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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Influence of Water Absorption on Volume Resistivity and the Dielectric Properties of Neat Epoxy Material

Sulaimani, Anwar Ali 15 July 2014 (has links)
Epoxy resins are widely used materials in the industry as electrical insulators, adhesives and in aircrafts structural components because of their high mechanical stiffness, strength and high temperature and chemical resistance properties. But still, the influence of water uptake due to moisture adsorption is not fully understood as it detrimentally modifies the electrical and chemical properties of the material. Here ,we investigate the influence of water moisture uptake on the neat epoxy material by monitoring the change in the volume resistivity and dielectric properties of epoxy material at three different thickness configurations: 0.250 mm, 0.50 mm and 1 mm thicknesses. Gravimetric analysis was done to monitor the mass uptake behaviour, Volume Resistivity was measured to monitor the change in conductivity of the material, and the dielectric properties were mapped to characterise the type of water mechanism available within the material during two ageing processes of sorption and desorption. Two-stage behaviours of diffusion and reaction have been identified by the mass uptake analysis. Moreover, the plot of volume resistivity versus mass uptake has indicated a non-uniform relationship between the two quantities. However, the analysis of the dielectric spectrum at medium range of frequency and time has showed a change in the dipolar activities and also showed the extent to which the water molecules can be segregated between bounding to the resin or existing as free water
2

Evaluation of carbon blacks and binders in polymer thick film resistors

Haria, Niraj January 2005 (has links)
This objective of this project is to develop an understanding of the ink and its interaction with substrate of Penny & Giles controls Ltd's conductive plastic potentiometers, so as to develop alternate ink, substrate and processing methods. Conductive plastic potentiometers comprises, a track containing polymer binder and carbon black, printed on a base plastic substrate. The objectives have to take into account the performance ofthe potentiometers, which are to be improved or maintained. The first stage of the project was concerned with investigating the properties of the carbon black used in the inks, which have a major effect on the performance of the potentiometers. Ten different carbon blacks with different properties were selected. The carbon blacks properties for most of these were characterised by techniques that included transmission electron microscopy, x-ray photoelectron spectroscopy, differential scanning calorimetry, laser induced mass spectrometry and the scanning electron microscope. Inks were made with most of individual carbon blacks, and then tracks were produced on the diallyl phthalate plastic substrate. The electric resistance of these tracks was measured allowing the effect of carbon black properties on performance of the track to be studied. Various carbon black were found to provide similar performance to the Vegetabke MR842N, carbon black used currently. The next stage was the investigation of effect of binder on the performance of resistor using the same techniques as used in the first stage so that comparison could be made with the current binder. A phenolic binder was used and again showed similar properties to the DAIP binder used currently

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