Orientador: Marcos Franke Pinto / Coorientador: Danielle de Bem Luiz / Coorientador: Elisa Helena Giglio Ponsano / Resumo: O crescimento sustentável da indústria de processamento de tilápia está diretamente relacionado com o uso eficiente de água e com a gestão da qualidade da água devolvida ao meio ambiente. Foi avaliado o uso global de água um uma planta de produção de filé de tilápia, bem como o uso de água em diferentes etapas do processamento. Para isso, foram instalados hidrômetros em 13 pontos do estabelecimento. Em seguida, foram sugeridas ações de minimização visando diminuir o uso de água. O uso global de água foi de 432 m³.dia-1, sendo a etapa de depuração responsável por 40,7% desse volume, seguida das atividades relacionadas com a limpeza (32,3%). As ações de minimização implantadas reduziram 29% do uso de água referente à área limpa do processamento da empresa. Em seguida, foi realizada a caracterização físico-química e microbiológica dos efluentes gerados na indústria para a determinação das suas cargas de poluentes. A indústria, como um todo, gerou um efluente com alta carga de matéria orgânica, sendo as etapas onde há maior contato da água com o pescado e seus resíduos (cabeça, carcaça, carne, pele, sangue e vísceras) as maiores fontes poluidoras. Os parâmetros de DBO, DQO e óleos e graxas apresentaram os valores acima dos limites estabelecidos pela legislação para lançamento em sistemas de esgotamento sanitário ou em corpos hídricos receptores. Isso evidenciou a necessidade de um tratamento prévio do efluente antes do seu descarte. Além disso, foi avaliado o potencial do efluent... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The sustainable growing of the tilapia processing industry is directly related to the efficient use of water and to the management of the quality of water returned to the environment. The global use of water in a tilapia fillet processing plant and the use of water in different processing stages were evaluated. For this, hydrometers were installed at 13 points within the premisses. Additionally, minimization actions were suggested aiming at reducing the water use. It was used 432 m3 .d-1 of water, being the depuration stage responsible for 40.7% of this volume, followed by the general cleaning process of the plant (32.3%). The applied minimization actions reduced in 29% the use of water in the clean area of the processing flow. After this, the physical-chemical and microbiological characterization of the effluents generated by the industry was performed in order to evaluate the pollutant load. The industry, as a whole, produced an effluent with high organic matter load, being the stages in which the water contacts the fish and the solid residues (head, carcass, meat trimmings, skin, blood and viscera) the main pollutant sources. The parameters BOD, COD, oils and greases presented values above the legal limits to dispose in the effluent treatment systems or in the hydric spring. This demonstrated the necessity of a previous treatment of the effluent before it is discarded. Besides that, the potential of the effluent from the depuration stage to be reused for urban purposes and... (Complete abstract click electronic access below) / Doutor

A regionalização hidrológica é uma técnica que permite transferir informação de regiões hidrologicamente monitoradas, para regiões com pouco ou sem monitoramento. Sendo assim, é uma ferramenta útil, a qual permite uma avaliação dinâmica dos recursos hídricos. No Brasil e no Estado de Santa Catarina as leis que são as principais referências para a gestão de recursos hídricos utilizam critérios anuais de disponibilidade hídrica, impossibilitando um maior uso em épocas onde a disponibilidade é maior e, assim, afetando o desenvolvimento econômico. As previsões sazonais servem de base para uma gestão e utilização sustentável dos recursos hídricos. A justificativa de não se usar critérios sazonais, talvez seja pelo fato de não existir trabalhos ou ferramentas que contemplam o estado da arte da regionalização hidrológica. O objetivo deste trabalho é fazer a regionalização hidrológica do Estado de Santa Catarina, mediante uma abordagem geoestatística baseada em modelos e na sazonalidade. Foram utilizados estações pluviométricas e fluviométricas disponibilizadas, respectivamente, pela Companhia de Pesquisa de Recursos Minerais (CPRM) e Agência Nacional das Águas (ANA). As estações são distribuídas regularmente e em alta densidade sobre o Estado. Para a modelagem geoestatística, inicialmente foi verificada algumas suposições a serem consideradas, entre elas, a normalidade e a estacionaridade espacial dos dados. Após as suposições terem sido aceitas foi verificado, por meio de testes estatísticos em função da verossimilhança, se a estrutura de dependência espacial do modelo geoestatístico aumentava o desempenho do mesmo, justificando o uso dessa estrutura para a espacialização das variáveis pluviométricas e fluviométricas. Para verificar os pressupostos de uma boa predição, foi avaliada a dispersão dos resíduos das interpolações espaciais, mediante uma validação cruzada. Os resultados mostraram um melhor desempenho para os modelos geoestatísticos com a estrutura de dependência espacial, para todas as variáveis; assim, esses modelos foram utilizados para a interpolação espacial, no qual foi observado pela dispersão dos resíduos uma boa predição. Este trabalho contribui para uma melhor representação espacial de variáveis sazonais no Estado de Santa Catarina e permite um avanço no estado da arte, uma vez que está embasado em critérios de verossimilhança para escolha de modelos que representam melhor o fenômeno estudado no espaço. / Hydrologic regionalization is a technique that allows the transfer of information from regions hydrologically monitored, for regions with little or no monitoring. Therefore, this technique allows a dynamic evaluation of water resources being a useful tool. In Brazil and in Santa Catarina state, the laws that are the main references for the management of water resources use annual criteria of water availability. Thus, using a greater amount of resources when availability is greater is infeasible and affects economic development. Seasonal forecasts provide the basis for sustainable management and use of water resources. The justification for not using seasonal criteria may be because there are no works or tools that contemplate the state of the art of hydrologic regionalization. The aim of this work is to make the hydrologic regionalization of Santa Catarina state, using a geostatistical approach based on models and in seasonality. Data from rain gauge and streamflow stations made available by the Mineral Resources Research Company (CPRM) and National Water Agency (ANA), respectively, were used. These stations have regular distribution and high density within the state. For the geostatistical modeling, some basic assumptions such as data normality and spatial stationarity were verified. After accepting the assumptions it was verified through statistical tests regarding its likelihood, if the structure of spatial dependence of the geostatistical model increase its performance, justifying the use of this structure for the precipitation and streamflow spatialization. To check the assumptions of good prediction, the residue dispersion of the spatial interpolations was evaluated through cross-validation. The results showed a better performance for the geostatiscal models with the spatial dependence structure, both for precipitation and streamflow. Thus, these models were used to the spatial interpolation, observing a good prediction through the residue dispersion. This work contributes to a better spatial representation of seasonal variables in Santa Catarina state and allows an advance in the state of the art, since it is based on likelihood criteria to choose models that better represent the phenomenon studied in space.

This dissertation works to create a clearer understanding of sustainability in water policy. Current water policy in four US cities was compared to a matrix of recommended sustainability themes that have been presented in the literature to determine the extent of which these themes have been implemented into water policy. To best analyze policy for sustainability it is necessary to look at the policy of cities that are considered sustainable. This was determined by a city’s inclusion in “Most Sustainable US Cities” lists. The two cities that best represented sustainability were Austin, TX and San Francisco, CA. The research also included cities that are not considered leaders in sustainability but are similar in demographics, population, and state; these two cities are Fort Worth, TX and San Jose, CA. Finally, the same matrix was applied to the state policy to establish how state policy influences city sustainability. The results of this study add to the current knowledge in this field as it contributes a current analysis of sustainable water policy. The final findings compile the themes into a sustainability pyramid framework of common, uncommon, and rare sustainability. It appears that the ‘sustainable’ cities have included more uncommon and rare themes than the traditional cities, while common themes are implemented across the board. Common themes are those that are traditionally associated with sustainability – themes like conservation, reuse, and reducing pollutant impact on water sources. In order increase sustainability, cities should apply more of the themes from the top of the pyramid.

It is well established that converting wastewater, a point-source of pollution, into reclaimed water makes management of nutrients more difficult. Not all service lines measure the volume of reclaimed water used by a customer, and frequently there are no restrictions on the amount of reclaimed water that is used. Nutrients applied in excess have the potential to runoff or leach through soils and contaminate surface and groundwater resources. This research attempted to determine if corresponding surface water quality monitoring sites in reclaimed service areas reflect elevated total nitrogen (TN) and total phosphorous (TP) concentrations. The Joe’s Creek Watershed in Pinellas County, FL is a highly urbanized watershed with one wastewater plant providing tertiary treatment for reclaimed water (Pinellas County Utilities Dept.) and another wastewater plant providing secondary treatment (City of St. Petersburg Water Resources Dept.). This research reviewed concentrations of TN and TP in the reclaimed water effluent for each wastewater treatment plant and at four tributary sites in the Joe’s Creek Watershed. One tributary site, Bonn Creek, is in the tertiary treated service area, another tributary site, Miles Creek, is in the secondary treated service area, and a third tributary, Joe’s Creek, provides two control sites which are both outside of reclaimed service areas. Based on the results of comparisons and statistical analyses of the 6-year period, the TN and TP concentrations of reclaimed water from the City of St. Pete Wastewater Treatment Plant (WWTP) far exceed those of the Pinellas County WWTP. The TN concentration in the reclaimed effluent from St. Pete was nine times higher than that of Pinellas County. The TP concentration was almost five times higher at St. Pete than Pinellas County. The sites within reclaimed service areas had higher concentrations of TN and TP when compared to the control sites for the same period. Miles Creek recorded the highest mean concentrations of TN and TP of the four monitoring sites. Bonn Creek recorded the second highest mean concentrations of TN and TP. Rainfall data were reviewed and results show that several monitoring dates for Miles Creek and Bonn Creek had elevated TN and TP concentrations which coincided with periods of rainfall deficit. These and other results of this research indicate a need to reconsider minimum wastewater treatment levels in urban environments in an effort to reduce nutrient pollution, as well as a need to expand watering restrictions and enforcement, and expand education of consumers about reclaimed water.

This study assessed the effect of an application of mycorrhizal fungi to stormwater filter media on urban bioswale soil and stormwater in an infiltration-based bioswale aged 20 years with established vegetation. The study tested the use of commercially available general purpose biotic soil blend PermaMatrix® BSP Foundation as a treatment to enhance Earthlite™ stormwater filter media amelioration of zinc, copper, and phosphorus in an ecologically engineered structure designed to collect and infiltrate urban stormwater runoff before it entered the nearby Willamette River. These results show that the application of PermaMatrix® BSP Foundation biotic soil amendment to Earthlite™ stormwater filter media contributed to the reduction of extractable zinc in bioswale soil (-24% and -26%), as compared to the control, which received a treatment of Earthlite™ stormwater filter media only, and experienced an increase in extractable zinc levels (23% and 39%). The results presented also show evidence that after establishment mycorrhizal treatment demonstrated lowered levels of phosphorus in bioswale soil (-41%) and stormwater (-100%), in contrast to the control, which had increased phosphorus levels. The treatment contributed to reductions between 67% and 100% in every metric detected in stormwater after an establishment period of 17 weeks, while the bioswale with no mycorrhizal treatment had increases between 50% and 117%. Treatment also appeared to enhance the reduction of ammonium and nitrates, while contributing to a greater increase in soil pH.

Access to safe drinking water is an important health factor in many developing countries. Studies have shown that unsafe drinking water and poor sanitation practices leads to diarrheal disease, which is one of the leading causes of death of children under five in developing countries. Provision and proper use of household water filters have been shown to effectively improve health. This thesis is focused on the refinement and validation of algorithms for data collected from pressure transducer sensors that are used in household water filters (the Vestergaard Frandsen LifeStraw Family 2.0) deployed in Rwanda by the social enterprise DelAgua Health. Statistical and signal processing techniques were used to detect the use of the LifeStraw water filters and to estimate the amount of water filtered at the time of usage. An algorithm developed by Dr. Carson Wick at Georgia Institute of Technology was the baseline for the analysis of the data. The algorithm was then refined based on data collected in the SweetLab at Portland State University, which was then applied to field data. Laboratory results indicated that the mean error of the improved algorithm is 11.5% as compared with the baseline algorithm mean error of 39%. The validation of the algorithm with field data yielded a mean error of 5%. Errors may be attributed to real-world behavior of the water filter, electronic noise, ambient temperature, and variations in the approximation made to the field data. This work also presents some consideration of the algorithm applied to soft-sided water backpacks.

Stream ecosystems have experienced significant negative impacts from land use, resource exploitation, and urban development. Statistical models allow researchers to explore the relationships between these landscape variables and stream conditions. Weighting the relevant landscape variables based on hydrologically defined distances offers a potential method of increasing the predictive capacity of statistical models. Using observations from three grouped watersheds in the Portland Metro Area (n=66), I have explored the use of three different weighting schemes against the standard method of taking an areal average. These four different model groups were applied to four stream temperature metrics: mean seven-day moving average maximum daily temperature (Mean7dTmax), number of days exceeding 17.8 °C (Tmax7d>17.8), mean daily range in stream temperature (Range_DTR), and the coefficient of variation in maximum daily temperature (CV_Tmax). These metrics were quantified for the 2011 dry season. The strength of these model groups were also examined at a monthly basis for each of the four months within the dry season. The results demonstrate mixed effectiveness of the weighting schemes, dependent on both the stream temperature metric being predicted as well as the time scale under investigation. Models for Mean7dTmax showed no benefit from the inclusion of distance weighted metrics, while models for Range_DTR consistently improved using distance weighted explanatory variables. Trends in the models for 7dTmax>17.8 and CV_Tmax varied based on temporal scale. Additionally, all model groups demonstrated greater explanatory power in early summer months than in late summer months.

Reducing the rates of greenhouse gas (GHG) emissions is critical in combatting global climate change. Carbon dioxide (CO2) and methane (CH4) are the two most important carbon-based GHGs, for their atmospheric warming potential. Wetlands such as the Florida Everglades play major roles in the global carbon cycle, as varying hydrologic conditions lead to differential production rates of these two GHGs. This study measured CO2 and CH4 emissions in a re-created Everglades ridge-and-slough wetland, where water levels were controlled to reflect natural flood patterns. As expected, lower elevations were flooded longer and produced more CH4, while higher elevations produced more CO2. Since CH4 has a relatively high global warming potential, CO2 production would need to be 70 times that of CH4, to balance their GHG output. The average ratio of CO2 to CH4 across elevations was 22.0 (mol:mol), indicating that future water management within wetlands should consider GHG production potential.

Densification and submergence of floating crude oil is proposed as a novel oil spills treatment method. Surface application of dry granular materials (e.g., quartz sand, limestone) on top of a floating oil layer increases the density of the floating oil phase/granule mixture and leads to formation of relatively large and stable aggregates with significant amounts of captured oil. The aggregates separate from the floating hydrophobic phase and settle by gravity. Implementation of this method will reduce the impact radius of a spill and its mobility, preventing direct contamination of beaches, coastal flora and fauna. The major objective of this research was to examine interactions of particles with hydrophobic liquid-water interface from different perspectives. The important characteristics of the process, such as oil removal efficiencies, optimal particle-to-oil ratios and particle size ranges, were experimentally defined. A series of experiments was conducted to investigate aggregation and dissolution rate constants of the submerged hydrophobic liquids in salt water and deionized water, and to study the impact of the surface porosity of the granular particles on oil capture efficiencies. In addition to crude oil (South Louisiana crude, MC 252), aggregation volumes of quartz sand with other hydrophobic liquids (alkanes and aromatics) were analyzed in relation to wetting characteristics and physical properties of the liquids. A classification of the main types of oil-particle aggregates was developed based on the formation characteristics of the aggregates. Moreover, under specific conditions, depending on the application rates of the granular materials, unique interactions of the particles with the hydrophobic liquid-water interface were observed and defined (bowl formation and roping). These concepts can be utilized to control surface mobility of floating oils, especially during the initial stages of an oil spill, while the oil layer is intact, and when other treatment methods may not be suitable near coastal areas, where transport of floating oils can significantly impact coastal ecosystems.

Kosovo is a disputed territory, in conflict with Serbia, the country it declared independence from in 1999. The two states share water resource, in the form of the Ibër river. Kosovo is facing issues of water scarcity and the water it has access to is heavily polluted with untreated wastewater metallurgy waste.Kosovo does not only have poor relations with Serbia, there are also conflict within Kosovo with communities of both Kosovo Albanian majority and Serb majority. These communities have shown different willingness to cooperate over the water management of the Ibër river basin. Cooperating over shared water resources have in other cases been used as a way to improve on relations in conflict affected societies, through environmental peacemaking. In this case study, the environmental and socio-political conditions for environmental peacemaking is investigated through interviews of municipal and regional stakeholders, involved in the management of the Ibër river basin. Interviews were conducted with two municipal employees and one representative from the regional river basin authority in Kosovo. These interviews were complemented with a comprehensive literature review. The findings were analysed, using a conceptual framework developed to analyse and compare different cases of environmental peacemaking. The conceptual framework consists of six elements: resource scarcity, interdependence, lack of environmental sustainability, mutual interests, shared values, and power (a)symmetries. External actions and interests was also included as an element to reveal in what way external actors can intervene and assist in improving relations through environmental peacemaking initiatives. The analysis concluded that the Ibër river basin is in a need of transboundary management to improve on the water quality in a more effective and efficient way. The resource scarcity that is currently facing the stakeholders could be used as a cooperative trigger between the different actors. And while there is a lot of complexity to within the socio-political conditions, the interviewees express the need and interest for increased cooperation. This indicates that increased collaboration could be possible, but most likely there would be a need for external interventions to create an ongoing dialogue, that in turn can build trust between the conflicting parties. / <p>Remote presentation on Teams</p>