In this thesis the experimental method is used to study the characteristics of a DMFC when a heterogeneous carbon fiber bipolar plate is applied to it. The first main study is about the effect of the different structures of the carbon fiber bunch on the fuel cell performance. Additionally, a high temperature hot-pressing process is performed to change the inner molecular structure so that the hydrogen ion can be blocked to avoid the lateral migration between two adjacent cells. Finally, the two techniques are applied to make our new portable DMFC stack. The bipolar plates with the sawtooth or non-sawtooth carbon fiber bunches have been used in making our DMFC stack. The experimental results display that the performances of the two structures both are better than the traditional graphite bipolar plate. However, the performance of DMFC with the sawtooth bipolar plate is much better than that without sawtooth, especially in high current density. When carbon fiber bunches with sawtooth use at anode and cathode of bipolar plates, the performance can be enhanced and its power density 27.6% higher than that without sawtooth. During our study we also found that part of hydrogen ions can laterally migrate to its adjacent cathode and do not directly cross to its opposite cathode, when the banded type MEA are used to multiple cell stack. Therefore, the performance cannot be performed well due to this type ion transfer. In order to block the lateral migration, the narrow area of the membrane between two adjacent electrodes is pressed with a high temperature hot-pressing device. After a short time hot-press between two adjacent electrodes, the hydrogenion migration phenomenon reduced, and the performance had been improved about 10% higher than that without hot-press. Finally, a double layer 2x6-cell flat type DMFC is made. This 12-cell stack is composed of each electrode area 0.5x5cm2, two sheets of membrane for 6-cell using Nafion 117, the anode catalyst Pt-Ru loading 4mg/cm2, and cathode catalyst Pt loading 4mg/cm2, the methanol concentration 3M, air-breathing, and operating in room temperature. The output power of the cell can reach an average power density 8.0mW/cm2 and total power 240mW with our handmade stack. If the performance of each fuel cell is more uniform, we expect that total power can reach 480 mW. The power level should be satisfied for any kind mobile phone.

The effects of the structure of new carbon fiber bunch heterogeneous unipolar plates on the performance of PEMFC are studied in this thesis. Internal structure of carbon fiber bunches can be modified by embedding different thickness or number of copper plates in the glue bonding area to increase the air permeability of carbon fiber bunches in its soft end. We can add different thickness or amount of coppers at the middle of bonding area, making the carbon fiber bunches soft side to form parallel to the longitudinal fiber bunch with a small flow channel. We can also make a trench at the appropriate place of the soft side of the carbon fiber bunches to form an extra air passage. In order to make the above flow channel, a new process for making the carbon fiber bunches is developed also. This process will be easier to produce a variety of different structures of carbon fiber bunch. Finally, several different experiments are performed to help us to understand the effect of the carbon fiber bunch structure on the performance and find out the best structure of the carbon fiber bunches. The carbon fiber bunch structures of the test cells on the anode side are all the same, but the carbon fiber bunch structures of on cathode side are all different. Experiments show that there are two structures among all test structures displayed better gas permeability. The first one is two 0.2 mm copper plates embedded within both sides of the glue ends of a cathode carbon fiber bunch, so that a small longitudinal flow channel are formed in soft end of the cathode carbon fiber bunch. When the HFC operates at room temperature and by air-breathing, the highest performance of the HFC can reach a value of 185 mW/cm2. The second one is a 0.2 mm copper plate embedded in the center of the glue end of a carbon fiber bunch, and then three 2 mm wide serrated slots are cut on the soft end of the carbon fiber bunch. The highest performance of the HFC can reach a value of 190 mW/cm2. The highest performance of the HFC with no copper plate and no slot structure can only reach a value 160 mW/cm2. The second design can increase the no structure cell performance 18.8%. Therefore, the internal structures of carbon fiber bunches are significant to affect on the fuel cell performance, and its internal design must be considered.

The bristlenose pleco (Ancistrus cirrhosus) is a species of armored catfish in the Loricariidae family that breathes air facultatively when the aquatic environment becomes hypoxic. The bristlenose pleco uses its highly vascularized stomach as an air breathing organ. The two main goals of this developmental study were to determine the size of onset of air breathing and to determine the frequency of air breathing behavior in bristlenose plecos from juveniles to adults. Developing juveniles reach functional maturity within four to six months of hatching and grow to an adult size of eight to ten cm in length. To examine the developmental timing for the onset of air breathing, we tested different sized juveniles beginning at one cm up until 8 cm in length. The developmental timing for the onset of air breathing was measured by exposing each fish to a slowly decreasing aquatic oxygen content from 100% air saturation down to 8% air saturation. Fish were first able to breathe air at just over 2 cm and 1 gram in mass. There was a weak negative correlation between fish length and % air saturation at which air breathing began. When exposed to 15% air saturation, frequency of air breathing was negatively correlated with fish length. Armored catfish are becoming an invasive species in the southern US, outcompeting local fauna potentially because of this adaptation. This research provides important insight into the development of the air breathing adaptation that may allow these fish to outcompete the others.

Design and development of future high speed aircraft require the use of advanced modeling tools early on in the design phase to study and analyze complex aeroelastic, thermoelastic, and aerothermal interactions. This phase, commonly referred to as the conceptual design phase, involves using first principle based analytical models to obtain a practical starting point for the preliminary and detailed design phases. These analytical models are expected to, firstly, capture the effect of complex interactions between various subsystems using basic physics, and secondly, minimize computational costs. The size of a typical air-breathing hypersonic vehicle can vary anywhere between 12 ft, like the NASA X-43A, to 100 ft, like the NASP demonstrator vehicle. On the other hand, the performance expectations can vary anywhere between cruising at Mach 5 @ 85; 000 ft to Mach 10 @ 110; 000 ft. Reduction of computational costs is essential to efficiently sort through such a vast design space, while capturing the various complex interactions between subsystems has shown to improve accuracy of the design estimates. This motivates the need to develop modelling tools using first principle based analytical models with "needed" fidelity, where fidelity refers to the extent of interactions captured. With the advent of multidisciplinary design optimization tools, the need for an integrated modelling and analysis environment for high speed aircraft has increased substantially over the past two decades. The ever growing increase in performance expectations has made the traditional design approach of optimize first, integrate later obsolete. Designing a closed-loop control system for an aircraft might prove to be a difficult task with a geometry that yields an optimal (L/D) ratio, a structure with optimal material properties, and a propulsion system with maximum thrust-weight ratio. With all the subsystems already optimized, there is very little freedom for control designers to achieve their high performance goals. Integrated design methodologies focus on optimizing the overall design, as opposed to individual subsystems. Control-oriented modelling is an approach that involves making appropriate assumptions while modelling various subsystems in order to facilitate the inclusion of control design during the conceptual design phase. Due to their high lift-to-drag ratio and low operational costs, air-breathing hypersonic vehicles have spurred some interest in the field of high speed aircraft design over the last few decades. Modeling aeroelastic effects for such an aircraft is challenging due to its tightly integrated airframe and propulsion system that leads to significant deflections in the thrust vector caused by flexing of the airframe under extreme aerodynamic and thermal loads. These changes in the orientation of the thrust vector in turn introduce low frequency oscillations in the flight path angle, which make control system design a challenging task. Inclusion of such effects in the vehicle dynamics model to develop accurate control laws is an important part of control-oriented modeling. The air-breathing hypersonic vehicle considered here is assumed to be a thin-walled structure, where deformations due to axial, bending, shear, and torsion are modeled using the six independent displacements of a rigid cross section. Free vibration mode shapes are computed accurately using a novel scheme that uses estimates of natural frequency from the Ritz method as initial guesses to solve the governing equations using SUPORE, a two-point boundary value problem solver. A variational approach involving Hamilton's principle of least action is employed to derive the second order nonlinear equations of motion for the flexible aircraft. These nonlinear equations of motion are then linearized about a given cruise condition, modal analysis carried out on the linearized system, and the coupling between various significant modes studied. Further, open-loop stability analysis in time domain is conducted. / Ph. D.

The annual hydrological cycle of floodplains supports fishes that are uniquely adapted to optimize resources throughout the year. Such adaptations to changing environments include air-breathing for seasonally hypoxic waters and directed movements to best utilize habitats as they become available. This study examined the environmental, temporal and body-size influences on air-breathing behavior and movement ecology of Arapaima sp., one of the most economically and ecologically significant species in the Amazon. Acoustic (n=15) and radio (n=12) telemetry was used to study the influences on air-breathing and movement ecology of arapaima in the Central Amazon. Generalized additive mixed models showed that temperature was the most influential predictor of air-breathing intervals, followed by body size. The shortest breathing intervals were associated with consecutive "aggressive" breaths while the longest breathing intervals had consecutive "calm" breaths. Generalized linear mixed models showed that flood stage was the most important predictor of residency time, directional movement, and rate of movement. Fish moved faster in the flood and dry stages than the rising and falling stages, and spent longer in one place in the rising and falling stages than the flood and dry stages. Findings of this study may be used to inform management decisions for arapaima conservation, such as protected habitat and population counts, with applications to fishes across river-floodplain ecosystems globally. / Master of Science

As the world begins to focus more and more on new and more effective means of energy production, fuel cells become increasingly more popular. While different fuel cells are already found in industry today, the direct methanol fuel cell (DMFC) is becoming an increasingly more probable means for portable power production. In such applications a passive air breathing direct methanol fuel cell would be ideal. However, successful use of the passive DMFC in such applications requires that the fuel cell be capable of operating at various temperatures and relative humidities. A passive air breathing direct methanol fuel cell was developed and manufactured for this study. This work studied the effects of varying relative humidity and temperature over a probable range of operating conditions for small scale portable power applications on the performance of the fuel cell, both in relation to power production and fuel consumption. Potentiostatic, electrochemical impedance spectroscopy, and polarization tests were performed in order to characterize the performance of the fuel cell. Additionally, a one dimensional steady state isothermal mass transport model was developed to provide insight to the behavior of the fuel cell. The experimental data and model results show that increasing the fuel cell temperature and decreasing the ambient relative humidity increases the current production capabilities of the fuel cell. Further, the experimental data suggests that the major problem hindering current production in passive air breathing direct methanol fuel cells is flooding of the cathode diffusion layer. / Master of Science

A new suboptimal guidance law design approach for aerospace vehicles is proposed in this thesis, followed by an advanced control design for supersonic air-breathing engines. The guidance law is designed using the newly developed Generalized Model Predictive Static Programming (G-MPSP), which is based on the continuous time nonlinear optimal control framework. The key feature of this technique is one-time backward propagation of a small-dimensional weighting matrix dynamics, which is used to update the entire control history. This key feature, as well as the fact that it leads to a static optimization problem, lead to its computational efficiency. It has also been shown that the existing model predictive static programming (MPSP), which is based on the discrete time framework, is a special case of G-MPSP. The G-MPSP technique is further extended to incorporate ‘input inequality constraints’ in a limited sense using the penalty function philosophy. Next, this technique has been developed also further in a ‘flexible final time’ framework to converge rapidly to meet very stringent final conditions with limited number of iterations. Using the G-MPSP technique in a flexible final time and input inequality constrained formulation, a suboptimal guidance law for a solid motor propelled carrier launch vehicle is successfully designed for a hypersonic mission. This guidance law assures very stringent final conditions at the injection point at the end of the guidance phase for successful beginning of the hypersonic vehicle operation. It also ensures that the angle of attack and structural load bounds are not violated throughout the trajectory. A second-order autopilot has been incorporated in the simulation studies to mimic the effect of the inner-loops on the guidance performance. Simulation studies with perturbations in the thrust-time behaviour, drag coefficient and mass demonstrate that the proposed guidance can meet the stringent requirements of the hypersonic mission. The G-MPSP technique in a fixed final time and input inequality constrained formulation has also been used for optimal guidance of an aerospace vehicle propelled by supersonic air-breathing engine, where the resulting thrust can be manipulated by managing the fuel flow and nozzle area (which is not possible in solid motors). However, operation of supersonic air-breathing engines is quite complex as the thrust produced by the engine is a result of very complex nonlinear combustion dynamics inside the engine. Hence, to generate the desired thrust, accounting for a fairly detailed engine model, a dynamic inversion based nonlinear state feedback control design has been carried out. The objective of this controller is to ensure that the engine dynamically produces the thrust that tracks the commanded value of thrust generated from the guidance loop as closely as possible by regulating the fuel flow rate. Simultaneously, by manipulating throat area of the nozzle, it also manages the shock wave location in the intake for maximum pressure recovery with sufficient margin for robustness. To filter out the sensor and process noises and to estimate the states for making the control design operate based on output feedback, an extended Kalman filter (EKF) based state estimation design has also been carried out and the controller has been made to operate based on estimated states. Moreover, independent control designs have also been carried out for the actuators so that their response can be faster. In addition, this control design becomes more challenging to satisfy the imposed practical constraints like fuel-air ratio and peak combustion temperature limits. Simulation results clearly indicate that the proposed design is quite successful in assuring the desired performance of the air-breathing engine throughout the flight trajectory, i.e., both during the climb and cruise phases, while assuring adequate pressure margin for shock wave management.

This study determined the effect of hypoxia on air-breathing onset and physiological and morphological characters in larvae of the air breathing fishes Trichopodus trichopterus and Betta splendens. Larvae were exposed intermittently (12/12 h daily) to 20, 17, and 14 kPa of PO2 from 1 to 40 days post-fertilization. Survival, onset of air breathing, wet body mass, O2, Pcrit were measured every 5 dpf. Hypoxia advanced by 4 days, and delayed by 9 days, the onset of air breathing in Betta and Trichopodus, respectively. Hypoxia increased larval body length, wet mass, and labyrinth organ respiratory surface of Betta, but did not affect these factors in Trichopodus. Hypoxic exposure increased O2 by 50-100% at each day throughout larval development in Betta, but had no effect on larval Trichopodus. Hypoxia decreased Pcrit in Betta by 37%, but increased Pcrit in Trichopodus by 70%. Larval Betta reared in hypoxia showed a modified heart rate:opercular rate ratio (3:1 to 2:1), but these changes did not occur in Trichopodus. Compared to Betta, the blood of Trichopodus had a higher P50 and much smaller Bohr and Root effects. These interspecific differences are likely due to ecophysiological differences: Betta is a non- obligatory air-breather after 36 dpf with a slow lifestyle reflected in its low metabolism, while Trichopodus is an obligatory air-breather past 32 dpf with an athletic fast lifestyle and accompanying high metabolism.

Approved for public release, distribution is unlimited / Operational characteristics of a valveless pulse detonation engine system were characterized by experimental measurements of thrust, fuel flow, and internal gas dynamics. The multi-cycle detonation experiments were performed on an axis-symmetric engine geometry operating on an ethylene/air mixtures. The detonation diffraction process from a small 'initiator' combustor to a larger diameter main combustor in a continuous airflow configuration was evaluated during multi-cycle operation of a pulse detonation engine and was found to be very successful at initiating combustion of the secondary fuel/air mixture at high frequencies. The configuration was used to demonstrate the benefit of generating an overdriven detonation condition near the diffraction plane for enhanced transmission of the larger combustor. Results have shown that the addition of optical sensors, such as tunable diode lasers, to provide fuel profile data are invaluable for providing high fidelity performance results. The performance results demonstrated the ability of the valveless pulse detonation engine to run at efficiencies similar to valved pulse detonation engine geometries and may be a low cost alternative to conventional air-breathing propulsion systems. / Funded By: N00014OWR20226. / Lieutenant, United States Navy

In the study, micro-PEM fuel cells are designed and fabricated in-house through a deep UV lithography SU-8 process and a wet etching technique for perforated holes plates (diameter is 750 £gm) of 50 £gm thickness of pure copper. Measurements of cell performance are performed using the low percentage of the weight concentration (1-10 wt. %) of NaOH solution, Al paper as the source material for hydrogen production, and different open ratios of the perforated plates to determine which best improves cell power density. Experimental results are presented in the form of polarization VI and PI curves under the above operating conditions. The experimental results show cell performance is enhanced by the self-heating, humidifying of hydrogen production, hydrogen internal circulation and accumulated pressure. Finally, the micro-PEM fuel cell system with DC/DC boost converter can generate 4.99 V for use in cellular phone accumulators charging.