Thesis (Ph.D.)--George Mason University, 2008. / Vita: p. 167. Thesis director: Menas Kafatos. Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Earth Systems an GeoInformation Sciences. Title from PDF t.p. (viewed Jan. 11, 2009). Includes bibliographical references (p. 156-166). Also issued in print.

The retrieval of an aerosol scattering phase function using a multi-satellite technique is proposed. A total of 33 phase functions were derived from 18 smoke cases and 15 dust cases. Each case was interrogated using four to nine satellite passes over the aerosol in a two to four hour time frame. The radiance values for the Red and Near-Infrared (NIR) channels were combined with backscattering angles to determine the shape of the scattering phase function. The radiance values were input into the Naval Postgraduate School (NPS) aerosol model to determine optical depths and sample phase functions. A comparison was made between the actual phase functions retrieved and the NPS model phase functions. It was found that the phase functions for the smoke cases more closely matched the model phase functions than in the dust cases. Some conclusions could be drawn about the actual aerosol size and density distribution based on how well it matched the model phase function. Further analysis is necessary to define the exact size and number of the aerosol particles. Fully understanding the aerosol composition is crucial in determining its effects on military sensors and impacts to operations.

El estudio de los niveles y composición del material particulado atmosférico (PM) medido simultáneamente en diferentes ambientes a escala regional se llevó a cabo en la cuenca del Mediterráneo Occidental con el fin de entender las fuentes y patrones de transformación y transporte de aerosoles en esta zona. Para esto, la medida de niveles y caracterización química de PM10, PM2.5 y PM1 se llevó a cabo en tres estaciones de monitoreo: Montsec (MSC, fondo continental, 1570 msnm), Montseny (MSY, fondo regional, 720 msnm) y Barcelona (BCN, fondo urbano, 68 msnm). Además, se midieron niveles de número de partículas (N) y carbono negro (BC) en BCN. Durante el invierno, la frecuente estabilidad atmosférica induce el estancamiento de masas de aire produciendo importantes episodios de contaminación en BCN. Sin embargo, MSY y, más frecuentemente MSC, quedan aislados de la contaminación regional. En determinados escenarios, el desarrollo de la capa límite y las brisas resultan en el transporte de masas de aire contaminadas a zonas rurales, aumentando notablemente los niveles de PM en función de la altitud y la distancia a las zonas fuente. Durante el verano, la circulación de brisas favorece la dispersión, mezcla y envejecimiento de contaminantes a escala regional y la reducción de las diferencias entre BCN, MSY y MSC. Se midieron niveles similares de algunos componentes (materia orgánica, sulfato) a escala regional. Los niveles de materia mineral aumentan en verano por una resuspensión favorecida y una mayor frecuencia de intrusiones africanas, más significativamente en el MSC, dado su impacto en altura. La mayor contribución al PM10 en BCN se debe principalmente al tráfico (50% del PM10), resultante de las emisiones del tráfico primarias, nitrato y aerosoles secundarios envejecidos. La materia mineral se origina por resuspensión del polvo de carretera por vehículos pero también resuspensión por viento y obras. La contribución regional en BCN (25%) es principalmente materia mineral, nitrato y sulfato amónico. La variabilidad horaria de los diferentes parámetros de medida de aerosoles en BCN (N, BC, PM10, PM2.5 y PM1) está muy marcada por emisiones de tráfico y meteorología (especialmente brisas). Sin embargo, algunos parámetros no se rigen solamente por emisiones directas del tráfico, como PM2.5-10 (resuspensión) y N (emisiones de partículas ultrafinas y procesos de nucleación fotoquímica). La influencia de las emisiones del tráfico en los niveles de partículas finas en BCN se refleja en los niveles anuales de PM1, que aumentan de 2003 a 2007 relacionados con un aumento progresivo del tráfico y la flota diesel en BCN. Sin embargo se observó una tendencia decreciente en las fracciones gruesas en BCN y MSY, que se atribuye a la meteorología y a cambios en emisiones industriales. El estudio simultáneo de diferentes parámetros ha mostrado que el control de PM1 (modos de nucleación y acumulación) y/o BC (procesos de combustión), y PM10, (combustión y aerosoles generados mecánicamente) puede ser una estrategia mejor que la combinación de PM2.5 y PM10 como estándares de medida de calidad del aire. La medida en paralelo de aerosoles en fondos urbano, regional y continental ha sido una estrategia útil para entender la fenomenología de aerosoles en la cuenca del Mediterráneo Occidental. Las emisiones urbanas e industriales tienen un impacto considerable en los niveles y composición de PM en zonas rurales situadas a diferentes alturas, tanto en verano, con una importante recirculación y mezcla de masas de aire a escala regional, como en invierno, con transporte de contaminantes activado por brisas. El gran impacto de la contaminación urbana a escala regional demuestra la importancia de aplicar estrategias de reducción de emisiones de tráfico urbano, a fin de mejorar la calidad del aire no sólo a nivel local, sino también a escala regional. / A detailed study of atmospheric particulate matter (PM) levels and composition measured simultaneously in different environments at a regional scale was performed in the Western Mediterranean Basin in order to understand the sources, transformation and transport of tropospheric aerosols in this area. In this direction, the monitoring of PM10, PM2.5 and PM1 levels and chemical characterization was carried out at three monitoring stations: Montsec (MSC, continental background, 1570 m.a.s.l.), Montseny (MSY, regional background, 720 m.a.s.l.) and Barcelona (BCN, urban background, 68 m.a.s.l.). In addition, number concentration (N) and black carbon (BC) levels were monitored at BCN. During winter, the frequent anticyclonic atmospheric stability induces the stagnation of air masses that produce important pollution episodes at BCN. However, atmospheric decoupling leaves MSY and, more frequently MSC, isolated from regional pollution during several days. In specific scenarios, the growth of the boundary layer and development of mountain breezes, activated by solar radiation, result in the transport of polluted air masses accumulated in the valley to the rural sites, increasing markedly PM levels at a different rate depending on the altitude and distance to the source areas. During summer, intense breeze circulations and atmospheric mixing favour the dispersion, recirculation and ageing of pollutants at a regional scale, reducing the differences between the urban and the rural sites. Similar levels of some components (organic matter or sulphate) were measured at a regional scale. Mineral matter levels increase during the summer, because of a favoured dust resuspension and higher frequency of African dust outbreaks, more significantly at MSC given the impact of African dust at higher altitudes. The major contribution to PM10 in BCN was mainly related to road traffic (50% of PM10), resulting from primary traffic emissions, secondary nitrate and aged secondary aerosols. Anthropogenic dust may originate from road dust resuspension by vehicles, but also wind resuspension and construction/demolition works. The regional contribution at the urban site (25%) was mainly mineral dust, ammonium sulphate and nitrate. The hourly variability of aerosol measurement parameters (N, BC, PM10, PM2.5 and PM1) at BCN is very influenced by road traffic emissions and meteorology (especially breezes). However, some parameters are not only governed by traffic exhaust emissions, as PM2.5-10 (dust resuspension processes) and N (direct ultrafine particle emissions but also photochemical nucleation processes). The influence of road traffic emissions on the levels of fine PM at BCN is reflected in PM1 mean annual levels, showing an increasing trend from 2003 to 2007 and correlation with the progressive rise in road traffic flow and diesel fleet in BCN. However a decreasing trend was observed for the coarser fractions at BCN and MSY, attributed to meteorology and changes in industrial emissions. The simultaneous study of different parameters showed that the monitoring of PM1 (nucleation and accumulation modes) and/or BC (combustion processes), and PM10 (combustion and mechanically-generated aerosols) may be a better strategy than the combination of PM2.5 and PM10 measurements as air quality standards. The parallel monitoring of aerosols at urban, regional and continental backgrounds was a useful strategy in order to understand the phenomenology of aerosols in the WMB. Urban and industrial emissions have a considerable impact in PM levels and composition in rural areas at different altitudes, both in summer, with important atmospheric recirculation and mixing of air masses at a regional scale, and winter, with breeze-activated transport of stagnated urban pollutants. The high contribution of urban emissions and the transport of air masses at a regional scale demonstrate the importance of applying emission abatement strategies for urban road traffic, in order to improve air quality not only at a local, but also at a regional scale.

Thesis (M.Phil.)--Hong Kong University of Science and Technology, 2008. / Includes bibliographical references (leaves 112-120). Also available in electronic version.

Thesis (M.S.)--Oregon State University, 2009. / Printout. Includes bibliographical references (leaves 47-49). Also available on the World Wide Web.

Thesis (Ph. D.)--University of Canterbury, 2008. / Typescript (photocopy). Includes bibliographical references (p. 171-177). Also available via the World Wide Web.

Thesis (Ph. D.)--University of California, Riverside, 2009. / Includes abstract. Available via ProQuest Digital Dissertations. Title from first page of PDF file (viewed March 10, 2010). Includes bibliographical references. Also issued in print.

Thesis (M.S.)--Rutgers University, 2008. / "Graduate Program in Mechanical and Aerospace Engineering." Includes bibliographical references (p. 102-104).

Thesis (M.Sc.)--Memorial University of Newfoundland, 2006. / Bibliography: leaves 194-204. Also available online.

Thesis (M.S. in Meteorology)--Naval Postgraduate School, March 2005. / Thesis Advisor(s): Philip A. Durkee. Includes bibliographical references (p. 77-78). Also available online.