When solving problems involving quantum mechanical systems, it is frequently desirable to find the matrix elements of a unitary representation $T$ of a real algebraic Lie group $G$. This requires defining an inner product on the Hilbert space $\mathbb{H}$ that carries the representation $T$. In the case where the representation is determined by a representation of a subgroup containing the lowest weight vector of $T$, this can be achieved through the coherent state construction. In both the scalar and vector coherent state methods, the process of finding the overlaps can be simplified by introducing the coherent state triplet ($\mathfrak{F}_{\mathbb{H}_D}$, $\mathbb{H}_D$, $\mathfrak{F}^{\mathfrak{H}_D}$) of Bargmann spaces. Coherent state wave functions -- the elements of $\mathfrak{F}_{\mathbb{H}_D}$ and of $\mathfrak{F}^{\mathbb{H}_D}$ -- are used to define the inner product on $\mathbb{H}_D$ in a way that simplifies the calculation of the overlaps. This inner product and the group action $\Gamma$ of $G$ on $\mathfrak{F}^{\mathbb{H}_D}$ are used to formulate expressions for the matrix elements of $T$ with coefficients from the given subrepresentation. The process of finding an explicit expression for $\Gamma$ relies on matrix factorizations in the complexification of $G$ even though the representation $T$ does not extend to the complexification. It will be shown that these factorizations are, in fact, justified, that the overlaps and $\Gamma$ action can be expressed in terms of the given subrepresentation, and that it is possible to find numerical values for the inner product in $\mathbb{H}$. The scalar and vector coherent state methods will both be applied to Sp($n$) and Sp($n,\mathbb{R}$).

When solving problems involving quantum mechanical systems, it is frequently desirable to find the matrix elements of a unitary representation $T$ of a real algebraic Lie group $G$. This requires defining an inner product on the Hilbert space $\mathbb{H}$ that carries the representation $T$. In the case where the representation is determined by a representation of a subgroup containing the lowest weight vector of $T$, this can be achieved through the coherent state construction. In both the scalar and vector coherent state methods, the process of finding the overlaps can be simplified by introducing the coherent state triplet ($\mathfrak{F}_{\mathbb{H}_D}$, $\mathbb{H}_D$, $\mathfrak{F}^{\mathfrak{H}_D}$) of Bargmann spaces. Coherent state wave functions -- the elements of $\mathfrak{F}_{\mathbb{H}_D}$ and of $\mathfrak{F}^{\mathbb{H}_D}$ -- are used to define the inner product on $\mathbb{H}_D$ in a way that simplifies the calculation of the overlaps. This inner product and the group action $\Gamma$ of $G$ on $\mathfrak{F}^{\mathbb{H}_D}$ are used to formulate expressions for the matrix elements of $T$ with coefficients from the given subrepresentation. The process of finding an explicit expression for $\Gamma$ relies on matrix factorizations in the complexification of $G$ even though the representation $T$ does not extend to the complexification. It will be shown that these factorizations are, in fact, justified, that the overlaps and $\Gamma$ action can be expressed in terms of the given subrepresentation, and that it is possible to find numerical values for the inner product in $\mathbb{H}$. The scalar and vector coherent state methods will both be applied to Sp($n$) and Sp($n,\mathbb{R}$).

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Dans ce mémoire, nous décrivons la réalisation d'un nouveau montage expérimental permettant de manipuler, à l'aide d'un champ radiofréquence de polarisation bien définie, l'état interne d'un atome de Rydberg à l'intérieur de la multiplicité Stark. Nous avons utilisé ce dispositif pour transférer, avec une efficacité proche de 1, les atomes depuis un niveau de faible moment angulaire, accessible par excitation optique depuis le fondamental, vers le niveau de Rydberg circulaire, de moment angulaire maximal. Nous avons ensuite cherché à induire des dynamiques quantiques nouvelles de l'état de l'atome et mis en évidence la dynamique Zénon quantique dans un système de grande dimension. En appliquant un champ micro-onde bien choisi, on peut restreindre l'évolution atomique induite par le champ radiofréquence à un sous-ensemble des niveaux Stark de la multiplicité. Cette dynamique confinée est très différente d'une dynamique classique, le système évoluant périodiquement vers un état " chat de Schrödinger ". Nous avons expérimentalement observé cette évolution dans l'espace des phases et mesuré la fonction de Wigner de l'atome au moment de l'apparition du chat, démontrant pour la première fois les aspects non-classiques de la dynamique Zénon quantique dans un espace de Hilbert non-trivial. / In this manuscript, we describe the realization of a new experimental setupto manipulate with a well-polarized radiofrequency electric field the internal state of aRydberg atom inside the Stark manifold. We used this setup to transfer with a nearly 1efficiency the atoms from a optically-accessible low-m state to the high angular momentumcircular Rydberg state. We then tried to induce new quantum dynamics of the atomicstate and we showed the quantum Zeno dynamics in a large Hilbert space. By applying awell-choose microwave field, one can restrict the atomic evolution induced by the radiofrequencyfield to a subspace of the Stark manifold. This confined dynamics is very differentfrom a classical dynamics. The system periodically evolves to a « Schrödinger cat state ».We experimentally observed this evolution in the phase space and mesured the atomicWigner function at the cat state . This is the first demonstration of the non-classicalaspect of the quantum Zeno dynamics in a non-trivial Hilbert space.

<p>Quantum dynamics is the study of time-dependent phenomena in fundamental processes of atomic and molecular systems. This thesis focuses on systems where nature reveals its quantum aspect; e.g. in vibrational resonance structures, in wave packet revivals and in matter wave interferometry. Grid based numerical methods for solving the time-dependent Schrödinger equation are implemented for simulating time resolved molecular vibrations and to compute photo-electron spectra, without the necessity of diagonalizing a large matrix to find eigenvalues and eigenvectors.</p><p>Pump-probe femtosecond laser spectroscopy on the sodium potassium molecule, showing a vibrational period of 450 fs, is theoretically simulated. We find agreement with experiment by inclusion of the finite length laser pulse and finite temperature effects.</p><p>Complicated resonance structures observed experimentally in photo-electron spectra of hydrogen- and deuterium chloride is analyzed by a numerical computation of the spectra. The dramatic difference in the two spectra arises from non-adiabatic interactions, i.e. the interplay between nuclear and electron dynamics. We suggest new potential curves for the 3²Σ⁺ and 4²Σ⁺ states in HCI⁺.</p><p>It is possible to guide slow atoms along magnetic potentials like light is guided in optical fibers. Quantum mechanics dictates that matter can show wave properties. A proposal for a multi mode matter wave interferometer on an atom chip is studied by solving the time-dependent Schrödinger equation in two dimensions. The results verifies a possible route for an experimental realization.</p><p>An improved representation for wave functions using a discrete set of coherent states is presented. We develop a practical method for computing the expansion coefficients in this non-orthogonal set. It is built on the concept of frames, and introduces an iterative method for computing a representation of the identity operator. The phase-space localization property of the coherent states gives adaptability and better sampling efficiency.</p>

Quantum dynamics is the study of time-dependent phenomena in fundamental processes of atomic and molecular systems. This thesis focuses on systems where nature reveals its quantum aspect; e.g. in vibrational resonance structures, in wave packet revivals and in matter wave interferometry. Grid based numerical methods for solving the time-dependent Schrödinger equation are implemented for simulating time resolved molecular vibrations and to compute photo-electron spectra, without the necessity of diagonalizing a large matrix to find eigenvalues and eigenvectors. Pump-probe femtosecond laser spectroscopy on the sodium potassium molecule, showing a vibrational period of 450 fs, is theoretically simulated. We find agreement with experiment by inclusion of the finite length laser pulse and finite temperature effects. Complicated resonance structures observed experimentally in photo-electron spectra of hydrogen- and deuterium chloride is analyzed by a numerical computation of the spectra. The dramatic difference in the two spectra arises from non-adiabatic interactions, i.e. the interplay between nuclear and electron dynamics. We suggest new potential curves for the 32Σ+ and 42Σ+ states in HCI+. It is possible to guide slow atoms along magnetic potentials like light is guided in optical fibers. Quantum mechanics dictates that matter can show wave properties. A proposal for a multi mode matter wave interferometer on an atom chip is studied by solving the time-dependent Schrödinger equation in two dimensions. The results verifies a possible route for an experimental realization. An improved representation for wave functions using a discrete set of coherent states is presented. We develop a practical method for computing the expansion coefficients in this non-orthogonal set. It is built on the concept of frames, and introduces an iterative method for computing a representation of the identity operator. The phase-space localization property of the coherent states gives adaptability and better sampling efficiency.

Infrared divergences arising in theories with massless gauge bosons have been shown to cancel in scattering amplitudes when using dressed states constructed from the Faddeev- Kulish approach to the asymptotic states. It has been established that these states are closely related to asymptotic symmetries of the theory, that is, non-vanishing gauge trans- formations at the asymptotic boundary. In this thesis, we review both of these aspects for QED and non-Abelian gauge theories. We also investigate the expectation value of the non-Abelian field strength tensor using dressed states. We then present a novel con- struction of the dressing operator for non-Abelian gauge theories using Wilson lines. We demonstrate, to order O(g2), that each term of the dressing operator is reproduced in the presented Wilson line approach, along with additional terms that warrant a more thorough understanding. This work extends previous results that pertained to QED and gravity.