The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. The experimental apparatus, procedures and results obtained in this thesis on scaled-down experiments of SST Early and Late Feed simulated solutions were adapted and reproduced under hot-cell with actual wastes by our partners at Hanford. To prepare the application of the pretreatment process to pilot scale process, several varation to the feed solutions were investigated including the presence of carboxylates and amines organics compounds and solids particles. Results of the study showed that 4 organics species presented complications to the process (NTA, HEDTA, EDTA and sodium citrate) while the other species (Formate, acetate, glycolate and IDA) and solids particles did not in the conditions of the stored wastes. In this thesis, the kinetics of the crystalline species formed at the condition of the early feed certification run (66 °C and 25 g/h evaporation) were determined along with the effect of the operating temperature and evaporation rate on these kinetics. On one hand, the study of evaporation rate values ranging from 25g/h to 75g/h showed that an increase in evaporation rate increased the specific nucleation while decreasing the specific growth rate. On the other hand, experiments on operating temperature ranging from 35 °C to 75 °C displayed that the nucleation rate of all species increased with temperature at the exception of sodium carbonate monohydrate and burkeite crystals, and that the growth rate of all species increased with temperature at the exception of sodium nitrate. Furthermore, sulfate based crystals such as trisodium fluoride sulfate were only roduced at 45 °C and 75 °C. A simple steady state MSMPR population balance model was developed expressing the total population density function as the sum of the specific population density functions. The specific semi-batch crystallization kinetics were implemented in this model.

The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. In this thesis, experimental apparatus, procedures and results are given on scaled-down experiments of SST Early Feed for hot-cell adaptation along with operating parameters and crystallization mechanism studies on early feed multi-solute crystallization. Moreover, guidance is given regarding future steps towards adapting the technology to multi-salt crystallization kinetic parameter estimates and modeling. Crystallization, Evaporative Fractional Crystallization, Nuclear Waste Pretreatment, Cesium Removal, Hanford, SST Early and Late feed, Multi-solute, Multi-salts, Simulant Testing

xvii, 382 p. : ill. (some col.), maps. A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / The debate concerning the role of natural versus anthropogenic burning in shaping the prehistoric vegetation patterns of the Willamette Valley of Oregon and Washington remains highly contentious. To address this, pollen and high-resolution charcoal records obtained from lake sediments were analyzed to reconstruct the Holocene fire and vegetation history, in order to assess the relative influence of climate variability and anthropogenic activity on those histories. Two sites provided information on the last 11,000 years. At one site at the northern margin of the Willamette Valley, shifts in fire activity and vegetation compared closely with millennial- and centennial-time scale variations in climate, and there was no evidence that anthropogenic burning affected the natural fire-climate linkages prior to Euro-American arrival. In contrast, the fire and vegetation history at a site in the central Willamette Valley showed relatively little vegetation change in response to both millennial- and centennial-scale climate variability, but fire activity varied widely in both frequency and severity. A comparison of this paleoecological reconstruction with archaeological evidence suggests that anthropogenic burning near the site may have influenced middle- to late-Holocene fire regimes. The fire history of the last 1200 years was compared at five sites along a north-south transect through the Willamette Valley. Forested upland sites showed stronger fire-climate linkages and little human influence, whereas lowland sites located in former prairie and savanna showed temporal patterns in fire activity that suggest a significant human impact. A decline in fire activity at several sites in the last 600 years was attributed to the effects of a cooling climate as well as the decline of Native American populations. The impacts of Euro-American settlement on the records include dramatic shifts in vegetation assemblages and large fire events associated with land clearance. The results of this research contribute to our understanding of long-term vegetation dynamics and the role of fire, both natural- and human-ignited, in shaping ecosystems, as well as provide an historical context for evaluating recent shifts in plant communities in the Willamette Valley. / Advisers: Cathy Whitlock, Patrick J. Bartlein

The purpose of this thesis was to examine a partial differential equation to model the Tacoma Narrows bridge failure. This thesis will examine the equation developed by Lazer and McKenna to model a suspension bridge in no wind.

Evidence of large earthquakes occurring along the Pacific Northwest coast is reflected in coastal stratigraphy from Oregon to British Columbia, where there also exists an extensive archaeological record of Native American occupation. Tse-whit-zen, a large Native American village dating between 1824 and 54 cal B.P. located on the Olympic Peninsula of Washington State, was excavated with exceptionally fine stratigraphic control allowing for precise comparison of natural and cultural records. Here I report on the >10,000 fish remains from one 2x2 m excavation block; this assemblage spans one earthquake event, allowing study of changes in relative taxonomic abundance through time that may coincide with earthquakes or other environmental changes. Results indicate use of a wide range of marine fish taxa including various sculpins (Cottidae), flatfish (Pleuronectiformes), herring (Clupea pallasii) and salmon (Oncorhynchusspp.). This illustrates a highly diverse diet throughout occupation, though relative abundances of more offshore taxa decrease through time in favor of some nearshore taxa, possibly indicating the presence of a coseismic event. This thesis serves as part of a pilot study for a collaborative project that is underway. This larger project addresses human response to both gradual and abrupt environmental change through the analysis of all classes of Tse-whit-zen faunal remains, which provide a link to impacts on animal populations and in turn human subsistence.

Indiana University-Purdue University Indianapolis (IUPUI) / The Antler and Sonoma orogenies occurred along the southwest-trending passive Pacific margin of North America during the Paleozoic concluding with the accretion of the McCloud Arc. A southeast-trending sinistral transform fault truncated the continental margin in the Permian, becoming a locus for initiation of an east-dipping subduction zone creating the Sierran magmatic arc. Constrained in age between two early Triassic tuff layers, the volcanic clasts in the breccia of Frog Lakes represent one of the earliest records of mafic magmatism in the eastern Sierra Nevada. Tholeiitic rock clasts found in the breccia of Frog Lakes in the Saddlebag Lake pendant in the east central Sierra Nevada range in composition from 48% to 63% SiO2. Boninites produced by early volcanism of subduction initiation by spontaneous nucleation at the Izu-Bonin-Mariana arc are more depleted in trace element concentrations than the clasts while andesites from the northern volcanic zone of the Andes produced on crust 50 km thick have similar levels of enrichment and provide a better geochemical modern analogue. Textural analysis of the breccia of Frog Lakes suggest a subaqueous environment of deposition from a mature magmatic arc built on continental crust > 50 km thick during the Triassic. The monzodiorites of Saddlebag and Odell Lakes are temporal intrusive equivalents of the breccia of Frog Lakes and zircon geochemistry indicates a magmatic arc petrogenesis.