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The Global ETD Search service is a free service for researchers
to find electronic theses and dissertations. This service is
provided by the
Networked Digital Library of Theses and Dissertations.
Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
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Showing 41 to 50 of 1634 (0.028 seconds)| 41 |
Tuning the flexibility in MOFs by SBU functionalizationBon, Volodymyr, Kavoosi, Negar, Senkovska, Irena, Müller, Philipp, Schaber, Jana, Wallacher, Dirk, Többens, Daniel M., Mueller, Uwe, Kaskel, Stefan 17 March 2017 (has links) (PDF)
A new approach for the fine tuning of flexibility in MOFs, involving functionalization of the secondary building unit, is presented. The "gate pressure" MOF [Zn3(bpydc)2(HCOO)2] was used as a model material and SBU functionalization was performed by using monocarboxylic acids such as acetic, benzoic or cinnamic acids instead of formic acid in the synthesis. The resulting materials are isomorphous to [Zn3(bpydc)2(HCOO)2] in the "as made" form, but show different structural dynamics during the guest removal. The activated materials have entirely different properties in the nitrogen physisorption experiments clearly showing the tunability of the gate pressure, at which the structural transformation occurs, by using monocarboxylic acids with varying backbone structure in the synthesis. Thus, increasing the number of carbon atoms in the backbone leads to the decreasing gate pressure required to initiate the structural transition. Moreover, in situ adsorption/PXRD data suggest differences in the mechanism of the structural transformations: from "gate opening" in the case of formic acid to "breathing" if benzoic acid is used.
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Unusual dimer formation of cyclometalated ruthenium NHC p-cymene complexesSchleicher, David, Tronnier, Alexander, Leopold, Hendrik, Borrmann, Horst, Strassner, Thomas 27 February 2017 (has links) (PDF)
We present the synthesis and structural characterization of novel ruthenium complexes containing C^C* cyclometalated N-heterocyclic carbene ligands, η6-arene (p-cymene) ligands and one bridging chlorine ion. Complexes of the general formula [Ru(p-cymene)(C^C*)Cl] were prepared via a one-pot synthesis using in situ transmetalation from the correspondent silver NHC complexes. These complexes react with sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaBArF4) to form dinuclear complexes of the general structure [Ru(p-cymene)(C^C*)-μ-Cl-(p-cymene)(C^C*)Ru]+[BArF4]−. Solid-state structures confirm that the pseudo-tetrahedral coordination around the metal center with the η6-ligand aligned perpendicularly to the C^C* ligand and the i-Pr group “atop” is retained in the bimetallic complexes.
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Fitness and mobility training in patients with Intensive Care Unit-acquired muscle weakness (FITonICU): study protocol for a randomised controlled trialMehrholz, Jan, Thomas, Simone, Burridge, Jane H., Schmidt, André, Scheffler, Bettina, Schellin, Ralph, Rückriem, Stefan, Meißner, Daniel, Mehrholz, Katja, Sauter, Wolfgang, Bodechtel, Ulf, Elsner, Bernhard 27 February 2017 (has links) (PDF)
Background
Critical illness myopathy (CIM) and polyneuropathy (CIP) are a common complication of critical illness. Both cause intensive-care-unit-acquired (ICU-acquired) muscle weakness (ICUAW) which increases morbidity and delays rehabilitation and recovery of activities of daily living such as walking ability. Focused physical rehabilitation of people with ICUAW is, therefore, of great importance at both an individual and a societal level. A recent systematic Cochrane review found no randomised controlled trials (RCT), and thus no supporting evidence, for physical rehabilitation interventions for people with defined CIP and CIM to improve activities of daily living. Therefore, the aim of our study is to compare the effects of an additional physiotherapy programme with systematically augmented levels of mobilisation with additional in-bed cycling (as the parallel group) on walking and other activities of daily living.
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Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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| 48 |
Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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| 49 |
Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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| 50 |
Statistischer Jahresbericht28 October 2016 (has links) (PDF)
Herausgegeben im Auftrag des Kanzlers
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