The effective mass transfer area (a [subscript e]), liquid film mass transfer coefficient (k [subscript L]), and gas film mass transfer coefficient (k [subscript G]) of eleven structured packings and three random packings were measured consistently in a 0.428 m packed column. Absorption of CO₂ with 0.1 gmol/L NaOH with 3.05 m packing was used to measure a [subscript e], while air stripping of toluene from water with 1.83 m packing was used to measure k [subscript L], and absorption of SO₂ with 0.1 gmol/L NaOH with 0.51 m packing was used to measure k [subscript G]. The experiments were conducted with liquid load changing from 2.5 to 75 m³/(m²*h) and gas flow rate from 0.6 to 2.3 m/s. Packings with surface area from 125 to 500 m²/m³ and corrugation angle from 45 to 70 degree were tested to explore the effect of packing geometries on mass transfer. The effective area increases with packing surface area and liquid flow rate, and is independent of gas velocity. The packing corrugation angle has an insignificant effect on mass transfer area. The ratio of effective area to surface area decreases as surface area increases due to the limit of packing wettability. A correlation has been developed to predict the mass transfer area with an average deviation of 11%. [Mathematical equation]. The liquid film mass transfer coefficient is only a function of liquid velocity with a power of 0.74, while the gas film mass transfer coefficient is only a function of gas velocity with a power of 0.58. Both k [subscript L] and k [subscript G] increase with packing surface area, and decrease with corrugation angle. A new concept, Mixing Point Density, was introduced to account for effect of the packing geometry on k[subscript L] and k [subscript G]. Mixing Point Density represents the frequency at which liquid film is refreshed and gas is mixed. The mixing point density can be calculated by either packing characteristic length or by surface area and corrugation angle: [mathematical equation]. The dimensionless k [subscript L] and k [subscript G] models can then be developed based on the effects of liquid/gas velocity, mixing point density, packing surface area: [mathematical equation] [mathematical equation]. Mi is the dimensionless form of Mixing Point Density (M), which is M divided by a [subscript P]³. Because Mi is only a function of corrugation angle (θ), it is a convenient transformation to represent the effect of θ on mass transfer parameters. An economic analysis of the absorber was conducted for a 250 MW coal-fired power plant. The optimum operating condition is between 50 to 80 % of flooding, and the optimum design is to use packing with 200 to 250 m²/m³ surface area and high corrugation angle (60 to 70 degree). The minimum total cost ranges from $4.04 to $5.83 per tonne CO₂ removed with 8 m PZ.

Doctor of Philosophy / Department of Mechanical and Nuclear Engineering / Steve Eckels / A new human thermal model was developed to predict the thermal responses of human body in various environments. The new model was based on Smith's model, which employed finite element method to discretize the human body. The body parts in our new model were not limited to the cylindrical shape as in Smith's model, but subjected to arbitrary shapes. Therefore, the new model is capable of dealing with more complicated shapes of the human body. Steady-state and transient temperatures of fifteen body parts were calculated for three environments: cold, neutral, and warm. Our results were compared with the data from Zhang's experimental research on the human subjects. For all three conditions, our results showed better agreement with experimental data than Smith's results did. The maximal deviation is 1ºC for neutral and warm condition; for cold condition, a maximal deviation of 3.5ºC is reported at hand. The comparison indicated that our new model could provide a more accurate prediction on the body temperatures. Follow-up experiments were conducted to investigate the local and overall heat transfer from a moving cylinder in air flow. This study was expected to provide the local convective heat transfer coefficients of the human body to our new human thermal model to simulate moving humans. An experiment of a stationary cylinder in cross flow was performed to verify the accuracy and consistency of our system. Then, the experiment of a transverse oscillating cylinder in cross flow was conducted, with a oscillation frequency of 0.15 and Strouhal number of 0.3 to 1.5, depending on wind velocity. The overall Nusselt number (Nu) of the oscillating cylinder remained unaffected, compared to the stationary cylinder. This observation showed agreement with previous studies. The pivot experiment was performed to investigate swinging movement of human arms. The cylinder was positioned axially in cross flow, and reciprocated on a fixed point between horizontal and vertical positions under three wind speeds and two oscillating frequencies. The results showed that the overall Nu was between the Nu at horizontal and vertical positions in stationary state. A correlation was presented to predict the Nu of pivotal moving cylinder by using stationary Nu at horizontal and vertical positions. The correlation was proved to be valid ( error less than 5%) within the range of conditions in our experiment.

Gas turbines are today used in numerous industrial and aeronautical applications. To increase the specific power output and efficiency, a high turbine inlet gas temperature is desired. The high temperature leads to the need of cooling critical components in the hot gas path. Siemens Industrial Turbomachinery AB, SIT AB, in Finspång manufactures gas turbines where the internal cooling of critical components is done through serpentine channels. To utilize the cooling air as efficiently as possible, vortex creating objects are placed inside the channel which result in higher heat transfer. To compute the heat transfer in the channel, correlation based approaches that will give a uniform value for an entire channel are often used. This thesis contains two parts. First, investigating how an automated CAE process can be developed that is able to be incorporated into the SIT AB CAE process of today and with a future vision of a, basically, "one-click-CFD" approach for non-generic geometries. Secondly, how CFD simulations for predicting heat transfer levels inside the cooling channels with high accuracy and that captures local features of heat transfer can be performed. The suggested CAE approach involves the CAD-tool NX for geometry creation and for managing an entire CFD project the ANSYS software Workbench, combined with ANSYS Meshing for generation of computational grid, CFX-pre and CFX for pre-processing and solving and CFD-post for post-processing. This approach is suggested for generic geometries due to the simplicity in incorporating it into existing CAE processes. For the future vision of non-generic geometries, the inhouse developed project manager Concept is suggested. It allows for customized coupling between a broader range of available software tools. To validate the CFX model and to investigate how the CFD calculations should be performed, two cases were set up, one where the CFD model and the inhouse code was compared to experimental data of a generic geometry and one where the CFD model and the inhouse code were compared at engine-like conditions. The results for the experimental case resulted in heat transfer coefficients from the CFD model that were 30% off from experimental data, and the inhouse code maximum deviation was 10%. Compared to previous numerical studies this was considered to be of acceptable accuracy, and the location of data extraction points were considered to cause the deviation in the CFD model. For the engine-like case both CFD and inhouse code predicted the heat transfer level as expected. The simulations were performed in steady state mode on automatically generated meshes with the SST-Reattachment turbulence model. The Reynolds number varied from 10 000 to 80 000 and the meshes were around 4-10M elements in size.

Dissipadores de calor baseados em microcanais são apresentados como solução para a remoção de fluxos de calor elevados em espaços restritos, pois proporcionam elevados coeficientes de transferência de calor quando comparados a canais convencionais. Tais trocadores também proporcionam elevadas razões entre a área superficial em contato com o refrigerante por unidade de volume do dissipador. Além dos microcanais, a utilização de nanofluidos também se apresenta como tecnologia com potencial de incremento do coeficiente de transferência de calor. Os nanofluidos consistem na adição de nanopartículas a um fluido base visando alterar suas propriedades de transporte termodinâmicas. Neste contexto, o objetivo do presente estudo é avaliar o coeficiente de transferência de calor para escoamentos monofásicos e ebulição convectiva de nanofluidos aquosos no interior de microcanais. Para isto, foram realizados experimentos em canais com diâmetro de 1,1 mm e comprimento de 200 mm para água deionizada, nanofluidos de alumina com diâmetros de 20-30 e 40-80 nm, nanofluidos de dióxido de silício com diâmetros de 15 e 80 nm, e nanofluidos de cobre com diâmetro de 25 nm. Estas soluções foram ensaiadas para concentrações volumétricas de nanopartículas de 0,001, 0,01 e 0,1, velocidades mássicas de 200, 400 e 600 kg/m2s e fluxos de calor de 20 a 350 kW/m2. A análise dos resultados revelou que a adição de nanopartículas a água deionizada proporciona o incremento do número de Nusselt para escoamentos monofásicos, principalmente na região inicial do tubo. Concluiu-se que os efeitos da adição de nanopartículas a um fluido base no coeficiente de transferência de calor durante a ebulição convectiva estão relacionados ao recobrimento da superfície com uma camada porosa. A deposição de nanopartículas com diâmetro inferior a 30 nm resultou na redução do coeficiente de transferência de calor e das instabilidades térmicas do escoamento em relação a água deionizada. O coeficiente de transferência de calor e as instabilidades térmicas não apresentaram variações significativas da deposição de nanopartículas com diâmetro superior a 40 nm. Por meio da análise da textura das superfícies recobertas e do critério de nucleação proposto por Kandlikar et al. (1997) concluiu-se que tal comportamento encontra-se associado aos efeitos do acabamento superficial na densidade de cavidades de nucleação ativas. / Microchannels based heat exchangers were introduced as a solution to high heat flux removal in restrict spaces due to their high heat transfer coefficients compared to heat exchangers based on conventional channels. The high ratio of surface are per volume is an additional advantage to microchannels in relation to conventional channels. Beside the microchannels technology, the nanofluids also present itself as a technique with potential to increase the heat transfer coefficient. Nanofluids consist of a solution containing nanoparticles dispersed in a base fluid with the goal to improve its thermodynamic and transport properties. In this context, the objective of the present study is to evaluate the heat transfer coefficient for single-phase flow and convective boiling of aqueous nanofluids inside microchannels. Experiments were performed for channels with internal diameter of 1.1mm and 200 mm long for DI-water, nanofluids containing alumina- (nanoparticles diameters of 20-30 and 40-80 nm), silicon dioxide (nanoparticles diameters of 15 and 80 nm), and copper (nanoparticles diameter of 25 nm). These solutions were evaluated for volumetric concentrations of 0.001, 0.01 and 0.1%, mass velocities of 200, 400 and 600 kg/m2s and heat fluxes from 20 to 350 kW/m2. The analysis of the results revealed that the addition of nanoparticles to DI-water causes an increment in the Nusselt number for single phase flows, especially at the inlet of the tube. The results for flow boiling indicated that the effects of adding nanoparticles to the base fluid are related to the deposition on the heating surface of a nanoparticles porous layer due to the boiling process. The deposition of nanoparticles smaller than 30 nm promoted a reduction of the heat transfer coefficient compared to DI-water on a clean surface, and thermal instabilities were minimized. For the deposition of nanoparticles larger than 40 nm these parameters did not presented significant variations in comparison to DI-water. A combined analysis of the surfaces finishing and the criterion of Kandlikar et al. (1997) for bubble nucleation revealed that such behaviors are correlated to the effects of the surface texture associated to the boiling process on the density of active nucleation cavities.

Em sistemas frigoríficos de compressão a vapor, o evaporador é o equipamento responsável direto pela retirada de calor de ambientes refrigerados. Por esta razão, este componente é a fonte de investigação do presente estudo, o qual teve por objetivo principal a busca por alternativas para a melhoria de desempenho térmico em sistema frigoríficos. Isto posto, o trabalho foi desenvolvido em três frentes de estudo, as quais encontram-se interligadas entre si: desenvolvimento de programa de simulação de serpentinas resfriadoras; realização de ensaios para determinação das capacidades de trocadores de calor; e revisão bibliográfica circunstanciada do coeficiente de transferência de calor do lado do ar. O programa de simulação desenvolvido, o qual tomou como base o modelo proposto por Rich, mostrou-se ser uma ótima ferramenta de trabalho, tanto no meio acadêmico como no industrial. Como conseqüência da elaboração do programa, fez-se uso de correlações já existentes para determinação dos coeficientes de transferência de calor do lado do refrigerante, Bo Pierre, e do lado do ar, McQuiston, sendo esta última escolhida a partir de um sumário de correlações levantadas quando no estudo dos coeficientes de transferência de calor descritos acima. Para que o programa fosse validado como ferramenta de trabalho, foram realizadas simulações dos ensaios das serpentinas testadas e seus resultados confrontados. Tais resultados apresentam uma adequada concordância,possibilitando validar o programa. Os ensaios foram realizados segundo recomendações da norma ASHRAE 25/1992. Dos dados obtidos nos testes, também foi proposto uma correlação para o fator j-Colburn para superfícies secas; no entanto, tratou-se apenas de especular acerca de seu comportamento com as demais correlações, as quais obtiveram boa concordância. / In refrigerating systems of compression to vapour, the evaporator is the direct responsible equipment for remove of heat of cooling environments. In this way, the component is the source of investigation of the present study, which had for main objective the search for alternatives to improvement the performance thermal in refrigeration systems. The research was developed in three studies fronts, that are connected each other: development of program of simulation of cooling coils; tests to find the performance of heat exchange; and revision bibliographical of the coefficient of heat transfer of air. The developed simulation program, based in the Rich\'s model, it showed to be a good work tool, as in the academic, as in the industrial behaviour. As consequence of the elaboration the program, it was used existents correlations to calculation the coefficients of refrigerant heat transfer, Bo Pierre, and to air, McQuiston, the last one was choose from a correlation\'s summary. Same simulations were made to validated the program of the tested serpentines and the results were confronted. Such results presented an appropriate agreement that contributed to validate the program. The tests were accomplished according to recommendations of the norm ASHRAE 25/1992. One correlation was proposed for the factor j-Colburn for dry surfaces in base of the testes results; however, the purpose was to speculated its behaviour with the other correlations, which obtained good agreement.

An experimental investigation has been conducted on CHTE quench probes and IVF quench probes to determine the influence of flow rate, spray distance and concentration of AQ251 polymer quenchant on the cooling rate and heat transfer coefficient during spray quenching. Time-temperature data has been collected for each spraying condition using the CHTE spray quenching system. Heat transfer coefficients as a function of temperature have been estimated and compared by using lumped thermal capacity model and an inverse heat conduction model. The results revealed that the maximum cooling rate increases with increasing in the flow rate in varying concentration of polymer quenchant in both probes. It was also found that the cooling rate decreases with the increase of the concentration of polymer quenchant.

<p>In modern gas turbines parts of combustion chamber and turbine section are under heavy heat load, for example, the rotor inlet temperature is far higher than the melting point of the rotor blade material. These high temperatures causes thermal stresses in the material, therefore it is very important to cool the components for safe operation and to achieve desired component life. But on the other hand the cooling reduces the turbine efficiency, for that reason it is vital to understand and optimize the cooling technique.</p><p>In this project Thermochromic Liquid Crystals (TLCs) are used to measure distribution of heat transfer coefficient over a scaled up combustor liner section. TLCs change their color with the variation of temperature in a particular temperature range. The color-temperature change relation of a TLC is sharp and precise; therefore TLCs are used to measure surface temperature by painting the TLC over a test surface. This method is called Liquid Crystal Thermography (LCT). LCT is getting popular in industry due to its high-resolution results, repeatability and ease of use.</p><p>Test model in present study consists of two plates, target plate and impingement plate. Cooling of the target plate is achieved by impingement of air coming through holes in the impingement plate. The downstream surface of the impingement plate is then cooled by cross flow and re-impingement of the coolant air.</p><p>Heat transfer on the target plate is not uniform; areas under the jet which are called stagnation points have high heat transfer as compare to the areas away from the center of jet. It is almost the same situation for the impingement plate but the location of stagnation point is different. A transient technique is used to measure this non-uniform heat transfer distribution. It is assumed that the plates are semi-infinitely thick and there is no lateral heat transfer in the plates. To fulfill the assumptions a calculated time limit is followed and the test plates are made of Plexiglas which has very low thermal conductivity.</p><p>The transient technique requires a step-change in the mainstream temperature of the test section. However, in practical a delayed increase in mainstream temperature is attained. This issue is dealt by applying Duhamel’s theorem on the step-change heat transfer equation. MATLAB is used to get the Hue data of the recorded video frames and calculate the time taken for each pixel to reach a predefined surface temperature. Having all temperatures and time values the heat transfer equation is iteratively solved to get the value of heat transfer coefficient of each and every pixel of the test surface.</p><p>In total fifteen tests are conducted with different Reynolds number and different jet-to-target plate distances. It is concluded that for both the target and impingement plates, a high Reynolds number provides better overall heat transfer and increase in jet-to-target distance</p><p>decreases the overall heat transfer.</p>

The ultimate goal of this study is to examine the feasibility of extracting silicon from silica through electrolysis. The objective of the thesis was to evaluate the physico-chemical properties of a cryolite-lithium fluoride mixture as an electrolyte for the electrolysis process. A study of 86.2wt%Cryolite and13.8wt%Lithium fluoride melt with silica concentration varying from 0-4wt% and temperature range of 900-1000°C was done. Three properties were measured using two sets of experiments: 1) Dissolution Behaviour Determination, to obtain a) solubility limit, b) dissolution rate (mass transfer coefficient) and 2) density using Archimedes’ Principle. The study concluded that solubility and dissolution rate increases with temperature and the addition of LiF to cryolite decreases the solubility limit but increases the rate at which silica dissolves into the melt. With addition of silica, the apparent density of electrolyte first increases up to 2-3wt% and the drops.

The ultimate goal of this study is to examine the feasibility of extracting silicon from silica through electrolysis. The objective of the thesis was to evaluate the physico-chemical properties of a cryolite-lithium fluoride mixture as an electrolyte for the electrolysis process. A study of 86.2wt%Cryolite and13.8wt%Lithium fluoride melt with silica concentration varying from 0-4wt% and temperature range of 900-1000°C was done. Three properties were measured using two sets of experiments: 1) Dissolution Behaviour Determination, to obtain a) solubility limit, b) dissolution rate (mass transfer coefficient) and 2) density using Archimedes’ Principle. The study concluded that solubility and dissolution rate increases with temperature and the addition of LiF to cryolite decreases the solubility limit but increases the rate at which silica dissolves into the melt. With addition of silica, the apparent density of electrolyte first increases up to 2-3wt% and the drops.

In modern gas turbines parts of combustion chamber and turbine section are under heavy heat load, for example, the rotor inlet temperature is far higher than the melting point of the rotor blade material. These high temperatures causes thermal stresses in the material, therefore it is very important to cool the components for safe operation and to achieve desired component life. But on the other hand the cooling reduces the turbine efficiency, for that reason it is vital to understand and optimize the cooling technique. In this project Thermochromic Liquid Crystals (TLCs) are used to measure distribution of heat transfer coefficient over a scaled up combustor liner section. TLCs change their color with the variation of temperature in a particular temperature range. The color-temperature change relation of a TLC is sharp and precise; therefore TLCs are used to measure surface temperature by painting the TLC over a test surface. This method is called Liquid Crystal Thermography (LCT). LCT is getting popular in industry due to its high-resolution results, repeatability and ease of use. Test model in present study consists of two plates, target plate and impingement plate. Cooling of the target plate is achieved by impingement of air coming through holes in the impingement plate. The downstream surface of the impingement plate is then cooled by cross flow and re-impingement of the coolant air. Heat transfer on the target plate is not uniform; areas under the jet which are called stagnation points have high heat transfer as compare to the areas away from the center of jet. It is almost the same situation for the impingement plate but the location of stagnation point is different. A transient technique is used to measure this non-uniform heat transfer distribution. It is assumed that the plates are semi-infinitely thick and there is no lateral heat transfer in the plates. To fulfill the assumptions a calculated time limit is followed and the test plates are made of Plexiglas which has very low thermal conductivity. The transient technique requires a step-change in the mainstream temperature of the test section. However, in practical a delayed increase in mainstream temperature is attained. This issue is dealt by applying Duhamel’s theorem on the step-change heat transfer equation. MATLAB is used to get the Hue data of the recorded video frames and calculate the time taken for each pixel to reach a predefined surface temperature. Having all temperatures and time values the heat transfer equation is iteratively solved to get the value of heat transfer coefficient of each and every pixel of the test surface. In total fifteen tests are conducted with different Reynolds number and different jet-to-target plate distances. It is concluded that for both the target and impingement plates, a high Reynolds number provides better overall heat transfer and increase in jet-to-target distance decreases the overall heat transfer.