Thesis (M. Sc.)--University of Canterbury, 2006. / Typescript (photocopy). Includes bibliographical references (leaves 104-110). Also available via the World Wide Web.

The Waipara – Kowai groundwater allocation zones (referred to as zones) are located 50 kilometers north of Christchurch. Land use in the Waipara zone has evolved from dry land farming towards horticultural and irrigated pastoral farming, and as such the demand for groundwater resources has increased significantly. Recent 14C age dating has shown that deep wells tap >1000 years old water, raising concerns about possible resource mining. The Kowai groundwater allocation zone has had minimal regional hydrogeological investigations and previously little is known about the groundwater resources here. The Waipara – Kowai groundwater allocation zones are located near obliquely convergent plate margin and the Porters Pass Fault System. Recent (early Quaternary) deformation has been noted by workers along margins and associated with emerging structures within basins. These emerging faults and folds within the basin are acting as hydrological barriers, hindering the passage of groundwater within the basin. A geomorphic map was constructed for this study based on existing soils maps, limited field soil surveys and morphometric analysis. Nine geomorphic surfaces are described, with inferred ages of modern to >73 ka. The geomorphic investigation revealed that the Kowai groundwater allocation zone surface is stepped, with increasing thickness of loess up gradient on the downlands. Near the coast there is intercalated terrestrial and marine sediments, to the west overlying the Kowai Formation are small alluvial fans. In the Waipara Basin the Waipara fan dominates the central portion of the basin, with smaller fluvial and alluvial fans building out from the margins. Groundwater recharge was investigated using chemical, isotopic, water level observations and a simple water balance. It was found that in the Kowai zone the major recharge sources were the rainfall, losses from the rivers and streams. The southern region of the Waipara zone is recharged by rainfall with small contributions from the Kowai River (North Branch). In the South region of the Waipara Basin groundwater recharge is derived from rainfall and losses from streams. The groundwater systems are conceptualized as being topographically driven, with slope – basin floors interactions being an important source of groundwater recharge.

The Waipara – Kowai groundwater allocation zones (referred to as zones) are located 50 kilometers north of Christchurch. Land use in the Waipara zone has evolved from dry land farming towards horticultural and irrigated pastoral farming, and as such the demand for groundwater resources has increased significantly. Recent 14C age dating has shown that deep wells tap >1000 years old water, raising concerns about possible resource mining. The Kowai groundwater allocation zone has had minimal regional hydrogeological investigations and previously little is known about the groundwater resources here. The Waipara – Kowai groundwater allocation zones are located near obliquely convergent plate margin and the Porters Pass Fault System. Recent (early Quaternary) deformation has been noted by workers along margins and associated with emerging structures within basins. These emerging faults and folds within the basin are acting as hydrological barriers, hindering the passage of groundwater within the basin. A geomorphic map was constructed for this study based on existing soils maps, limited field soil surveys and morphometric analysis. Nine geomorphic surfaces are described, with inferred ages of modern to >73 ka. The geomorphic investigation revealed that the Kowai groundwater allocation zone surface is stepped, with increasing thickness of loess up gradient on the downlands. Near the coast there is intercalated terrestrial and marine sediments, to the west overlying the Kowai Formation are small alluvial fans. In the Waipara Basin the Waipara fan dominates the central portion of the basin, with smaller fluvial and alluvial fans building out from the margins. Groundwater recharge was investigated using chemical, isotopic, water level observations and a simple water balance. It was found that in the Kowai zone the major recharge sources were the rainfall, losses from the rivers and streams. The southern region of the Waipara zone is recharged by rainfall with small contributions from the Kowai River (North Branch). In the South region of the Waipara Basin groundwater recharge is derived from rainfall and losses from streams. The groundwater systems are conceptualized as being topographically driven, with slope – basin floors interactions being an important source of groundwater recharge.

Climate is one of the most important factors influencing where wine grapes can be grown and the quality of wine produced from those grapes. A plants habitat has a profound influence on its growth and development. The surrounding climatic conditions at both the macro- and meso-scales influence the plant-climate miro-scale interactions. The main study site is the McKenzie Vineyard that is owned by Torlesse Wines. The climatic conditions of the surrounding Waipara region was also studied using climate data from the following vineyards; Canterbury House, River Terrace and Waipara West. The overall aim of this research is to improve understanding of the influence of the climatic environment on grapevine development at the meso- to micro-scale. The main findings of the research were firstly, that the most important climatic factor influencing grapevine development and growth is temperature and secondly that there is variability in the temperature across the Waipara Basin. Future research should be conducted for the entire growth season to gain a better understanding of how temperature influences the development of grapevine over the growing season as a whole.

Climate is one of the most important factors influencing where wine grapes can be grown and the quality of wine produced from those grapes. A plants habitat has a profound influence on its growth and development. The surrounding climatic conditions at both the macro- and meso-scales influence the plant-climate miro-scale interactions. The main study site is the McKenzie Vineyard that is owned by Torlesse Wines. The climatic conditions of the surrounding Waipara region was also studied using climate data from the following vineyards; Canterbury House, River Terrace and Waipara West. The overall aim of this research is to improve understanding of the influence of the climatic environment on grapevine development at the meso- to micro-scale. The main findings of the research were firstly, that the most important climatic factor influencing grapevine development and growth is temperature and secondly that there is variability in the temperature across the Waipara Basin. Future research should be conducted for the entire growth season to gain a better understanding of how temperature influences the development of grapevine over the growing season as a whole.

Nutrients for plant growth are often limited in soil systems and additions are required in the form of fertiliser. Potassium is an essential macro-nutrient for plants and demands for K are expected to increase in the future. Glaucony is an abundant marine mineral which may provide an alternative K-rich fertiliser resource. The South Island of New Zealand contains deposits of glaucony-rich rocks which were deposited in the Early- to Mid-Cenozoic during periods of low sedimentation to the seafloor. Here, the geochemistry of glaucony from the Waitaki Basin (Otago), the Waipara Greensand (North Canterbury) and the Stoney Creek Limestone (Karamea) was examined using spatially resolved geochemical analysis and dissolution experiments. Grain-by-grain analysis using Laser Ablation Induction Coupled Plasma Mass Spectrscopy (LA-ICP-MS) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM + EDS) revealed that glaucony from all deposits were of the mature type and were enriched in K. Glaucony derived from growth inside faecal pellets was found to contain elevated K and Fe concentrations compared to bioclast hosted glaucony. These variations can be explained by the physical properties of host grains and sea-floor redox conditions at the time of precipitation, both of which increased ionic mobility into the zone of glauconitisation. Solubility analysis showed that K^{+} was released from glaucony more rapidly than any other element. Additionally, decreasing the pH and introducing an oxidising agent (i.e, birnessite which is ubiquitous in soil environments) accelerated K^{+} release 13-fold. Trace metals including Cr, Zn, Cu and Ni were present in the solid phase analysis, however further investigation revealed that these elements were released into solution in low concentrations and may present a source of micro-nutrients, not a soil contaminant. These results suggest that glaucony may offer a source of slow releasing K fertiliser, and the South Island of New Zealand is ideally situated as a place to consider using glaucony as a locally sourced, environmentally sustainable K resource for agriculture.