The ocean emission and subsequent oxidation of dimethylsulfide (DMS) provides a source of sulfate in the atmosphere, potentially affecting the amount of solar radiation reaching the Earth's surface through both direct and indirect radiative effects of sulfate aerosols. DMS in the ocean can be quite variable with season and location, which in turn leads to high spatial and temporal variability of ocean DMS emissions. This study tested currently available observational and empirically-based climatologies of DMS concentration in the surface ocean. The exploration of the existing parameterizations mainly reveals the limitations of estimating DMS with an empirical model based on variables such as chlorophyll and mixed layer depth. The different algorithms show significant differences in spatial pattern, and none correlate strongly with observations. There is considerable uncertainty both in terms of the spatiotemporal distribution in DMS concentration and flux, as well as in the global total DMS flux. The present research investigates the influence of DMS on sulfate aerosols and radiative fluxes given different DMS climatologies in the fourth generation of the Canadian Global Atmospheric Climate Model (CanAM4.1). In general, the response in the radiative flux seems to follow the variation in the global mean flux of DMS linearly. Differences in the spatial and temporal structure of oceanic DMS have only a secondary effect on the radiative changes. The overall response of the atmosphere to the presence or absence of structure of DMS in space and time is distinctly smaller compared to the possible uncertainty of this response associated with the magnitude of the annually averaged global flux. / Graduate / 0425 / 0725 / 0416 / jetesdal@uvic.ca

abstract: Land-atmosphere interactions of semiarid shrublands have garnered significant scientific interest. One of the main tools used for this research is the eddy covariance (EC) method, which measures fluxes of energy, water vapor, and carbon dioxide. EC fluxes can be difficult to interpret due to complexities within the EC footprint (i.e. the surface conditions that contribute to the flux measurements). Most EC studies use a small number of soil probes to estimate the land surface states underlying the measured fluxes, which likely undersamples the footprint-scale conditions, especially in semiarid shrublands which are characterized by high spatial and temporal variability. In this study, I installed a dense network of soil moisture and temperature probe profiles in the footprint region of an EC tower at two semiarid sites: a woody savanna in southern Arizona and a mixed shrubland in southern New Mexico. For data from May to September 2013, I link land surface states to EC fluxes through daily footprints estimated using an analytical model. Novel approaches are utilized to partition evapotranspiration, estimate EC footprint soil states, connect differences in fluxes to footprint composition, and assess key drivers behind soil state variability. I verify the hypothesis that a small number of soil probes poorly estimates the footprint conditions for soil moisture, due to its high spatial variability. Soil temperature, however, behaves more consistently in time and space. As such, distributed surface measurements within the EC footprint allow for stronger ties between evapotranspiration and moisture, but demonstrate no significant improvement in connecting sensible heat flux and temperature. I also find that in these systems vegetation cover appears to have stronger controls on soil moisture and temperature than does soil texture. Further, I explore the influence of footprint vegetation composition on the measured fluxes, which reveals that during the monsoon season evaporative fraction tends to increase with footprint bare soil coverage for the New Mexico site and that the ratio of daily transpiration to evapotranspiration increases with grass coverage at the Arizona site. The thesis results are useful for understanding the land-atmosphere interactions of these ecosystems and for guiding future EC studies in heterogeneous landscapes. / Dissertation/Thesis / M.S. Civil and Environmental Engineering 2013

In semiarid regions, where water resources are limited and precipitation dynamics are changing, understanding land surface-atmosphere interactions that regulate the coupled soil moisture-precipitation system is key for resource management and planning. We present a modeling approach to study soil moisture and albedo controls on planetary boundary layer height (PBLh). We used Santa Rita Creosote Ameriflux and Tucson Airport atmospheric sounding data to generate empirical relationships between soil moisture, albedo, and PBLh. Empirical relationships showed that similar to 50% of the variation in PBLh can be explained by soil moisture and albedo with additional knowledge gained by dividing the soil profile into two layers. Therefore, we coupled these empirical relationships with soil moisture estimated using a two-layer bucket approach to model PBLh under six precipitation scenarios. Overall we observed that decreases in precipitation tend to limit the recovery of the PBL at the end of the wet season. However, increases in winter precipitation despite decreases in summer precipitation may provide opportunities for positive feedbacks that may further generate more winter precipitation. Our results highlight that the response of soil moisture, albedo, and the PBLh will depend not only on changes in annual precipitation, but also on the frequency and intensity of this change. We argue that because albedo and soil moisture data are readily available at multiple temporal and spatial scales, developing empirical relationships that can be used in land surface-atmosphere applications have great potential for exploring the consequences of climate change.

The mesoscale organization and structure of convective clouds is thought to be rooted in the thermodynamic properties of the atmosphere and in the turbulent to mesoscale dynamics of the flow. Such structure may contribute to the transition between shallow and deep convection. The thermodynamic state of the boundary layer is forced by the amount of surface fluxes from below. Conversely, landscape patterns and land-cover heterogeneity may equally give rise to focused regions for deep convection triggering, in particular when patch sizes exceed 10 km. Since the convective boundary layer has a mediating function between the surface and deep storm clouds, the connection between surface and upper atmosphere is not straightforward. It is generally believed to involve local erosion of the capping inversion layer, the build-up of a moist energy supply, gradual humidification of the lower-free troposphere that reduces dry air entrainment into burgeoning deeper clouds, and thermal mesoscale circulations that can generate moisture convergence and locally forced ascent. To what extent microscale realistic surface heterogeneity and an interactive surface response matter to shallow and deep convection and its organization remains an open question. In this dissertation, we describe the coupling of a physiology-based vegetation model (HYBRID) and of a sea surface flux algorithm (COARE) to the cloud-resolving Active Tracer High-resolution Atmospheric Model (ATHAM). We investigate the full diurnal cycle of convection based on the example of the Hector storm over Tiwi Islands, notably the well-characterized event on 30th November 2005. The model performs well in terms of timing and cloud dynamics in comparison to a range of available observations. Also, ATHAM-HYBRID seems to do well in terms of flux partitioning. Whilst awaiting more thorough flux validation, we remain confident that the interactive surface response of both HYBRID and COARE is suited for the purpose of simulating convective-scale processes. We find the storm system evolution in 3D simulations to be robust with respect to differences in surface configuration and initialization. Within our 3D sensitivity runs, we could not identify a strong dependence on either realistic surface heterogeneity in the island landscape or on the interactive surface response. We conclude that in our case study at least, atmospheric (turbulent) dynamics likely dominate over surface heterogeneity effects, provided that the bulk magnitude of the surface energy fluxes, and their partitioning into sensible and latent heat (Bowen ratio), remain unaltered. This is consistent with 2D sensitivity studies, where we find model grid-spacing and momentum diffusion, governing the dynamics, to have an important influence on the overall evolution of deep convection. Fine grid-spacing is necessary, as the median width of updraught cores mostly does not exceed 1000 m. We associate this influence with the dry air entrainment rate in the wake of rising parcels, and with how resolution and diffusion act on coherent structures in the flow. In 2D sensitivity studies with differences in realistic heterogeneities of surface properties, we find little evidence for a clear deterministic influence of these properties on the transition between shallow and deep convection, in spite of largely different storm evolutions across the various runs. In these runs, we tentatively ascribe triggering to stochastic features in the flow, without discarding the relevance of convergence lines produced by mesoscale density currents, such as the sea breeze and cold pool storm outflows.

Soil moisture influences the water and energy cycles of terrestrial environments, and thus plays an important climatic role. However, the behavior of soil moisture at large scales, including its impact on atmospheric processes such as precipitation, is not well characterized. Satellite remote sensing allows for indirect observation of large-scale soil moisture, but validation of these data is complicated by the difference in scales between remote sensing footprints and direct ground-based measurements. To address this problem, a method, based on information theory (specifically, mutual information), was developed to determine the useful information content of satellite soil moisture records using precipitation observations. This method was applied to three soil moisture datasets derived from Advanced Microwave Scanning Radiometer for EOS (AMSR-E) measurements over the contiguous U.S., allowing for spatial identification of the algorithm with the least inferred error. Ancillary measures of biomass and topography revealed a strong dependence between algorithm performance and confounding surface properties. Next, statistical causal identification methods (i.e. Granger causality) were used to examine the link between AMSR-E soil moisture and the occurrence of next day precipitation, accounting for long term variability and autocorrelation in precipitation. The probability of precipitation occurrence was modeled using a probit regression framework, and soil moisture was added to the model in order to test for statistical significance and sign. A contrasting pattern of positive feedback in the western U.S. and negative feedback in the east was found, implying a possible amplification of drought and flood conditions in the west and damping in the east. Finally, observations and simulations were used to demonstrate the pitfalls of determining causality between soil moisture and precipitation. It is shown that ignoring long term variability and precipitation autocorrelation can result in artificial positive correlation between soil moisture and precipitation, unless explicitly accounted for in the analysis. In total, this dissertation evaluates large-scale soil moisture measurements, outlines important factors that can cloud the determination of land surface-atmosphere hydrologic feedback, and examines the causal linkage between soil moisture and precipitation at large scales.

Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro / Recentes observações satelitais têm demonstrado um aumento na extensão total do gelo marinho Antártico e redução do gelo marinho no Ártico. Apesar destas constatações, no Oceano Sul análises regionais apontam tendências negativas nos mares de Bellingshausen-Amundsen e positivas no mar de Ross, enquanto que para o Ártico ocorrer uma redução uniforme do gelo marinho. Neste estudo, foi realizada uma análise multivariada para identificar as mudanças na extensão do gelo marinho Antártico e Ártico em resposta à variabilidade de um conjunto de forçantes/parâmetros/índices climáticos de reconhecida importância em escala global. Especificamente, as associações entre o gelo marinho e os parâmetros e forçantes climáticos foram examinadas através da correlação linear e da análise de agrupamento. Diferentes respostas em diferentes setores foram examinadas e discutidas. Os resultados indicam que a variabilidade do gelo marinho Antártico e Ártico é um fenômeno multivariado e que a extensão de gelo marinho mínima, média e máxima podem apresentar diferentes padrões espaciais e responderem a diferentes conjuntos de parâmetros e forçantes climáticos. Foi identificado um significativo impacto de forçantes/parâmetros/índices climáticos sobre o gelo marinho no Oeste Antártico. No hemisfério Norte o aumento da temperatura média global e do CO2 atmosférico são os principais responsáveis pela redução na extensão do gelo marinho. / Recent satellite observations have shown an increase in the total extent of Antarctic sea ice and a reduction of sea ice in the Arctic. Despite these findings, regional analyses in the Southern Ocean indicates negative trends in the Bellingshausen-Amundsen Sea and positive trends in the Ross Sea, while in the Arctic seems to occur a uniform reduction of sea ice. In this study, mutivariate analysis was performed to identify changes in Antarctic sea ice in response to changes in a set of climate forcings/parameters/indices. More specifically, the relationships between sea ice and climate forcings and parameters were examined by linear correlation and cluster analysis. Different responses in different sectors were examined and discussed. The findings indicate that Antarctic sea ice variability is a multivariate phenomenon and that the minimum, maximum, and mean sea ice extent depicts different spatial pattern and may respond to a different set of climate forcings/parameters/indices. A significant impact of climate forcings/parameters/indices occurs over western Antarctic. In the northern hemisphere the increase in global mean temperature and atmospheric CO2 seems to be the major responsible for the reduction in sea ice extent.

Uncertainty of predicted change in precipitation frequency and intensity motivates the scientific community to better understand, quantify, and model the possible outcome of dryland ecosystems. In pulse dependent ecosystems (i.e. monsoon driven) soil moisture is tightly linked to atmospheric processes. Here, I analyze three overarching questions; Q1) How does soil moisture presence or absence in a shallow or deep layer influence the surface energy budget and planetary boundary layer characteristics?, Q2) What is the role of vegetation on ecosystem albedo in the presence or absence of deep soil moisture?, Q3) Can we develop empirical relationships between soil moisture and the planetary boundary layer height to help evaluate the role of future precipitation changes in land surface atmosphere interactions?. To address these questions I use a conceptual framework based on the presence or absence of soil moisture in a shallow or deep layer. I define these layers by using root profiles and establish soil moisture thresholds for each layer using four years of observations from the Santa Rita Creosote Ameriflux site. Soil moisture drydown curves were used to establish the shallow layer threshold in the shallow layer, while NEE (Net Ecosystem Exchange of carbon dioxide) was used to define the deep soil moisture threshold. Four cases were generated using these thresholds: Case 1, dry shallow layer and dry deep layer; Case 2, wet shallow layer and dry deep layer; Case 3, wet shallow layer and wet deep layer, and Case 4 dry shallow and wet deep layer. Using this framework, I related data from the Ameriflux site SRC (Santa Rita Creosote) from 2008 to 2012 and from atmospheric soundings from the nearby Tucson Airport; conducted field campaigns during 2011 and 2012 to measure albedo from individual bare and canopy patches that were then evaluated in a grid to estimate the influence of deep moisture on albedo via vegetation cover change; and evaluated the potential of using a two-layer bucket model and empirical relationships to evaluate the link between deep soil moisture and the planetary boundary layer height under changing precipitation regime. My results indicate that (1) the presence or absence of water in two layers plays a role in surface energy dynamics, (2) soil moisture presence in the deep layer is linked with decreased ecosystem albedo and planetary boundary layer height, (3) deep moisture sustains vegetation greenness and decreases albedo, and (4) empirical relationships are useful in modeling planetary boundary layer height from dryland ecosystems. Based on these results we argue that deep soil moisture plays an important role in land surface-atmosphere interactions.

abstract: Land surface fluxes of energy and mass developed over heterogeneous mountain landscapes are fundamental to atmospheric processes. However, due to their high complexity and the lack of spatial observations, land surface processes and land-atmosphere interactions are not fully understood in mountain regions. This thesis investigates land surface processes and their impact on convective precipitation by conducting numerical modeling experiments at multiple scales over the North American Monsoon (NAM) region. Specifically, the following scientific questions are addressed: (1) how do land surface conditions evolve during the monsoon season, and what are their main controls?, (2) how do the diurnal cycles of surface energy fluxes vary during the monsoon season for the major ecosystems?, and (3) what are the impacts of surface soil moisture and vegetation condition on convective precipitation? Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling. / Dissertation/Thesis / Doctoral Dissertation Civil and Environmental Engineering 2016

abstract: Rapid urban expansion and the associated landscape modifications have led to significant changes of surface processes in built environments. These changes further interact with the overlying atmospheric boundary layer and strongly modulate urban microclimate. To capture the impacts of urban land surface processes on urban boundary layer dynamics, a coupled urban land-atmospheric modeling framework has been developed. The urban land surface is parameterized by an advanced single-layer urban canopy model (SLUCM) with realistic representations of urban green infrastructures such as lawn, tree, and green roof, etc. The urban atmospheric boundary layer is simulated by a single column model (SCM) with both convective and stable schemes. This coupled SLUCM-SCM framework can simulate the time evolution and vertical profile of different meteorological variables such as virtual potential temperature, specific humidity and carbon dioxide concentration. The coupled framework has been calibrated and validated in the metropolitan Phoenix area, Arizona. To quantify the model sensitivity, an advanced stochastic approach based on Markov-Chain Monte Carlo procedure has been applied. It is found that the development of urban boundary layer is highly sensitive to surface characteristics of built terrains, including urban land use, geometry, roughness of momentum, and vegetation fraction. In particular, different types of urban vegetation (mesic/xeric) affect the boundary layer dynamics through different mechanisms. Furthermore, this framework can be implanted into large-scale models such as Weather Research and Forecasting model to assess the impact of urbanization on regional climate. / Dissertation/Thesis / Doctoral Dissertation Civil and Environmental Engineering 2016

Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro / Recentes observações satelitais têm demonstrado um aumento na extensão total do gelo marinho Antártico e redução do gelo marinho no Ártico. Apesar destas constatações, no Oceano Sul análises regionais apontam tendências negativas nos mares de Bellingshausen-Amundsen e positivas no mar de Ross, enquanto que para o Ártico ocorrer uma redução uniforme do gelo marinho. Neste estudo, foi realizada uma análise multivariada para identificar as mudanças na extensão do gelo marinho Antártico e Ártico em resposta à variabilidade de um conjunto de forçantes/parâmetros/índices climáticos de reconhecida importância em escala global. Especificamente, as associações entre o gelo marinho e os parâmetros e forçantes climáticos foram examinadas através da correlação linear e da análise de agrupamento. Diferentes respostas em diferentes setores foram examinadas e discutidas. Os resultados indicam que a variabilidade do gelo marinho Antártico e Ártico é um fenômeno multivariado e que a extensão de gelo marinho mínima, média e máxima podem apresentar diferentes padrões espaciais e responderem a diferentes conjuntos de parâmetros e forçantes climáticos. Foi identificado um significativo impacto de forçantes/parâmetros/índices climáticos sobre o gelo marinho no Oeste Antártico. No hemisfério Norte o aumento da temperatura média global e do CO2 atmosférico são os principais responsáveis pela redução na extensão do gelo marinho. / Recent satellite observations have shown an increase in the total extent of Antarctic sea ice and a reduction of sea ice in the Arctic. Despite these findings, regional analyses in the Southern Ocean indicates negative trends in the Bellingshausen-Amundsen Sea and positive trends in the Ross Sea, while in the Arctic seems to occur a uniform reduction of sea ice. In this study, mutivariate analysis was performed to identify changes in Antarctic sea ice in response to changes in a set of climate forcings/parameters/indices. More specifically, the relationships between sea ice and climate forcings and parameters were examined by linear correlation and cluster analysis. Different responses in different sectors were examined and discussed. The findings indicate that Antarctic sea ice variability is a multivariate phenomenon and that the minimum, maximum, and mean sea ice extent depicts different spatial pattern and may respond to a different set of climate forcings/parameters/indices. A significant impact of climate forcings/parameters/indices occurs over western Antarctic. In the northern hemisphere the increase in global mean temperature and atmospheric CO2 seems to be the major responsible for the reduction in sea ice extent.