The present work deals with developing a tribological test machine that had been built earlier but did not function properly. It was giving out abnormal noises and vibrations and was not corresponding to its desired functions. In this study, the root of these problems is analyzed and some solutions are suggested by developing a new construction concept for the machine.

Lightweight aluminium-silicon alloy is an attractive material for making engine cylinders in automobiles. It imparts good power to weight ratio to the engine. High silicon containing aluminium alloys are used in current engine block castings where the bore surface is etched or honed to partially expose the silicon particles to provide the primary contact between the piston ring and certain regions of the piston and the cylinder. Piston reversal near the top dead centre however causes starvation of lubrication which leads to wear. To explore the wear behaviour of etched aluminium-silicon alloys under nominally dry conditions and extreme lubricated conditions, a host of mechanical and spectroscopic techniques are used here to characterize mechanical and chemical changes caused by wear. In the absence of complex chemical transformations on the wear surface in dry condition, allows a close examination of surface and subsurface microstructures. Given this understanding of the wear under dry condition, we explore the effect of boundary lubrication, where chemical transformations leading to surface modifications are involved. In dry sliding tribology of aluminium-silicon alloy slid against a steel ball four stages of wear are identified; ultra-mild wear, mild wear, severe wear and post severe oxidative wear. In the ultra-mild wear regime silicon particles bears the load. Transition to mild wear occurs when the protruded silicon particles disappear(by sinking and fracture) under higher pressure and sliding. The sinking of silicon particles under normal loading is further investigated using a naoindenter. It is found that the resistance to sinking of such particles into the matrix increases with the unexposed surface area to the buried volume of the particles. In that sense, small particles are seen to provide the stiffest resistance to sinking. While in ultra-mild wear regime the basic energy dissipation mechanism is sinking/tilting, in mild wear regime the subsurface is either in an elastic or an incipiently plastic state. Subsurface plasticity in mild wear regime leads to a grain refinement, fracture of silicon and nucleation of cracks at silicon-matrix interfaces but does not promote large scale flow of the matrix. Transition to severe wear occurs when the contact pressure exceeds the plastic shakedown limit. Under this condition gross plasticity leads to a severe fragmentation of silicon particles and the fragmented silicon are transported by the matrix as it undergoes incremental straining with each cyclic contact at the asperity level. A large reduction in the inter-particle distance com-pared to that in a milder stage of wear, gives rise to high strain gradients in the severe wear regime which contribute to the enhancement of dislocation density. The resulting regions of very high strains at the boundaries of the recrystallised grains as well as within the subgrains lead to the formation of microvoids/ cracks. This is accompanied by the formation of brittle oxides at these subsurface inter-faces due to enhanced diffusion of oxygen. We believe that the abundance of such microcracks in the near surface region, primed by severe plastic deformation, is what distinguishes a severe wear regime from that in the mild wear. The transition from severe wear to post severe oxidative wear is thermally induced and it transfers the metal to metal contact interaction to metal to ceramic interaction. A thick oxide layer is abraded and spalls while the metal underneath continues to flow and delaminate. A study of lubricated tribology of ultra-mild and mild wear regime of aluminium-silicon alloy shows that the initial stages of sliding friction is controlled by the abrasion of the steel pin by the protruding silicon particles of the aluminium-silicon disc. Thegeneration of nascent steel chips helps to breakdown the additive in the oil by a cationic exchange that yields chemical products of benefits to the tribology. The friction is initially controlled by abrasion, but the chemical products gain increasing importance in controlling friction with sliding time. After long times, depending on the contact pressure, the chemical products determine sliding friction exclusively. In the mild wear chemically induced low friction is achieved in short periods of time whereas in ultra-mild wear regime it takes very long time to reach this low friction state. While the basic dissipation mechanisms are the same in the ultra-mild wear and mild wear regimes ,the matrix remains practically unworn in the low pressure ultra-mild wear regime. In the higher pressure mild wear regime at long sliding times a small but finite wear rate prevails. Incipient plasticity in the subsurface controls the mechanism of wear.

The current socio-economic and environmental context worldwide, with different actors and needs, requires continued progress towards energy efficiency and environmental improvements in order to create a sustainable future, and this implies a scientific and technologic effort to achieve the proposed goals. Transport by propulsive systems based on reciprocating internal combustion engines (ICE) is one of the major agents affecting future environmental sustainability. Included in the wide research done in this area, one of the options considered is the use of low viscosity oils (LVO) as an option for increasing ICE efficiency. This technology presents a modest contribution to the efficiency target, but the excellent cost-effectiveness ratio and ease of application to current and future vehicle parc are two reasons that has driven towards research into the use of these oils. The low viscosity oils base their contribution to improving energy efficiency by reducing mechanical losses associated with viscous friction in hydrodynamic regime. This in turn reduces energy consumption to operate the system, and it is associated with a reduction of pollutant emissions for the same performance. The hypotheses of application of LVO are well founded, but there are a number of uncertainties surrounding the application of low viscosity oils in MCIA today. On one hand, it is possible to expect a modification of the ICE tribological performance, as well as changes in lubricant performance which ultimately could lead to a reduction in the period of useful life, an early lubrication failure or other consequences difficult to predict. Also, a reduction in viscosity may increase wear production, so there is also an interest in the remote diagnosis of lubricated system status. In this Thesis a concise review of the state-of-the-art has been done applied to ICE tribology and lubricating oils, with special interest in the low viscosity oils development. Then, a series of different studies have been performed to deepen the understanding of oil performance and its influence on ICE wear, supported by a set of physico-chemical analytical techniques applied to diagnose the state of the lubricating oil. The different results obtained show that the application of low viscosity oils in ICE is a viable alternative, since the results obtained in the various tests validate the different hypotheses done, and it opens a line of research possibilities around future enhancements and technology development. / La situación actual a nivel mundial, enmarcada en un contexto socioeconómico y medioambiental complejo, con diferentes actores y necesidades presentes, requiere un avance continuo hacia la eficiencia energética y las mejoras medioambientales de cara a poder crear un futuro sostenible, así como de un esfuerzo científico y tecnológico para poder alcanzar los objetivos propuestos. El transporte mediante sistemas propulsivos basados en motores de combustión interna alternativos (MCIA) es uno de los grandes agentes que afectan a la sostenibilidad medioambiental futura. Dentro de la profunda investigación que se realiza en éste ámbito, una de las opciones estudiadas es la del uso de aceites de baja viscosidad (LVO) como opción para el aumento de la eficiencia de los MCIA. Esta tecnología presenta una aportación modesta al objetivo de eficiencia energética, pero la excelente relación coste-beneficio y la facilidad de aplicación al parque automovilístico actual y futuro son dos razones que han impulsado a la industria hacia la investigación en el uso de estos aceites. Los aceites de baja viscosidad basan su aportación a la mejora de la eficiencia energética en la reducción de las pérdidas mecánicas asociadas a la fricción viscosa en régimen hidrodinámico. Así, se consigue reducir el consumo de energía utilizado para hacer funcionar el sistema, y lleva asociada una reducción de las emisiones contaminantes para el mismo desempeño. La hipótesis de aplicación de los aceites de baja viscosidad están bien fundamentadas, pero existen una serie de incertidumbres alrededor de la aplicación de los aceites de baja viscosidad en MCIA a día de hoy. Por un lado, es posible esperar una modificación del comportamiento tribológico en el propio MCIA, así como una variación del propio comportamiento del lubricante que en último lugar podría provocar una reducción del período de vida útil del mismo, un fallo temprano de lubricación u otras consecuencias difíciles de prever. Además, la bajada de viscosidad puede aumentar el fenómeno de desgaste, por lo que existe también un interés en la cuantificación y diagnóstico de manera continua y remota del estado del sistema lubricado. Así, en esta Tesis se ha realizado un conciso trabajo de revisión del estado del arte de la tribología aplicada a MCIA y de los aceites lubricantes, poniendo especial interés en el desarrollo de la idea de los aceites de baja viscosidad. A continuación, y con el apoyo de un conjunto de técnicas analíticas físico-químicas aplicadas a diagnosticar el estado del aceite lubricante, se han planteado una serie de estudios desde diferentes ámbitos para poder profundizar en el conocimiento del comportamiento del aceite y de su influencia en el desgaste en MCIA. Los diferentes resultados obtenidos señalan que la aplicación de los aceites de baja viscosidad en MCIA es una alternativa viable y exitosa, ya que los resultados obtenidos en los diferentes ensayos realizados validan el comportamiento de esta opción, y abre una línea de posibilidades de investigación alrededor de futuras mejoras y de desarrollo de la tecnología. / La situació actual a nivell mundial, emmarcada en un context socioeconòmic i mediambiental complex, amb diferents actors i necessitats presents, requereix d'un avanç continu cap a l'eficiència energètica i les millores mediambientals de cara a poder crear un futur sostenible, així com d'un esforç científic i tecnològic per poder assolir els objectius proposats. El transport mitjançant sistemes propulsius basats en motors de combustió interna alternatius (MCIA) és un dels grans agents que afecten la sostenibilitat mediambiental futura. Dins de la profunda investigació que es realitza en aquest àmbit, una de les opcions estudiades és la de l'ús d'olis de baixa viscositat (LVO) com a opció per a l'augment de l'eficiència dels MCIA. Aquesta tecnologia presenta una aportació modesta a l'objectiu d'eficiència energètica, però l'excel¿lent relació cost-benefici i la facilitat d'aplicació al parc automobilístic actual i futur són dues raons que han impulsat a la indústria cap a la investigació en l'ús d'aquestos olis. Els olis de baixa viscositat basen la seva aportació a la millora de l'eficiència energètica en la reducció de les pèrdues mecàniques associades a la fricció viscosa en règim hidrodinàmic. Així, s'aconsegueix reduir el consum d'energia utilitzat per fer funcionar el sistema, i porta associada una reducció de les emissions contaminants per a l'obtenció del mateix resultat. Les hipòtesis d'aplicació dels olis de baixa viscositat estan ben fonamentades, però hi ha una sèrie d'incerteses al voltant de l'aplicació dels olis de baixa viscositat en MCIA a dia de hui. D'una banda, és possible esperar una modificació del comportament tribològic en el propi MCIA, així com una variació del propi comportament del lubricant que en últim lloc podria provocar una reducció del període de vida útil d'aquest, una fallada de lubricació primerenca o altres conseqüències difícils de preveure. A més, la baixada de viscositat pot augmentar el fenomen de desgast, pel que existeix també un interès en la quantificació i diagnòstic de manera contínua i remota de l'estat del sistema lubricat. Així, en aquesta Tesi s'ha realitzat un concís treball de revisió de l'estat de l'art de la tribologia aplicada a MCIA i dels olis lubricants, posant especial interès en el desenvolupament de la idea dels olis de baixa viscositat. A continuació, i amb el suport d'un conjunt de tècniques analítiques fisico-químiques aplicades a diagnosticar l'estat de l'oli lubricant, s'han plantejat una sèrie d'estudis des de diferents àmbits per poder aprofundir en el coneixement del comportament de l'oli i de la seva influència en el desgast en MCIA. Els diferents resultats obtinguts assenyalen que l'aplicació dels olis de baixa viscositat en MCIA és una alternativa viable, ja que els resultats obtinguts en els diferents assajos realitzats validen el comportament d'aquesta opció, i obre una línia de possibilitats d'investigació al voltant de futures millores i de desenvolupament de la tecnologia. / Miró Mezquita, G. (2017). Estudio del comportamiento y de la influencia en el desgaste de los aceites lubricantes de baja viscosidad en MCIA [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/78615 / TESIS

Working at elevated temperature has its challenges due to the high level of complexity whenthe tribosystems operate under harsh conditions, commonly resulting in an increase on thefriction and thermal softening that goes into severe adhesion, severe abrasion and materialtransfer. Despite considerable research, there is a lack of research on tribology applied to hightemperature processes.  The aim of this project is to understand the tribological behavior of tool steel sliding againstaluminum under lubrication conditions working at high temperature. Salt-based, graphite-based, and polymer-based lubricants were evaluated as they are commonly used for aluminum forming. The cleanability of the lubricants after being subjected to elevated temperatures is also studied. High temperature tribological tests were carried out in a reciprocating sliding flat-on-flat configuration for 15 seconds. Optical microscope, SEM and EDS were performed to analyze the specimens after the tribological tests. Then a cleanability study was done to evaluate the cleanability of the lubricants and the effect of temperature on the cleanability of the lubricant. The concentration of the lubricants played an important role in the lubricant’s friction stability and dispersion, particularly for the polymer-based and graphite-based lubricants. Under the tested conditions the salt-based lubricant was ineffective as it showed high and unstable friction. The 10 wt.% polymer-based lubricant concentration presented severe adhesion and material transfer from the aluminum onto the tool steel.  The effect of temperature on the cleanability of the lubricants was correlated to the temperature in which the lubricants start to degrade. Nevertheless, the best cleanability was achieved when using ethanol as a cleaning agent in combination with high pressure spraying, and wirebrush techniques. Mild and high alkaline agents had poor cleanability abilities resulting insurface damage and corrosion on the tool steel.

The purpose of the project work was to build knowledge of the tribological behaviour of self-lubricating laser cladding, with and without external solid lubricant during conditions relevant for hot metal forming of aluminium. The materials used during the project were plates coated with a Ni-based self-lubricating clad and a reference sample of work tool steel. The self-lubricating laser clad was applied using a high power direct diode laser. The external solid lubricant used was a graphite dispersion. The external solid lubricant was applied on the samples using a spraying technique, leaving a dry layer of solid graphite on the plates. To test the tribological behaviour of the plates, linear reciprocating friction and wear tests were performed both under lubricated and dry conditions. During the dry tests, different surface roughness of the plates where investigated. The pins for the tribological test were made of AA7075. Parameters chosen for the tribological tests were based on conditions during hot forming of aluminium. After having taken images of the plates using scanning electron microscopy, and using a 3D optical profiler, the wear volume and material transfer was evaluated, and wear mechanism analysis was performed.   The tribological behaviour of polished Ni-based laser clad under dry conditions is comparable to that of the reference sample at its best performance. Using a mirror polished Ni-based laser clad under dry condition can be an option to not using external solid lubricant during hot forming of aluminium. Also, the surface roughness of the self-lubricating clad under dry conditions does not affect the coefficient of friction.

Silicon nitride on steel sliding contacts may provide advantageous tribological properties over traditional self-mated pairs, however the friction and wear behavior at high sliding speeds (>1 m/s) is not well understood. Previous studies at low sliding speeds (< 1 m/s) have found that the wear mechanisms change as a function of the operating parameters, e.g. atmosphere, sliding speed, load, and temperature, due to the formation of transition metal oxides such as Fe2O3 and Fe3O4. This study detected transient effects of the dry silicon nitride on steel contact over a range of sliding speeds to understand their relation to tribochemical reactions and the resulting tribological behavior. Two sets of dry silicon nitride on steel experiments were conducted at 1.45 GPa maximum Hertzian pressure. The first set were low sliding speed reciprocating experiments, conducted at an average of 0.06 m/s, conducted at variable operating temperature, ranging from 23 °C to 1000 °C. In the low sliding speed experiments, transitions of the wear mechanism from adhesive wear, to abrasive wear, then to oxidative wear was observed when the operating temperature increased. The second set were high sliding speed experiments, conducted at variable sliding speeds, ranging from 1 m/s to 16 m/s. In the high sliding speed experiments, a transition from adhesive wear to oxidative wear was observed when the sliding speed surpassed 4.5 m/s. The high sliding speed experiments were accompanied by in-situ instrumentation which detected the presence of a tribofilm which correlated to a reduction in friction, and its formation was linked to tribochemical reactions induced by high flash temperatures. Both sets of experiments had a maximum estimated contact temperature of 1000 °C where oxidative wear was prevalent. Although, the low sliding speed experiments underwent severe bulk oxidation and thermal softening effects, while the high sliding speed experiments experienced localized flash heating events with temperatures sufficient to form a semi-coherent tribofilm that was lubricious and significantly improved wear resistance. Therefore, the effects of transition metal oxides in sliding contacts are determined to be significantly influenced on their mechanisms of formation and interrelated to the operating parameters as found for dry sliding silicon nitride on steel contacts.

Hard gold thin films and coatings are widely used in electronics as an effective material to reduce the friction and wear of relatively less expensive electrically conductive materials while simultaneously seeking to provide oxidation resistance and stable sliding electrical contact resistance (ECR). The main focus of this dissertation was to synthesize nanocrystalline Au films with grain structures capable of remaining stable during thermal exposure and under sliding electrical contact stress and the passing of electrical current. Here we have utilized a physical vapor deposition (PVD) technique, electron beam evaporation, to synthesize Au films modified by ion implantation and codeposited ZnO hardened Au nanocomposites. Simultaneous friction and ECR experiments of low fluence (< 1x10^17 cm^-2) He and Ar ion implanted Au films showed reduction in friction coefficients from ~1.5 to ~0.5 and specific wear rates from ~4x10^-3 to ~6x10^-5 mm^3/N·m versus as-deposited Au films without significant change in sliding ECR (~16 mΩ). Subsurface microstructural changes of He implanted films due to tribological stress were analyzed via site-specific cross-sectional transmission electron microscopy (TEM) and revealed the formation of nanocrystalline grains for low energy (22.5 keV) implantation conditions as well as the growth and redistribution of cavities. Nanoindentation hardness results revealed an increase from 0.84 GPa for as-deposited Au to ~1.77 GPa for Au uniformly implanted with 1 at% He. These strength increases are correlated with an Orowan hardening mechanism that increases proportionally to (He concentration)1/3. Au-ZnO nanocomposite films in the oxide dilute regime (< 5 vol% ZnO) were investigated for low temperature aging stability in friction and ECR. Annealing at 250 °C for 24 hours Au-(2 vol%)ZnO retained a friction coefficient comparable to commercial Ni hardened Au of ~ 0.3 and sliding ECR values of ~35 mΩ. Nanoindentation hardness increases of these films (~2.6 GPa for 5 vol% ZnO) are correlated to microstructure via high resolution TEM and scanning electron microscope cross-sections to both Hall-Petch and Orowan strengthening mechanisms. Also presented is a correlation between electrical resistivity and grain size in the oxide dilute range based on the Mayadas-Shatzkes (M-S) electron scattering model. Using the M-S model in combination with a model describing solute drag stabilized grain growth kinetics we present a new technique to probe grain boundary mobility and thermal stability from in-situ electrical resistivity measurements during annealing experiments.

Over the last decade, the application of ultra-high strength steel as safety components and structural reinforcements in automobile applications has increased due to their favourable high-strength-to-weight ratio. The complex shaped components are widely produced using hot stamping. However, this process encounters problems such as galling and increased wear of the tools due to harsh operating conditions associated to the elevated temperatures. Moreover, quenching is a critical step that affects the hot formed components. Slow cooling rates results in inhomogeneous mechanical properties and increased cycle time. Therefore, fast and homogeneous quenching of the formed components in combination with reduction of wear rates during hot forming are important targets to ensure the quality and efficiency of the process. The use of additive manufacturing (AM) technologies opens up potential solutions for novel tooling concepts. The manufacturing of complex shape cooling channels and integration of high-performance alloys at the surface could benefit the tribological performance in the forming operation. However, the research into high temperature tribological behaviour of AM materials in hot forming applications is very limited. The aim of this work is to study the tribological performance of additively manufactured materials. Two steels were used – a maraging steel and modified H13 tool steel. The hot work tool steel H13 is commonly applied for dies in metal forming processes. In this thesis it was used to study additive manufacturing as the processing route instead of conventional casting. The choice of a maraging steel is motivated by a possible application of high-performance alloys as a top layer on dies. The materials were post-machined and studied in milled, ground and shot-blasted conditions. The different post-machining operations were applied to study the effect of surface finish on the tribological behaviour and also to evaluate different methods of post-machining an AM surface. As fabricated dies are usually manufactured with milled surface. During its use, the dies undergo refurbishment after certain number of cycles and the surface condition is changed to a ground surface. These surface finishes are commonly tested for hot forming applications. The shot blasted operation was chosen as alternative surface finish. The process allows to prepare large sized tools easily and the surface has beneficial compressive stresses. The tribological behaviour of AM steels was studied using a hot strip drawing tribometer during sliding against a conventional Al-Si coated 22MnB5 steel. The workpiece temperature during the tests was 600 and 700°C. The results of the tribological performance of AM materials were compared to conventionally cast tool steel QRO90.The results have shown that the friction behaviour of both maraging and H13 steels at 600°C was stable and similar whereas at 700°C the COF was more unstable and resulted in an earlier failure of the tests due to increased material transfer of Al-Si coating from the workpiece surface.The main wear mechanisms for AM materials were galling and abrasion at both temperatures. Abrasion is more severe for the AM steels in comparison to cast tool steel QRO90. The galling formation on milled and ground surfaces showed similar behaviour to cast steel and it increased with higher workpiece temperatures. The shot-blasted surfaces showed less build-up of transferred material on the surface but folding of asperities and entrapment of Al-Si particles within surface defects generated during shot-blasting.

This study aims to develop coatings which show wear resistant behaviour along with multiple functions such as improved ice adhesion, better freezing delay etc which help in improving the effectiveness of the wind turbine efficiency. The significance of anti-icing/de-icing solutions for wind turbines is emphasized since ice accretion can cause serious issues in generation of power and might lead to damage of blades. The use of active and passive anti-icing/de-icing technologies in wind turbine blade applications is reviewed. The discrepancy between passive anti-icing, which depends on surface treatment, coatings, de-icing fluids and active anti-icing, which uses heating devices, sensors such as actuators, transducers, is explored along with the current challenges in industry. In this study we’ve developed interesting methods for improving the anti-icing/de-icing capabilities of wind turbine blades by using gelcoat coatings in which are filler particles (boron nitride and graphene) and oils (vegetable and paraffin oil) are incorporated. Evaluating the impacts of type of fillers, oils, their concentrations on anti-icing efficacy, as well as the prospects for this technique to enhance wind energy production's reliability and productivity will be explored. In summary, this study aims to develop multi-functional polymer coatings for anti-icing/de-icing application in wind turbine blades. The coatings with boron-nitride and graphene showed an increase in the surface roughness and contact angles, while there’s no change in the chemical composition in comparison with pure gelcoat. The thermal conductivity of the coatings was increased with addition of fillers. For the wear test, the operating parameters chosen are a load of 5N and 1Hz frequency of slider, which is run for a duration of 10 min. The COF for both the coatings is lesser than baseline coatings whereas graphene provided better wear resistance. The hardness was increased for boron-nitride coatings and it remained almost same for graphene coatings. The ice adhesion strength, freezing delay and thermal analysis (TGA) for these coatings showed better performance than pure gelcoat. Whereas for coatings with vegetable and paraffin oils, the contact angles were increased and surface roughness was increased in case of paraffin oil coatings whereas it reduced for vegetable oil coatings. Both the coatings offered better wear resistance and reduced COF, whereas the hardness was reduced. The ice adhesion strength and freezing delay improved drastically and are much better than both pure gelcoat as well as coatings with boron-nitride and graphene. There is slight increase in the glass transition temperature than pure gelcoat coating.

Environmentally adaptable grease (EAG) lubricants are essential in applications with loss lubrication due to their biodegradable nature. This is because the lubricants could be expelled into the environment during usage in some applications e.g., marine and mining applications. However, although this type of grease is sustainable to use, it also needs to bridge the performance gap it has with the mineral-based grease counterpart.  In this thesis project, a tribological evaluation comparison between the performance of EAGs and traditional mineral-based greases in large open gears is carried out. A twin disc tribometer is used to mimic the contact mechanisms of the test gears while being lubricated automatically by the grease samples through a syringe pump. For the experiments, the material surface of all the discs in the tribometer setup is steel while the different grease samples are tested for each setup. Two of the grease samples; UPL 04123 (NLGI 1.5) and UPL 04124 (NLGI 0.5) are fully formulated EAGs, while the third is a popular commercial mineral-based grease currently used in large open gears in the mining industry. An investigation of the wear of the discs used in each grease test is carried out using optical interferometry and a Scanning electron microscope (SEM). The wear volumes and wear rates are then analysed and compared to evaluate the performance of the grease samples. The wear results from the tribological characterisation using the twin disc are validated with the ISO 14635-3 standard on the FZG back-to-back test rig. Also, chemical characterisation of the unused and used grease is carried out using the advanced ATR-FTIR method to evaluate additive depletion and lastly an SEM-EDS analysis to confirm the presence of tribofilm on the surfaces of the disc samples. In conclusion, it is found that there is a correlation between the consistency of the grease sample and wear prevention; where the commercial grease with the least consistency performs best, followed by the 0.5G and lastly the 1.5G. Also, there are clear indications in the wear rates of the actions of extreme pressure additives activation at high contact pressures between the discs. The inadequacies of the ATR-FTIR and SEM-EDS methods to evaluate additives and tribofilm respectively are also discussed.