Made available in DSpace on 2017-07-21T20:42:44Z (GMT). No. of bitstreams: 1 Marcos Pontes.pdf: 4006153 bytes, checksum: 42b95748e61f5bc3de1b41ca1fbd649b (MD5) Previous issue date: 2012-02-29 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / The processing by equal channel angular extrusion of a duplex stainless steel UNS32205/S31803, with ferritic-austenitic structures, was studied, processing until four passes each sample. The reason of this processing was to promote a grain refinement in the material, to achieve ultrafined grain material by severe plastic deformation. Different number of passes were used in this processing to evaluate how the number of extrusions in the same sample influences the deformation imposed to the material. After processing, some different heat treatments were done in the samples to evaluate the recrystallization process in the processed material. In this study, it was possible to verify the increasing level of deformation in the material after every new processing in the sample, this was verified by the changes in grain orientation and by microstructure evaluation. It was possible to reduce the stress level to values that can avoid the breaking of punctures during processing, this allowed to process the material with a greater number of passes in a material with a high resistance like the duplex stainless steels. Strain bands were found in the structure of the processed material, this indicates high levels of deformation. / Foi realizado o estudo do processamento de um aço inoxidável dúplex SAF2205,com microestrutura ferrítica-austenítica, por extrusão em canal angular por até quatro passes. O objetivo deste processamento foi a obtenção de um refino de grãos no material, atingindo uma estrutura de grãos ultrafinos, a partir da aplicação de deformações plásticas severas. Foram realizados diferentes modos de processamento, variando o número de passes pela matriz e depois foi avaliado como este parâmetro influencia na deformação imposta ao material. Após o processamento por ECA (Extrusão por Canal Angular), foram realizados diferentes tratamentos térmicos para avaliar a cinética de recristalização do material. Foi possível verificar o nível crescente de deformação do material após cada passe, com o acompanhamento da orientação dos grãos e avaliações microestruturais. Foi possível reduzir os níveis de tensões o suficiente para evitar a quebra de punções durante o processamento, permitindo um número maior de passes para um material com a resistência do aço inoxidável dúplex. Foram verificadas bandas de deformação no material processado, indicando níveis elevados de deformação.

Neste trabalho investigou-se o comportamento sistemático do campo hiperfino magnético nos compostos intermetálicos Gd(Ni,Pd,Cu)In , Tb(Ni,Pd)In, Dy(Ni,Pd)In e Ho(Ni,Pd)In, com a técnica de Correlação Angular γ-γ Perturbada, nos sítios dos elementos terras raras com o núcleo de prova 140Ce e no sítio do In com o núcleo de prova 111Cd. Os resultados obtidos da dependência com a temperatura do Campo Hiperfino Magnético (Bhf) de cada composto foram primeiramente comparados com a teoria do campo molecular por meio da função de Brillouin, da qual foram extrapolados os valores de saturação de Bhf para cada composto estudado. Os valores extrapolados a zero Kelvin de Bhf (Bhf(T=0)) para os compostos estudados neste trabalho foram usados na comparação com valores de Bhf da literatura para outros compostos contendo o mesmo elemento R (R=Terra Rara). O resultado mostrou uma dependência linear com a temperatura de ordenamento magnético, o mesmo previsto pelo modelo RKKY o que indica que a principal contribuição para Bhf vem da polarização dos elétrons de condução (CEP) via interação de contato de Fermi. O comportamento de Bhf saturado para cada família de compostos de terras raras pesados RNiIn e RPdIn como função da projeção do spin 4f do elemento R mostrou também uma relação linear, com exceção dos resultados para os compostos RNiIn obtidos com 111Cd onde foi observado um leve desvio da linearidade. Foi feita uma investigação dos parâmetros hiperfinos elétricos em função da temperatura para os compostos RPdIn e GdNiIn com o núcleo de prova 111Cd, e os resultados mostram que para o composto GdPdIn pode ocorrer desordem Gd-In a altas temperaturas. / Systematic behavior of magnetic hyperfine field (Bhf) in the intermetallic compounds Gd(Ni,Pd,Cu)In , Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In was studied by Perturbed Gamma-Gamma Angular Correlation spectroscopy. The measurements of Bhf were carried out at the rare earth atom and In sites using the nuclear probes 140Ce and 111In respectively. The variation of hyperfine field with temperature, in most cases, follows the Brillouin function predicted from the molecular field theory. The hyperfine field values at rare earth atom sites obtained from 140Ce probe as well as at In sites obtained from 111In probe for each series of compounds were extrapolated to zero Kelvin Bhf(T=0) from these curves. These values were compared with the values of the literature for other compounds containing the same rare earth element and all of them show a linear relationship with the ordering temperature. This indicates that the main contribution to Bhf comes from the conduction electron polarization (CEP) through Fermi contact interaction and the principal mechanism of magnetic interaction in these compounds can be described by the RKKY type interaction. The values of Bhf(T=0) for each family of intermetallic compounds RNiIn and RPdIn when plotted as a function of 4f spin projection of rare earth element also shows a linear relationship. Exceptions are the results for the compounds RNiIn obtained with 111Cd probe where a small deviation from linearity is observed. The results of the measurements carried out with the 111Cd probe were also analyzed to obtain the hyperfine parameters of the quadrupole interaction as a function of temperature for RPdIn and GdNiIn compounds. The results show that for the compound GdPdIn there might be some Gd-In disorder at high temperature.

Title: Study of b-quark processes in the Belle experiment Author: Daniel Červenkov Department: Institute of Particle and Nuclear Physics Supervisor: Zdeněk Doležal Co-Supervisor: Karim Trabelsi Abstract: A study regarding the plausability of using the B0 → D∗ ρ± decay channel and the data set of the Belle experiment to measure sin(2φ1+φ3) has been carried out. Two fitters have been created. A time-independent one, which ex- hibits high stability and reports gratifying fit uncertainties, and a time-dependent one. During the testing of the latter we have discovered an EvtGen flaw and pro- posed a temporary workaround. Nevertheless, the time-dependent fitter fails to recover the correct values. More work will be needed to reach conclusive results. Keywords: B meson, CP violation, angular analysis, time-dependent, fitter

Neste trabalho investigou-se o comportamento sistemático do campo hiperfino magnético nos compostos intermetálicos Gd(Ni,Pd,Cu)In , Tb(Ni,Pd)In, Dy(Ni,Pd)In e Ho(Ni,Pd)In, com a técnica de Correlação Angular γ-γ Perturbada, nos sítios dos elementos terras raras com o núcleo de prova 140Ce e no sítio do In com o núcleo de prova 111Cd. Os resultados obtidos da dependência com a temperatura do Campo Hiperfino Magnético (Bhf) de cada composto foram primeiramente comparados com a teoria do campo molecular por meio da função de Brillouin, da qual foram extrapolados os valores de saturação de Bhf para cada composto estudado. Os valores extrapolados a zero Kelvin de Bhf (Bhf(T=0)) para os compostos estudados neste trabalho foram usados na comparação com valores de Bhf da literatura para outros compostos contendo o mesmo elemento R (R=Terra Rara). O resultado mostrou uma dependência linear com a temperatura de ordenamento magnético, o mesmo previsto pelo modelo RKKY o que indica que a principal contribuição para Bhf vem da polarização dos elétrons de condução (CEP) via interação de contato de Fermi. O comportamento de Bhf saturado para cada família de compostos de terras raras pesados RNiIn e RPdIn como função da projeção do spin 4f do elemento R mostrou também uma relação linear, com exceção dos resultados para os compostos RNiIn obtidos com 111Cd onde foi observado um leve desvio da linearidade. Foi feita uma investigação dos parâmetros hiperfinos elétricos em função da temperatura para os compostos RPdIn e GdNiIn com o núcleo de prova 111Cd, e os resultados mostram que para o composto GdPdIn pode ocorrer desordem Gd-In a altas temperaturas. / Systematic behavior of magnetic hyperfine field (Bhf) in the intermetallic compounds Gd(Ni,Pd,Cu)In , Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In was studied by Perturbed Gamma-Gamma Angular Correlation spectroscopy. The measurements of Bhf were carried out at the rare earth atom and In sites using the nuclear probes 140Ce and 111In respectively. The variation of hyperfine field with temperature, in most cases, follows the Brillouin function predicted from the molecular field theory. The hyperfine field values at rare earth atom sites obtained from 140Ce probe as well as at In sites obtained from 111In probe for each series of compounds were extrapolated to zero Kelvin Bhf(T=0) from these curves. These values were compared with the values of the literature for other compounds containing the same rare earth element and all of them show a linear relationship with the ordering temperature. This indicates that the main contribution to Bhf comes from the conduction electron polarization (CEP) through Fermi contact interaction and the principal mechanism of magnetic interaction in these compounds can be described by the RKKY type interaction. The values of Bhf(T=0) for each family of intermetallic compounds RNiIn and RPdIn when plotted as a function of 4f spin projection of rare earth element also shows a linear relationship. Exceptions are the results for the compounds RNiIn obtained with 111Cd probe where a small deviation from linearity is observed. The results of the measurements carried out with the 111Cd probe were also analyzed to obtain the hyperfine parameters of the quadrupole interaction as a function of temperature for RPdIn and GdNiIn compounds. The results show that for the compound GdPdIn there might be some Gd-In disorder at high temperature.

O presente trabalho teve como objetivo utilizar a técnica nuclear de Correlação Angular γ-γ Perturbada (CAP) para a medida de interações hiperfinas em filmes finos e amostras em pó de óxidos semicondutores SnO2 e TiO2 puros e dopados com metais de transição para uma investigação sistemática de defeitos estruturais e do magnetismo sob o ponto de vista atômico tendo como principal motivação a candidatura à aplicação desses óxidos em spintrônica. O trabalho também teve como foco a preparação e caracterização das amostras por meio de técnicas convencionais, como difração de raios X, microscopia eletrônica de varredura, espectroscopia de energia dispersiva e medidas de magnetização. Amostras puras dos filmes foram medidas mediante a variação sistemática da temperatura de tratamento térmico e do campo magnético aplicado. Tais medidas foram realizadas no HISKP, na Universidade de Bonn (Rheinische Friedrich-Wilhelms-Universität Bonn), através de implantação de íons de 111In(111Cd) ou 181Hf(181Ta); no IPEN, por sua vez, essas medidas foram realizadas após a difusão dos mesmos núcleos de prova. Outra parte das medidas CAP foram feitas através de implantação de íons de 111mCd(111Cd) e 117Cd(117In) no Isotope Mass Separator On-Line (ISOLDE) do Centre Européen Recherche Nucléaire (CERN). As medidas foram realizadas nos intervalos de temperatura de 8 K a 1173 K. Para análise de ferromagnetismo, medidas foram feitas à temperatura ambiente com e sem aplicação de campo magnético externo. Após a comparação dos resultados das medidas macroscópicas e atômicas das amostras, foi possível concluir que há uma correlação entre os defeitos, o magnetismo e a mobilidade dos portadores de carga nos semicondutores aqui estudados. Um passo adiante na busca de semicondutores, cujo ordenamento magnético possibilite o seu uso na eletrônica baseada em spin. Alguns resultados já foram publicados, incluindo resultados obtidos na Universidade de Bonn durante o período de doutorado sanduíche [1-7]. / This study aimed the use of nuclear technique Perturbed γ-γ Angular Correlation Spectroccopy (PAC) to measure the hyperfine interactions in thin films and powder samples of SnO2 and TiO2 pure and doped with transition metals to obtain a systematic investigation of defects and magnetism from an atomic point of view with the main motivation the application in spintronics. The work also focused on the preparation and characterization of samples by conventional techniques such as X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy and magnetization measurements. Pure samples of the films were measured by the systematic variation of thermal treatment and applied magnetic field. These measurements were performed in HISKP at the University of Bonn (Rheinische Friedrich-Wilhelms-Universität Bonn) using 111In(111Cd) or 181Hf (181Ta); at IPEN, in turn, these measurements were performed after the diffusion of the same probe nuclei. Another part of PAC measurements were carried out using 111mCd(111Cd) and 117Cd (117In) in Isotope Mass Separator On-Line (ISOLDE) at Centre Européen Recherche Nucléaire (CERN). The measurements were performed from 8 K to 1173 K. After comparing results from macroscopic techniques with those from PAC, it was concluded that there is a correlation between the defects, magnetism and the mobility of charge carriers in semiconductors studied here. A step forward in the search for semiconductors, whose magnetic ordering allows its use in electronics based on spin. Some results have been published, including results obtained at the University of Bonn for the sandwich doctorate period [1-7].

Prohibitive cost and large size of conventional angular rate sensors have limited their use to large scale aeronautical applications. However, the emergence of MEMS technology in the last two decades has enabled angular rate sensors to be fabricated that are orders of magnitude smaller in size and in cost. The reduction in size and cost has subsequently encouraged new applications to emerge, but the accuracy and resolution of MEMS angular rate sensors will have to be greatly improved before they can be successfully utilised for such high end applications as inertial navigation. MEMS angular rate sensors consist of a vibratory structure with two main resonant modes and high Q factors. By means of an external excitation, the device is driven into a constant amplitude sinusoidal vibration in the first mode, normally at resonance. When the device is subject to an angular rate input, Coriolis acceleration causes a transfer of energy between the two modes and results in a sinusoidal motion in the second mode, whose amplitude is a measure of the input angular rate. Ideally the only coupling between the two modes is the Coriolis acceleration, however fabrication imperfections always result in some cross stiffness and cross damping effects between the two modes. Much of the previous research work has focussed on improving the physical structure through advanced fabrication techniques and structural design; however attention has been directed in recent years to the use of control strategies to compensate for these structural imperfections. The performance of the MEMS angular rate sensors is also hindered by the effects of time varying parameter values as well as noise sources such as thermal-mechanical noise and sensing circuitry noise. In this thesis, MEMS angular rate sensing literature is first reviewed to show the evolu- tion of MEMS angular rate sensing from the basic principles of open-loop operation to the use of complex control strategies designed to compensate for any fabrication imperfections and time-varying effects. Building on existing knowledge, a novel adaptively controlled MEMS triaxial angular rate sensor that uses a single vibrating mass is then presented. Ability to sense all three components of the angular rate vector with a single vibrating mass has advantages such as less energy usage, smaller wafer footprint, avoidance of any mechanical interference between multiple resonating masses and removal of the need for precise alignment of three separate devices. The adaptive controller makes real-time estimates of the triaxial angular rates as well as the device cross stiffness and cross damping terms. These estimates are then used to com- pensate for their effects on the vibrating mass, resulting in the mass being controlled to follow a predefined reference model trajectory. The estimates are updated using the error between the reference model trajectory and the mass's real trajectory. The reference model trajectory is designed to provide excitation to the system that is sufficiently rich to enable all parameter estimates to converge to their true values. Avenues for controller simplification and optimisation are investigated through system simulations. The triaxial controller is analysed for stability, averaged convergence rate and resolution. The convergence rate analysis is further utilised to determine the ideal adaptation gains for the system that minimises the unwanted oscillatory behaviour of the parameter estimates. A physical structure for the triaxial device along with the sensing and actuation means is synthesised. The device is realisable using MEMS fabrication techniques due to its planar nature and the use of conventional MEMS sensing and actuation elements. Independent actuation and sensing is achieved using a novel checkerboard electrode arrangement. The physical structure is refined using a design automation process which utilises finite element analysis (FEA) and design optimisation tools that adjust the design variables until suitable design requirements are met. Finally, processing steps are outlined for the fabrication of the device using a modified, commercially available polysilicon MEMS process.

The former Viking settlement Birka is located on Björkö Island in Lake Mälaren, the third largest lake in Sweden. Birka is a well-known archeological site that onshore has been carefully examined. The lake floor of the waters surrounding the island has been less investigated but has a great potential to host not yet discovered archeological objects from this former hub for seafarers. Therefore, a geophysical survey including multibeam sonar mapping and subbottom profiling was carried out mainly along the shores of western Björkö Island. Processing and analysis of these collected data form the basis of this thesis. The main aims of this study are to produce a suite of geological maps and stratigraphic profiles that are used to geologically interpret the uppermost sediment stratigraphy and the bathymetry of the area. In addition, the processed data are investigated for archeological objects. The result shows that the acoustic records of the sediment stratigraphy reaches back to glacial clay formed as a consequence of the retreat of the Late Weichselian ice sheet, and that the uppermost sediment units probably are from the time after the isolation of Lake Mälaren from the Baltic Sea. The bathymetry and backscatter results have revealed that this relatively shallow study area contains several objects that potentially could be of interest from an archeological point of view. These objects include several unidentified objects in the Björkö strait and two unregistered shipwrecks where ground truthing data need to be collected to determine their respective origin.

This thesis aims to study the theoretical complexity and empirical performance of decomposition algorithms. We focus on linear programs with a block-angular structure. Decomposition algorithms used to be the only way to solve large-scale special structured problems, in terms of memory limit and CPU time. However, with the advances in computer technology over the past few decades, many large-scale problems can now be solved simply by using some general purpose LP software, without exploiting the problems' inner structures. A question arises naturally, should we solve a structured problem with decomposition, or directly solve it as a whole? We try to understand how a problem's characteristics influence its computational performance, and compare the relative efficiency of algorithms with and without decomposition. Two comparisons are conducted in our research: first, the Dantzig-Wolfe decomposition method (DW) versus the simplex method (simplex); second, the analytic center cutting plane method (ACCPM) versus the interior point method (IPM). These comparisons fall into the two main solution approaches in linear programming: simplex-based algorithms and IPM-based algorithms. Motivated by our observations of ACCPM and DW decomposition, we devise a hybrid algorithm combining ACCPM and DW, which are the counterparts of IPM and simplex in the decomposition framework, to take the advantages of both: the quick convergence rate of IPM-based methods, as well as the accuracy of simplex-based algorithms. A large set of 316 instances is incorporated in our experiments, so that different dimensioned problems with primal or dual block-angular structures are covered to test our conclusions.

This thesis aims to study the theoretical complexity and empirical performance of decomposition algorithms. We focus on linear programs with a block-angular structure. Decomposition algorithms used to be the only way to solve large-scale special structured problems, in terms of memory limit and CPU time. However, with the advances in computer technology over the past few decades, many large-scale problems can now be solved simply by using some general purpose LP software, without exploiting the problems' inner structures. A question arises naturally, should we solve a structured problem with decomposition, or directly solve it as a whole? We try to understand how a problem's characteristics influence its computational performance, and compare the relative efficiency of algorithms with and without decomposition. Two comparisons are conducted in our research: first, the Dantzig-Wolfe decomposition method (DW) versus the simplex method (simplex); second, the analytic center cutting plane method (ACCPM) versus the interior point method (IPM). These comparisons fall into the two main solution approaches in linear programming: simplex-based algorithms and IPM-based algorithms. Motivated by our observations of ACCPM and DW decomposition, we devise a hybrid algorithm combining ACCPM and DW, which are the counterparts of IPM and simplex in the decomposition framework, to take the advantages of both: the quick convergence rate of IPM-based methods, as well as the accuracy of simplex-based algorithms. A large set of 316 instances is incorporated in our experiments, so that different dimensioned problems with primal or dual block-angular structures are covered to test our conclusions.

Hexagonal closed packed (hcp) materials, in contrast to cubic materials, possess several processing challenges due to their anisotropic structural response, the wide variety of deformation textures they exhibit, and limited ductility at room temperature. The aim of this work is to investigate, both experimentally and theoretically, the effect os severe plastic deformation, ultrafine grain sizes, crystallographic textures and number of phases on the flow stress anisotropy and tension compression asymmetry, and the mechanisms responsible for these phenomena in two hcp materials: AZ31B Mg alloy consisting of one phase and Zn-8wt.% Al that has an hcp matrix with a secondary facecentered cubic (fcc) phase. Mg and its alloys have high specific strength that can potentially meet the high demand for light weight structural materials and low fuelconsumption in transportation. Zn-Al alloys, on the other hand, can be potential substitutes for several ferrous and non-ferrous materials because of their good mechanical and tribological properties. Both alloys have been successfully processed using equal channel angular extrusion (ECAE) following different processing routes in order to produce samples with a wide variety of microstructures and crystallographic textures for revealing the relationship between microstructural parameters, crystallographic texture and resulting flow stress anisotropy at room temperature. For AZ31B Mg alloy, the texture evolution during ECAE following conventional and hybrid ECAE routes was successfully predicted using visco-plastic self-consistent (VPSC) crystal plasticity model. The flow stress anisotropy and tension-compression (T/C) asymmetry of the as received and processed samples at room temperature were measured and predicted using the same VPSC model coupled with a dislocation-based hardening scheme. The governing mechanisms behind these phenomena are revealed as functions of grains size and crystallographic texture. It was found that the variation in flow stress anisotropy and T/C asymmetry among samples can be explained based on the texture that is generated after each processing path. Therefore, it is possible to control the flow anisotropy and T/C asymmetry in this alloy and similar Mg alloys by controlling the processing route and number of passes, and the selection of processing conditions can be optimized using VPSC simulations. In Zn-8wt.% Al alloy, the hard phase size, morphology, and distribution were found to control the anisotropy in the flow strength and elongation to failure of the ECAE processed samples.