<p>The study of culture in wild animals has received wide theoretical and empirical attention, providing preliminary evidence of at least rudimentary culture across a broad range of taxa. However, the majority of previous studies of animal cultural behavior have focused on demonstrating the existence of behavioral variants across study sites, armed only with an assumption that ecological and genetic alternatives are unlikely to sufficiently explain observed geographic variation in behavior. Moreover, previous studies have reported the presence of behavioral variation at the level of the population, without first confirming the presence of such variation in individual repertoires, which could create artificial patterns within or between populations. </p><p>Using more rigorous methods than previous studies, I examined rarely tested alternatives to field-based claims of cultural repertoire variation based on ecological heterogeneity and genetic variation. This dissertation relies on a natural experiment to compare two wild orangutan populations. Sungai Lading, a previously unstudied, high-density population of wild Pongo pygmaeus wurmbii, was compared to Tuanan, a P.p.wurmbii population separated from Sungai Lading by an impassable river barrier, but ranging in a broadly similar habitat. Preliminary genetics results indicate that at least some individuals from both sites cluster in the same mitochondrial subclade and that low levels of gene flow must have occurred between the two sites. Even after applying rigorous controls for variation in sampling intensity for individual orangutans, several differences in innovative behaviors exhibited at each site were identified, many of which occurred in the nesting context.</p><p>The orangutan is a model taxon for such an investigation, because wild populations exhibit a wide range of sociality, which has been linked to opportunities for social learning. Comparisons between the Tuanan and Sungai Lading populations indicated that cultural variants observed at only one site clustered significantly by population, although only dietary differences were unique at both sites. Orangutans at Sungai Lading maintain significantly lower rates of female-female association and lower individual repertoire sizes of putative cultural variants, a result that is consistent with the possibility that the orangutans of Sungai Lading may have reduced opportunities for social learning as a result of severe population compression, which could constrain opportunities for cultural transmission of key innovative behaviors. </p><p>From a broader perspective, the patterns revealed in this study strongly suggest that the last common ancestor of Homo and Pongo shared culturally modified behavior. They further suggest that the extent of cumulative cultural behavior in humans may surpass that of orangutans as a result of lost opportunities for social transmission, owing to varying degrees of limited association among group members.</p> / Dissertation

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The purpose of this study was to use controlled release technology combining with in situ chemical oxidation (ISCO) and permeable reactive barrier (PRB) to remediate TCE-contaminated groundwater. In this study, potassium permanganate (KMnO4) releasing material was designed for potassium permanganate release in groundwater. The components of potassium permanganate releasing material included poly (£`-caprolactone) (PCL), potassium permanganate, and starch with a weight ratio of 2:1:0.5. Approximately 63.8% (w/w) of potassium permanganate was released from the material after 76 days of operation. The released was able to oxidize contaminant in groundwater. Results from the solid oxidation demand (SOD) experiment show that the consumption rate increased with increased contaminant concentration. TCE removal efficiency increased with the increased TCE concentration. The second-order rate law can be used to simulate the TCE degradation trend. In the column experiment, results show that the released MnO4- could oxidize TCE and TCE degradation byproducts when 95.6 pore volume (PV) of contaminated groundwater was treated. More than 95% of TCE removal can be observed in the column study. Although the concentration of manganese dioxide (MnO2) began to rise after 8.8 PV of operation, TCE removal was not affected. Results also show that low level of hexavalent chromium was detected (< 0.05 mg/L). Results from the scanning electron microscope (SEM) and energy-dispersive spectroscope (EDX) analyses show that the amounts of manganese and potassium in the materials decreased after the releasing experiment. Results indicate that the concentration of TCE and SOD need to be analyzed before the releasing materials are applied in situ. In the practical application, the releasing materials will not become solid wastes because they are decomposed after use. If this slow-releasing technology can be combined with a permeable reactive barrier system, this technology will become a more economic and environmentally-friendly green remedial system.

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Soil and groundwater at many existing and former industrial areas and disposal sites is contaminated by organic solvent compounds that were released into the environment. Organic solvent compounds are heavier than water. When they are released into the subsurface, they tend to adsorb onto the soils and cause the appearance of LNAPL (light nonaqueous phase liquid) and DNAPL (dense nonaqueous phase liquid) pool. The industrial petroleum hydrocarbons (e.g., methyl tertiary-butyl ether, MTBE and benzene) and chlorinated solvent (e.g., trichloroethylene, TCE) are among the most ubiquitous organic compounds found in subsurface contaminated environment. One cost-effective approach for the remediation of the chlorinated solvent and petroleum products contaminated aquifers is the installation of permeable reactive zones or barriers within aquifers. As contaminated groundwater moves through the emplaced reactive zones, the contaminants are removed, and uncontaminated groundwater emerges from the downgradient side of the reactive zones. The objectives of this study were developed to evaluate the feasibility of applying in-situ chemical oxidation (ISCO) barrier and in-situ slow polycolloid-releasing substrate (SPRS) biobarrier system on the control of petroleum hydrocarbons and chlorinated solvent plume in aquifer. In the ISCO barrier system, it contained oxidant-releasing materials, to release oxidants (e.g., persulfate) contacting with water for oxidating contaminants existed in groundwater. In this study, laboratory-scale fill-and-draw experiments were conducted to determine the compositions ratios of the oxidant-releasing materials and evaluate the persulfate release rates. Results indicate that the average persulfate-releasing rate of 7.26 mg S2O82-/d/g was obtained when the mass ratio of sodium persulfate/cement/sand/water was 1/1.4/0.24/0.7. The column study was conducted to evaluate the efficiency of in situ application of the developed ISCO barrier system on MTBE and benzene oxidation. Results from the column study indicate that approximately 86-92% of MTBE and 95-99% of benzene could be removed during the early persulfate-releasing stage (before 48 pore volumes of groundwater pumping). The removal efficiencies for MTBE and benzene dropped to approximately 40-56% and 85-93%, respectively, during the latter part of the releasing period due to the decreased persulfate-releasing rate. Results reveal that acetone, byproduct of MTBE, was observed and then further oxidized completely. Results suggest that the addition of ferrous ion would activate the persulfate oxidation. However, excess ferrous ion would compete with organic contaminants for persulfate, causing the decrease in contaminant oxidation rates. In the SPRS biobarrier system, the food preparation industry has tremendous experiences in producing stable oil-in-water (W/O, 50/50) emulsions with a uniformly small droplet size. Surfactant mixture (71 mg/L of SL and 72 /L of SG) blending with water could yield a stable and the optimal emulsion was considered the best. The small absolute value of the emulsion zeta potential reduces inter-particle repulsion, causing the emulsion droplets to stick to each other when they collided. Overtime, large masses of flocculated droplets can form which then clog the sediment pores. The results can be used to predict abiotic interactions and distribution of contaminant mass expected after SPRS injection, and thus provides a more accurate estimate of the mass of TCE removed due to enhanced biodegradation. The effect of TCE partitioning to the vegetable oil on contaminant migration rates can be approximated using a retardation factor approach, where 0.28 years through a 3 m barrier. In anaerobic microcosm experiments, result show that SPRS can be fermented to hydrogen and acetate could be used as a substrate to simulate reductive dehalorination. The apparent complete removal of nitrate and sulfate by SPRS addition was likely a major factor that promoted the complete reduction of TCE at later stages of this study. Results from the column experiment indicate that occurrence of anaerobic reductive dechlorination in the biobarrier system can be verified by: (1) the oil: water partition coefficients of dissolved TCE into vegetable oil were be used to predict abiotic interactions and distribution of contaminant mass expected after SPRS injection. (2) The SPRS can ferment to hydrogen and acetate could be used as a substrate to simulate reductive dechlorination. The proposed treatment scheme would be expected to provide a more cost-effective alternative to remediate other petroleum hydrocarbons and chlorinated solvents-contaminated aquifers. Experiments and operational parameters obtained from this study provide an example to design a passive barriers system for in-site remediation.

We report an intriguing giant dielectric and magnetodielectric (MD) response on double perovskite Pr2CoMnO6(PCMO) system. The Arrhenius plot indicates that the origin of giant dielectric is internal barrier layer capacitance. Meanwhile, at the highest applied magnetic field 9T, the giant dielectric constant around Tm ~ 150 K is enhanced almost ~ 20% (at 10 kHz frequency) compared with that at zero field. The observed positive MD effect is considered to be associated with the direct consequence of negative magnetoresistance changes (~ -20% at 150 K) which was calculated by temperature dependent impedance spectras. Concomitantly, a pronounced ferromagnetic ordering is observed near Tc ~ 150 K coinciding with Tm of £`¡¬(T). These experimental results suggest that the magnetoresistive and MD effect response is very strongly by magnetic property of PCMO.

Millions of square feet of mechanically stabilized earth retaining wall are constructed annually in the United States. When used in highway fill applications in conjunction with bridges, these MSE walls are typically constructed with a roadside barrier system supported on the edge of the wall. This barrier system generally consists of a traffic barrier or bridge rail placed on a continuous footing or structural slab. The footing is intended to reduce the influence of barrier impact loads on the retaining wall system by distributing the load over a wide area and to provide stability for the barrier against sliding or overturning. The proper design of the roadside barrier, the structural slab, and the MSE wall system requires a good understanding of relevant failure modes, how barrier impact loads are transferred into the wall system, and the magnitude and distribution of these loads. In this study, a procedure is developed that provides guidance for designing: 1. the barrier-moment slab, 2. the wall reinforcement, and 3. the wall panels. These design guidelines are developed in terms of AASHTO LRFD procedures. The research approach consisted of engineering analyses, finite element analyses, static load tests, full-scale dynamic impact tests, and a full-scale vehicle crash test. It was concluded that a 44.5 kN (10 kips) equivalent static load is appropriate for the stability design of the barrier-moment slab system. This will result in much more economical design than systems developed using the 240 kN (54 kips) load that some user agencies are using. Design loads for the wall reinforcement and wall panels are also presented.

The study of place has been a component of the recreation literature for about three decades. Most researchers have sought to either describe the cognitive and evaluative beliefs (place meaning) recreational visitors ascribe to a setting or identify the intensity of the human-place bond (place attachment). Few have attempted to qualitatively investigate the meanings visitors ascribe to a setting and quantitatively measure the intensity of their attachment to that setting within the same study design. Nor has there been much work aimed at understanding these concepts in marine environments. In this dissertation, I began to fill these gaps in the literature through the use of a three- phase multiple-method research design. In the first phase, I conducted 20 interviews to identify the meanings that recreational visitors ascribe to the Great Barrier Reef Marine Park (GBRMP) and to further explore how the symbolic interactionist framework can be used to understand place meanings. Ten place meaning themes emerged from the informants' statements. The second phase used 34 items developed from the 10 meaning themes that emerged from the previous interviews and a place attachment scale to explore how recreational visitors' attachment to a marine resource was reflected in their depictions of why the resource is meaningful. Three hundred and twenty-four individuals, living in Queensland, Australia, responded to a postal/email survey conducted during January and February of 2009. The results indicated that all the meanings recreational visitors ascribe to the GBRMP provide context for the attachment they hold for the setting, however particular sets of meanings are important in differentiating between attachment intensity levels. The final phase, which also used the postal/email survey described, identified how place attachment affected the relationship, identified by Stern et al. (1995), between the recreational visitors' environmental world view (EWV) and attitudes toward negative impacts on the reef ecosystem. I found that place attachment partially mediated the relationship between EWV and attitudes toward impacts. The conclusions presented in this dissertation filled in gaps in the recreation literature's understanding of place while providing further insight into how place meaning influences other constructs important to natural resource management.

The family Callitrichidae encompasses the marmosets and tamarins, the smallest of the anthropoid primates and one of the most species-rich of platyrrhine families. Seven new species of Amazonian marmosets (Callithrix, Callitrichidae) have been discovered in recent years, as well as the exceptional dwarf marmoset Callibella humilis. Most of these species were described on the basis of their pelage and presumed separation by major rivers. I performed analyses of craniometric variables by taxa and by river basins, in order to determine if there are significant cranial distinctions between taxa separated by rivers. I analyzed quantitative cranial and mandibular characters of Callibella humilis to determine if it could be distinguished from other callitrichids. I found that Callibella is clearly distinct from all other genera of marmosets and tamarins, in particular in the morphology of the lower jaw. I also analyzed representative species of Amazonian Callithrix and found support for the theory of separation by river-barriers. In my analyses the Amazonian marmosets were divided into three separate species groups, with the easternmost species (Callithrix argentata and C. leucippe) strongly distinct and separated from the others by the broad Rio Tapajos. Two additional species, C. chrysoleuca and C. saterei, formed a discrete group in the central Amazon, and the westernmost species - C. melanura, C. nigriceps and the Rondonia marmoset - formed a third distinct group. These results from cranial morphology align with recent genetic studies indicating that the Amazonian marmosets are strongly divided by the Rio Tapajos, and offer additional support to the theory of river-barriers. Although these species are typically considered to be of low conservation priority, many of them are found in areas experiencing accelerated deforestation. An initial analysis of protected-area coverage for the Amazonian marmosets demonstrates that while some species may be found in a number of protected areas, others are virtually uncovered, and the lack of comprehensive information on their distributions may preclude an effective conservation strategy. The dwarf marmoset Callibella is known from an exceptionally restricted range, with almost no protected areas, and this unique species should be a conservation priority.

Abstract A novel process of combining electrokinetic remediation and nano-sized iron wall was used for studying its effectiveness of treating nitrate-containing soil. Nitrates and nitrites are commonly found in surface water and groundwater. These substances, in general, could pose a threat to both organisms in the water bodies and human health. Traditionally, nitrogen oxides in various water bodies are treated by biological denitrification processes. However, it would take a longer time to yield a satisfactory result as compared with physicochemical processes. In recent years, permeable reactive barriers (PRBs) using zero-valent iron have been successfully used for degradation of various compounds including nitrates. Electrokinetic processing (EK) also is considered as an effective in-situ technology for removing both inorganic and organic substances from the treatment zone. In this work, the synthesized nano-scale iron particles were incorporated into a PRB, which was further combined with EK to form a novel process for the degradation of nitrates. Various operating parameters were studied in this work. The nano-sized iron particles were determined to be ranging from 50-80nm in size and having specific surface area of 37.83m2. The isoelctric point of these nanoparticles was found to be at pH 7.3. Experimental results have shown that the best location of the iron wall was 5cm from the anode reservoir. Also, the optimal treatment time would be six days in this study. The treatment efficiency was found to increase with increasing dose of nano-sized iron particles in the PRB. Operating with the polarity reverse would slightly increase the overall treatment efficiency as compared with the case of no polarity reverse (92.38% versus 88.34%). An electric gradient of 1.5V/cm was determined to be the optimal electric field strength in this study. In this work, it was also found that 2.5g nano-scale iron particles outperformed 20g micro-scale iron particles (75-150&#x00B5;m) in terms of nitrate degradation. In a study of using an extended treatment time up to 20 days, the black colored iron wall would fade away becoming a rusty plume toward the cathode as the treatment time elapsed. Furthermore, the Fe2+ concentration was elevated throughout the soil column after the 20-day treatment. Therefore, it is evident that nano-sized iron particles would migrate when they are subjected to EK. Based on the research findings obtained, the novel process employed in this study was found to be an effective one for in-situ treatment of nitrate-containing soil.