Lakes can be used for recreational purposes, agricultural irrigation, domestic water supply or industrial use. However, these functions of the lakes can be impaired due to excess nutrient loadings from industrial facilities, agricultural activities, and discharge of wastewaters from sewage systems. Uluabat Lake is one of the important lakes in Turkey faced with water quality problems due to excess nutrient loading from point and non-point sources. In this study, Water Quality Analysis Simulation Program (WASP Version 7.2), supported by the Environmental Protection Agency (EPA), was used to simulate the water quality of the lake. The model was calibrated using a set of data belonging to the time period from January 1st to June 1st, 2000, for dissolved oxygen (DO), chlorophyll-a (Chl-a), ortho-phosphate (PO4-P) and nitrate (NO3-N). An acceptable similarity was obtained between the predicted and observed water quality values in calibration. Then, the model was verified for another data set. Verification period was from 1st of June to 31st of December, 1999. Verification results were also coherent with the observed values. Following the calibration and verification, the model was used as a management tool to predict the future quality conditions for the lake for different management scenarios. According to the results, sediment dredging had a significant impact on the water quality. Additional methods on top of sediment dredging improved the quality of the lake. The best result was obtained when buffer zone was formed, phosphorus loads from the MustafakemalpaSa District sewage system and Emet and Orhaneli Watersheds were decreased by 50% and 50% decrease was considered in the fertilizer usage throughout the agricultural lands, in addition to sediment dredging.

ABSTRACT SOIL AND WATER ANALYSIS TECHNIQUES FOR AGRICULTURAL PRODUCTION Maral, Nuh M. Sc., Department of Chemistry Supervisor: Prof. Dr. G. inci G&ouml / kmen May 2010, 108 pages In Turkey, usage of increasing amounts of fertilizers and pesticides by some unconscious farmers cause soil pollution and soil infertility for the crop production. Usage of water in excessive amounts and/or in poor quality for irrigation creates problems during the plant production. So in this study, soil and water samples were analyzed by using simple and reliable techniques for the soil and water quality in laboratories of METU and Soil Fertilizer and Water Resources Central Research Institute Laboratory in Ankara. The soil and water samples were collected using the standard techniques from Ankara, Bolu, &Ccedil / orum and Kirikkale. According to the soil test results, the textures of the soil samples are found as loam and clay loam. The total salt content of the soil samples are between 0.033 &ndash / 0.063 % (w/w), meaning they are low salinity soils (total salt less than 0.15 % w/w). The pH of the soil samples are between 7.86&ndash / 8.15, they are slightly alkaline. The phosphorus concentrations of soil samples are in a range 4.95 to 35.45 P2O5 kg/da. Some of the soil samples have too high phosphorus content (greater than 12 P2O5 kg/da). The potassium content of soil samples are found between 141&ndash / 286 K2O kg/da, so the soil is efficient for crop production. Lime content of the soil samples is between 1.04&ndash / 2.67 % (w/w) CaCO3. It means all of the soil samples are calcareous but it is not too high for the agricultural production. Organic matter content of soil samples are found between 0.83&ndash / 2.04 % (w/w). This means the soils are limited in their organic matter content for the crop production. Analysis of 22 water samples yielded EC values between 0.384 &ndash / 1.875 dS/m. Water samples have moderate to high-salinity (if EC values between 0.205 and 2.250 dS/m), yet these can be used for the irrigation of the crops. pH values of water samples are found between 7.18-8.10, meaning that they are slightly alkaline. Bicarbonate concentrations of 19 of the water samples are greater than 200 mg/L. These waters may not be suitable for irrigation of ornamental plants. All of the water samples, except water samples from G&ouml / lbaSi, have sodium absorption ratio (SAR) values between 1 and 9. Water samples with low SAR values, except water samples from G&ouml / lbaSi, can be used for irrigation of almost all soils with little danger of developing harmful levels of sodium. The Residual Sodium Carbonate (RSC) values of water samples Ankara G&ouml / lbaSi and Sincan-1 are greater than 2.50 meq/L and these water samples are not suitable for the irrigation. RSC values of Etimesgut, Sincan-2 and Kazan water samples are positive and lower than the value 2.00 meq /L. All the other water samples have negative RSC values so they are the safe to use for irrigation. It has been observed that development of practical field analysis techniques for all soil and water quality parameters may be possible with exception of micronutrient determination. For determining soil and water quality parameters in the rural areas there is a need to establish a small laboratory with necessary equipment and apparatus and training one or two farmers. With the experience gained in this study, some of these techniques may be adapted to the rural field applications, so soil and water may be tested by the farmers for better yields.

This study aimed to investigate the activity change of the sludge in a bioreactor after the addition of industrial wastewater and the influence on water quality of nearby waterway after the entrance of the treated effluent. Furthermore, with respect to the industrial effluent¡¦s direct discharge to the near sea, the investigation of water quality was also undertaken to set up the database of water quality for the related receiving waters and further to provide information useful for the future monitoring and assessing the possible water pollution caused by the Tainan Technology Industrial Park (TTIP). At this present study, the TTIP, which was not at the stage of formal operation, was selected as the research object to investigate the possible adverse effects of the effluent from Hi-tech industries on the environment. In the first part of this study, several techniques for sludge diagnosis were used to evaluate the activity of sludge in various types of wastewaters in order to choose appropriate biological indices to represent the performance of a bioreactor. The results showed that dissolved oxygen was proportional to DHA concentration and number of bacteria. In addition, that both suspended solids (SS) and volatile suspended solids (VSS) had poor correlation with dissolved oxygen led to their failure to be the biological indices. In the second part of this study, the influence on the water quality after the treated wastewater discharged into the nearby receiving waters was investigated. The results of field investigation showed that the effluent did not cause significant negative effects on the receiving waters but positive effects instead due to its lowering the concentrations of water pollutants. Summarily, the effluent emitted from the TTIP had no significant impact on the nearby receiving waters by now. However, in the future, when most of the factories in the park begin to produce products, further studies are required to make sure whether the effluent will cause adverse impact on the nearby water environments.

Concentrated animal feeding operations (CAFOs) have caused water quality concerns in many rural watersheds, sometimes forcing the State of Texas to conduct Total Maximum Daily Load (TMDL) assessments of stream nutrients such as nitrogen (N) and phosphorus (P). One suggested Best Management Practice (BMP) is the export of phosphorus (P) through turfgrass sod produced with composted dairy manure from an impaired rural watershed to an urban watershed. The manure-grown sod releases P slowly and would not require additional P fertilizer for up to 20 years in the receiving watershed. This would eliminate P application to the sod and improve the water quality of urban streams. The Soil and Water Assessment Tool (SWAT) was used to model a typical suburban watershed that would receive the transplanted sod. The objective of the modeling was to determine the water quality changes due to the import of sod transplanted from turf fields and grown with composted dairy manure. The SWAT model was calibrated to simulate historical flow and sediment and nutrient loading to Mary's Creek. The total P stream loading to Mary's Creek was lower when manure-grown sod was imported instead of commercial sod grown with inorganic fertilizers. Yet, flow, sediment yield, and total N yield increased equally for both cases at the watershed outlet. The SWAT simulations indicate that a turfgrass BMP can be used effectively to import manure P into an urban watershed and reduce in-stream P levels when compared to sod grown with inorganic fertilizers.

The Upper North Bosque River (UNBR) watershed is under a Total Maximum Daily Load (TMDL) mandate to reduce Phosphorus (P) due to excess nutrients in the watershed. To address these problems, Texas A&M University researchers have developed a turfgrass sod Best Management Practice (BMP) to remove excess nutrients from impaired watersheds. Turfgrass harvest of manure fertilized sod removes a thin layer of topsoil with most of the manure applied P. Plot and field scale research has demonstrated the effectiveness of turfgrass to remove manure phosphorus (P). In order to assess the impact of the turfgrass BMP on a watershed scale, the Soil and Water Assessment Tool (SWAT) was used to predict water quality in the UNBR watershed. The SWAT model was modified to incorporate turfgrass harvest routines to predict manure and soil P export through turfgrass sod and soil during harvest. SWAT simulations of the BMP predicted stream load reductions of 20 to 36% for P loads in the UNBR depending on the implementation scenario, an average reduction of 31% for total N and 16.7% for sediment for all the scenarios, at the watershed outlet. The SWAT model also predicted up to 176 kg/ha P removed per sod harvest when fertilized with 100 kg manure P/ha, and 258 kg/ha of P removed per sod harvest when the manure P application rate was 200 kg/ha. In addition, depending on the implementation scenario, the turfgrass BMP could export between 262 and 784 metric tons of P out of the UNBR watershed every year. Manure fertilized turfgrass has the advantage of slow releasing nutrients from the composted dairy manure, so it would not require any additional P for life. This means reduced urban non-point source pollution and lower maintenance cost compared to regular sod. These modeling simulations complement the wealth of research that shows the effectiveness of the turfgrass BMP.

Pharmaceuticals and personal care products (PPCPs) are widely used, resulting in trace amounts being detected in the aquatic environment. This presence is of human health and ecological concern and it is necessary to determine the best methods to eliminate them from our waters. The oxidation of PPCPs by permanganate was evaluated using a spectrophotometer to monitor permanganate reduction. Thirty-nine compounds were chosen to represent numerous classifications, including beta blockers, cephalosporins, fluoroquinolones, macrolides, non-steroidal anti-inflammatory drugs, phenol structures, polypeptides, sulfonamides, tetracyclines, and triazines. The reactivity of each compound was determined by measuring the absorbance of permanganate over time as it reacted with an excess of the compound. The absorbance data was fit to a pseudo-first-order reaction model that accounted for the growth of manganese dioxide colloids. The most reactive groups that reduced permanganate within minutes at pH 7.0 were the cephalosporins, phenol structures, and tetracyclines. The majority of the remaining pharmaceuticals and personal care products were moderately or weakly reactive (reducing permanganate within hours). Caffeine, carbadox, monensin, simetone, and tri(2-carboxyethyl)phosphine were poorly reactive (reducing permanganate over days). Metoprolol was the only selected compound that was determined to be potentially non-reactive (no reaction after 1 day). Polarizability and refractive index of the organic compounds showed significant positive correlations (R-squared > 0.50) with the first-order reaction rates for non-steroidal anti-inflammatory drugs and the phenol structures group. The half-life of each PPCP was determined based on a typical dosage of permanganate used for pre-oxidation. Eleven of the thirty-nine PPCPs had a half-life of less than thirty minutes (a typical contact time), indicating that oxidation by permanganate may be a viable option. There are many opportunities for further research in this area, including investigating more PPCPs, physicochemical property correlations, and the impact of water quality conditions

Thesis (M.S.)--Eastern Illinois University, 2009. / Includes bibliographical references (leaves [117]-125).

Thesis (Ph. D.)--West Virginia University, 2009. / Title from document title page. Document formatted into pages; contains ix, 199 p. : ill. (some col.), col. maps. Includes abstract. Includes bibliographical references (p. 142-172).

Thesis (M.S.)--University of North Carolina at Wilmington, 2003. / Includes bibliographical references (leaves : [56]-59).

Thesis (Ph. D.)--University of Hong Kong, 2010. / Includes bibliographical references (p. 199-216). Also available in print.