Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) were used to examine a series of six revolver barrels manufactured by the Colt Patent Arms Manufacturing Company between 1853 and 1863. SEM micrographs revealed a vast range of surface morphologies among the corroded samples. XRD diffraction patterns showed varying levels of magnetite on the blackened samples, but hematite could not be identified. EDS was used to map elemental distribution and quantify elemental abundances on the gun surfaces; further investigation using this technique may reveal more definitive information on whether some elements present were deposited during patination.

3D seismic data are widely used for many different purposes. Despite different objectives, a common goal in almost all 3D seismic programs is to attain better understanding of the subsurface features. In gas injection projects, which are mainly for Enhanced Oil Recovery (EOR) and recently for environmental purposes, seismic data have an important role in the gas monitoring phase. This thesis deals with a 3D seismic investigation at the CO2 injection site at Ketzin, Germany. I focus on two critical aspects of the project: the internal architecture of the heterogeneous Stuttgart reservoir and the detectability of the CO2 response from surface seismic data. Conventional seismic methods are not able to conclusively map the internal reservoir architecture due to their limited seismic resolution. In order to overcome this limitation, I use the Continuous Wavelet Transform (CWT) decomposition technique, which provides frequency spectra with high temporal resolution without the disadvantages of the windowing process associated with the other techniques. Results from applying this technique reveal more of the details of sand bodies within the Stuttgart Formation. The CWT technique also helps to detect and map remnant gas on the top of the structure. In addition to this method, I also show that the pre-stack spectral blueing method, which is presented for the first time in this research, has an ability to enhance seismic resolution with fewer artifacts in comparison with the post-stack spectral blueing method. The second objective of this research is to evaluate the CO2 response on surface seismic data as a feasibility study for CO2 monitoring. I build a rock physics model to estimate changes in elastic properties and seismic velocities caused by injected CO2. Based on this model, I study the seismic responses for different CO2 injection geometries and saturations using one dimensional (1D) elastic modeling and two dimensional (2D) acoustic finite-difference modeling. Results show that, in spite of random and coherent noises and reservoir heterogeneity, the CO2 seismic response should be strong enough to be detectable on surface seismic data. I use a similarity-based image registration method to isolate amplitude changes due to the reservoir from amplitude changes caused by time shifts below the reservoir. In support of seismic monitoring using surface seismic data, I also show that acoustic impedance versus Poisson’s ratio cross-plot is a suitable attribute for distinguishing gas-bearing sands from brine-bearing sands. / CO2SINK Project

Unconventional nanofabrication techniques; both those which have been newly developed and those under development, had brought inexpensive, facile, yet high quality means to fabricate nanostructures that have feature sizes of less than 100 nm in industry and academia. This dissertation focuses on developing unconventional fabrication techniques, building studying platforms, and studying the mechanisms behind them. The studies are divided into two main facets and four chapters. The first facet, in Chapter II and Chapter III, deals with the research and development of different nanofabrication techniques and nanostructures. These techniques include litho-synthesis, colloidal lithography, and photolithography. The nanostructures that were fabricated by these techniques include the metal nanoparticle arrays, and the self-assembled CdSe nanoring arrays. At the same time, the dissertation provides mechanisms and models to describe the physical and chemical nature of these techniques. The second area of this study, in Chapter III to Chapter V, presents the applications of these nanostructures in fundamental studies, i.e. the mechanisms of plasmon enhanced fluorescence and photo-oxidation kinetics of CdSe quantum dots, and applications such as molecular sensing and material fabrication. More specifically, these applications include tuning the optical properties of CdSe quantum dots, biomodification of CdSe quantum dots, and copper ion detection using plasmon and photo enhanced CdSe quantum dots. We have successfully accomplished our research goals in this dissertation. Firstly, we were able to tune the emission wavelength of quantum dots, blue-shifted for up to 45 nm, and their surface functionalization with photo-oxidation. A kinetic model to calculate the photo-oxidation rates was established. Secondly, we established a simple mathematical model to explain the mechanism of plasmon enhanced fluoresce of quantum dots. Our calculation and experimental data support the fluorescence resonance energy transfer (FRET) mechanism between quantum dots and the metal nanoparticles. Thirdly, we successfully pattered the CdSe quantum dots (diameter ~4 nm) into nanorings with tunable diameters and annular sizes on different substrates. We also established a physical model to quantitatively explain the mechanism with the forces that involved in the formation of the nanorings.