Thesis (M Arch)--Montana State University--Bozeman, 2008. / Typescript. Chairperson, Graduate Committee: John Brittingham. Includes bibliographical references (leaves 90-92).

Thesis (M.E.S.)--Evergreen State College, 2009. / "June, 2009." Title from title screen (viewed 3/16/2010). Includes bibliographical references (p. 150-171).

Global warming and greenhouse gas (GHG) emissions have recently become the significant focus of engineering research. The geological sequestration of greenhouse gases such as carbon dioxide (CO₂) is one approach that has been proposed to reduce the greenhouse gas emissions and slow down global warming. Geological sequestration involves the injection of produced CO₂ into subsurface formations and trapping the gas through many geological mechanisms, such as structural trapping, capillary trapping, dissolution, and mineralization. While some progress in our understanding of fluid flow in porous media has been made, many petrophysical phenomena, such as multi-phase flow, capillarity, geochemical reactions, geomechanical effect, etc., that occur during geological CO₂ sequestration remain inadequately studied and pose a challenge for continued study. It is critical to continue to research on these important issues. Numerical simulators are essential tools to develop a better understanding of the geologic characteristics of brine reservoirs and to build support for future CO₂ storage projects. Modeling CO₂ injection requires the implementation of multiphase flow model and an Equation of State (EOS) module to compute the dissolution of CO₂ in brine and vice versa. In this study, we used the Integrated Parallel Accurate Reservoir Simulator (IPARS) developed at the Center for Subsurface Modeling at The University of Texas at Austin to model the injection process and storage of CO₂ in saline aquifers. We developed and implemented new petrophysical models in IPARS, and applied these models to study the process of CO₂ sequestration. The research presented in this dissertation is divided into three parts. The first part of the dissertation discusses petrophysical and computational models for the mechanical, geological, petrophysical phenomena occurring during CO₂ injection and sequestration. The effectiveness of CO₂ storage in saline aquifers is governed by the interplay of capillary, viscous, and buoyancy forces. Recent experimental data reveals the impact of pressure, temperature, and salinity on interfacial tension (IFT) between CO₂ and brine. The dependence of CO₂-brine relative permeability and capillary pressure on IFT is also clearly evident in published experimental results. Improved understanding of the mechanisms that control the migration and trapping of CO₂ in the subsurface is crucial to design future storage projects for long-term, safe containment. We have developed numerical models for CO₂ trapping and migration in aquifers, including a compositional flow model, a relative permeability model, a capillary model, an interfacial tension model, and others. The heterogeneities in porosity and permeability are also coupled to the petrophysical models. We have developed and implemented a general relative permeability model that combines the effects of pressure gradient, buoyancy, and capillary pressure in a compositional and parallel simulator. The significance of IFT variations on CO₂ migration and trapping is assessed. The variation of residual saturation is modeled based on interfacial tension and trapping number, and a hysteretic trapping model is also presented. The second part of this dissertation is a model validation and sensitivity study using coreflood simulation data derived from laboratory study. The motivation of this study is to gain confidence in the results of the numerical simulator by validating the models and the numerical accuracies using laboratory and field pilot scale results. Published steady state, core-scale CO₂/brine displacement results were selected as a reference basis for our numerical study. High-resolution compositional simulations of brine displacement with supercritical CO₂ are presented using IPARS. A three-dimensional (3D) numerical model of the Berea sandstone core was constructed using heterogeneous permeability and porosity distributions based on geostatistical data. The measured capillary pressure curve was scaled using the Leverett J-function to include local heterogeneity in the sub-core scale. Simulation results indicate that accurate representation of capillary pressure at sub-core scales is critical. Water drying and the shift in relative permeability had a significant impact on the final CO₂ distribution along the core. This study provided insights into the role of heterogeneity in the final CO₂ distribution, where a slight variation in porosity gives rise to a large variation in the CO₂ saturation distribution. The third part of this study is a simulation study using IPARS for Cranfield pilot CO₂ sequestration field test, conducted by the Bureau of Economic Geology (BEG) at The University of Texas at Austin. In this CO₂ sequestration project, a total of approximately 2.5 million tons supercritical CO₂ was injected into a deep saline aquifer about ~10000 ft deep over 2 years, beginning December 1st 2009. In this chapter, we use the simulation capabilities of IPARS to numerically model the CO₂ injection process in Cranfield. We conducted a corresponding history-matching study and got good agreement with field observation. Extensive sensitivity studies were also conducted for CO₂ trapping, fluid phase behavior, relative permeability, wettability, gravity and buoyancy, and capillary effects on sequestration. Simulation results are consistent with the observed CO₂ breakthrough time at the first observation well. Numerical results are also consistent with bottomhole injection flowing pressure for the first 350 days before the rate increase. The abnormal pressure response with rate increase on day 350 indicates possible geomechanical issues, which can be represented in simulation using an induced fracture near the injection well. The recorded injection well bottomhole pressure data were successfully matched after modeling the fracture in the simulation model. Results also illustrate the importance of using accurate trapping models to predict CO₂ immobilization behavior. The impact of CO₂/brine relative permeability curves and trapping model on bottom-hole injection pressure is also demonstrated. / text

published_or_final_version / Applied Geosciences / Master / Master of Science

published_or_final_version / Applied Geosciences / Master / Master of Science

When a patient is exposed surgical stress, the endocrine system secretes hormones in response to that stress. These hormones further activate the immune system to release cytokines and other acute phase reactions. These processes are supposed to protect the body by upregulating the innate immune system and producing an inflammatory response that acts to protect and heal. However, uncontrolled surgical stress may cause a weaker immune response that may lead to delayed wound healing. The phenomenon of unplanned perioperative hypothermia is known to expose patients to additional surgical stress. The purpose of this preliminary experimental study was to determine the effect of a preoperative warming intervention on the acute phase response of surgical stress in surgical patients. Specifically, the aim of this study was to evaluate the effect of a prewarming intervention using a forced-air warming (FAW) device versus routine care (RC) using warmed cotton blankets on the development of unplanned hypothermia, cytokine production, and endocrine responses. It was hypothesized that 1) the FAW participants would experience less unplanned perioperative hypothermia than the RC participants; 2) the FAW participants would experience lower catecholamine and cortisol levels than the RC participants; and 3) the FAW participants would experience higher proinflammatory cytokine and CRP production intra- and postoperatively than the RC participants. Infrared tympanic temperatures and 4 blood samples were taken at 4 time intervals from each of the 28 (n = 14 each group) randomized participants that underwent routine general anesthesia surgery. Serum concentrations of CRP, cortisol and IL-1beta, IL- 6, TNF-alpha, and IFN-gamma, and plasma concentrations of epinephrine and norepinephrine were measured. To test the hypotheses across time and between groups, a repeated measures ANOVA design was used. Though FAW was not associated with a differential endocrine or inflammatory response in this small, preliminary study, further study of forced air warming as a preoperative nursing intervention is warranted. The finding of higher than expected IL-6 levels in the preoperative period suggests a potential role for anxiety, an important factor in psychoneuroimmunological pathways, that could affect recovery and healing. The relationship between surgical stress, anxiety, and preoperative IL-6 deserves further study.

In recent decades, the environmental issues from the construction sector have attracted increasing attention from both the public and authorities. Notably, the bridge construction is responsible for considerable amount of energy and raw material consumptions. However, the current bridges are still mainly designed from the economic, technical, and safety perspective, while considerations of their environmental performance are rarely integrated into the decision making process. Life Cycle Assessment (LCA) is a comprehensive, standardized and internationally recognized approach for quantifying all emissions, resource consumption and related environmental and health impacts linked to a service, asset or product. LCA has the potential to provide reliable environmental profiles of the bridges, and thus help the decision-makers to select the most environmentally optimal designs. However, due to the complexity of the environmental problems and the diversity of bridge structures, robust environmental evaluation of bridges is far from straightforward. The LCA has rarely been studied on bridges till now. The overall aim of this research is to implement LCA on bridge, thus eventually integrate it into the decision-making process to mitigate the environmental burden at an early stage. Specific objectives are to: i) provide up-to-date knowledge to practitioners; ii) identify associated obstacles and clarify key operational issues; iii) establish a holistic framework and develop computational tool for bridge LCA; and iv) explore the feasibility of combining LCA with life cycle cost (LCC). The developed tool (called GreenBridge) enables the simultaneous comparison and analysis of 10 feasible bridges at any detail level, and the framework has been utilized on real cases in Sweden. The studied bridge types include: railway bridge with ballast or fix-slab track, road bridges of steel box-girder composite bridge, steel I-girder composite bridge, post tensioned concrete box-girder bridge, balanced cantilever concrete box-girder bridge, steel-soil composite bridge and concrete slab-frame bridge. The assessments are detailed from cradle to grave phases, covering thousands of types of substances in the output, diverse mid-point environmental indicators, the Cumulative Energy Demand (CED) and monetary value weighting. Some analyses also investigated the impact from on-site construction scenarios, which have been overlooked in the current state-of-the-art. The study identifies the major structural and life-cycle scenario contributors to the selected impact categories, and reveals the effects of varying the monetary weighting system, the steel recycling rate and the material types. The result shows that the environmental performance can be highly influenced by the choice of bridge design. The optimal solution is found to be governed by several variables. The analyses also imply that the selected indicators, structural components and life-cycle scenarios must be clearly specified to be applicable in a transparent procurement. This work may provide important references for evaluating similar bridge cases, and identification of the main sources of environmental burden. The outcome of this research may serve as recommendation for decision-makers to select the most LCA-feasible proposal and minimize environmental burdens. / <p>QC 20150311</p>

The most devastating effects of climate change may be avoided if humans reduce activities that produce greenhouse gases and engage instead in more sustainable ecological behaviors. The current mixed methods study of 279 undergraduate students explored whether environmental worldview, belief in climate change, knowledge of climate change, personal efficacy, and intention to address climate change influenced participants’ engagement in ecological behavior. Results indicated that those with a stronger intention to address climate change and a more ecocentric worldview reported significantly more ecological behavior. Next, the study examined whether participants’ intentions to address climate change mediated the relationship between their belief in climate change and engagement in ecological behavior and whether intentions mediated the relationship between efficacy and ecological behavior. Intentions to address climate change did not mediate the relationship between belief and ecological behavior but fully mediated the relationship between efficacy to address climate change and ecological behavior.

Over seventy percent of the 2.5 billion people who still lack access to basic sanitation worldwide live in rural areas (WHO/UNICEF, 2012). Despite concerns of water scarcity, resource depletion, and climate change little research has been conducted on the environmental sustainability of household sanitation technologies common in rural areas of developing countries or the potential of resource recovery to mitigate the environmental impacts of these systems. The environmental sustainability, in terms of embodied energy and carbon footprint, was analyzed for four household sanitation systems: (1) Ventilated Improved Pit (VIP) latrine, (2) pour-flush latrine, (3) composting latrine, and (4) biodigester latrine. Variations in design and construction materials used change the embodied energy of the systems. It was found that systems that used clay brick in the construction of the superstructure had an average cumulative energy demand 4,307 MJ and a global warming potential 362 kilograms of greenhouse gas equivalent (kgCO2 eq) higher than systems that used adobe brick in the construction of the superstructure. It was also found that systems that incorporate resource recovery, such as a composting or biodigester latrine, can become net energy producers over their service life, recovering between 29,333 and 253,190 MJ over a 20-year period, compared to the 11,275 to 19,990 MJ required for their construction and maintenance. Recovering the resources from the waste also significantly lowered the global warming potential of these systems from 2,079-49,655 kgCO2 eq to 616-1,882 kgCO2 eq; significantly less than the global warming potential of VIP latrine or pour-flush latrines (8,642-15,789 kgCO2 eq). In addition, two community wastewater treatment systems that serve 420-1,039 individuals considered in a similar study had a higher cumulative energy demand per household (44,869 MJ and 38,403 MJ) than the household sanitation systems (11,275-19,990 MJ). The community wastewater treatment systems had a lower global warming potential (2019-2,092 kgCO2 eq) than household systems that did not recover resources (8,642-15,789 kg CO2 eq), but higher than household systems that incorporate resource recovery (616-1,882 kgCO2 eq). The goal of this study is to provide insight to policy makers in the development field to promote decision making based on environmental sustainability in the implementation of improved sanitation coverage in rural areas of developing countries.

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