The study demonstrates the systematic investigation of thermophysical properties of synthetic slags and commercial mold fluxes in a wide temperature range. Focal points of the work are (i) the development and the construction of the transient hot-wire method for the thermal conductivity measurement of solid and molten slags and (ii) the investigation of the thermal conductivity of all layers of casting powders being in the mold. The work includes viscosity, density and surface tension measurements as well as the investigation of characteristic temperatures. The crystallization behavior of mold fluxes was characterized using a SHTT/DHTT (single hot and double hot thermocouple technique). The study discusses the temperature dependence, the influence of the basicity and the non-bridging oxygen per tetrahedra (NBO/T) on the slag properties. The novelty of the work is the systematic characterization of properties of two commercial mold fluxes and the thermal conductivity measurement in the glass transition temperature range.

The Fennoscandian Shield as a part of a large Precambrian basement area is located in northern Europe and hosts economically important mineral deposits including base metals and precious metals. Regional geophysical data such as potential field and magnetotelluric data in combination with other geoscientific data contain information of importance for an understanding of the crustal and upper mantle structure. Knowledge about regional-scale structures is important for an optimized search for mineralisation. In order to investigate in more detail the spatial distribution of regional electrically conductive structures and near-surface mineral deposits, complementary magnetotelluric measurements have been done within the Precambrian Shield in the north-eastern part of the Norrbotten ore province. The potential field data provided by the Geological Survey of Sweden have been included in the current study. Processing of magnetotelluric data was performed using a robust multi-remote reference technique. The dimensionality analysis of the phase tensors indicates complex 3D structures in the area. A 3D crustal model of the electrical conductivity structure was derived based on 3D inversion of the data using the ModEM code. The final inversion 3D resistivity model revealed the presence of strong crustal conductors with the conductance of more than 3000 S at depth of tens of kilometres within a generally resistive crust. A significant part of the middle crust conductors is elongated in directions that coincide with major ductile deformation zones that have been mapped from airborne magnetic data and geological fieldwork. Some of these conductors have near-surface expression where they spatially correlate with the locations of known mineralisation. Processing and 3D inversion of the regional magnetic and gravity field data were performed, and the structural information derived from these data by using an open-source object-oriented package code written in Python called SimPEG. In this study, a new approach is proposed to extract and analyse the correlation between the modelled physical properties and for domain classification. For this, a neural net Self-Organizing Map procedure (SOM) was used for data reduction and simplification. The input data to the SOM analysis contain resistivity, magnetic susceptibility, and density model values for some selected depth levels. The domain classification is discussed with respect to geological boundaries and composition. The classification is furthermore applied for prediction of favourable areas for mineralisation. Based on visual inspection of processed regional gravity and magnetic field data and a SOM analysis performed on higher-order derivatives of the magnetic data, an interpretation of a sinistral fault with 52 km offset is proposed. The fault is oriented N10E and can be traced 250 km from Karesuando at the Swedish-Finish border southwards to the Archaean-Proterozoic boundary marked by the Luleå-Jokkmokk Zone.

The application of the entropy concept to stabilize oxide systems opens the possibility of discovering new materials with unique structural and functional properties. High-entropy alloys and oxides, which are based on the entropy stabilization concept and composed of multi-principal elements, have the potential to tailor structural and functional properties to meet specific needs. The study of lanthanum-based perovskite materials that benefit from the entropy stabilization approach is a promising area of research.However, the inherent randomness of multi-principal elements presents new challenges, making it difficult to predict their behavior. To understand these difficulties, we have initiated a methodical investigation of La-based medium- and high-entropy perovskite oxides. This study focuses on the synthesis, characterization, sintering mechanism, and electrical conductivity properties of nine La1-xCax(A1/3, B1/3, C1/3)O3 medium-entropy perovskite oxide systems (A, B, and C = three combination of Cr or Co or Fe or Ni or Mn) and one La1-xCax(Cr0.2Co0.2Fe0.2Ni0.2Mn0.2)O3 high-entropy perovskite oxide system (for x = 0.1 to 0.3). This research aims to provide better understanding of: (1) synthesis process, (2) temperature of single-phase formation, (3) the impact of various combinations of multiple B-site transitional elements and Ca doping on crystal structure, and microstructure (4) sintering mechanism and (5) electrical conductivity properties.

京都大学 / 新制・課程博士 / 博士(理学) / 甲第24436号 / 理博第4935号 / 新制||理||1705(附属図書館) / 京都大学大学院理学研究科化学専攻 / (主査)教授 北川 宏, 教授 有賀 哲也, 教授 吉村 一良 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

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This thesis investigates the validity of the standard thermal response test (TRT) results when performed on a series of boreholes (string). The typical TRT consists of subjecting a single borehole to a constant heat injection rate to obtain the temperature response in the ground which can then be used to determine the ground thermal conductivity. When completed on a single borehole, the results may be analyzed with the line source theory, since the assumption of a single line heat source is valid. For multiple boreholes, the assumption of a single line source becomes invalid if the spacing between the boreholes is small enough for borehole thermal interaction to occur. Moreover, for boreholes that are charged in series, heat transfer from the horizontal pipes that connect the vertical boreholes may also influence the ground thermal response. This thesis takes an in-depth look at the different factors that affect the results of TRTs performed on borehole strings. Different analysis methods are implemented to determine areas of improvement for determining the thermal conductivity of the soil surrounding the borehole string. For the analysis, the infinite line source (ILS) model and a model developed using TRNSYS 18 were used to determine the effective thermal conductivity. The results show that TRNSYS is unable to accurately model a TRT performed on a borehole string. The horizontal pipe model within TRNSYS proved to have significant fundamental issues, as the effective thermal conductivity is greatly underestimated with values of 1.2±0.1W/mK and the results of increasing the horizontal length both increased and decreased the effective thermal conductivities. The results from the ILS demonstrate that an effective thermal conductivity of 1.7±0.2W/mK is an appropriate estimate of the soil at the BTES field tested, as the borehole string with the furthest spacing between boreholes gave an effective thermal conductivity of 1.7W/mK. Performing multiple thermal response tests within the same BTES field also provided evidence of the need to implement multiple TRTs as common practise. The testing presented shows that the effective thermal conductivity can vary within ±0.2W/mK within the same relative location. With better knowledge of the thermal properties within the BTES field location comes the opportunity for improved planning of operation and control of thermal distribution within the field. This would be especially beneficial when dealing with seasonal BTES fields / Thesis / Master of Applied Science (MASc)

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