Renewable energy is a critical component in combating climate change. Ocean wave energy is a source of renewable energy that can be harvested using Wave Energy Converters (WECs). One such WEC is the floating Oscillating Water Column (OWC), which has been successfully field tested and warrants further exploration. This research implements a publicly accessible code in MatLab and SimuLink to simulate the dynamics of a floating OWC in the time domain. This code, known as the Floating OWC Iterative Time Series Solver (FlOWCITSS), uses the pressure distribution model paired with state space realization to capture the internal water column dynamics of the WEC and estimate pneumatic power generation. Published experimental results of floating moored structures are then used to validate FlOWCITSS. While FlOWCITSS seemed to capture the period and general nature of the heave, surge, and internal water column dynamics, the magnitude of the response sometimes had errors ranging from 1.5% −37%. This error could be caused by the modeling techniques used, or it could be due to uncertainties in the experiments. The presence of smaller error values shows potential for FlOWCITSS to achieve consistently higher fidelity results as the code undergoes further developments. To demonstrate the use of FlOWCITSS, geometry variations of a Backward Bent Duct Buoy (BBDB) are explored for a wave environment and mooring configuration. The reference model from Sandia National Labs, RM6, performed significantly better than a BBDB with an altered stern geometry for a 3 second wave period, indicating that stern geometry can have a significant impact on pneumatic power performance. / Master of Science / Renewable energy is a critical component in combating climate change. Ocean wave energy is a source of renewable energy that can be converted into electricity using Wave Energy Converters (WECs). One such WEC is the floating Oscillating Water Column (OWC), which has been successfully field tested and warrants further exploration. Floating OWCs are partially submerged floating structures that have an internal chamber which water oscillates in. The motions of the water displace air inside this chamber, causing the air to be forced through a high speed turbine, which generates electricity. This research develops a publicly accessible code using MatLab and SimuLink to evaluate the motions and power generation capabilities of floating OWCs. This code is then validated against physical experiments to verify its effectiveness in predicting the device's motions. This publicly accessible code, known as the Floating OWC Iterative Time Series Solver (FlOWCITSS), showed error ranging from 1.5 % - 37% for the most important motions that are relevant to energy harvesting and power generation. These errors could be caused by the numerical models used, or uncertainties in experimental data. The presence of smaller error values shows potential for FlOWCITSS to achieve consistently higher fidelity results as the code undergoes further developments. To demonstrate the use of FlOWCITSS, geometry variations of floating OWCs are explored.

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Denna rapport ämnar undersöka de vanligast förekommande typerna av teknologier för vågkraftverk (eng. Wave Energy Converter, WEC) teknologier för att jämföra de olika konceptens förmåga att absorbera vågenergi. Koncept som undersöks är punktabsorbatorer och oscillerande vattenkolumner. I denna rapport används de vanligt använda engelska översättningarna point absorber och oscillating water column (OWC). Beräkningar görs för de olika koncepten i liknande vågförhållanden för att kunna jämföra den energi som kan utvinnas. I rapporten sker beräkningar under optimala vågförhållanden. Vågorna antas vara linjära och vågkraftverken antas vara i fas med vågens svängningsrörelse. Den vågdata som använts är uppmätt utanför Belmullet i Irland. Beräkningar görs på vågor med en signifikant våghöjd på 1,25 m och en periodtid på 7,5 s. Det görs även beräkningar på den största uppmätta förekommande vågen. I huvudsak används effektberäkningar enligt en modell som Kjell Budal. Syftet är att grafiskt och numeriskt jämföra den teoretiska och faktiska maxeffekt som kan utvinnas ur respektive våg. Resultatet från undersökningen visar att den största bidragande faktorn till en hög energiutvinning beror på bojens volym. Volymen måste anpassas för de vågförhållanden som finns där bojen ska placeras.Vid beräkningar av en OWC med tvärsnittsarea på 19 m2 visar det sig att den effekt som kan utvinnas av en luftkammare med tillhörande turbin är ungefär 10 kW, 1/30 av de 300kW som kan utvinnas av en point absorber. En OWC består dock sällan utav en ensam luftkammare utan ofta i en array med ett flertal luftkammare med separata turbiner för att öka effekten. / This report intends to examine the most common types of wave energy converter technologies to compare the different concepts' ability to absorb wave energy. Concepts being investigated are point absorbers and oscillating water columns (OWC). Calculations are made for the different concepts in the same wave conditions to be able to compare the energy that can be extracted. In the report, calculations are made under optimal wave conditions. The waves are assumed to be linear and the wave energy converter is assumed to be in phase with the oscillating motion of the wave. The wave data used is measured outside Belmullet in Ireland. Calculations are made on waves with a significant wave height of 1.25 m and a period time of 7.5 s. Calculations are also made on the largest measured wave present. In essence, power calculations are used according to a model developed by Kjell Budal and with the help of this be able to graphically and numerically compare the theoretical and actual maximum power that can be extracted from each scale. The results from the survey show that the largest contributing factor to high energy recovery is due to the volume of the buoy. The volume must be adapted to the wave conditions that exist where the buoy is to be placed.When calculating an OWC with a cross sectional area of 19 m2, it turns out that the power that can be extracted from an air chamber with an associated turbine is approximately 10 kW, 1/30 of the 300 kW that can be extracted by one point absorber. However, an OWC rarely consists of a single air chamber but often in a construction with several air chambers with separate turbines to increase the power.

Wave energy is one of the most promising renewable energy sources for future exploitation. This thesis focuses on thermodynamic effects within Oscillating Water Column (OWC) devices equipped withWells turbines, particularly humidity effects. Previous theoretical studies of the operation of OWCs have resulted in expressions for the oscillation of the water surface in the chamber of an OWC based on linear wave theory, and the air expansion{compression cycle inside the air chamber based on ideal gas theory. Although in practice high humidity levels occur in OWC devices open to the sea, the influence of atmospheric conditions such as temperature and moisture on the performance of Wells turbines has not yet been studied in the field of ocean energy. Researchers have reported substantial differences between predicted and measured power output, and performance rates of OWCs presently coming into operation. The effect of moisture in the air chamber of the OWC causes variations on the atmospheric conditions near the turbine, modifying its performance and efficiency. Discrepancies in available power to the turbine are believed to be due to the humid air conditions, which had not been modelled previously. This thesis presents a study of the influence of humid air on the performance of an idealised Wells turbine in the chamber of an OWC using a real gas model. A new formulation is presented, including a modified adiabatic index, and subsequent modified thermodynamic state variables such as enthalpy, entropy and specific heat. The formulation is validated against experimental data, and found to exhibit better agreement than the ideal approach. The analysis indicates that the real gas behaviour can be explained by a non{dimensional number which depends on the local pressure and temperature in the OWC chamber. A first approach to the OWC formulation through the calculation of real air flow in the OWC is given, which predicts a 6% decrease in efficiency with respect to the ideal case when it is tested with a hypothetical pulse of pressure. This is important because accurate prediction of efficiency is essential for the optimal design and management of OWC converters. A numerical model has also been developed using computational fluid dynamics (CFD) to simulate the OWC characteristics in open sea. The performance of an OWC turbine is studied through the implementation of an actuator disk model in Fluent®. A set of different regular wave tests is developed in a 2D numerical wave flume. The model is tested using information obtained from experimental tests on a Wells{type turbine located in a wind tunnel. Linear response is achieved in terms of pressure drop and air flow in all cases, proving effectively the applicability of the actuator disk model to OWC devices. The numerical model is applied first to an OWC chamber containing dry air, and then to an OWC chamber containing humid air. Results from both cases are compared, and it is found that the results are sensitive to the degree of humidity of the air. Power decreases when humidity increases. Finally, results from the analytical real gas and numerical ideal gas models are compared. Very satisfactory agreement is obtained between the analytical and the numerical models when humidity is inserted in the gaseous phase. Both analytical and numerical models with humid air show considerable differences with the numerical model when dry air is considered. However, at the resonance frequency, results are independent of the gas model used. At every other frequency analysed, the real gas model predicts reduced values of power that can fall to 50% of the ideal power value when coupled to the radiation-diffraction model for regular waves. It is recommended that real gas should be considered in future analyses of Wells turbines in order to calculate accurately the efficiency and expected power of OWC devices.

Glenbrook Lagoon, an 8 hectare lake receiving rainfall runoff from a residential catchment, is experiencing nutrient enrichment problems expressed as excessive aquatic plant presence. This study aims to assess the relative nutrient contribution of the total system compartments, including catchment loading, water column, aquatic plants and surface sediment. This information is utilised in the formulation of management strategies which may produce a sustainable nutrient reduction and general improvement in the system. The total nutrient content of the aquatic system was determined to be high in comparison with the present nutrient loading from the catchment. The ideal management case considers nutrient reduction of the surface sediment compartment firstly, followed by the aquatic plant community, with the water column and catchment influence as relatively low priority compartments. Various strategies for managing these are proposed. The total system benefits of the ideal management case are reductions in nutrients, aquatic plant biovolume and suspended solid loading. Unavoidable constraints placed upon the ideal management case include the excessive aquatic plant presence restricting accessability to the surface sediment for dredging. The resulting best management case requires aquatic plant eradication prior to sediment management, with the total system benefits associated with the ideal management case being retained. / Master of Science (Hons)

Phytoplankton mirrors changes in the environment and plays an important role in biogeochemical processes. Phytoplankton dynamics is the outcome of both autogenic succession and external disturbances. This thesis focused on the seasonal variation of water column stability and its effects on phytoplankton, particularly considering the influence of mixing events on phytoplankton development. Lake Erken is a dimictic lake with weak and often interrupted summer stratification, which represents an intermediate case between a polymictic lake and a lake with strong summer stratification. There are two diatom phases annually. The spring bloom is caused by pioneer centric diatoms, and the autumn diatom phase is dominated by meroplanktonic diatoms induced by turnover. A summer Cyanobacteria bloom – mainly Gloeotrichia echinulata, depended on the length and stability of stratification. Winter and spring air temperature is found to play an important role in the annual succession of phytoplankton by initiating changes in ice/snow-cover and lake thermal stability and setting the basic status. Instead of starting from zero, the vernal phytoplankton piles up on the overwintering community, this trans-annual ecological memory influences both the composition and diversity and taxonomic distinctness of spring phytoplankton. Water column stability during summer in Lake Erken is mainly influenced by wind-induced turbulence and internal seiches. As thermal stratification develops from early until late summer, variations in stability and gradual deepening of the thermocline depth influence phytoplankton dynamics directly by changing its distribution, and also indirectly by altering the nutrient and light availability. A new disturbance index (DI) was defined to quantify environmental stability/disturbance and tested well to indicate phytoplankton equilibrium status in two summer stratification periods. The concept of species and functional groups was generally used in this study. However, a next generation sequencing based approach was also tested and proved to provide an excellent candidate for revealing distribution patterns of phytoplankton in inland waters.

Water column methane measurements have been used to understand both the global distribution of methane in the oceans and the local flux of methane from geologic sources on the continental margins, including methane vents and gas-hydrate-bearing sites. We have measured methane concentrations in 1607 water samples collected along the central California continental margin. Methane supersaturation of the surface mixed layer (0-50 msbsl) is widespread and above a well-defined subsurface particle maximum (~50 mbsl) that generally corresponds with the pycnocline. Local production of methane appears to be occurring in the surface mixed layer above the particle maximum and may not be particle-associated. Methane concentrations in water column CTD cast profiles and ROV-collected bottom waters obtained in Partington, Hueneme, Santa Monica, and Redondo submarine canyons increase towards the seafloor and are distinctly higher (up to 186 nM) compared to open-slope and shelf waters at similar depths. These values are in excess of measured surface water methane concentrations and could not be generated by mixing with surface water. Elevated methane concentrations in these submarine canyons and persistent mid-water methane anomalies in Ascension and Ano Nuevo Canyons could result from restricted circulation and/or proximity to gas vents, seafloor exposure of methane gas hydrates, recently-eroded methane-rich sediment, submarine discharge of methane-rich groundwater, or particle-associated methane production. On the Santa Barbara shelf water column methane profiles near known gas vents also increase in concentration with increasing depth. Thus, elevated bottom water methane concentrations observed in submarine canyons may not be diagnostic of proximity to methane vents and may be caused by other processes.

The distribution of heavy metals between soil and soil solutions is a key issue in evaluating the environmental impact of long term applications of heavy metals to land. Contamination of soils by heavy metals has been reported by many workers. Metal adsorption is affected by many factors, including soil pH, clay mineralogy, abundance of oxides and organic matter, soil composition and solution ionic strength. The pH is one of the many factors affecting mobility of heavy metals in soils and it is likely to be the most easily managed and the most significant. To provide the appropriate level of protection for aquatic life and other uses of the resource, it is important to be able to predict the environmental distribution of important metals on spatial and temporal scales and to do so with particular emphasis on the water column concentrations. Regulatory levels reflected in water quality criteria or standards are based on water column concentrations. Predicting water column concentrations requires a consideration of the interactions of water column contaminants with both bed sediments and suspended particulates as critical components in the assessment. The adsorption behaviour of cadmium, copper, lead and zinc onto soils is studied under the various geo-environmental conditions of pH, concentration of adsorbate and adsorbent, and solution compositions. Experiments were conducted to determine the equilibrium contact time of various adsorbates for adsorbent in different systems. Experiments were also conducted to check the efficiency of various acid-mixtures to extract heavy metal from soils into the aqueous phase. The adsorption behaviour of heavy metals onto soils was also studied from sea-water system. Soils are characterized in terms of the role of clay minerals to remove the metals from the solution phase, back-ground levels of metals, maximum adsorption capacity to adsorb various heavy metals from different adsorption systems, and type of surface sites present. The experimental data of metal adsorption is described by Langmuir adsorption model. The adsorption data are also expressed in terms of surface loading, surface acidity, adsorption density, and affinity of soils for heavy metals in different adsorption systems. Ecological implications of changes in physical and chemical conditions in aquatic systems on heavy metals uptake by soils are also discussed. This research covers the following areas: the environmental impact of heavy metal discharge into the aquatic systems, the study of the mobility patterns of different heavy metals as function of geo-environmental conditions, and determination of the pathways and the ultimate fate of heavy metals in the environment.

Commercial viability of Wave Energy Converters (WEC) depends on addressing not only the energetic effciency, but also in solving the practical issues related to manufacturing methods, access to technology, handling, transportation and installation, operation and maintenance, impact on marine life and most importantly the cost per kW-h. The UFCAP WEC is one concept which has the potential to facilitate handling, manufacturing, and installation activities as well as to be able to lower the current wave energy cost per kW-h, however its feasibility had not been properly assessed nor proved. It consists of multiple interconnected Oscillating Water Columns (OWC) chambers, it is modular, and simple, with no-moving parts in contact with the water and can use a simpler one-direction turbine which is more economic, and more effcient than self-rectifying turbines used in most of the OWCs devices. Testing of the device to fully assess its feasibility required a low pressure check-valve, and a customized turbine which were developed during the present work. Check-valves are widely used in the industry for medium or high-pressures, but were not available at all for large-flows with low-pressure-differences. A novel check-valve was devised for this application, along with the scaled UFCAP prototypes developed to be tested in a wave-flume and in the ocean to validate UFCAPs concept feasibility, and identify critical design parameters and features such as the conduit/air-chamber ratio. Ocean tests allowed to observe performance at component and assembly levels, learning new failure-modes and stablishing best-practices for future deployments. Testing confirmed the UFCAP WEC is not only an idea, but a concept which works and can generateing electricity at a competitive cost. / Graduate

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