<p>Unmanned aerial systems (UASs) are at the intersection of robotics and aerospace re-<br> search. Their rise in popularity spurred the growth of interest in urban air mobility (UAM)<br> across the world. UAM promises the next generation of transportation and logistics to be<br> handled by UASs that operate closer to where people live and work. Therefore safety and<br> security of UASs are paramount for UAM operations. Monitoring UAS traffic is especially<br> challenging in urban canyon environments where traditional radar systems used for air traffic<br> control (ATC) are limited by their line of sight (LOS).<br> This thesis explores the design and preliminary results of a target tracking system for<br> urban canyon environments based on a network of camera nodes. A network of stationary<br> camera nodes can be deployed on a large scale to overcome the LOS issue in radar systems<br> as well as cover considerable urban airspace. A camera node consists of a camera sensor, a<br> beacon, a real-time kinematic (RTK) global navigation satellite system (GNSS) receiver, and<br> an edge computing device. By leveraging high-precision RTK GNSS receivers and beacons,<br> an automatic calibration process of the proposed system is devised to simplify the time-<br> consuming and tedious calibration of a traditional camera network present in motion capture<br> (MoCap) systems. Through edge computing devices, the tracking system combines machine<br> learning techniques and motion detection as hybrid measurement modes for potential targets.<br> Then particle filters are used to estimate target tracks in real-time within the airspace from<br> measurements obtained by the camera nodes. Simulation in a 40m×40m×15m tracking<br> volume shows an estimation error within 0.5m when tracking multiple targets. Moreover,<br> a scaled down physical test with off-the-shelf camera hardware is able to achieve tracking<br> error within 0.3m on a micro-UAS in real time.</p>

This dissertation comprises multiple studies surrounding demand estimation, feasibility and capacity analysis, and environmental impact of the Urban Air Mobility (UAM) or Advanced Air Mobility (AAM). UAM is a concept aerial transportation mode designed for intracity transport of passengers and cargo utilizing autonomous (or piloted) electric vehicles capable of Vertical Take-Off and Landing (VTOL) from dense and congested areas. While the industry is preparing to introduce this revolutionary mode in urban areas, realizing the scope and understanding the factors affecting the attractiveness of this mode is essential. The success of UAM depends on its operational efficiency and the relative utility it offers to current travelers. The studies presented in this dissertation primarily focus on analyzing urban travelers' current behavior using revealed preference data and estimating the potential UAM demand for different trip purposes in multiple U.S. urban areas. Chapter II presents a methodology to estimate commuter demand for UAM operations in the Northern California region. A mode-choice model is calibrated from the commuter mode-choice behavior observed in the survey data. An integrated demand estimation framework is developed utilizing the calibrated mode-choice model to estimate UAM demand and place vertiports. The feasibility of commuter UAM operations in Northern California is further analyzed through a series of sensitivity analyses. This study was published in Transportation Research Part A: Policy and Practice journal. In an effort to analyze the feasibility of UAM operations in different use cases, demand estimation frameworks are developed to estimate UAM demand in the airport access trips segment. Chapter III and Chapter IV focus on developing the UAM Concept of Operations (ConOps) and demand estimation methodology for airport access trips to Dallas-Fort Worth International Airport (DFW)/Dallas Love Field Airport (DAL) and Los Angeles International Airport (LAX), respectively. Both studies utilize the latest available originating passenger survey data to understand arriving passengers' mode-choice behavior at the airport. Mode-choice conditional logit models are calibrated from the survey data, further used to estimate UAM demand. The former study is published in the AIAA Aviation 2021 Conference proceeding, and the latter is published in ICNS 2021 Conference proceedings. UAM vertiport capacity may be a barrier to the scalability of UAM operations. A heavy concentration of UAM demand is observed in specific areas such as Central Business Districts (CBD) during the spatial analysis of estimated UAM demand. However, vertiport size could be limited due to land availability and high infrastructure costs in CBDs. Therefore, operational efficiency is critical for capturing maximum UAM demand with limited vertiport size. The study included in Chapter V focuses on analyzing factors impacting vertiport capacity. A discrete-event simulation model is developed to simulate a full day of commuter operations at the San Francisco Financial District's busiest vertiport. Besides calculating the capacity of different fundamental vertiport designs, sensitivity analyses are carried to understand the impact of several assumptions such as service time at landing pads, service time at parking stall, charging rate, etc. The study explores the importance of pre-positioning UAM vehicles during the time of imbalance between arrival and departure requests. This study is published in ICNS 2021 Conference proceedings. Community annoyance from aviation noise has often been a reason for limiting commercial operations at several major airports globally. Busy airports are located in urban areas with high population densities where noise levels in nearby communities could govern capacity constraints. Commercial aviation noise is only a concern during landing and take-offs. Hence, the impact is limited to communities close to the airport. However, UAM vehicles would be operated at much lower altitudes and have more frequent taking-off and landing operations. Since the UAM operations would mostly be over dense urban spaces, the noise potential is significantly high. Chapter VI includes a study on preliminary estimation of noise levels from commuter UAM operations in Northern California and the Dallas-Fort Worth region. This study is published in the AIAA Aviation 2021 Conference proceedings. The final chapter in this dissertation explores the impact of airspace restrictions on UAM demand potential in New York City. Integration of UAM operations in the current National Airspace System (NAS) has been recognized as critical in developing the UAM ecosystem. Several pieces of urban airspace are currently controlled by Air Traffic Control (ATC), where commercial operation density is high. Even though the initial operations are expected to be controlled by the current ATC, the extent to which UAM operations would be allowed in the controlled spaces is still unclear. As the UAM system matures and the ecosystem evolves, integrating UAM traffic with other airspace management might relax certain airspace restrictions. Relaxation of airspace restrictions could increase the attractiveness of UAM due to a decrease in travel time/cost and relatively more optimal placement of vertiports. Quantifying the impact of different levels of airspace restrictions requires an integrated framework that can capture utility changes for UAM under different operational ConOps. This analysis uses a calibrated mode-choice model, restriction-sensitive vertiport placement methodology, and demand estimation process. This study has been submitted for ICNS 2022 Conference. / Doctor of Philosophy / Urban Air Mobility (UAM) or Advanced Air Mobility (AAM) are concept transportation modes currently in development. It proposes transporting passengers and cargo in urban areas using all-electric Vertical Take-Off and Landing (eVTOL) vehicles. UAM is a multi-modal concept involving low-altitude aerial transport. The high capital costs involved in developing vehicles and infrastructure suggests the need for meticulous planning and strong strategy development in the rolling out of UAM. Moreover, urban travelers are relatively more sensitive to travel time savings and travel time reliability; therefore, the efficiency of UAM is critical for its success. This dissertation comprises multiple studies surrounding demand estimation, feasibility and capacity analysis, and the environmental impact of UAM. To estimate the potential for UAM, we need first to understand the mode-choice making behavior of urban travelers and then estimate the relative utility UAM could possibly offer. The studies presented in this dissertation primarily focus on analyzing urban travelers' current behavior and estimating the potential UAM demand for different trip purposes in multiple U.S. urban areas. The system planners would need to know the individual or combined effect of various parameters in the system, such as cost of UAM, network size of UAM, etc., on UAM potential. Therefore, sensitivity analyses with respect to UAM demand are performed against various framework parameters. Capacity constraints are not initially considered for potential demand estimation. However, like any other transportation mode, UAM could suffer from capacity issues that can cause operational delays. A simulation study is dedicated to model UAM operations at a vertiport and estimating factors affecting vertiport capacity. After observing the demand potential for certain optimistic scenarios, we realized the possibility of a large number of low-flying vehicles, which could cause annoyance and environmental impacts. Therefore, the following study focuses on developing a noise estimation framework from a full-day of UAM operations and estimating a highly annoyed population in the Bay Area and Dallas-Fort Worth Region. In our studies, modeling restricted airspaces (due to commercial operations at large airports) was always a critical part of the analysis. The urban airspaces are already quite congested in some urban areas, and we assumed that UAM would not operate in the restricted airspaces. The last study in this dissertation focuses on quantifying the impact of different levels of airspace restrictions on UAM demand potential in New York. It would help system planners gauge the level of integration required between the UAM and National Airspace System (NAS).

The aim of the study was to determine the 13 health risk PAHs (phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, ideno(1,2,3-cd)perylene and coronene; c-PAU highlighted) in the fractions of size-segregated aerosol of the urban air in Ostrava (2012, 2014) and Mlada Boleslav (2013) at low temperatures in winter, and to verify experimentally a sampling artifact, i.e., to quantify PAHs in the gas phase. For the particle size separation high-volume cascade impactor Hi-Vol BGI 900 was used. PAHs were determined by HPLC-FLD/PDA. In Ostrava in 2012 during the winter inversion (up to -25 řC), mean concentration of 13 PAHs in aerosol was 432 ng.m-3 ; in fraction 10 - 1 µm 119 ng.m-3 , 1 - 0,5 µm 185 ng.m-3 , 0,5 - 0,17 µm 91 ng.m-3 , in fraction < 0,17 µm 37 ng.m-3 and in the gaseous phase of min. 40 ng.m-3 . In the most unfavorable day 2. 2. 2012 (-18.6 ř C) reached the 24-hour average of 13 PAHs 890 ng.m-3 , the sum of carcinogenic PAHs 237 ng.m-3 and benzo(a)pyrene 32.3 ng.m-3 . An irregular and different decline of PAHs concentrations after inversion was measured: in fraction 1 - 10 µm 2.8 times, 0.5 - 1 µm 4.2 times, 0.5 - 0.17 µm 4 times and for <0.17 µm up to 7.6 times....

La pollution de l'air est un problème environnemental et social majeur. Parallèlement, c'est un problème complexe qui pose de multiples défis en termes de gestion et d'atténuation des polluants atmosphériques. Ceux-ci sont émis par des sources anthropiques et naturelles. Ils peuvent être soit émis directement (polluants primaires) soit formés dans l'atmosphère (en tant que polluants secondaires). Leurs impacts sur la santé, les écosystèmes, l'environnement, et le climat est avéré. Une action efficace pour réduire les impacts de la pollution de l'air nécessite une bonne compréhension de ses causes, de la manière dont les polluants sont transportés et transformés dans l'atmosphère et de leur impact sur l’Homme, les écosystèmes, le climat, la société, l'économie et le bâti. Aujourd’hui, les politiques et les plans d’aménagements visent à rendre les villes durables. Cela implique la prise en compte des interactions internes qui font de la ville un système complexe. Il est nécessaire de considérer les déterminants de la qualité de l’air. La modélisation s’impose comme un des principaux outils d’aide à la décision. Il existe actuellement peu de travaux de modélisation intégrant plusieurs champs disciplinaires en termes de qualité de l’air. Les travaux de recherche visent à développer une approche innovante de la modélisation de la qualité de l’air en intégrant des composantes sociales, économiques et de logistique de transport / Air pollution is a major environmental and social problem and, at the same time, it is a complex problem that poses multiple challenges in terms of management and mitigation of air pollutants. Air pollutants are emitted by anthropogenic and natural sources. They can be either emitted directly (primary pollutants) or formed in the atmosphere (secondary pollutants). Their impacts on health, ecosystems, the urban texture and the climate are proven. Effective action to reduce the impacts of air pollution requires a good understanding of its causes, how pollutants are transported and transformed in the atmosphere and their impact on humans, ecosystems, climate, society, the economy and buildings. Today, policies and development plans aim to make cities sustainable which involves taking into account the internal interactions that make the city a complex system. It is necessary to consider the determinants of air quality. Modeling is one of the most important tools for decision support. There is currently little modeling work integrating several disciplinary fields in terms of air quality. This research aims to develop an innovative approach to the modeling of air quality by integrating social, economic and transportation logistics

A base case modelling investigation was conducted to explore the chemical and physical behaviour of ground-level ozone (O3) and its precursor nitrogen dioxide (NO2) in Ontario using the U.S. Environmental Protection Agency (EPA) Community Multiscale Air Quality (CMAQ) model. Two related studies were completed to evaluate the performance of CMAQ in reproducing the behaviour of these species in both rural and urban environments by comparing to surface measurements collected by the Ontario Ministry of the Environment (MOE) network of air quality stations. The first study was a winter examination and the second study was conducted for a period during the summer of the same year. The municipality of North Bay was used to represent a rural setting given its smaller population relative to the city of Ottawa which was the base of the urban site. Statistical and graphical analyses were used to validate the model output. CMAQ was found to replicate the spatial variation of O3 and NO2 over the domain in both the winter and summer, but showed some difficulty in simulating the temporal allocation of the species. Validation statistics for North Bay and Ottawa showed overall O3 mean biases (MB) of 3.35 ppb and 2.25 ppb, respectively, and overall NO2 MB of -8.75 ppb and -4.37 ppb, respectively for the winter. Summer statistics generated O3 MB of 4.66 ppb (North Bay) and 10.05 ppb (Ottawa) while both MB for NO2 were between -2.20 ppb to -2.55 ppb. Graphical analysis showed that the model was not able to reproduce the lower levels of O3, especially at night, or the higher levels of NO2 during the day at the North Bay site for either season. This was expected since the comparisons were made between point measurements and 36 km grid-averaged model results. The presence of high amounts of NO2 emissions local to the monitoring sites compared to the levels represented in the emissions inventory may also be a contributing factor. The simulations for Ottawa demonstrated better agreement between model results and measurements as CMAQ provided a more accurate reproduction of both the higher and lower mixing ratios of O3 and NO2 during the winter and summer seasons. Results indicate that CMAQ is able to simulate urban environments better than rural ones.

Benzene is an important toxic chemical in urban air and known human carcinogen released substantially by mobile sources. It's important to understand the spatial variation of benzene concentrations in order to understand exposures of susceptible sub-populations such as children and minority groups. Current monitoring networks use large and expensive air samplers that require electricity and restrict the location and number of samplers, not allowing for fine spatial resolution data. The goals of this study are to develop and evaluate protocols for passive sampling and analysis of ambient benzene concentrations, and conduct a pilot study investigating small-scale variations over an area where children are likely to be exposed. Protocols were developed for the use and analysis of the Radiello RAD130 passive sampler for field sampling over the spatial scale of a city park adjacent to an elementary school. A pilot study was conducted from 4/27/11-5/4/11, where 11 samplers were exposed for a seven day sampling period at the park. After sampler exposure, benzene concentrations were determined through solvent desorption followed by analysis using a Varian gas chromatograph with mass spectrometer. Co-location with the existing regulatory active sampler in the county and of two samplers at the same site was done to evaluate the accuracy and precision of the methods, respectively. Health risk estimates were calculated using risk assessment guidance from the U.S. and California Environmental Protection Agencies. Concentrations over the park were found to range from 0.23 0.34 µg m^-3 with a coefficient of variation of 11%. A relative percent difference of 3% was found between the co-located sampler and the active sampler, and a 14% relative percent difference was found between the two duplicate samplers. The variation in health risk from concentration variation due to sampler placement contributed less to the overall uncertainty in the estimates than the uncertainty built in to the calculation parameters of inhalation unit risk and cancer potency factor, as estimated by the U.S. EPA and California EPA, respectively. These results suggest that the exposure of an individual at the park would be characterized sufficiently for standard health risk analysis through the use of one sampler. Further research is necessary into using passive samplers over both the same spatial scale in other areas, as well as on a larger scale to determine intra-urban benzene concentration distributions. The protocols developed here will be used in a future planned study of benzene concentration measurements to characterize neighborhood-scale exposures in Hillsborough County.

A base case modelling investigation was conducted to explore the chemical and physical behaviour of ground-level ozone (O3) and its precursor nitrogen dioxide (NO2) in Ontario using the U.S. Environmental Protection Agency (EPA) Community Multiscale Air Quality (CMAQ) model. Two related studies were completed to evaluate the performance of CMAQ in reproducing the behaviour of these species in both rural and urban environments by comparing to surface measurements collected by the Ontario Ministry of the Environment (MOE) network of air quality stations. The first study was a winter examination and the second study was conducted for a period during the summer of the same year. The municipality of North Bay was used to represent a rural setting given its smaller population relative to the city of Ottawa which was the base of the urban site. Statistical and graphical analyses were used to validate the model output. CMAQ was found to replicate the spatial variation of O3 and NO2 over the domain in both the winter and summer, but showed some difficulty in simulating the temporal allocation of the species. Validation statistics for North Bay and Ottawa showed overall O3 mean biases (MB) of 3.35 ppb and 2.25 ppb, respectively, and overall NO2 MB of -8.75 ppb and -4.37 ppb, respectively for the winter. Summer statistics generated O3 MB of 4.66 ppb (North Bay) and 10.05 ppb (Ottawa) while both MB for NO2 were between -2.20 ppb to -2.55 ppb. Graphical analysis showed that the model was not able to reproduce the lower levels of O3, especially at night, or the higher levels of NO2 during the day at the North Bay site for either season. This was expected since the comparisons were made between point measurements and 36 km grid-averaged model results. The presence of high amounts of NO2 emissions local to the monitoring sites compared to the levels represented in the emissions inventory may also be a contributing factor. The simulations for Ottawa demonstrated better agreement between model results and measurements as CMAQ provided a more accurate reproduction of both the higher and lower mixing ratios of O3 and NO2 during the winter and summer seasons. Results indicate that CMAQ is able to simulate urban environments better than rural ones.

Doctor of Philosophy(PhD) / Abstract This thesis employs a statistical regression method to estimate models for testing the hypothesis of the thesis of vehicle emissions interdependencies. The thesis at the beginnings, reviews critically the formation of emissions in gasoline-fuelled engines, and also reviews existing and emerging models of automotive emissions. The thesis then, presents the relationships between the urban transport system and vehicle emissions. Particularly, it summarises different types of emissions and the contributory factors of the urban transport system to such emissions. Subsequently, the thesis presents the theory of vehicle emissions interdependencies and the empirical framework for testing the hypothesis of the thesis. The scope of testing the hypothesis of the thesis is only limited to gasoline-fuelled conventional vehicles in the urban transport environment. We use already available laboratory-based testing dataset of 542 passenger vehicles, to investigate the hypothesis of the thesis of vehicle emissions interdependencies. HC, CO, and NOX emissions were collected under six test drive-cycles, for each vehicle before and after vehicles were tuned. Prior to using any application, we transform the raw dataset into actionable information. We use three steps, namely conversion, cleaning, and screening, to process the data. We use classification and regression trees (CART) to narrow down the input number of variables in the models formulated for investigating the hypothesis of the thesis. We then, utilise initial results of the analysis to fix any remaining problems in the data. We employ three stage least squares (3SLS) regression to test the hypothesis of the thesis, and to estimate the maximum likelihood of vehicle variables and other emissions to influence HC, CO, and NOX emissions simultaneously. We estimate twelve models, each of which consists of a system of three simulations equations that accounts for the endogenous relations between HC, CO and NOX emissions when estimating vehicle emissions simultaneously under each test drive-cycle. The major contribution of the thesis is to investigate the inter-correlations between vehicle emissions within a well controlled data set, and to test the hypothesis of vehicle emissions interdependencies. We find that HC, CO, and NOX are endogenously or jointly dependent in a system of simultaneous-equations. The results of the analysis demonstrate that there is strong evidence against the null hypothesis (H0) in favour of the alternative hypothesis (H1) that HC, CO, and NOX are statistically significantly interdependent. We find, for the thesis sample, that NOX and CO are negatively related, whereas HC and CO emissions are positively related, and HC and NOX are positively related. The results of the thesis yield new insights. They bridge a very important gap in the current knowledge on vehicle emissions. They advance not only our current knowledge that HC, CO, and NOX should be predicted jointly since they are produced jointly, but also acknowledge the appropriateness of using 3SLS regression for estimating vehicle emissions simultaneously. The thesis measures the responses of emissions to changes with respect to changes in the other emissions. We investigate emission responses to a one percent increase in an emission with respect to the other emissions. We find the relationship between CO and NOX is of special interest. After vehicles were tuned, we find those vehicles that exhibit a one percent increase in NOX exhibit simultaneously a 0.35 percent average decrease in CO. Similarly, we find that vehicles which exhibit a one percent increase in CO exhibit simultaneously a 0.22 percent average decrease in NOX. We find that the responses of emission to changes with respect to other emissions vary with various test drive-cycles. Nonetheless, a band of upper and lower limits contains these variations. After vehicle tuning, a one percent increase in HC is associated with an increase in NOX between 0.5 percent and 0.8 percent, and an increase in CO between 0.5 percent and one percent Also, for post-tuning vehicles, a one percent increase in CO is associated with an increase in HC between 0.4 percent and 0.9 percent, and a decrease in NOX between 0.07 percent and 0.32 percent. Moreover, a one percent increase in NOX is associated with increase in HC between 0.8 percent and 1.3 percent, and a decrease in CO between 0.02 percent and 0.7 percent. These measures of the responses are very important derivatives of the hypothesis investigated in the thesis. They estimate the impacts of traffic management schemes and vehicle operations that target reducing one emission, on the other non-targeted emissions. However, we must be cautious in extending the results of the thesis to the modern vehicles fleet. The modern fleet differs significantly in technology from the dataset that we use in this thesis. The dataset consists of measurements of HC, CO, and NOX emissions for 542 gasoline-fuelled passenger vehicles, under six test drive-cycles, before and after the vehicles were tuned. Nevertheless, the dataset has a number of limitations such as limited model year range, limited representations of modal operations, and limitations of the measurements of emissions based only on averages of test drive-cycles, in addition to the exclusion of high-emitter emission measurements from the dataset. The dataset has a limited model year range, i.e., between 1980 and 1991. We highlight the age of the dataset, and acknowledge that the present vehicle fleet varies technologically from the vehicles in the dataset used in this thesis. Furthermore, the dataset has a limited number of makes - Holden, Ford, Toyota, Nissan, and Mitsubishi. There are also a limited number of modal operations. The model operations presented in the dataset are cold start, warming-up, and hot stabilised driving conditions. However, enrichment episodes are not adequately presented in the test-drive cycles of the dataset. Moreover, the dataset does not take into account driving behaviour influences, and all measurements are cycle-based averages. The emission measurements of laboratory-based testings are aggregated over a test drive cycle, and the test drive-cycle represents an average trip over an average speed. The exclusion of the measurements of high emitting vehicles from the dataset introduces further limitations. Remote sensing studies show that 20 percent of the on-road vehicle fleet is responsible for 80 percent of HC and CO emissions. The findings of the thesis assist in the identification of the best strategies to mitigate the most adverse effects of air-pollution, such as the most severe pollution that have the most undesirable pollution effects. Also, they provide decision-makers with valuable information on how changes in the operation of the transport system influence the urban air-quality. Moreover, the thesis provides information on how vehicle emissions affect the chemistry of the atmosphere and degrade the urban air-quality.

Doctor of Philosophy(PhD) / Abstract This thesis employs a statistical regression method to estimate models for testing the hypothesis of the thesis of vehicle emissions interdependencies. The thesis at the beginnings, reviews critically the formation of emissions in gasoline-fuelled engines, and also reviews existing and emerging models of automotive emissions. The thesis then, presents the relationships between the urban transport system and vehicle emissions. Particularly, it summarises different types of emissions and the contributory factors of the urban transport system to such emissions. Subsequently, the thesis presents the theory of vehicle emissions interdependencies and the empirical framework for testing the hypothesis of the thesis. The scope of testing the hypothesis of the thesis is only limited to gasoline-fuelled conventional vehicles in the urban transport environment. We use already available laboratory-based testing dataset of 542 passenger vehicles, to investigate the hypothesis of the thesis of vehicle emissions interdependencies. HC, CO, and NOX emissions were collected under six test drive-cycles, for each vehicle before and after vehicles were tuned. Prior to using any application, we transform the raw dataset into actionable information. We use three steps, namely conversion, cleaning, and screening, to process the data. We use classification and regression trees (CART) to narrow down the input number of variables in the models formulated for investigating the hypothesis of the thesis. We then, utilise initial results of the analysis to fix any remaining problems in the data. We employ three stage least squares (3SLS) regression to test the hypothesis of the thesis, and to estimate the maximum likelihood of vehicle variables and other emissions to influence HC, CO, and NOX emissions simultaneously. We estimate twelve models, each of which consists of a system of three simulations equations that accounts for the endogenous relations between HC, CO and NOX emissions when estimating vehicle emissions simultaneously under each test drive-cycle. The major contribution of the thesis is to investigate the inter-correlations between vehicle emissions within a well controlled data set, and to test the hypothesis of vehicle emissions interdependencies. We find that HC, CO, and NOX are endogenously or jointly dependent in a system of simultaneous-equations. The results of the analysis demonstrate that there is strong evidence against the null hypothesis (H0) in favour of the alternative hypothesis (H1) that HC, CO, and NOX are statistically significantly interdependent. We find, for the thesis sample, that NOX and CO are negatively related, whereas HC and CO emissions are positively related, and HC and NOX are positively related. The results of the thesis yield new insights. They bridge a very important gap in the current knowledge on vehicle emissions. They advance not only our current knowledge that HC, CO, and NOX should be predicted jointly since they are produced jointly, but also acknowledge the appropriateness of using 3SLS regression for estimating vehicle emissions simultaneously. The thesis measures the responses of emissions to changes with respect to changes in the other emissions. We investigate emission responses to a one percent increase in an emission with respect to the other emissions. We find the relationship between CO and NOX is of special interest. After vehicles were tuned, we find those vehicles that exhibit a one percent increase in NOX exhibit simultaneously a 0.35 percent average decrease in CO. Similarly, we find that vehicles which exhibit a one percent increase in CO exhibit simultaneously a 0.22 percent average decrease in NOX. We find that the responses of emission to changes with respect to other emissions vary with various test drive-cycles. Nonetheless, a band of upper and lower limits contains these variations. After vehicle tuning, a one percent increase in HC is associated with an increase in NOX between 0.5 percent and 0.8 percent, and an increase in CO between 0.5 percent and one percent Also, for post-tuning vehicles, a one percent increase in CO is associated with an increase in HC between 0.4 percent and 0.9 percent, and a decrease in NOX between 0.07 percent and 0.32 percent. Moreover, a one percent increase in NOX is associated with increase in HC between 0.8 percent and 1.3 percent, and a decrease in CO between 0.02 percent and 0.7 percent. These measures of the responses are very important derivatives of the hypothesis investigated in the thesis. They estimate the impacts of traffic management schemes and vehicle operations that target reducing one emission, on the other non-targeted emissions. However, we must be cautious in extending the results of the thesis to the modern vehicles fleet. The modern fleet differs significantly in technology from the dataset that we use in this thesis. The dataset consists of measurements of HC, CO, and NOX emissions for 542 gasoline-fuelled passenger vehicles, under six test drive-cycles, before and after the vehicles were tuned. Nevertheless, the dataset has a number of limitations such as limited model year range, limited representations of modal operations, and limitations of the measurements of emissions based only on averages of test drive-cycles, in addition to the exclusion of high-emitter emission measurements from the dataset. The dataset has a limited model year range, i.e., between 1980 and 1991. We highlight the age of the dataset, and acknowledge that the present vehicle fleet varies technologically from the vehicles in the dataset used in this thesis. Furthermore, the dataset has a limited number of makes - Holden, Ford, Toyota, Nissan, and Mitsubishi. There are also a limited number of modal operations. The model operations presented in the dataset are cold start, warming-up, and hot stabilised driving conditions. However, enrichment episodes are not adequately presented in the test-drive cycles of the dataset. Moreover, the dataset does not take into account driving behaviour influences, and all measurements are cycle-based averages. The emission measurements of laboratory-based testings are aggregated over a test drive cycle, and the test drive-cycle represents an average trip over an average speed. The exclusion of the measurements of high emitting vehicles from the dataset introduces further limitations. Remote sensing studies show that 20 percent of the on-road vehicle fleet is responsible for 80 percent of HC and CO emissions. The findings of the thesis assist in the identification of the best strategies to mitigate the most adverse effects of air-pollution, such as the most severe pollution that have the most undesirable pollution effects. Also, they provide decision-makers with valuable information on how changes in the operation of the transport system influence the urban air-quality. Moreover, the thesis provides information on how vehicle emissions affect the chemistry of the atmosphere and degrade the urban air-quality.

Atmospheric aerosols have adverse effects on human health, air quality, and visibility and frequently result in severe pollution events, particularly in urban areas. However, the sources of aerosols and the processes governing their behaviour in the atmosphere, including those which lead to high concentrations, are not well understood thus limit our ability to accurately assess and forecast air quality. Presented here are the first long-term chemical composition measurements from an urban environment using an Aerodyne compact Time-of-Flight Aerosol Mass Spectrometer (cToF-AMS). Organic aerosols (OA) were observed to account for a significant fraction (44%) of the total non-refractory submicron mass during 2012 at the urban background site in North Kensington, London, followed by nitrate (28%), sulphate (14%), ammonium (13%), and chloride (1%). The sources and components of OA were determined using Positive Matrix Factorisation (PMF) and attributed as hydrocarbon-like OA (HOA), cooking OA (COA), solid fuel OA (SFOA), type 1 oxygenated OA (OOA1), and type 2 oxygenated OA (OOA2), where HOA, COA, and SFOA were observed to be of equal importance across the year. The concentration of secondary OA increased during the summer yet the extent of oxidation, as defined by the oxygen content, showed no variability during the year. The main factors governing the diurnal, monthly, and seasonal trends observed in all organic and inorganic species were meteorological conditions, specific nature of the sources, and availability of precursors. Regional and transboundary pollution influenced total aerosol concentrations and high concentration events were observed to be governed by different factors depending on season. High-Resolution ToF-AMS measurements were used to further probe OA behaviour, where two SFOA factors were derived from PMF analysis in winter, which likely represent differences in burn conditions. In the summer an OA factor was identified, likely of primary origin, which was observed to be strongly associated with organic nitrates and anthropogenic emissions. This work uses instruments and techniques that have not previously been used in this way in an urban environment, where the results further the understanding of the chemical components of urban aerosols. Aerosol sources are likely to change in the future with increases in solid fuel burning as vehicular emissions decrease, with significant implications on air quality and health. Thus it is important to understand aerosol sources and behaviour in order to develop effective pollution abatement strategies.