Thesis (M.P.A.)--University of Hong Kong, 1999. / Includes bibliographical references (leaves 101-110). Also available in print.

Thesis (Ph. D.)--University of Southern California, 1997. / Includes bibliographical references (leaves 109-116).

Composting is a sustainable method to deal with huge amount of daily organic waste due to its robustness and easy operation. However, food waste (FW) as the main material in composting has disadvantages such as the heterogenous properties, high foreign matters contamination, high moisture content, low C/N ratio, poor structure, low porosity and high acidity during the initial phase of composting. These shortcomings not only influence degradation efficiency but also cease the composting process. Therefore, a bulking agent is required to increase the porosity and adjust the moisture content as well as C/N ratio of the composting mixture (Wong et al., 2010). For previous research, sawdust (SD) and tree barks were commonly used as the bulking agent in composting system but the demand for sawdust and tree barks significantly increased the cost of the composting process, and this has stimulated the demand of alternative substitutes. Therefore, the ideal situation is to find the bulking agent which is not only suitable for composting but is also a waste. Traditional Chinese medicine is widely used nowadays and huge amount of residues are accumulated and treated in landfilling (Wang and Li, 2013). According to previous research, only 5% of the active ingredients can be extracted from the medicinal plants which means there are still a large fraction of active ingredients remain in the herbal residues (Wu et al., 2013). In addition to the bulking property of Chinese medicinal herbal residues (CMHRs), it is assumed mature CMHRs compost have the ability to hinder regular metabolic pathway of phytopathogens after land application (Bernal-Vicente et al., 2008). The first experiment of this study investigated the formula between food waste, sawdust and CMHRs in order to achieve efficient composting. The experimental results demonstrated positively the use of CHMRs is a suitable candidate to co-compost with food waste. In terms of biodegradation decomposition efficiency and compost maturity, the treatment 1:1:1 (FW: SD: CHMRs, dry wt. basis) showed the best performance among all treatments with 67% organic matter degradation and 157% seed germination index. Only well-matured composting product can suppress plant diseases in soil since it has some microorganisms which can inhibit phytopathogens. The treatment 5:5:1 (FW: SD: CHMRs, dry wt. basis) also reached maturity but with a longer composting period; however, it was the treatment which could accommodate the highest quantity of food waste. The log copy number of the bacterial population was 7-8 initially, which decreased and stabilized along the composting. Results revealed that the CHMRs can be used as a bulking agent with food waste, and a dry weight ratio of 1:1:1 (FW: SD: CHMRs) would be optimum to achieve higher organic decomposition and faster maturity. However, the initial lower microbial population in the treatment, though without any adverse effect on the overall microbial decomposition, will warrant further work to indicate the total population is not a practical means to illuminate the effective microbial decomposition. Besides, the advantage in using CHMRs will need further experiment to indicate its potential pathogen suppression capability. Humification during co-composting of food waste, sawdust and CMHRs was investigated to reveal its correlation with compost maturity. The huge decrease in the treatment 1:1:1 (FW: SD: CHMRs, dry wt. basis) of aliphatic organics in humic acids (HA) demonstrated the degradation of the readily available organics, while an increase in aromatic functional groups indicated the maturity of compost. Disappearance of hemicellulose and weak intensity of lignin in the CMHRs treatments indicated that the lignin provided the nucleus for HA formation; and the CMHRs accelerated the compost maturity. Humic acid to fulvic acid (HA/FA) ratio of 1:1:1 treatment was the highest at the end of composting and showed a clear correlation with compost maturity as also evidenced through the presence of higher aromatic functional groups in the HA fraction. Pyr-TMAH-GC-MS results indicated that dominant groups were aliphatic and alicyclic esters and ethers at the early composting stages in all treatments. Long chain fatty acids were broken down into smaller molecular compounds earlier in treatment 1:1:1 (FW: SD: CHMRs, dry wt. basis), resulting from the faster decomposition rate. The complicated ring-structure components appeared dominantly at the later phase of composting. The peak intensities in treatment 1:1:1 (FW: SD: CHMRs, dry wt. basis) indicated that the composts became mature earlier than the other two treatments. In brief, the treatment with dry weight ratio 1:1:1 had greatest humification degree with more cyclic structures and stable final products at the end of composting. Water and acetone extract of composts with food waste and CMHRs were tested with their antipathogenic effect on two kinds of commonly found phytopathogens, Alternaria solani (A. solani) and Fusarium oxysporum (F. oxysporum). Seventeen bacterial species and 22 fungal species were isolated and identified as prevalently existed microbes during composting process. The results of MIC50 indicated that the treatment with dry weight ratio 1:1:1 (FW: SD: CHMRs, dry wt. basis) required least concentration of composts extraction to kill half quantity of the phytopathogens, 16% for A. solani and 22% for F. oxysporum extracted by acetone. The phytopathogen suppression capacity of composts was partially due to antagonistic abilities from some of the isolated microorganisms as well as the inhibition of active compounds. As shown in the comparison, the interfere/compete between antagonistic microorganisms and target pathogens were more powerful than individually influenced by chemical compounds. However, the influencing factors should not be considered independently since antagonistic interactions between microbes in composts and phytopathogens are highly dependent on the abiotic properties of the composts and the alternative environment. In a word, the antipathogenic effects from composts were synergism of both antagonism and chemical factors. Suppressive capacity on phytopathogens is one of the major function of mature composts and the antipathogenic effect was stimulated when CMHRs was used as the bulking agent in composting process. The abiotic inhibitory rates of treatment 1:1:1 (FW: SD: CHMRs, dry wt. basis) indicated that more powerful bioactive components were remained at the end of composting than in the treatment 5:5:1 and control which had no CMHRs but plastic beads as the bulking agent. Hence sensitive and comprehensive analytical technique of ultra-performance liquid chromatography coupled with time-of-flight mass spectrometry (UPLC-QTOF-MS) was utilized to acquire a better understanding of the complicated structures of final composting products. Seven dominant among 22 active compounds with antibacterial/antifungal properties were obtained in the treatments with CMHRs while 17 kinds of compounds with higher contents were shared in all treatments, which should be derived from food waste. The bioactive components from CMHRs composting were mainly from the groups of alkaloids, flavonoids and coumarins. Mature composts were used as biofertilizer to protect plants (Brassica chinensis and Lycopersicon esculentum) from phytopathogenic infection. This study showed the crop yields were increased with the addition of mature CMHRs composts to acid soil, and 5% CMHRs compost was the optimum application rate, while at the higher application rate of 10% (dry weight basis, w/w) plant growth was inhibited which might be due to the higher salt contents and the phytotoxicity of alkaloids, flavonoids and coumarins in the CMHRs. According to the biomass results, Brassica chinensis was more sensitive to the inhibitory effect of phytopathogen inoculation, while nutrient supply was to a less extent due to the short growth period as compared to Lycopersicon esculentum. The present study showed clearly that mature compost provided Lycopersicon esculentum and Brassica chinensis sufficient nutrients such as nitrogen and phosphorus. Additionally, the advantage of using mature CMHRs compost as a soil conditioner was also observed for blocking phytopathogenic infection from plant roots. The mechanism was mainly derived from the bioactive components in mature CMHRs compost which inhibited phytopathogenic activities in soil. Many identified compounds were alkaloids, flavonoids and coumarins which have powerful antifungal and antibacterial abilities and most of them maintained during growth period though their amounts reduced greatly due to their photolytic and pyrolytic properties. Therefore, mature CMHRs compost can be the substitute to reduce the usage of fungicides and its associated environmental hazards. The present study demonstrates clearly the beneficial effects of using CMHRs as a bulking agent to co-compost with food waste with the additional phytopathogens suppression property. Therefore, it is concluded that Chinese medicinal herbal residues can be a good choice of bulking agent in food waste composting system. Organic matter degradation and humification process were accelerated by CMHRs addition and mature CMHRs compost had antipathogenic effect and protect plants from infection

Composting is considered as an effective and sustainable food waste treatment technology from the perspectives of volume reduction, stabilization and releasing the pressure on landfills. Community composter is a decentralized composting facility in fed-batch operational mode which is usually being installed in the backyard of institutes, hospitals, housing estate etc. to handle the food wastes generated daily. Albeit numerous operational issues including high initial acidity and oil content, poor decomposition and odor generation are commonly encountered in these facilities, which make it difficult to be accepted by the public. Therefore, the aim of the present study is to develop a composting mix formulation that can provide a solution to all these issues in a fed-batch food waste composting process. The first phase of this study aims at finding out an optimized formulation in a batch-scale food waste composting process through the use of alkaline amendments and microbial inoculum. For the first two experiments, artificial food wastes were prepared by mixing 1.3kg bread, 1kg boiled rice, 1kg cabbage, 0.5kg fully boiled pork and mixed with sawdust to obtain a C/N of 30 and adjusted moisture of the mixtures to 55%. The effect of different concentrations of zeolite compared to lime was studied in the first experiment. Zeolite was amended with food wastes and sawdust mixtures at 2% (ZI-2), 5% (ZI-5), 10% (ZI-10) to compare with lime in 2.25% (L-2.25) w/w (dry weight basis) and composted for 56 days. Results demonstrated that 10% of zeolite was optimal amendment rate compared to lower dosage of zeolite (2% & 5%) with stronger pH buffering capacity and greater decomposition efficiency. Addition of 2.25% of lime buffered the pH efficiently but increased the ammonia loss significantly which eventually reduced total nitrogen (TN) content of final product and posed odor emission problem. Amendment of 10% zeolite provided a higher adsorption affinity on ammonia resulting in 2.05% of TN value of final product which was higher than 1.72% of lime treatment. Furthermore, significantly higher seed germination 150% was achieved of ZI-10 compost compared to 135% of L-2.25 due to low ammonium content of product. The first experiment showed that application of less than 10% zeolite was not sufficient to buffer the acidity; as a result, organic matter decomposition was inhibited. However, the cost and reduction in treatment percentage of food waste in 10% application rate of zeolite is an issue of concern. To tackle this dilemma, food waste was amended with struvite salts at 1:2 molar ratio of MgO and K2HPO4 (Mg:P) with or without zeolite amended at either 5% or 10% amendment (Mg:P, Z5 + Mg:P & Z10 + Mg:P) and a control treatment with food waste only was also included. Results showed that treatment of Z10 + Mg:P was synergistically achieved of pH and EC buffering, and N conservation but not for the case of 5 % zeolite. Treatment of Z10 + Mg:P further reduced the N loss to 18% compared to 25% and 27% of Mg:P and Z5 + Mg:P respectively. However, there was insignificant difference in the final nitrogen content and decomposition rate among all treatments with struvite salts amendment. Comparing to the treatment of Z-10 of the first experiment to Z10 + Mg:P of the second experiment, Z-10 showed superior performance since better decomposition efficiency, shorter time to require to pass the GI (28 Days) and lower cost because of salts exclusion. To develop a multipurpose formulation for the fed-batch operational food waste composter, high lipids problem in food waste cannot be neglected because it is a critical factor to hinder the decomposition efficiency. Inoculation of oil degradative microorganisms was reported as an effective approach to facilitate the lipids. Therefore, the third experiment was to investigate the overall composting performance supplemented with 10% zeolite and microbial consortium. 10% zeolite with bacterial consortium significantly reduced the lipid contents from 7% to 1% compared to control treatments. Furthermore, treatments amended with 10% zeolite was proved to reduce ammonia emission and total volatile fatty acids level in the composting mass, therefore the total odor emission level can be reduced. Zeolite at 10% was found to be a suitable optimum additive for both synthetic and real-food wastes. Therefore, treatment of 10% zeolite with bacterial consortium is selected as an optimized formulation for further study of its application in a fed-batch composter. Following the food waste zeolite composting formulation obtained in Phase I, the aim of Phase II was to develop an ideal composting mix formulation for on-site commercial composters. Although the results have been demonstrated 10% zeolite with bacterial consortium facilitated the composting efficiency in batch composter, those amendments may be over-estimated if applied in a fed batch composter by using real food wastes. With this constraint, the applicability of these additives in commercial fed-batch composter needs to be assessed using locally generated food wastes. Treatments included food waste and sawdust mixtures at 4:1 mixing ratio (wet weight basis) were mixed with 2.25% of lime (L2.25), 10% of zeolite (Z10) and 10% zeolite with bacterial inoculum (Z10+O) and a control of food waste with sawdust mixture only was also included. 35 kg compost mixture was fed into each composter respectively daily for a period of 42 days. Only Z10+O was the most suitable composting mix for fed-batch food waste composting process with continuous sustained high temperature (55-60oC), optimal moisture (55%-60%), alkaline pH and low EC during the experimental period. Bacterial inoculum significantly improved the lipids decomposition from 22.16% (C) to 3.10% (Z10+O) after the composting period. In contrast, lime and zeolite alone treatments could not maintain the optimal pH that led to reduce degradation and longer stabilization period. Only compost taken from Z10+O treatment could be classified as mature compost. The aim of the third study phase was to examine an optimal application rate of food waste compost produced from decentralized food waste composter for plant. A plant growth experiment was conducted in this phase to evaluate the change in soil properties and plant growth of Brassica chinensis and Lycopersicon esculentum. The experiment was conducted in a loamy soil amended with 0%, 2.5%, 5% and 10% food waste compost amendment rate compared to the control soil with chemical fertilizer amendment only. Results indicated that 5% was the optimal application rate of food waste compost for both crops among all treatments which can be evidenced by the highest biomass production and nutrients value of the plant tissues. Plant available nutrients such as NH4+, NO3-, PO43- were proportionally increased with increase in compost application rate. However, 2.5% of the food waste compost did not provide sufficient nutrients for plant growth and 10% showed negative effects due to increased salts content. Plants amended with chemical fertilizer had relatively low biomass production compared to compost amended treatments due to soil compaction and fast leaching of nutrients. It can be concluded that application of 10% zeolite with microbial consortium is an ideal composting mix formulation for on-site commercial composters and 5% is an optimal application rate of food waste compost of Brassica chinensis and Lycopersicon esculentum

Made available in DSpace on 2014-10-09T12:33:36Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:04:02Z (GMT). No. of bitstreams: 0 / Dissertação (Mestrado) / IPEN/D / Instituto de Pesquisas Energéticas e Nucleares - IPEN-CNEN/SP

Made available in DSpace on 2014-10-09T12:33:36Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:04:02Z (GMT). No. of bitstreams: 0 / Os resíduos sólidos galvânicos despertam especial atenção, devido à sua composição tóxica. Tais resíduos geralmente são estocados nas empresas de galvanoplastia, criando um preocupante passivo ambiental, em particular, nas áreas densamente povoadas, como a zona leste da cidade de São Paulo, que, por sua vez, possui um pólo de empresas de galvanoplastia do setor de cromação. Face ao pressuposto, na primeira parte do trabalho, um estudo foi realizado com a compilação dos dados de empresas galvânicas situadas na zona leste de São Paulo, abordando aspectos socioeconômicos e de processo, que influenciam na geração e na destinação dos resíduos sólidos industriais. Na segunda parte do trabalho, amostras selecionadas de resíduos sólidos foram avaliadas quanto às suas características químicas e físico-químicas e foi apresentada a viabilidade do uso tecnológico visando o aproveitamento destes resíduos. Os principais resultados obtidos mostraram que nas dezessete empresas visitadas são geradas 106 toneladas de resíduos sólidos por ano e estes são armazenados em condições precárias, podendo afetar a população vizinha em caso de acidentes ambientais. Os resíduos constituídos majoritariamente por Ni, Cr, B, Cu, Ca, S, C, Na, Fe e Zn, quando aquecidos até 1400°C, apresentaram formações de compostos identificados como Ca2Cr2O5, BaCrO4, NiCr2O4, CuCrO2, CaSO4, Ni2SiO4, NiO e CuO. Estes compostos são difíceis de serem obtidos e, por si só, apresentam potencial para comercialização como matérias-primas para a produção de produtos cerâmicos. Os resíduos sólidos galvânicos foram incorporados em matrizes vítreas, indicando uma alternativa satisfatória e de baixo custo para a inertização dos constituintes nocivos à saúde. Os vidros obtidos apresentaram aspectos coloridos, podendo ser utilizados como produtos finais ou como matérias-primas para a produção de esmaltes cerâmicos ou pigmentos inorgânicos. Existem diversas possibilidades de destinação dos lodos galvânicos e, independente de qual seja adotada, conclui-se que é de extrema importância a sua retirada de dentro das empresas, para eliminar o enorme e crescente passivo ambiental. / Dissertação (Mestrado) / IPEN/D / Instituto de Pesquisas Energéticas e Nucleares - IPEN-CNEN/SP

Orientador: Egle Novaes Teixeira / Dissertação (mestrado) - Universidade Estadual de Campinas. Faculdade de Engenharia Civil, Arquitetura e Urbanismo / Made available in DSpace on 2018-08-04T04:06:18Z (GMT). No. of bitstreams: 1 Nagle_ElizabethCamargo_M.pdf: 5086545 bytes, checksum: 5c6c4c2a956d9e08cd7d649d79ad6390 (MD5) Previous issue date: 2004 / Resumo: Com o crescimento urbano e a mudança dos padrões de consumo, houve o aumento da quantidade e qualidade do material descartado. Desta forma, com a produção de material cada vez mais complexo e a composição do resíduo sendo freqüentemente alterada, a estratégia de gestão e gerenciamento para solucionar o problema, fica mais difícil. A tendência mundial, em relação aos problemas provenientes do resíduo sólido, é a busca contínua de formas adequadas para dispô-lo e, com a consciência ambiental sendo fortemente incentivada, deve-se buscar minimizá-lo, como princípio. A realidade do futuro sustentável do ambiente traz como premissas, a redução, reutilização e reciclagem, ou seja, a Minimização de Resíduo. O objetivo deste trabalho foi avaliar o potencial de Minimização do Material Biodegradável de Alimentação contido no Resíduo Sólido Domiciliar de Municípios da Região Metropolitana de Campinas. Identificou-se o que estava presente no resíduo sólido domiciliar, através de caracterização (determinação da composição gravimétrica), adaptada para a minimização, que foi realizada durante o período de um ano, nos domicílios dos municípios de Valinhos, Vinhedo e na macrozona três do município de Campinas. Escolheu-se os bairros e trinta domicílios por município, considerando-se a classe social. Em cada dia pré estabelecido, coletou-se o resíduo diretamente nas casas, perfazendo um total de 480 amostras no período analisado. Após o tratamento dos dados, foi calculado o potencial de minimização do material biodegradável de alimentação, que apresentou valores acima de 50%, indicando que muito tem para ser feito. As possibilidades de minimização do resíduo foram avaliadas e para cada tipo de desperdício são apresentadas maneiras para viabilizá-lo. No âmbito de gerenciamento integrado de resíduo dos municípios, esta pesquisa fornece parâmetros científicos para embasar ações e mecanismos de planejamento que incentivem e conduzam a população ao desenvolvimento consciente, à melhor utilização dos produtos/ material, sem desperdício e levando em consideração a esgotabilidade do ambiente / Abstract: An increase of the amount and quality of the discarded material has arisen as a result of the urban growth and the change of consumption standards. With the production of material each day more complex and the composition of the waste being frequent1y modified, the treatment to this problem becomes more difficult. The worldwide trend, in relation to the problems associated with solid waste, is the continuous search for adequate forms for its disposal, and with the environment conscience being strongly stimulated; one must pursue means to minimize it, as a principle. The reality of the sustainable future of the environment brings as premises, the reduction, reutilization and recycling, or either, the Waste Minimization. The objective of this work was to evaluate the potential of Minimization of the Food Biodegradable Material contained in the Domiciliary Solid Waste in Cities of the Metropolitan Region of Campinas. It was identified what was present in the domiciliary solid waste, through the characterization, determination of the gravimetrical composition, that was carried through during the period of one year, in Valinhos, Vinhedo and in the macro zone three of Campinas, choosing the regions and the thirty domiciles, collecting the residue direct1y in these and considering its social standards. After the treatment of the data, the potential of the minimization of the biodegradable food material, which was found to be above 50%, was calculated and the possibilities of minimization were evaluated taking into account viable mechanisms to make it. Within the scope of the integrated municipal solid-waste management plan, the current research provides scientific parameters to support actions and mechanisms that stimulate and lead the population to the conscientious development, better use of the materials, without wastefulness and taking in consideration the environment exhaustion / Mestrado / Saneamento e Ambiente / Mestre em Engenharia Civil

The proper handling and disposal of medical waste in accordance with national guidelines is very important. This study was undertaken to investigate the state of medical waste and management practices in different hospitals in the north-eastern Free State Province, South Africa. A random sample of ten (10) hospitals was selected. Observation of operations was carried over a period of six months. A stratified random sample of 138 staff members spread across the ten medical facilities was selected and face-to-face interviews were conducted. The hospitals were grouped into 3 categories namely large, medium and small in terms of the number of hospital beds. Data collection through observation and covered waste generation, storage, handling, transportation, treatment and management procedures. Data analysis made use of SPSS to generate descriptive statistics, correlation coefficients and t-tests in hypothesis testing. The findings reveal that medical personnel do not treat medical waste as specified in official guidelines, there is no formal training for personnel, medical waste is not a key priority, there are low levels of environmental awareness, inappropriate treatment of waste at some sites, and inadequate budget allocations for medical waste management. These findings indicate that there is an urgent need for addressing issues of awareness for managers, better on-the job training for personnel, better systems for on-ward conveyance of waste from facilities to official medical waste treatment plants, an up-grade of existing incinerators and a consistent schedule of data capture should be implemented. / Thesis (Msc Env Science) North-West University, Mafikeng Campus, 2013

The application of multi-concentration group mathematical modelling to the leaching of radionuclide waste-forms which have continuous porous matrix such as cemented waste form is described. The modelling is illustrated analysing a hypothetical of some transport mechanisms such as molecular diffusion, ionic migration and convective flow for release of interest radionuclide from a solidified waste form which contains discrete particles of radioactive Sr-85 nuclides into the aqueous environment. The group parameters are derived from the classical electrochemistry concept of ion transport in dilute electrolytic solution. The numerical analysis is based on the Crank-Nicolson Implicit Methods which assures the stability of the solution at a practical time step. The results show that, for a short-time period of leaching in demineralized water the leaching behavior follows the predominating diffusion mechanism. After this point, the role of other processes apparent and continue until all radionuclides in the cement waste are leached out when compared to the Semi-Infinite Diffusion model which is based on pure diffusion mechanism. The multi-concentration group model can also be applied to long-term prediction of complicated release mechanisms of the radionuclides in the waste form of a particular disposal environment, unless the variables of interest such as the corrosion rate, the chemical reaction, erosion rate and etc. are determined by experiment or theoretical hypothesis. The appropriate differential equation then can be solved by the same general numerical approach. Also, the results of the modelling indicate which parameters should be measured experimentally in order to provide a quantitative test of the hypothetical release mechanism.

No description available.