Shu Shu thermal springs are located in central KwaZulu-Natal in South Africa at an altitude of 250m above mean sea level at the bottom of the Tugela Valley. They have been investigated in an attempt to ascertain whether or not they possibly share a common origin with fifteen other springs which are located in a north-northwestern trending, 1000km long zone within the eastern interior of the country. They have also been studied to establish if they potentially represent a viable and sustainable geothermal energy resource that may be developed in the future. Isotope ratios confirm that the thermal springs are meteoric in origin, and are likely recharged within a 130km long band located to the west toward the Great South African Escarpment. These waters then descend vertically to a depth of approximately 1827m – 2153m, at which point the fractures along which they move close due to escarpment-associated confining pressure. It is a reduction in this self-same confining pressure along the coastal plain, which occurs due to the continual removal of overburden, which forces the thermal water to migrate toward the east along ever-more opening fractures. Due to a slightly elevated geothermal gradient of 3.1°C / 100m at depth, this groundwater reaches a temperature of approximately 75°C – 85°C as it traverses toward the Shu Shu thermal springs over a time period of > 61 years (at present). The geochemical signature of the Shu Shu thermal waters is derived through leaching from the basement rocks through which they pass, with elevated concentrations of Na, K, Ca, Mg, Fe, Al, Si, F, Sr and SO₄ detected. Once below the floor of the Tugela Valley, at a depth of approximately 990m, the thermal groundwater commences its ascent, likely along the west-southwest – east-northeast orientated thrusts and associated fractures of the Tugela Terrane of the Natal Metamorphic Province. However, the thermal waters abut against those brittle structures trending north-northwest – south-southeast, which are perpendicular to the axis of least principle compressive stress, and so are ultimately forced to rise within the Shu Shu thermal springs. Prior to surfacing, the temperatures of these waters drop to approximately 67°C as a result of natural, conductive cooling processes. However intermixing with shallow, cold groundwater, which is discernible through geochemical and isotopic variations, and atmospheric impacts, further cool the thermal waters to a surfacing temperature of approximately 50°C. Nevertheless, a binary cycle geothermal energy power plant remains a possibility. Although thermal efficiency and volume flow rate values are favourable, heat transfer values are low and require further investigation through exploratory drilling. Nevertheless, the establishment of a 400kW power plant, should it occur, will typically be sufficient to service 625 rural homes. / Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2013.

Soil cover systems are an integral part of a mine reclamation program and are increasing in area. Knowledge of temperatures and thermal properties in the cover system provide important information regarding the energy balance, thermal regime, as well as preliminary insight into soil water content. Cover system temperatures and thermal properties are measured at a small number of vertically intensive profiles. Current methods do not provide any information as to the spatial variation of temperatures and thermal properties at scales other than the point scale. The objective of this study was to investigate the spatial scaling of thermal properties in reclamation cover systems. A distributed temperature sensing (DTS) system was installed in three cover systems of various textures and configurations. Semivariogram analysis demonstrated that on a 40 m slope consisting of mineral soil over sand (Site #1) soil temperatures did not exhibit any spatial structure, due to the presence of vegetation. A 100 m cover system comprised of a structureless sand (Site #2) was confirmed to be spatially uniform through semivariogram analysis. Semivariograms at Site #2 displayed secondary structure that corresponded to the 65 m plateau and 35 m slope. Site #3 consisted of a uniform peat and a 2% slope. Spatial structure was non-existent at Site #3 and was attributed to the unique thermal properties of peat that magnified the effect of microtopography on the surface energy balance. A method to estimate apparent thermal inertia (ATI) using DTS measurements at the soil surface was developed. Apparent thermal inertia was found to be less uncertain than the current standard apparent thermal diffusivity. The ATI method was determined to be the preferred method as it was related to soil water content and not prone to estimation errors due to imprecise depth measurement. The spatial scaling properties of a 236 m cover system (Site #3) were investigated using estimations of ATI. Measurements were taken every meter along the transect for bulk density, elevation, air-dried thermal conductivity and air-dried volumetric heat capacity. The dominant scale of variation in ATI was not related to physical or thermal properties, which tended towards the 3 m scale (bulk density and thermal conductivity) or the 108 m and field scale trend (elevation and volumetric heat capacity). The dominant scale of variation in ATI shifted between 30 m and the field scale trend and was related to water content as represented by the soil matric potential. A dry cover system tended to homogenize thermal property distribution, leading to a dominance of the 108 m and field scale trend. Wetter days led to a shift to the 30 m scale, with intermediate days showing a mix in scale dominance. Information on thermal property spatial scaling properties of cover systems can be used to optimally design monitoring systems that measure at the same scale as that which the cover is performing. Characterizing the spatial variability of the system will lead to better cover system designs and ultimately a more sustainable system.

This study covers grafting of Acrylic Acid (AA) and Methacrylic Acid (MAA) on Ultrahigh Molecular Weight Polyethylene (UHMWPE) thin films by surface grafting and xylene-swollen grafting methods with Co-60 &amp / #947 / -ray in air. Also characterizations of pure, irradiated and grafted films were made by applying gravimetric, spectroscopic, thermal and mechanic tests. The thin films of UHMWPE were prepared by using compression molding. AA and MAA grafting on thin UHMWPE films were carried out by surface grafting and xylene-swollen grafting methods. During grafting processes, homopolymerization of monomers was avoided by using Fe2+ and Cu2+ ions. Grafting degree of AA and MAA were calculated for the samples irradiated at different doses. To verify grafting of AA and MAA on UHMWPE films, FTIR spectra of grafted films were used. Metal-uptake capacity is important property of grafted polyethylene for environmental applications. Thus, we examined metal-uptake capacities of AA and MAA grafted films for Fe(III) and Ni (II) and it was found that AA and MAA grafted UHMWPE films showed good affinity towards Fe(III) and Ni(II) metals. Thermal behavior of films were examined by DSC analysis. First run and second run DSC thermograms showed the thermal stability of films under heat. Mechanical properties of UHMWPE decrease with irradiation and grafting. However stress at break values of xylene-swollen grafted samples tend to increase with irradiation dose. In conclusion, water soluble monomers were successfully grafted on UHMWPE and these AA and MAA grafted UHMWPE films can be used in biomedical, environmental applications and other related areas.

In this study, the thermal and mechanical properties of poly(ethylenetheraphthalate) (PET)-thermotropic liquid crystal polyester (TLCP), mixtures and poly(methyl methacrylate) (PMMA)-TLCP mixtures were studied. The curing of PMMA-TLCP mixtures was done by heat, gamma radiation and microwave. The amount of TLCP in mixtures was % 0.5, 2 and 5 TLCP by weight. TLCP was synthesized by melt-acidolysis system, and PET-TLCP mixtures were prepared by using lab scale batch mixer. PMMA samples were prepared according to denture manufacturer&rsquo / s procedure. The characterization of polymer samples and mixtures were carried by FT-IR, NMR, DSC, DMA, tensile, impact, three point bending tests and light microscopy. The mixing of TLCP with PMMA yielded heterogeneous dispersions. This was observed from light micrographs. The mechanical and rheological properties of all polymers were not positively affected by inclusion of TLCP. It is also worthwhile to note that weakening of PET-TLCP mixtures were due to the thermal degradation as the thermal age of the mixtures is much higher.

The research presented in this thesis focuses on the structural studies and the high pressure behavior of oxide negative thermal expansion (NTE) materials that can be classified as framework materials. First two chapters were devoted to TaO2F which adopts the ReO3-type cubic structure. Our studies under pressure revealed a rather complicated high pressure behavior for this deceivingly simple compound. The diffraction measurements at variable temperature and high pressure indicated that pressure had a significant effect on the linear coefficient of thermal expansion of TaO2F. In the remainder of the thesis, compounds that belong to the Sc2W3O12 family were examined. High-pressure in-situ powder diffraction studies were conducted on Zr2WO4(PO4)2, Zr2MoO4(PO4)2, Hf2WO4(PO4)2, and Sc2W3O12 in order to investigate the effects of pressure on the coefficients of thermal expansion, existence of phase transitions, phase transition pressures and structural changes occurring upon phase transitions.

<p>Low thermal conductivity is a primary limitation in the development of energy-efficient heat transfer fluids that are required in numerous industrial sectors. Recently submicron and high aspect ratio particles (nanoparticles and nanotubes) were introduced into the heat transfer fluids to enhance the thermal conductivity of the resulting nanofluids. The aim of this project was to investigate the physico-chemical properties of nanofluids synthesized using submicron and high aspect ratio particles suspended in heat transfer fluids .</p>