The diploma thesis deals with the issue of pollution of the generated gas after the gasification process and its subsequent cleaning using a barrier filter. The theoretical part of thesis consists of research on the gasification process, the effects on the gasification process, pollutants in the gas and gas cleaning with a focus on the purification of gas from tar. The experimental part of this thesis is devoted to the gasification itself in a fluidized bed gasification reactor in order to test the effect of the catalyst, which was calcined dolomite, the composition of the gas at variable parameters of water vapor and the temperature inside the laboratory filter.

This diploma thesis deals with the issue of pollution of the generated gas during gasification. It consists of two parts. The first part is theoretical, where there is a search describing the course of gasification. There is also an overview of impurities in the generated gas and a description of methods suitable for gas purification. The second part of the work is focused experimentally, where various fillings of the barrier filter are tested during gas cleaning.

The Gautrain Rapid Rail Link is a state-of-the-art rail route and one of the ten Spatial Development Initiatives planned in Gauteng Province, South Africa. The route comprises two links, namely a link between Tshwane (Pretoria) and Johannesburg and a link between OR Tambo International Airport and Sandton. A total of 10 stations are linked by approximately 80 kilometres of rail along the proposed route. Between Johannesburg and Pretoria in the southern Tshwane region, the rail alignment is underlain by dolomite bedrock for approximately 15km in the vicinity of Centurion between Nelmapius Drive and The Fountains, including nearly 6km elevated on a viaduct. The stability of the rapid rail link constructed over the dolomitic sections was considered a major project risk due to its proneness to sinkholes and subsidences along this route. Construction on heterogeneous soils, pinnacled bedrock and other geohazards posed major challenges to the construction team. To facilitate detailed design and adapt proper foundation options for the viaducts founded over the dolomitic terrain, rigorous and comprehensive ground investigations were conducted by the Bombela Civils Joint Venture (BCJV). This work presents the different ground investigation methods used and how the results have led to the adoption of five suitable foundation solutions namely: large diameter shafts to rock, piles to rock, floating foundations over grouted ground, spread footings on shallow bedrock and concrete U shaped structures. Additional information available on a CD stored at the Merensky Library on 3rd Floor / Dissertation (MSc)--University of Pretoria, 2012. / Geology / unrestricted

Zinc is one of the essential elements required for the normal growth plants. The total amount of zinc commonly occurring in soils is usually many times greater than that necessary to supply the needs of actively growing plants. The ability of the soil to "fix" zinc in form unavailable for plant use, however, has made the zinc deficiency disease an important plant nutrition problem in the major fruit and nut growing regions of the West. Fixation mechanisms which have been postulated as contributing to zinc deficiency include organic complexes, precipitation of insoluble inorganic salts, and strong zinc-clay interactions. It may be possible that in certain soils naturally occurring soil minerals, other than the clay minerals, may also exert an influence on the capacity of the soil to retain zinc. The accumulation of lime minerals is a distinguishing profile characteristic of soils in arid and semi-arid region and semi-arid regions. These minerals include: calcite (CaCO3), dolomite (CaMg(CO3)2), and magnesite (MgCO3). Despite the widespread occurrence of these minerals in the soil system, relatively few data exist which specifically isolate the interaction between cations in solution and the solid phase of the above-named lime minerals.

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yes / The non-isothermal kinetic and thermal behaviour of a naturally formed dolomite in conditions that approach in situ CO2 capture in chemical looping reforming, were investigated. The performance of this dolomite was studied at micro-scale in ‘dry’ conditions, as well as at macro-scale in ‘dry’ and ‘wet’ conditions to investigate the effects of scale (3 mg, 2.5 g), partial pressures of CO2 (<15 kPa) and steam, and deactivation upon limited cycling. The carbonation and calcination kinetics were modelled using an improved iterative Coats–Redfern method. Increasing CO2 partial pressures on the ‘dry’ macroscale exacerbated the experimental carbonation conversions in an inversely proportional trend when compared with those at micro-scale. The presence of steam had a positive effect on CO2 chemisorption. Steam had a negligible influence on the calcination activation energies. The activation energies of carbonation were increased for the experiments at the highest CO2 partial pressures under wet conditions.