M.S.

Recent studies funded by the US Department of energy have shown that coal and coal byproducts contain elevated contents of Rare Earth Elements (REEs), making them a potential resource for these critical materials. The approach employed in this research focused on the concentration and extraction of REEs from fine coal refuse derived from various preparation plants in the Appalachian coal basin of the United States. Initial efforts in this research focused on the identification and characterization of REEs in various fine coal refuse streams from nine distinct industrial preparation plants in Appalachia. The average REE content in these materials was determined to be approximately 200 ppm, but the REE content showed a strong correlation to the aluminum content, suggesting that the REEs are closely associated with the clay minerals present in the refuse. Given the relatively low REE concentrations, initial efforts sought to concentrate the REEs through decarbonization and dispersive liberation steps. In these tests, high-shear agitation in the presence of a polyelectrolyte, followed by sedimentation was able to isolate the REE-enriched fine clay particles from siliceous gangue minerals. Following the dispersive liberation step, all samples were found to have an REE content greater than 300 ppm, a benchmark used for many initial exploratory studies. In one case, the REE content was increased by more than 125%. Subsequent extraction tests initially utilized a direct ion-exchange leaching approach with ammonium sulfate as lixiviant. In all cases, the simple ion-exchange leaching process failed to recover significant quantities of rare earth elements, ultimately suggesting that the REEs in fine coal waste may be passivated or bound in a colloidal phase. To access this colloidal phase, several alternative approaches were evaluated, including leaching with alternative ion-exchange lixiviants, reductive leaching, gas-purged leaching, and others. The approach that showed the most promise was strong alkaline pretreatment, followed by ion-exchange leaching with ammonium sulfate at pH 4. A combination of strong alkali and high-temperatures treatment successfully liberated the REEs, converting them to a form amenable to ion-exchange leaching. The highest REE recovery achieved with this method was determined to be 39%. Lastly, bench-scale solvent extraction tests were used to further concentrate REEs in the leach solution and demonstrate that mixed rare earth concentrates can be successfully produced from fine coal refuse. / Master of Science / Since the introduction of personal electronics, rare earth elements (REEs) have become essential raw materials for modern life. They are used in many common household goods such as cell phones, computers, and flat screen TVs. They are also vital components in various industrial, medical, and military applications. Currently, the majority of the world's supply is obtained from China, which has raised concerns on the vulnerability of the supply chain and the potential impacts of supply disruption on clean energy technologies. In light of this risk, the US Department of Energy has classified a number of REEs as critical elements and has subsequently funded research to investigate ways to diversify the supply chain through alternative resources. The approach employed in this research seeks to extract and recover REEs from fine coal refuse. This industrial waste is a byproduct of the coal mining and beneficiation processes. Given the long legacy of coal mining in the Appalachian region, hundreds of millions of tons of fine waste are currently being stored in surface impoundments, and millions of tons of additional fine coal waste is being produced each year from active mining and beneficiation operations. By valorizing this waste material through REE recovery, mining companies will be incentivized to reprocess existing impoundments, ultimately promoting superior economic and environmental outcomes. Despite their name, rare earths are not "rare" from the standpoint of raw abundance; however, their scarcity is derived from the complexity of the extraction and separation processes. In China, the majority of the heavy rare earth elements are produced from ion-exchangeable clays. These clays have REEs weakly attached to the surface, so that they can be readily recovered by washing them with a salt solution that remove the positively charged rare earth ions from surface. The technical approach employed in this project sought to replicate this process for the clay materials found in fine coal refuse. Additional steps were needed to properly concentrate, activate, and extract the REEs; however, the end-to-end processing tests confirmed that mixed rare earth concentrates can be produced from fine coal wastes consisting primarily clay minerals.

M.S.

M.S.

Coal is one of the world's largest remaining mineral resources. The supply of this rich source of fuel and chemicals is sufficient to serve the world for several thousand years. Coal is used directly and is also heat treated at high and low temperatures to produce fuel and by-products. Of the several methods of treatment that can be used, low-temperature carbonization is one of the most promising. Nearly all of the coke and coal chemicals produced today come from the production of high temperature coke. However, there are many lower rank coals not suited for metallurgical purposes that will produce an excellent char and high yields of by-products. One of the disadvantages of many lower rank coals is their tendency to swell and become plastic when heated to carbonization temperatures, and this property has to a great extent made the operation of the retorts difficult. In an effort to reduce or circumvent this undesirable property, several methods of pretreating the raw coal have been tried including preoxidation, dilution with non-coking coal, preheating, and weathering. The type and severity of the pretreatments vary in their effects on the coking properties of different coals. The purpose of this investigation was to study the effect of preoxidation on the coking properties and the quantities and composition of the byproducts and char obtained from the low-temperature carbonization of Penn-Lee coal. / Master of Science

The usage of the coal is very extensive. For each particular process, there is always a better method to burn some kinds of coals than the others. Each application of the combustion of coal is an individual problem. This problem involves not only the single factor of burning of coal but also the factors of the economy, materials, and manufacture. An efficient burning process is not always the suitable one to be used. On some practical field of coal combustion the testing, or trial method serves very satisfactorily for finding the best firing method. The boiler and furnace testing method applied in the steam power plant is an excellent example. However, there is an important thing in common in all the coal firing processes which is the burning of coal. An understanding of the fundamental characteristics of the coal burning is obviously very helpful to the practical usages, especially to the design of a new process. / Master of Science

During the past decade, carbon capture, utilization, and storage (CCUS) has gained considerable recognition as a viable option to mitigate carbon dioxide (CO2) emissions. This process involves capturing CO2 at emission sources such as power plants, refineries, and processing plants, and safely and permanently storing it in underground geologic formations. Many CO2 injection tests have been successfully conducted to assess the storage potential of CO2 in saline formations, oil and natural gas reservoirs, organic-rich shales, and unmineable coal reservoirs. Coal seams are an attractive reservoir for CO2 storage due to coal's large capacity to store gas within its microporous structure, as well as its ability to preferentially adsorb CO2 over naturally occurring methane resulting in enhanced coalbed methane (ECBM) recovery. A small-scale CO2 injection test was conducted in Southwest Virginia to assess the storage and ECBM recovery potential of CO2 in a coalbed methane reservoir. The goal of this test was to inject up to 20,000 tons of CO2 into a stacked coal reservoir of approximately 15-20 coal seams. Phase I of the injection test was conducted from July 2, 2015 to April 15, 2016 when a total of 10,601 tons of CO2 were injected. Phase II of the injection was conducted from December 14, 2016 to January 30, 2017 when an additional 2,662 tons of CO2 were injected, for a total of 13,263 total tons of CO2 injected. A customized monitoring, verification, and accounting (MVA) plan was created to monitor CO2 injection activities, including surface, near-surface, and subsurface technologies. As part of this MVA plan, chemical tracers were used as a tool to help track CO2 plume migration within the reservoir and determine interwell connectivity. The work presented in this dissertation will discuss the development and implementation of chemical tracers as a monitoring tool, detail wellbore-scale tests performed to characterize CO2 breakthrough and interwell connectivity, and present results from both phases of the CO2 injection test. / PHD / During the past decade, carbon capture, utilization, and storage (CCUS) has gained considerable recognition as a viable option to mitigate carbon dioxide (CO2) emissions. This process involves capturing CO2 at emission sources such as power plants, refineries, and processing plants, and safely and permanently storing it in underground geologic formations. Many CO2 injection tests have been successfully conducted to assess the storage potential of CO2 in saline formations, oil and natural gas reservoirs, organic-rich shales, and unmineable coal reservoirs. Coal seams are an attractive reservoir for CO2 storage due to coal’s large capacity to store gas within its microporous structure, as well as its ability to preferentially adsorb CO2 over naturally occurring methane resulting in enhanced coalbed methane (ECBM) recovery. A small-scale CO2 injection test was conducted in Southwest Virginia to assess the storage and ECBM recovery potential of CO2 in a coalbed methane reservoir. The goal of this test was to inject up to 20,000 tons of CO2 into a stacked coal reservoir of approximately 15-20 coal seams. Phase I of the injection test was conducted from July 2, 2015 to April 15, 2016 when a total of 10,601 tons of CO2 were injected. Phase II of the injection was conducted from December 14, 2016 to January 30, 2017 when an additional 2,662 tons of CO2 were injected, for a total of 13,263 total tons of CO2 injected. A customized monitoring, verification, and accounting (MVA) plan was created to monitor CO2 injection activities, including surface, near-surface, and subsurface technologies. As part of this MVA plan, chemical tracers were used as a tool to help track CO2 plume migration within the reservoir and determine interwell connectivity. The work presented in this dissertation will discuss the development and implementation of chemical tracers as a monitoring tool, detail wellbore-scale tests performed to characterize CO2 breakthrough and interwell connectivity, and present results from both phases of the CO2 injection test.

There is significant historical research on coal, education, religion, churches, and cultural values of the Tazewell County. However, there is no research weaving all of these elements together to tell a story of the county and its political development. This research project is a qualitative study in which I wish to reveal the story of the culture, specifically the political culture, of Tazewell County. I would like to examine objectively whether or not the mining industry has had an effect on the cultural aspects of the county. I want to ask: Is there evidence that the coal industry has shaped the political culture of Tazewell County and, if so, through what mechanisms did it exert this influence? Research will include the examination of mechanisms by which a political culture is created in single-dominant industry communities, such as Tazewell County Virginia. Research will include elements of political socialization such as peer groups, coal camps, church groups, family and community. The research will specifically focus on religion and education and how they have or have not defined the political culture of the area. / Master of Arts

Mining induced seismicity can lead to bumps which cause problems at many mines within the United States and around the world. This seismicity, often referred to as bumps or bursts, can result in injuries, fatalities, and expensive capital damage and production interruptions. There are many factors that contribute to mining induced seismicity but there is still no concrete method to forecast future seismic activity around a mine. One of the main precursors to large seismic events is an increase in situ stress. One way to find areas within geological strata that are highly stressed is to measure p-wave propagation velocities. High p-wave propagation velocities are associated with high in-situ stress levels. By using tomography programs a three-dimensional velocity model can be constructed. When seismic activity is present the event arrival times at each geophone, the locations of each geophone, and the three dimensional velocity model are used in conjunction with one another to locate the seismic events. This research compares the locations of seismic events from a deep coal mine longwall panel in the western United States with the associated p-wave propagation velocities from the previous 24 hours. The aim of this comparison is to provide a link between high velocities and seismic activity that could potentially be used to forecast future seismic activity. The comparison is completed both qualitatively through the use of a visual analysis, and quantitatively using various numerical and correlation comparisons on the seismic and velocity data. The qualitative comparison is completed using the event locations from the tomography program SIMULPS. The quantitative comparison is completed twice using two different tomography programs, SIMULPS and TomoDD, which use different methods for locating the seismic events. Before these comparisons were completed the stresses around the longwall panel were first modeled using the boundary element modeling program LAMODEL to study the effects of three backfilled cross panel entries which were located ahead of the mining face. The modeling showed similar vertical stress distributions as a panel without cross panel entries but higher stress magnitudes. The qualitative analysis involved comparing tomograms created with SIMULPS with seismicity plots from the following day. One noticeable feature of these tomograms is the presence of a stressed area directly ahead of the face. This stressed area represents the forward abutment. The results of this qualitative analysis illustrate a correlation between high p-wave velocities and seismic activity 24 hours later for several of the days studied. The other days showed little to no correlation. Additionally, not all high p-wave velocity regions resulted in seismic activity. Due to these inconsistencies visually analyzing velocity plots obtained from the program SIMULPS is not a reliable way to forecast the locations of seismic activity 24 hours later. The result of the quantitative comparisons completed with the programs SIMULPS and TomoDD further highlighted inconsistencies in the correlation between high p-wave velocities and associated seismic activity 24 hours later. TomoDD provided better correlation values than SIMULPS and generally showed that as the level of seismicity increased the p-wave propagation velocities 24 hours prior also increased. Although TomoDD provided good correlations for some of the data pairs studied, the overall inconsistencies prompt the need for further study in this area using TomoDD to find the optimal forecasting time period. / Master of Science

It is predicted that coal mining in Southwest Virginia, and the economic stability that it brings to the area, will continue to decline over the next decade unless an environmentally sound, and economically viable means can be found to extract seams of high quality coal in the thickness range of 14 to 28 inches. Research into autonomous machine guidance, coupled with developments of thin-seam mining equipment, offer new opportunities for devising mining layouts suitable for extracting these thin seams in a cost effective manner. These layouts must involve well-planned transportation and ventilation routes that will allow safe conditions for personnel. This implies that the mining face, where coal is extracted, will be completely automated, ensuring the safety of the workers. This thesis presents a brief overview of current technologies utilized for underground coal mining in the United States. This is followed by a review of developments in highwall mining that are potentially applicable in underground mining of thin seams. Some past attempts at thin seam mining are discussed, and evaluated for their short comings. An overview of the more recent advances in the guidance systems for use in autonomous mining machines is also presented. The new advances that several manufacturers are developing to address the integration of mining and continuous haulage systems are also investigated. That background is employed in devising a conceptual mining system for the underground mining of coal seams in the 14 to 28 inch range of thickness. This thesis proves that adapting new technologies and concepts from existing ones can lead to meaningful advances in the field of natural resources recovery. This system utilizes a newly designed panel layout that takes into account haulage, supplying, ventilation, equipment, and machine guidance. This system is proposed to show that new ways can be developed to take advantage of the reserves in the 14 to 28 inch range of thickness. This shows that new technology and design innovation can turn currently uneconomic resources, into economic reserves. This kind of innovation is what is needed to keep this region of Southwest Virginia economically viable. This system is a huge step in the direction that thin-seam research needs to take. Most of the equipment suggested for this proposed system is already available. / Master of Science