Antarctic ice shelves control the ice flux from the continent to the ocean. As such, they play a major role in the stability of the ice sheet and its potential contribution to sea level rise, especially in the context of global change. Below some of these ice shelves, marine ice can be found which is a product of the Deep Thermohaline Circulation. Due to its specific genetic process, marine ice has intrinsic physical (grain size, ice fabric, bubble content, ) and chemical (impurities, water stable isotopes) properties, that differ from those of 'meteoric ice' formed on the continent through snow metamorphism or 'sea ice' resulting from sea water freezing at the ocean-atmosphere surface. Until now however, the effect of these specific properties on marine ice rheology is still very poorly understood.<p><p>The principal objective being to include realistic mechanical parameters for marine ice in ice shelf flow models, uniaxial compression experiments have been performed on various types of marine ice samples. Technical developments are an important component of this thesis has they were necessary to equip the laboratory with the appropriate tools (pneumatic rig, automatic ice fabric data handling).<p><p>Results from experimental compression on isotropic marine ice show that it represents the higher boundary for meteoric ice viscosity throughout the whole temperature range, thereby validating Cuffey and Paterson's relationship with an enhancement factor equals to 1.<p><p>Marine ice is however often quite anisotropic, showing elongated crystals and wide single maximum fabric, that should impact its mechanical properties. Experiments on pre-oriented marine ice samples have therefore been carried out combining the study of epsilon_{oct} vs. tau_{oct} with a thorough analysis of microstructural data 'before' and 'after' the experiment. <p><p>Depending on the orientation of the sample in the applied stress field and on the intensity of the latter, anisotropic marine ice can be harder or softer than its isotropic counterpart, with n=4 often observed in Glen's flow law. Associating the experimental geometrical settings to potential natural equivalent, results suggest that anisotropic marine ice would strengthen ice shelf flow in most areas (for a same given temperature), apart from suturing areas between individual ice streams as they merge to form the ice shelf, where it could become weaker than meteoric ice in certain circumstances.<p><p>Finally, preliminary sensitivity studies, using a simple ice shelf model with our experimental parameters of Glen's flow law have allowed us to discuss the potential impact of rift location, rift size and thermal regime in the ice shelf behavior. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

Chapter 1: Antarctic fishes are extremely cold adapted. Despite their inability to upregulate heat shock proteins, recent studies have demonstrated a capacity for heat response in these animals. A cDNA microarray study looked at the Notothenioid fish Trematomus bernacchii and revealed heat sensitivities for hundreds of genes, two of which code for members of the CCAAT/Enhancer-binding protein (C/EBP) family of transcription factors. These molecular switches are best known for their roles in apoptosis, inflammation and cell cycle arrest. This dissertation further elucidates the role of C/EBP-delta in the Antarctic fishes T. bernacchii and Pagothenia borchgrevinki. Chapter 2: C/EBP-delta is constitutively expressed in unstressed, field-acclimated (ca. -1.86°C) animals in a highly tissue-specific manner. White muscle tissue contains the highest C/EBP-delta concentration, which is further increased in response to sublethal heat stress at 2.0 or 4.0°C. This response is mostly acute and transitory, but a lesser upregulation was observed in fishes held for one month at 4.0°C. Chapter 3: The heat-induced nuclear translocation of C/EBP-delta--as determined by immunohistochemistry--appears to be time, tissue and species specific with spleen, heart and retinae being particularly responsive in certain situations. Chapter 4: Protein concentrations of proliferating cell nuclear antigen are tissue specific and variably heat responsive. Surprisingly, levels appear to be positively correlated with C/EBP-delta. Chapter 5: Flow cytometry revealed increasingly high temperatures reduce the proportion of G1 cells while increasing the abundance of apoptotic cells. Chapter 6: These findings are discussed in the context of global climate change and the cellular stress response.

京都大学 / 0048 / 新制・課程博士 / 博士(情報学) / 甲第20034号 / 情博第629号 / 新制||情||109(附属図書館) / 33130 / 京都大学大学院情報学研究科通信情報システム専攻 / (主査)教授 佐藤 亨, 教授 守倉 正博, 教授 山本 衛 / 学位規則第4条第1項該当 / Doctor of Informatics / Kyoto University / DFAM

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Primär emittierte marine Aerosolpartikel haben einen wichtigen Einfluss auf den Strahlungshaushalt der Erde, indem sie unter anderem als Kondensations (CCN)- oder Eiskeime (INP) für die Bildung von Wolken wirken. In den ozeanisch geprägten Polarregionen dominieren diese marinen Aerosolpartikel in der Luft und können dort eine bedeutende bzw. sich noch verändernde Rolle im Rahmen des Klimawandels einnehmen. Sie entspringen vordergründig aus dem ozeanische Oberflächenwasser und dem hauchdünnen Oberflächenfilm, dem sogenannte sea surface microlayer (SML), und werden durch das Platzen von durch Wind eingetragene Luftblasen freigesetzt. Primär emittierte marine Aerosolpartikel bestehen aus anorganischem Meersalz und organischen Kohlenstoffverbindungen, deren relative Anteile sich stark in Abhängigkeit vom Aerosoldurchmessers unterscheiden. In diesem Zusammenhang stellen die marinen Kohlenhydrate eine wichtige organische Stoffgruppe dar, deren ozeanische Quellen, Übergang vom Ozean in die Atmosphäre, Veränderungen in der Atmosphäre als auch deren Beitrag bei der Kondensation und Eiskeimbildung noch nicht ausreichend verstanden sind. Dieser begrenzte Kenntnisstand ist unter anderem auf das mangelnde Vorhandensein analytischer Methoden zurückzuführen, die eine zuverlässige Bestimmung von Kohlenhydraten in den stark salzhaltigen Matrices bei sehr niedrigen Massekonzentrationen mit hohen Wiederfindungsraten gewährleisten. Im Rahmen dieser Doktorarbeit wurde durch Kombination der Hochleistungs-Anionenaustauschchromatographie mit gepulster amperometrischer Detektion (HPAEC-PAD) und einer Entsalzung durch Elektrodialyse eine analytische Methode entwickelt, welche die Bestimmung eines breiten Spektrums an gelösten Kohlenhydraten in freier (als Monosaccharide) und gebundener (als Oligo- oder Polysaccharide) Form in Meerwasser und anderen salzhaltigen Matrices ermöglicht. Mithilfe dieser neuen Methode wurde ein biogeochemischer Zusammenhang zwischen dem Vorkommen von freier Glucose und der eiskeimbildenden Aktivität im arktischen SML beobachtet. Außerdem wurde im meereisfreien Teil des Südlichen Ozeans der primäre Transfer von Kohlenhydraten vom Ozean über den SML in die Atmosphäre und deren sekundäre atmosphärische Veränderungen erforscht. Die umfangreichen Untersuchungen mariner Kohlenhydrate in polarem Meerwasser und Aerosolpartikeln zeigen Indizien einer bisher noch unterschätzten atmosphärischen Bedeutung mikrobiologischer Prozesse auf.:1. Introduction ............................................................................................................................................... 1 1.1 The Polar Oceans ................................................................................................................................. 3 1.1.1 Geographical Definitions and Characteristics.......................................................................... 3 1.1.2 Role in Earth’s Climate System ................................................................................................ 5 1.1.3 Changing Climate and Consequences ...................................................................................... 6 1.2 Sea Spray Aerosol over the Polar Oceans ........................................................................................... 9 1.2.1 Production Mechanisms of Sea Spray Aerosol ........................................................................ 9 1.2.2 Chemo-Selective Sea-Air Transfer and Atmospheric Aging ................................................... 10 1.2.3 Impact on Earth’s Radiation Budget ...................................................................................... 12 1.3 The Surface of the Polar Oceans ....................................................................................................... 15 1.3.1 The Sea Surface Microlayer ................................................................................................... 15 1.3.2 Selective Enrichment of Chemical Compounds ..................................................................... 15 1.3.3 Atmospheric Relevance for Atmospheric Chemistry and Cloud Microphysics ..................... 24 1.4 Marine Carbohydrates....................................................................................................................... 26 1.4.1 Chemical Structures ............................................................................................................... 26 1.4.2 Microbial Role ........................................................................................................................ 28 1.4.3 Marine Carbohydrates in the Atmosphere ............................................................................ 30 1.4.4 Chemical Analysis and Sea Salt Interference ......................................................................... 31 2. Results and Discussions ........................................................................................................................... 35 2.1 First Publication ................................................................................................................................. 35 2.1.1 Glucose as a Potential Chemical Marker for Ice Nucleating Activity in Arctic Seawater and Melt Pond Samples ......................................................................................................................... 35 2.1.2 Supporting Information ......................................................................................................... 47 2.2 Second Publication ............................................................................................................................ 55 A protocol for quantifying mono-and polysaccharides in seawater and related saline matrices by electro-dialysis (ED) – combined with HPAEC-PAD ........................................................................ 55 2.3 Third Publication ............................................................................................................................... 70 2.3.1 Aerosol Marine Primary Carbohydrates and Atmospheric Transformation in the Western Antarctic Peninsula ......................................................................................................................... 70 2.3.2 Supporting Information ......................................................................................................... 88 3. Atmospheric Implications ........................................................................................................................ 95 4. Summary ................................................................................................................................................ 98 5. References ............................................................................................................................................. 101 List of Abbreviations .................................................................................................................................. 121 List of Figures ............................................................................................................................................. 123 List of Tables .............................................................................................................................................. 124 Curriculum Vitae ........................................................................................................................................ 125 / Primary marine aerosol particles impact Earth’s radiation budget by acting, among other things, as cloud condensation nuclei (CCN) or ice nucleating particles (INP) for the formation of clouds. Over the polar oceans, primary marine aerosol emissions dominate the atmospheric particles and can play a significant and changing role there in the context of climate change. These particles are primarily emitted from the oceanic surface water and a thin surface film, the so-called sea surface microlayer (SML), by the bursting of air bubbles entrained by the wind. They consist of inorganic sea salt and organic matter (OM), whose relative proportions differ greatly depending on the aerosol diameter. In this context, the marine carbohydrates represent an important group of OM, whose oceanic sources, their transition from the sea to the atmosphere, atmospheric aging and contribution to the condensation of water droplets and ice nucleation are not well understood. This limited level of knowledge is due, among other things, to the lack of analytical methods that enable a reliable determination of carbohydrates at very low mass concentrations with high recovery rates in the salty matrices. Within the framework of this PhD thesis, an analytical method was developed by combining high-performance anion-exchange chromatography with pulsed amperometric detection (HPAEC-PAD) and a prior desalination by electro-dialysis (ED), which enables the determination of a wide range of dissolved carbohydrates in their free (as monosaccharides) and combined (as oligo- or polysaccharides) forms in seawater and other saline matrices. With this new method, a biogeochemical connection between the presence of free glucose and the ice nucleating activity in the Arctic SML could be observed. In addition, the primary transfer of carbohydrates from the ocean via the SML into the atmosphere and subsequent secondary atmospheric transformations were investigated in the sea ice-free part of the Southern Ocean. Consequently, the extensive investigations of marine carbohydrates in seawater and aerosol particles indicate an atmospheric importance of microbiological processes that has been underestimated until now.:1. Introduction ............................................................................................................................................... 1 1.1 The Polar Oceans ................................................................................................................................. 3 1.1.1 Geographical Definitions and Characteristics.......................................................................... 3 1.1.2 Role in Earth’s Climate System ................................................................................................ 5 1.1.3 Changing Climate and Consequences ...................................................................................... 6 1.2 Sea Spray Aerosol over the Polar Oceans ........................................................................................... 9 1.2.1 Production Mechanisms of Sea Spray Aerosol ........................................................................ 9 1.2.2 Chemo-Selective Sea-Air Transfer and Atmospheric Aging ................................................... 10 1.2.3 Impact on Earth’s Radiation Budget ...................................................................................... 12 1.3 The Surface of the Polar Oceans ....................................................................................................... 15 1.3.1 The Sea Surface Microlayer ................................................................................................... 15 1.3.2 Selective Enrichment of Chemical Compounds ..................................................................... 15 1.3.3 Atmospheric Relevance for Atmospheric Chemistry and Cloud Microphysics ..................... 24 1.4 Marine Carbohydrates....................................................................................................................... 26 1.4.1 Chemical Structures ............................................................................................................... 26 1.4.2 Microbial Role ........................................................................................................................ 28 1.4.3 Marine Carbohydrates in the Atmosphere ............................................................................ 30 1.4.4 Chemical Analysis and Sea Salt Interference ......................................................................... 31 2. Results and Discussions ........................................................................................................................... 35 2.1 First Publication ................................................................................................................................. 35 2.1.1 Glucose as a Potential Chemical Marker for Ice Nucleating Activity in Arctic Seawater and Melt Pond Samples ......................................................................................................................... 35 2.1.2 Supporting Information ......................................................................................................... 47 2.2 Second Publication ............................................................................................................................ 55 A protocol for quantifying mono-and polysaccharides in seawater and related saline matrices by electro-dialysis (ED) – combined with HPAEC-PAD ........................................................................ 55 2.3 Third Publication ............................................................................................................................... 70 2.3.1 Aerosol Marine Primary Carbohydrates and Atmospheric Transformation in the Western Antarctic Peninsula ......................................................................................................................... 70 2.3.2 Supporting Information ......................................................................................................... 88 3. Atmospheric Implications ........................................................................................................................ 95 4. Summary ................................................................................................................................................ 98 5. References ............................................................................................................................................. 101 List of Abbreviations .................................................................................................................................. 121 List of Figures ............................................................................................................................................. 123 List of Tables .............................................................................................................................................. 124 Curriculum Vitae ........................................................................................................................................ 125

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This study examines a small body of 19th-century American literature about the Antarctic: Adam Seaborn's (pseud.) Symzonia (1820), Edgar Allan Poe's "MS. Found in a Bottle" (1833) and The Narrative of Arthur Gordon Pym (1838), Peter Prospero's (pseud.) "The Atlantis" (1838-39), and James Fenimore Cooper's The Monikins (1835) and The Sea Lions (1849). These were written in a transitional phase in the history of the Antarctic. At the start of the period, the region was almost completely unknown. Towards the end of the period, however, the region had been mapped in its essence, and the existence of an Antarctic continent had been verified. For complex reasons, the region came into cultural focus in the U.S. during the 1820s to 40s, culminating in the first major American scientific expedition in 1838-42 to explore the South Seas and the Antarctic. The study is primarily historical, tracing ideas to their historical contexts in order to determine what these authors used the unknown space of the Antarctic for. These texts were written in imaginative response to contemporary notions of the Antarctic, which is reflected in the mode of representation. The literature is in the mode of speculative fiction-most of texts imagining a tropical, inhabited Antarctic-up until the region is explored, at which point it turns to realism. The texts fall into three categories: the utopian, liminal, and realistic. The utopian texts-Symzonia, The Monikins, and "The Atlantis"-are works of social criticism, using the blank space of the Antarctic to treat a diverse range of issues, including politics, evolutionary theories, race, and gender. Poe's "MS" and Pym represent the liminal category; they dramatize the anticipation of an imminent Antarctic discovery, narrating up to a point of revelation, only to stop short. The Sea Lions is the only realistic text, coming after the Antarctic is explored. Here the knowledge of the Antarctic has solidified into the environment we know today, but with religiously symbolical overtones.

VILLELA, FRANCO N. J. Análise decadal do fluxo de CO2 entre o oceano e a atmosfera na passagem de Drake, Oceano Austral. 2011. 148 f. Dissertação (mestrado) Programa de Pós-Graduação em Ciência Ambiental (PROCAM), Universidade de São Paulo, São Paulo, 2011. Para a área delimitada pelos paralelos 60ºS e 62,5ºS e pelos meridianos 60ºW e 65ºW, localizada no sul da Passagem de Drake, no Oceano Austral, próximo à Península Antártica, foram calculadas as distribuições médias de 2000 a 2009, sazonais e anual, do fluxo de CO2 na interface oceano-atmosfera e de suas variáveis associadas: a pressão parcial de CO2 na superfície marinha (PCO2sw), a pressão parcial de CO2 na atmosfera (PCO2ar), a diferença da pressão parcial de CO2 entre o oceano e a atmosfera (PCO2) e a taxa de transferência gasosa (TR), que é produto do coeficiente solubilidade do CO2 na água do mar pela velocidade de transferência gasosa. A parametrização utilizada no cálculo dos fluxos foi a de Takahashi et al. (2009) com TR dependente da velocidade do vento ao quadrado multiplicada por um fator de escala 0,26. A área de estudo tem cerca de 75 mil km2 e foi dividida em uma grade espacial de 0,5º x 0,5º, resultando em 50 quadrículas. Foram utilizados mais de 46 mil medições de PCO2sw, que na média espacial variou de 362,7 ±11,2 a 371,9 ±17,5 µatm, no verão e primavera respectivamente. A PCO2 variou de -0,4 a 5,7 µatm no outono e primavera, respectivamente. A TR variou de 0,065 ±0,04 a 0,088 ±0,002 gC.mês-1.m-2.µatm-1, no verão e inverno, respectivamente. O fluxo líquido, se tomando a concentração de gelo como negligenciável, variou de -0,039 ±0,865 a 0,456 ±1,221 gC.m-2.mês-1, no outono e inverno, respectivamente. O fluxo total anual de carbono, estimado através da média espacial por quadrícula, foi de 95 GgC.ano-1. Dessa maneira, na estimativa anual, a superfície do mar se comporta como fonte de CO2 para a atmosfera, principalmente devido à região da plataforma continental com PCO2sw consideravelmente maior que o da atmosfera. Sazonalmente sugere-se que no verão a maior disponibilidade de radiação solar, a temperatura da superfície do mar (TSM) mais elevada e os ventos mais fracos favorecem a produção de biomassa fitoplanctônica, fazendo com que a bomba biológica seja o processo dominante na diminuição da PCO2sw e na absorção de CO2 atmosférico pela superfície marinha. Já no inverno, os ventos se intensificam e, associados com o forte resfriamento da TSM, promovem a mistura com águas profundas ricas em carbono inorgânico dissolvido, levando a superfície marinha a um estado de supersaturação de CO2 em relação à atmosfera. Ventos circumpolares de oeste mais intensos e deslocados para sul tem sido apontados como a causa do aumento da PCO2sw em igual ou maior taxa do que ocorre na atmosfera. Na área de estudo foi levantada uma tendência média da intensidade do vento de 0,23 ±0,03 m.s-1.década-1 e um aumento na freqüência da componente zonal de oeste (positiva) de 1,47 ± 1,13 % .década-1. Sugere-se que estas tendências estejam relacionadas com o Modo Anular Austral (SAM). Entretanto, a tendência decadal estimada para a PCO2sw foi menor que para a atmosfera, apesar de ambas indicarem tendência de aumento. Acredita-se que a grande variabilidade e distribuição esparsa de dados tenham mascarado a magnitude da estimativa da tendência de PCO2sw. / VILLELA, FRANCO N. J. Decadal analysis of the CO2 sea-air flux in the Drake Passage, Southern Ocean 2011. 148 f. Dissertação (mestrado) Programa de Pós-Graduação em Ciência Ambiental (PROCAM), Universidade de São Paulo, São Paulo, 2011. For the area bounded by parallels 60°S and 62.5°S and meridians 60°W and 65°W, located in the southern Drake Passage in the Southern Ocean, near the Antarctic Peninsula, mean seasonal and annual distributions of CO2 flux at the ocean-atmosphere interface, from 2000 to 2009, have been computed, as well as their associated variables: the CO2 partial pressure at sea surface (PCO2sw), the CO2 partial pressure in atmosphere (PCO2ar), the CO2 pressure difference between ocean and atmosphere (PCO2), and the gas transfer rate (TR), which is the product of the CO2 solubility coefficient in sea water by the gas transfer velocity. The parameterization used to calculate fluxes was that of Takahashi et al. (2009) with TR depending on the squared wind speed multiplied by a scale factor 0.26. The study area has about 75,000 km2 and was divided into a grid of 0.5° x 0.5°, resulting in 50 area boxes. Over 46,000 PCO2sw measurements were used, which in the spatial mean varied from 362.7±11.2 to 371.9±17.5 µatm, in summer and spring, respectively. The PCO2 varied from 0.4 to 5.7 µatm in autumn and spring, respectively. TR varied from 0.065±0.04 to 0,088±0.002 gC.month-1.m-2.µatm-1, in summer and winter, respectively. The net flux, taking ice concentration as negligible, varied from 0.039±0.865 to 0.456±1.221 gC.month-1.m-2, in autumn and winter, respectively. The total annual carbon flux, estimated through the spatial mean per square, was 95 GgC.y-1. Thus, in the annual estimate the region acts as a source to the atmosphere, mainly due to the continental shelf having PCO2sw considerably greater than that of the atmosphere. Seasonally, it is suggested that in summer the greater availability of solar radiation, warmer sea surface temperature (SST), and weaker winds favor the production of phytoplanktonic mass, making the biological pump the dominating process in lowering the PCO2sw and the absorption of atmospheric CO2 by the sea surface. On the other hand, in winter winds intensify and, in association with the strong cooling of the SST, promote mixing with deep waters rich in dissolved inorganic carbon, leading the sea surface to a state of supersaturation in CO2 relative to the atmosphere. Stronger circumpolar west winds and displaced to the south have been pointed as the cause for the increase of PCO2sw at a rate equal to or greater than that occurring in the atmosphere. In the study area it has been detected a mean trend of wind intensity 0.23±0.03 m.s-1.decade-1 and an increase in the western zonal component of 1.47±1.3%.decade-1. It is suggested that these trends are related to the Southern Annular Mode (SAM). However, the decadal trend estimated for the PCO2sw was smaller than for the atmosphere, in spite of both indicating increasing tendencies. It is believed that the great variability and scatter distribution of the data have masked the magnitude of the PCO2SW trend estimate.