This thesis aims to modal-choice and changes of transport behaviour, especially for students on the route from Praha to České Budějovice. The route is chosen due to expanding of the highway and to newly introduced bus and train services. The category of the students is interesting terms to limited options in the context of finances in relation to employees. The comparison of the preferences of these groups is the goal of the thesis. The goal verification has been completed by quantitative and qualitative research by questionnaire. The questionnaire for employees was created by Public opinion research centre, while the questionnaire for the students was created specifically by the author of the thesis. Contrary to the original assumptions, the thesis found that students prefer travel time ahead of the price and employees prefer flexibility ahead of the travel time. The goal of this thesis is determination of meaning chosen factors in modal-choice and monitoring differences of these factors between employees and students. Further, the thesis evaluate competitiveness each of transport modes on the chosen route. Keywords: modal-choice, transport behaviour, public transport

Reactive transport models are essential tools for predicting contaminant fate and transport in the subsurface and for designing effective remediation strategies. Sound understanding of subsurface mixing in heterogeneous porous media is the key for the realistic modeling of reactive transport. This dissertation aims to investigate the extent of mixing and improve upscaling effective macroscopic models for mixing-controlled reactive transport in connected heterogeneous formations, which usually exhibit strongly anomalous transport behavior. In this research, a novel approach is developed for an accurate geostatistical characterization of connected heterogeneous formations transformed from Gaussian random fields. Numerical experiments are conducted in such heterogeneous fields with different connectivity to investigate the performance of macroscopic mean transport models for simulating mixing-controlled reactive transport. Results show that good characterization of anomalous transport of a conservative tracer does not necessarily mean that the models may characterize mixing well and that, consequently, it is questionable that the models capable of characterizing anomalous transport behavior of a conservative tracer are appropriate for simulating mixing-controlled reactive transport. In connected heterogeneous fields with large hydraulic conductivity variances, macroscopic mean models ignoring concentration variations yield good prediction, while in fields with intermediate conductivity variances, the models must consider both the mean concentration and concentration variations, which are very difficult to evaluate both theoretically and experimentally. An innovative and practical approach is developed by combining mean conservative and reactive breakthrough curves for estimating concentration variations, which can be subsequently used by variance transport models for prediction. Furthermore, a new macroscopic framework based on the dual-permeability conceptualization is developed for describing both mean and concentration variation for mixing-controlled reactive transport. The developed approach and models are validated by numerical and laboratory visualization experiments. In particular, the new dual-permeability model demonstrates significant improvement for simulating mixing-controlled reactive transport in heterogeneous media with intermediate conductivity variances. Overall, results, approaches and models from this dissertation advance the understanding of subsurface mixing in anomalous transport and significantly improve the predictive ability for modeling mixing-controlled reactive transport in connected heterogeneous media.

Submarine landslides retrogressively fail from intact material at the headwall and then become fluidized by strain weakening; the final deposits of these flows have low porosity, which controls their character in seismic reflection data. Submarine landslides occur on the open slope and also localized areas including margins of turbidite channel-levee systems. I develop and quantify this model with 3-D seismic reflection data, core and log data from Integrated Ocean Drilling Program Expedition 308 (Ursa Basin, Gulf of Mexico), flume experiments, and numerical modeling. At Ursa, multiple submarine slides over the last 60 ky are preserved as mass transport deposits (MTDs). Retrogression proceeded from an initial slope failure that created an excavated headwall, which reduced the horizontal stress behind the headwall and resulted in normal faults. Fault blocks progressively weakened until the gravitational driving stress imposed by the bed slope exceeded soil strength, which allowed the soil to flow for more than 10 km away from the source area. The resulting MTDs have lower porosity (higher bulk density) relative to non-failed sediments, which ultimately produces high amplitude reflections at the base and top of MTDs. In the laboratory, I made weak (low yield strength) and strong flows (high yield strength) from mixtures of clay, silt, and water. Weak flows generate turbidity currents while moving rapidly away from the source area. They create thin and long deposits with sinuous flow features, and leave behind a relatively smooth and featureless source area. In contrast, strong flows move slowly, do not generate a turbidity current, and create blocky, highly fractured source areas and short, thick depositional lobes. In Pleistocene turbidite channels of the Mississippi Fan, deep-seated rotational failures occurred in the flanking levees. The rotational failures displaced material into the channel from below where it became eroded by turbidity flows. This system achieved a delicate steady state where levee deposition and displacement along the fault into the channel was balanced by erosion rate of turbidity flows. This work enhances our understanding of geohazards and margin evolution by illuminating coupled processes of sedimentation, fluid flow, and deformation on passive continental margins. / text