The aim of the thesis was to complete the development of the Czech version of the extremal ultraviolet (XUV) argon capillary laser working at the wavelength 46.9 nm and its adaptation for the first practical applications. A multi-discipline complex of mutually interconnected problems was analyzed and studied: The reasons for a capillary low life-time were investigated using defectoscopic methods, a pre- pulse regime influence was studied with the help of spectroscopy on a physical model. By performing necessary construction and technology changes as well as by the multi-parametric optimisation of working regime, the indicated weaknesses were suppressed. The XUV laser was focused into a footprint of the size about 100 µm and the apparatus was extended by a set of practical aids and accessories for special applications, especially for exposition of the samples at extreme temperatures. As practical applications of the XUV laser, measurements of multilayer mirror reflectivity and filter transmissivity were performed. Using the XUV laser for a thin layer deposition and radiation resistance testing was verified to be practicable in principle. Probably a first temperature dependence of an XUV laser ablation rate was measured, in the temperature range from -180 deg.C to +200 deg.C, on BaF2.

Title: Characterization and focusing of capillary-discharge XUV-laser beam for purposes of thin-film deposition Author: Peter Pira Department: Department of Surface and Plasma Science Supervisor: doc. RNDr. Jan Wild, CSc., Department of Surface and Plasma Science Abstract: The paper deals with the first results of the interaction of a desk-top high repetition rate XUV laser (wavelength of 46.9 nm) radiation with materials suitable for optoelectronics, in particular the ionic crystals CsI, LiF, etc. Using surface physics methods (AFM, DIC Normanski microscopy) pulse laser imprints were investigated. Based on the results obtained, general information on the nature of ablation and desorption was obtained, which were compared with the results of the XUV-ABLATOR modified code modeling. Plasma arising from ablation was examined by a modified Langmuir probe system. The main result is the pulse laser deposition of thin films of Bi and CsI. Keywords: ablation, Pulsed Laser Deposition, XUV laser

La caractérisation spectrale détaillée des lasers XUV générés dans des plasmas est un enjeu important des projets actuels de développement qui visent à augmenter la puissance crête de ces sources. En effet les propriétés spectrales de ces lasers conditionnent d'autres propriétés importantes, telle que la durée minimum accessible (limite de Fourier). La plus courte durée actuellement démontrée expérimentalement est de 1 picoseconde. La technique d'injection d'un plasma de laser XUV avec une impulsion femtoseconde de rayonnement harmonique d'ordre élevé offre des perspectives très prometteuses pour réduire la durée d'impulsion jusqu'à quelques 100 femtosecondes, pourvu que l'on sache maintenir une bande spectrale de gain suffisamment large.Les lasers XUV pompés par excitation collisionnelle dans des ions néonoïdes et nickeloïdes ont été développés dans des plasmas chauds créés aussi bien par décharge électrique rapide que par différents types de lasers de puissance. On a ainsi accès à une large variété de sources lasers XUV, qui diffèrent par les caractéristiques du faisceau émis, mais aussi par les paramètres du plasma (densité, température) dans la zone de gain. On peut donc s'attendre à des propriétés spectrales différentes. Le but du travail que nous présentons est d'étudier les propriétés spectrales des différents types de lasers XUV collisionnels existants, et d'évaluer leur capacité à amplifier des impulsions de durée inférieure à 1 picoseconde, dans un mode injecté.La caractérisation spectrale des lasers XUV est expérimentalement difficile parce que la résolution spectrale nécessaire (∆λ/λ ~10-5) n'est pas accessible avec les meilleurs spectromètres actuels. Dans notre étude, nous avons atteint cette résolution en mesurant la cohérence temporelle de la source à l'aide d'un interféromètre à division de front d'onde, spécifiquement conçu pour ces mesures, à partir desquelles largeur spectrale peut être déduite.Nous avons caractérisé trois types de lasers XUV collisionnels, développés dans trois laboratoires différents: pompage transitoire dans le molybdène nickeloïde, pompage par décharge électrique dans l'argon néonoïde et pompage quasi-stationnaire dans le zinc néonoïde. Dans chaque cas la cohérence temporelle a été mesurée précisément. De plus nous avons étudié l'effet de la saturation de l'amplification et (pour le Ni-like Mo) l'influence du mode injecté. Nous avons également étudié le comportement temporel du laser transitoire Ni-like Mo à l'aide d'une caméra streak X ultra-rapide. Nos mesures spectrales sont comparées à des résultats de simulations numériques prenant en compte les différents mécanismes d'élargissement ainsi que les effets de transfert radiatif. Nous avons étudié l'évolution du profil spectral avec l'amplification et la saturation, et nous avons évalué les limites de Fourier correspondantes.Le temps de cohérence le plus court (ie la largeur spectrale la plus grande) est mesuré pour le laser XUV quasi-stationnaire, qui correspond au plasma qui a la plus forte densité et la plus forte température ionique. / Improving the knowledge of the spectral and temporal properties of plasma-based XUV lasers is an important issue for the ongoing development of these sources towards significantly higher peak power. The spectral properties of the XUV laser line actually control several physical quantities that are important for applications, such as the minimum duration that can be achieved (Fourier-transform limit). The shortest duration experimentally achieved to-date is ~1 picosecond. The demonstrated technique of seeding XUV laser plasmas with a coherent femtosecond pulse of high-order harmonic radiation opens new and promising prospects to reduce the duration to a few 100 fs, provided that the gain bandwidth can be kept large enough.XUV lasers pumped by collisional excitation of Ni-like and Ne-like ions have been developed worldwide in hot plasmas created either by fast electrical discharge, or by various types of high-power lasers. This leads to a variety of XUV laser sources with distinct output properties, but also markedly different plasma parameters (density, temperature) in the amplification zone. Hence different spectral properties are expected. The purpose of our work was then to investigate the spectral behaviour of the different types of existing collisional excitation XUV lasers, and to evaluate their potential to support amplification of pulses with duration below 1 ps in a seeded mode.The spectral characterization of plasma-based XUV lasers is challenging because the extremely narrow bandwidth (typically ∆λ/λ ~10-5) lies beyond the resolution limit of existing spectrometers in this spectral range. In our work the narrow linewidth was resolved using a wavefront-division interferometer specifically designed to measure temporal coherence, from which the spectral linewidth is inferred. We have characterized three types of collisional XUV lasers, developed in three different laboratories: transient pumping in Ni-like Mo, capillary discharge pumping in Ne-like Ar and quasi-steady state pumping in Ne-like Zn. Besides the accurate measurement of the temporal coherence of the laser in each case, we have studied the spectral behaviour when the laser is operated in the saturation regime and (in Ni-like Mo) when it is seeded with high-order harmonic radiation. We have also investigated the temporal behaviour of the Ni-like Mo transient XUV laser, using an ultrafast X-ray streak camera. Our linewidth measurements are compared with detailed numerical calculations including relevant broadening mechanisms as well as radiative transfer effects. The evolution of the spectral profile with amplification and saturation was studied for different plasma parameters, and corresponding Fourier-transform limit duration were evaluated.The shortest temporal coherence (ie the largest bandwidth) is measured for the quasi-steady state pumping XUV laser, which operates at the highest density and ionic temperature.

Improving the knowledge of the spectral and temporal properties of plasma-based XUV lasers is an important issue for the ongoing development of these sources towards significantly higher peak power. The spectral properties of the XUV laser line actually control several physical quantities that are important for applications, such as the minimum duration that can be achieved (Fourier-transform limit). The shortest duration experimentally achieved to-date is ~1 picosecond. The demonstrated technique of seeding XUV laser plasmas with a coherent femtosecond pulse of high-order harmonic radiation opens new and promising prospects to reduce the duration to a few 100 fs, provided that the gain bandwidth can be kept large enough.XUV lasers pumped by collisional excitation of Ni-like and Ne-like ions have been developed worldwide in hot plasmas created either by fast electrical discharge, or by various types of high-power lasers. This leads to a variety of XUV laser sources with distinct output properties, but also markedly different plasma parameters (density, temperature) in the amplification zone. Hence different spectral properties are expected. The purpose of our work was then to investigate the spectral behaviour of the different types of existing collisional excitation XUV lasers, and to evaluate their potential to support amplification of pulses with duration below 1 ps in a seeded mode.The spectral characterization of plasma-based XUV lasers is challenging because the extremely narrow bandwidth (typically ∆λ/λ ~10-5) lies beyond the resolution limit of existing spectrometers in this spectral range. In our work the narrow linewidth was resolved using a wavefront-division interferometer specifically designed to measure temporal coherence, from which the spectral linewidth is inferred. We have characterized three types of collisional XUV lasers, developed in three different laboratories: transient pumping in Ni-like Mo, capillary discharge pumping in Ne-like Ar and quasi-steady state pumping in Ne-like Zn. Besides the accurate measurement of the temporal coherence of the laser in each case, we have studied the spectral behaviour when the laser is operated in the saturation regime and (in Ni-like Mo) when it is seeded with high-order harmonic radiation. We have also investigated the temporal behaviour of the Ni-like Mo transient XUV laser, using an ultrafast X-ray streak camera. Our linewidth measurements are compared with detailed numerical calculations including relevant broadening mechanisms as well as radiative transfer effects. The evolution of the spectral profile with amplification and saturation was studied for different plasma parameters, and corresponding Fourier-transform limit duration were evaluated.The shortest temporal coherence (ie the largest bandwidth) is measured for the quasi-steady state pumping XUV laser, which operates at the highest density and ionic temperature.

A hybrid quantum-classical approach to the interaction of atomic clusters with intense laser fields in the vacuum ultra-violet (VUV) has been developed. Much emphasis is put on localized electrons, those quasi-free electrons which localize about the ions and screen them. These electrons set a time scale, which is used to interpolate between the quantum, rate based description of photon absorption by bound electrons and the classical, deterministic description of the cluster nano-plasma. Typical observables such as total energy absorption, electron and ion spectra are in very good agreement with the experimental findings. A scheme to probe the multi-electron motion in clusters with attosecond laser pulses is introduced. Conventional final state measurements in the energy domain cannot provide information about earlier states of the system due to the incoherent nature of the dynamics. Time-delayed attosecond pulses in the extreme ultra-violet (XUV) are used to probe the transient charging of the cluster ions during the interaction with the laser by measuring the kinetic energy of the electrons detached by the probe pulse. This information is otherwise lost at later times due to recombination. Knowledge about the transient charging would also shed more light on the still controversial subject of the energy absorption mechanisms in the VUV regime. Moving to shorter duration of the excitation, the characteristic time-scales for ionization and plasma equilibration are inversed. An attosecond laser pulse in the VUV regime creates a dense, warm nano-plasma far from equilibrium. Time-delayed attosecond pulses in the XUV probe then both the creation and the relaxation. The latter shows the breakup of the Bogoliubov hierarchy of characteristic times, indicating strongly-coupled plasma dynamics and drawing parallels to the relaxation of extended ultra-cold neutral plasmas with millions of particles.

A hybrid quantum-classical approach to the interaction of atomic clusters with intense laser fields in the vacuum ultra-violet (VUV) has been developed. Much emphasis is put on localized electrons, those quasi-free electrons which localize about the ions and screen them. These electrons set a time scale, which is used to interpolate between the quantum, rate based description of photon absorption by bound electrons and the classical, deterministic description of the cluster nano-plasma. Typical observables such as total energy absorption, electron and ion spectra are in very good agreement with the experimental findings. A scheme to probe the multi-electron motion in clusters with attosecond laser pulses is introduced. Conventional final state measurements in the energy domain cannot provide information about earlier states of the system due to the incoherent nature of the dynamics. Time-delayed attosecond pulses in the extreme ultra-violet (XUV) are used to probe the transient charging of the cluster ions during the interaction with the laser by measuring the kinetic energy of the electrons detached by the probe pulse. This information is otherwise lost at later times due to recombination. Knowledge about the transient charging would also shed more light on the still controversial subject of the energy absorption mechanisms in the VUV regime. Moving to shorter duration of the excitation, the characteristic time-scales for ionization and plasma equilibration are inversed. An attosecond laser pulse in the VUV regime creates a dense, warm nano-plasma far from equilibrium. Time-delayed attosecond pulses in the XUV probe then both the creation and the relaxation. The latter shows the breakup of the Bogoliubov hierarchy of characteristic times, indicating strongly-coupled plasma dynamics and drawing parallels to the relaxation of extended ultra-cold neutral plasmas with millions of particles.