Composite materials are widely used in demanding applications in aerospace and other industries. In order to understand the complex behaviour of the composite materials and their components, standardised test methods are used. One example is the double cantilever beam (DCB) test in which the test specimen is loaded in an opening, i.e., tensile mode. Failures in composite materials loaded compression are different from those in tension, for example, kink band or buckling-like failures can occur. In this project, several DCBs are designed and a new fixture which allows for compression testing of a DCB is developed for an existing Instron testing machine. The fixture overcomes a known problem of tensile peak causing the failure of the adhesive at the inner surfaces of the DBC by applying additional compressive loads along the outer surfaces of the DBC. The compressive forces can induce the desired kink band formation so that researchers can better study the failure mode. The conceptual development of the new DCBs and the new fixture are presented. Several prototypes of the specimens and the fixture are modelled using the three-dimensional (3D) computer-aided design software Creo Parametric 2.0.  One of the fixtures is selected to further study. The different DCB specimens are studied in order to obtain information about the kink band using 3D finite element analysis with the software programme Abaqus CAE. The selected fixture is analysed to determine if there are any areas of concern. Finally, the behaviour of the compression stress along the DCB using two pairs of forces is studied. Unfortunately, it is determined that the tensile peak experienced by the adhesive cannot be eliminated by the application of two pairs of compressive loads, one at the free end and the other in the vicinity of the tensile peak. Several suggestions are made for future work which might serve to reduce the tensile peak; e.g., the movable force couple is applied as a surface load instead of a point load. For this, the fixture will have to be modified with a new geometry, although the DCB could be the same. This will allow further work to focus on the combined behaviour of the tensile peak and the fixture.

This work describes the development of an improved mode I fracture testing procedure for adhesively-bonded wood, and demonstrates the sensitivity of this approach. The two significant improvements were: 1) the use of the flat double cantilever beam (DCB) geometry, which has been uncommon for wood and 2) the application of an established and powerful data analysis using a corrected compliance method from beam theory. Three studies were conducted using various wood adhesives and DCB specimens were fabricated from yellowpoplar (Liriodendron tulipifera) sapwood. The sensitivity of this methodology showed significant differences in fracture performance as the degree of cure increased for a phenol formaldehyde adhesive, and yielded maximum strain energy release rate (SERR) values of 370 - 560 J/m2. A second study showed performance differences between two polymeric diphenylmethane diisocyanate (pMDI) adhesives and one polyurethane adhesive. Typical maximum SERR values were 160 and 130 J/m2 for the pMDI adhesives and 160 J/m2 for the polyurethane adhesive. A third study investigated the effect of loading rates on a cross-linked polyvinyl acetate adhesive and maximum SERR values of 370 - 560 J/m2 were achieved. Adhesive penetration and cure were determined by image analysis with fluorescence microscopy, and by micro-dielectric analysis, respectively. Since the geometry of the fracture procedure dictates the absence of wood failure, the resulting fractured surfaces were readily analyzable. The surface analysis techniques of laser ionization mass analysis, solid-state nuclear magnetic resonance and field emission scanning electron microscopy were used to investigate the locus of failure for the smooth fractured surfaces. / Master of Science

Submitted by Lucienne Costa (lucienneferreira@ufcg.edu.br) on 2018-04-10T19:51:47Z No. of bitstreams: 1 THIAGO TAKUMI TAN – DISSERTAÇÃO (PPGEM) 2017.pdf: 9018003 bytes, checksum: 45bd9458239c0c274dabe5c7aee2f165 (MD5) / Made available in DSpace on 2018-04-10T19:51:47Z (GMT). No. of bitstreams: 1 THIAGO TAKUMI TAN – DISSERTAÇÃO (PPGEM) 2017.pdf: 9018003 bytes, checksum: 45bd9458239c0c274dabe5c7aee2f165 (MD5) Previous issue date: 2017-03-13 / O objetivo desta dissertação foi desenvolver dispositivos que possam ser utilizados para ensaios de fratura interlaminar modo-I e modo-II em materiais dissimilares, para aplicação de cargas dinâmicas. Para o desenvolvimento dos dispositivos foi utilizada uma adaptação da metodologia de projeto apresentada por Maribondo (2000), que consiste em projeto informacional, projeto conceitual, projeto preliminar, projeto detalhado, fabricação e testes. A escolha dos ensaios que podem ser utilizados para obter tais modos de fratura foi realizada com base no estudo de trabalhos acadêmicos, que apontou o ensaio double cantilever beam (DCB), como sendo o mais utilizado para estudo de fratura interlaminar modo-I, e também foi observado o crescimento do uso do ensaio end-loaded split (ELS), para estudo de fratura interlaminar modo-II. Os dispositivos desenvolvidos foram testados em uma máquina de impacto por queda de peso, onde foram utilizados corpos de prova de junta adesiva de alumínio/epóxi. Realizaram-se testes modo-I e modo-II bem-sucedidos, analisando o comportamento dos dispositivos e dos corpos de prova durante o ensaio e após o mesmo. / The main objective of this dissertation for the devices that can be used for mode-I and mode-II interlaminar fracture test in dissimilar materials. For the development of devices for design methodology that projects in informational design, conceptual design, preliminary design, detailed design, fabrication and testing. The choice of the tests that can be used to obtain such fracture modes was made based on the study of academic papers, which pointed to the double beam cantilever (DCB) test, as being the most used for the study of interlaminar mode-I, and end-loaded split (ELS) for the study of mode-II interlaminar fracture. The developed devices were tested in a weight drop impact machine, where aluminum / epoxy adhesive joints were used. Testing and analysis of the behavior of the devices and test bodies were carried out during and after the test.

The primary direction of this thesis was towards exploring qualitative and quantitative characteristics necessary for refining and understanding the flat wood double cantilever beam (DCB) as a valid means for testing Mode I fracture energy in wood adhesive bonds. Southern yellow pine (SYP) adherends were used with epoxy and phenol formaldehyde (PF) impregnated films, providing two systems with different characteristics for investigation. An adhesive penetration analysis was performed for both the epoxy and PF bonds. The PF penetration into the SYP was shown to be relatively shallow. The epoxy penetration was shown to be deeper. Epoxy-SYP DCBs were quasi-statically tested with varying widths (10 mm, 15 mm, and 20 mm), showing decreases in scatter of critical and arrest strain energy release rates, GIc and GIa, with increases in specimen width. Quasi-static fracture testing was also performed on PF SYP-DCBs, showing much higher critical and arrest fracture energy values than the epoxy-SYP DCBs, indicating that deep adhesive penetration is not necessarily a requisite for higher Mode I fracture energy values. Grain distribution influences were computationally investigated because of the stiffness difference between latewood and earlywood growth and the grain angle along the length of the beams. The grain angle and the stiffness difference between latewood and earlywood growth caused the effective stiffness, (ExxI)eff, to vary along the length of the beam. The effective stiffness variation caused variations in the beam's ability to receive and store strain energy, complicating and confounding determination of experimental results. Cyclic loading tests were performed on PF-SYP DCB's. The cycle frequency was 3Hz, with a valley to peak load ratio of R = 0.5. Specimen softening was observed with cycling, with re-stiffening occurring with crack growth. Contrary to expectations, specimen compliance occasionally decreased with small crack extensions. A toughening mechanism was frequently observed, whereby subsequent crack lengths required more cycles to failure than the previous crack length. Monotonically extending the crack length far from the fatigued region created a fresh crack that did not show the toughened behavior. But toughening did resume with subsequent crack lengths. / Master of Science

No description available.

The interfacial fracture performance of dicyandiamide cured epoxy/steel adhesive systems was thoroughly investigated. Fracture mechanics based testing was utilized to study several variables which were believed to influence the epoxy/steel interphase region, specifically the elasomeric toughener concentration, the dicyandiamide concentration, and the cure temperature. Bulk mechanical measurements were conducted to provide background information for comparison with the fracture data, and surface analyses were carried out on the neat adhesives and failed fracture specimens to provide insight into the locus and causes of failure. The addition of toughener drastically impacted the morphological, bulk mechanical, and adhesive properties in these latent cure systems. Modulus values decreased and bulk fracture toughness values increased with increasing toughener content. Static double cantilever beam (DCB), fatigue DCB, and notched coating adhesion (NCA) interfacial fracture performances all increased. X-ray photoelectron spectroscopy (XPS) and tunneling electron microscopy (TEM) analyses of the failed specimens revealed that chemical changes were more prominent at the epoxy/steel interphase than in the bulk of the materials. Morphological variations were also apparent with toughener level variations, but for a single formulation no differences between the bulk and intephase morphologies were seen. Evaluations were conducted on a series of elastomer modified model epoxy formulations cured with varying amounts of dicyandiamide. The modulus and bulk fracture toughness values were shown to be independent of dicyandiamide concentration, whereas the adhesive performance was greatly influenced. For increases in the concentration of dicyandiamide, single lap shear (SLS) failure strength values increased while quasi-static DCB and NCA test performances decreased. Fatigue DCB results showed improved adhesive performance at both high and low levels of dicyandiamide content. The results of the failure surface evaluations suggest that dicyandiamide variations produce significant chemical changes only in the epoxy/steel interphase region, and not in the bulk. Analyses were conducted on all of the above systems using two additional cure temperatures. The purpose of this work was to alter the dicyandiamide solubility, and possibly the dicy/epoxy reaction mechanisms, and to determine what influence these changes had on the interfacial fracture performance. In general it was found that performance increased as the cure temperature was increased. / Ph. D.

A research group at University of Skövde has developed an interphase element for implementation in the commercial FE-software Abaqus. The element is using the Tvergaard & Hutchinson cohesive law and is implemented in Abaqus Explicit version 6.7 using the VUEL subroutine. This bachelor degree project is referring to evaluate the interphase element and also highlight problems with the element. The behavior of the interphase element is evaluated in mode I using Double Cantilever Beam (DCB)-specimens and in mode II using End Notch Flexure (ENF)-specimens. The results from the simulations are compared and validated to an analytical solution. FE-simulations performed with the interphase element show very good agreement with theory when using DCB- or ENF-specimens. The only exception is when an ENF-specimen has distorted elements. When using explicit finite element software the critical time step is of great importance for the results of the analyses. If a too long time step is used, the simulation will fail to complete or complete with errors. A feasible equation for predicting the critical time step for the interphase element has been developed by the research group and the reliability of this equation is evaluated. The result from simulations shows an excellent agreement with the equation when the interphase element governs the critical time step. However when the adherends governs the critical time step the equation gives a time step that is too large. A modification of this equation is suggested.

Finite element analysis using Cohesive Zone Method (CZM) is a commonly used method to investigate delamination in laminated composites. In this study, two plane strain, zero-thickness six-node quadratic (6-NQ) and four-node linear (4-NL) interface elements are developed to implement CZM. Two main approaches for CZM formulation are categorized as Unified Mode Approach (UMA) and Separated Mode Approach (SMA), and implemented into 6-NQ interface elements to model a double cantilever beam (DCB) test of a unidirectional laminated composite. The results of the approaches are nearly identical. However, it is theoretically shown that SMA spawns non-symmetric tangent stiffness matrices, which may lower convergence and/or overall performance, for mixed-mode loading cases. Next, a UMA constitutive relationship is rederived. The artificial modifications for improving convergence rates such as lowering penalty stiffness, weakening interfacial strength and using 6-NQ instead of 4-NL interface elements are investigated by using the derived UMA and the DCB test model. The modifications in interfacial strength and penalty stiffness indicate that the convergence may be improved by lowering either parameter. However, over-softening is found to occur if lowering is performed excessively. The morphological differences between the meshes of the models using 6-NQ and 4-NL interface elements are shown. As a consequence, it is highlighted that the impact to convergence performance and overall performance might be in opposite. Additionally, benefits of selecting CZM over other methods are discussed, in particular by theoretical comparisons with the popular Virtual Crack Closure Technique. Finally, the numerical solution scheme and the Arc-Length Method are discussed.

<p>A research group at University of Skövde has developed an interphase element for implementation in the commercial FE-software Abaqus. The element is using the Tvergaard & Hutchinson cohesive law and is implemented in Abaqus Explicit version 6.7 using the VUEL subroutine. This bachelor degree project is referring to evaluate the interphase element and also highlight problems with the element.</p><p>The behavior of the interphase element is evaluated in mode I using Double Cantilever Beam (DCB)-specimens and in mode II using End Notch Flexure (ENF)-specimens. The results from the simulations are compared and validated to an analytical solution.</p><p>FE-simulations performed with the interphase element show very good agreement with theory when using DCB- or ENF-specimens. The only exception is when an ENF-specimen has distorted elements.</p><p>When using explicit finite element software the critical time step is of great importance for the results of the analyses. If a too long time step is used, the simulation will fail to complete or complete with errors. A feasible equation for predicting the critical time step for the interphase element has been developed by the research group and the reliability of this equation is evaluated.</p><p>The result from simulations shows an excellent agreement with the equation when the interphase element governs the critical time step. However when the adherends governs the critical time step the equation gives a time step that is too large. A modification of this equation is suggested.</p>

In this dissertation, four test approaches were developed to characterize the adhesion performance and durability of adhesive bonds for specific applications in areas spanning from structural adhesive joints to popular confectionaries such as chewing gum. In the first chapter, a double cantilever beam (DCB) specimen geometry is proposed for combinatorial fracture studies of structural adhesive bonds. This specimen geometry enabled the characterization of fracture energy vs. bondline thickness trends through fewer tests than those required during a conventional "one at a time" characterization approach, potentially offering a significant reduction in characterization times. The second chapter investigates the adhesive fracture resistance and crack path selection in adhesive joints containing patterns of discreet localized weak interfaces created using physical vapor deposition of copper. In a DCB specimen tested under mode-I conditions, fracture energy within the patterned regions scaled according to a simple rule of mixture, while reverse R-curve and R-curve type trends were observed in the regions surrounding weak interface patterns. Under mixed mode conditions such that bonding surface with patterns is subjected to axial tension, fracture energy did not show R-curve type trends while it was observed that a crack could be made to avoid exceptionally weak interfaces when loaded such that bonding surface with defects is subjected to axial compression. In the third chapter, an adaptation of the probe tack test is proposed to characterize the adhesion behavior of gum cuds. This test method allowed the introduction of substrates with well-defined surface energies and topologies to study their effects on gum cud adhesion. This approach and reported insights could potentially be useful in developing chewing gum formulations that facilitate easy removal of improperly discarded gum cuds from adhering surfaces. In the fourth chapter we highlight a procedure to obtain insights into the long-term performance of silicone sealants designed for load-bearing applications such as solar panel support sealants. Using small strain constitutive tests and time-temperature-superposition principle, thermal shift factors were obtained and successfully used to characterize the creep rupture master curves for specific joint configurations, leading to insights into delayed failures corresponding to three years through experiments carried out in one month. / Ph. D.