<p><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">The most significant human impacts on the hydrological system are due to land-use change. The conversion of land to agricultural, mining, industrial, or residential uses significantly alters the hydrological characteristics of the land surface and modifies pathways and rates of water flow. If this occurs over large or critical areas of a catchment, it can have significant short and long-term impacts, on the quality of water. While there are methods available to quantify the pollutants in surface water, methods of linking non-point source pollution to water quality at catchment scale are lacking. Therefore, the research presented in this thesis investigated modelling techniques to estimate the effect of land-cover type on water quality. The main goal of the study was to contribute towards improving the understanding of how different land-covers in an urbanizing catchment affect surface water quality. The aim of the research presented in this thesis was to explain how the quality of surface runoff varies on different land-cover types and to provide guidelines for minimizing water pollution that may be occurring in the Kuils-Eerste River catchment. The research objectives were / (1) to establish types and spatial distribution of land-cover types within the Kuils-Eerste River catchment, (2) to establish water quality characteristics of surface runoff from specific land-cover types at the experimental plot level, (3) to establish the contribution of each land-cover type to pollutant loads at the catchment scale.<span style="mso-spacerun:yes"> </span><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">Land-cover characteristics and water quality were investigated using GIS and Remote Sensing tools. The application of these tools resulted in the development of a land-cover map with 36 land classifications covering the whole catchment. Land-cover in the catchment is predominantly agricultural with vineyards and grassland covering the northern section of the catchment. Vineyards occupy over 35% of the total area followed by fynbos (indigenous vegetation) (12.5 %), open hard rock area (5.8 %), riparian forest (5.2 %), mountain forest<span style="mso-spacerun:yes">&nbsp / &nbsp / </span>(5 %), dense scrub (4.4 %), and improved grassland (3.6 %). The residential area covers about 14 %. Roads cover 3.4 % of the total area. </span><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">Surface runoff is responsible for the transportation of large quantities of pollutants that affect the quality of water in the Kuils-Eerste River catchment. The different land-cover types and the distribution and concentration levels of the pollutants are not uniform. Experimental work was conducted at plot scale to understand whether land-cover types differed in their contributions to the concentration of water quality attributes emerging from them.<span style="color:black"> Four plots each with a length of 10 m to 12 m and 5 m width were set up. Plot I was set up on open grassland, Plot II represented the vineyards, Plot III covered the mountain forests, and Plot IV represented the fynbos land-cover.</span> Soil samples analyzed from the experimental plots fell in the category of sandy soil (Sa) with the top layer of Plot IV (fynbos) having loamy sand (LmSa). The soil particle sizes range between fine sand (59.1 % and 78.9 %) to coarse sand (between 7 % and 22 %). The content of clay and silt was between 0.2 % and 2.4 %. Medium sand was between 10.7 % and 17.6 %. In terms of vertical distribution of the particle sizes, a general decrease with respect to the size of particles was noted from the top layer (15 cm) to the bottom layer (30 cm) for all categories of the particle sizes. There was variation in particle size with depth and location within the experimental plots.</span><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">Two primary methods of collecting water samples were used / grab sampling and composite sampling. The quality of water as represented by the samples collected during storm events during the rainfall season of 2006 and 2007 was<span style="mso-spacerun:yes">&nbsp / </span>used to establish <span style="mso-spacerun:yes">&nbsp / </span>water quality characteristics for the different land-cover types. The concentration of total average suspended solids was highest in the following land-cover types, cemeteries (5.06 mg L^-1), arterial roads/main roads (3.94 mg L^-1), low density residential informal squatter camps (3.21 mg L^-1) and medium density residential informal townships (3.21 mg L^-1). Chloride concentrations were high on the following land-cover types, recreation grass/ golf course (2.61 mg L^-1), open area/barren land (1.59 mg L^-1), and improved grassland/vegetation crop (1.57 mg L^-1). The event mean concentration (EMC) values for NO₃-N were high on commercial mercantile (6 mg L^-1) and water channel (5 mg L^-1). The total phosphorus concentration mean values recorded high values on improved grassland/vegetation crop (3.78 mg L^-1), medium density residential informal townships (3mgL^-1) and low density residential informal squatter camps (3 mg L^-1). Surface runoff may also contribute soil particles into rivers during rainfall events, particularly from areas of disturbed soil, for example areas where market gardening is taking place. The study found that different land cover types contributed differently to nonpoint source pollution. </span><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">A GIS model was used to estimate the diffuse pollution of five pollutants (chloride, phosphorus, TSS, nitrogen and NO₃-N) in response to land cover variation using water quality data. The GIS model linked land cover information to diffuse nutrient signatures in response to surface runoff using the Curve Number method and EMC data were developed. Two models (RINSPE and N-SPECT) were used to estimate nonpoint source pollution using various GIS databases. The outputs from the GIS-based model were compared with recommended water quality standards. It was found that the RINSPE model gave accurate results in cases where NPS pollution dominate the total pollutant inputs over a given land cover type. However, the N-SPECT model simulations were too uncertain in cases where there were large numbers of land cover types with diverse NPS pollution load. All land-cover types with concentration values above the recommended national water quality standard were considered as areas that needed measures to mitigate the adverse effects of nonpoint pollution. </span><span lang="EN-GB" style="font-size: 12.0pt / line-height:150% / font-family:&quot / Times New Roman&quot / ,&quot / serif&quot / ">The expansion of urban areas and agricultural land has a direct effect on land cover types within the catchment. 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Dowel bars in jointed plain concrete pavement (JPCP) have the important function of transferring wheel loads from one slab to the other, hence ensuring that the deflections on each side of the joint are kept almost equal. As well, the dowels should not impede the concrete pavement movements due to environmental effects (temperature and moisture). Dowel bar misalignment, attributed to deficient construction practice, is a major cause of joint distress or faulting by inhibiting the free movement of the slab at the joint. To prevent these issues, tolerance guidelines on misalignment levels are implemented by transportation agencies. Review of previous studies indicate that many researchers analysed the effects of dowel bar misalignment on pavement behaviour using a pull-out test, that is a forcebased opening of the joint. These approaches neglect that joints movements in the field are strain-governed by non-linear temperature and shrinkage actions, leading to combined axial movements and curling of the slab. In this study, the fundamental dowel bar behaviour under shrinkage and thermal loading was determined through detailed 3D finite element modelling (3D-FEM). To that end, models of dowel jointed concrete slabs were developed and subjected to realistic non-linear profiles of shrinkage and thermal strains. Studies were carried out on a single-bar model, taking into account bar-concrete friction and plastic concrete behaviour. The parameters that were investigated included different configurations and levels of bar misalignment and different friction coefficients between the steel and the concrete, simulating the use of bond-breakers. To interpret the results from the numerical analysis, criteria for concrete damage were developed and used in parallel with measures of joint load transfer efficiency; these were obtained by examining the response of the slab under a Falling Weight Deflectometer (FWD) drop at the joint. The results were verified by comparing the outputs of a model consisting of one half of a slab to published data. The analysis of the models revealead that none of the models showed signs of significant damage after the application of shrinkage and two thermal cycles. Analyses with up to ten thermal cycles did not indicate progressive accumulation of damage, suggesting that for the chosen parameters there is no the concrete around the dowel bar will not fail. Models with bars placed higher in the slab and bars with angular misalignment exhibited more damage than the non-misaligned models without reaching the damage criteria used in this study. The models did not exhibit the amount of damage reported in the studies on dowel bar misalignment having used pull-out tests. It was found that no significant difference existed between uncoated and coated dowel bars models results with regards to concrete damage at the joint. However, a high coefficient of friction between the dowel and the concrete, simulating dowel bar corrosion, proved to be the most detrimental to joint integrity. All of the models performed very well with respect to joint load transfer efficiency, suggesting that the plastic strains in the concrete around the dowel did not have a significant impact on joint performance for the realistic range of parameters investigated.

Hedging a contingent claim with an asset which is not perfectly correlated with the underlying asset results in an imperfect hedge. The residual risk from hedging with a correlated asset is priced using an actuarial standard deviation principle in infinitesmal time, which gives rise to a nonlinear partial differential equation (PDE). A fully implicit, monotone discretization method is developed for solving the pricing PDE. This method is shown to converge to the viscosity solution. Certain grid conditions are required to guarantee monotonicity. An algorithm is derived which, given an initial grid, inserts a finite number of nodes in the grid to ensure that the monotonicity condition is satisfied. At each timestep, the nonlinear discretized algebraic equations are solved using an iterative algorithm, which is shown to be globally convergent. Monte Carlo hedging examples are given, which show the standard deviation of the profit and loss at the expiry of the option.

Dowel bars in jointed plain concrete pavement (JPCP) have the important function of transferring wheel loads from one slab to the other, hence ensuring that the deflections on each side of the joint are kept almost equal. As well, the dowels should not impede the concrete pavement movements due to environmental effects (temperature and moisture). Dowel bar misalignment, attributed to deficient construction practice, is a major cause of joint distress or faulting by inhibiting the free movement of the slab at the joint. To prevent these issues, tolerance guidelines on misalignment levels are implemented by transportation agencies. Review of previous studies indicate that many researchers analysed the effects of dowel bar misalignment on pavement behaviour using a pull-out test, that is a forcebased opening of the joint. These approaches neglect that joints movements in the field are strain-governed by non-linear temperature and shrinkage actions, leading to combined axial movements and curling of the slab. In this study, the fundamental dowel bar behaviour under shrinkage and thermal loading was determined through detailed 3D finite element modelling (3D-FEM). To that end, models of dowel jointed concrete slabs were developed and subjected to realistic non-linear profiles of shrinkage and thermal strains. Studies were carried out on a single-bar model, taking into account bar-concrete friction and plastic concrete behaviour. The parameters that were investigated included different configurations and levels of bar misalignment and different friction coefficients between the steel and the concrete, simulating the use of bond-breakers. To interpret the results from the numerical analysis, criteria for concrete damage were developed and used in parallel with measures of joint load transfer efficiency; these were obtained by examining the response of the slab under a Falling Weight Deflectometer (FWD) drop at the joint. The results were verified by comparing the outputs of a model consisting of one half of a slab to published data. The analysis of the models revealead that none of the models showed signs of significant damage after the application of shrinkage and two thermal cycles. Analyses with up to ten thermal cycles did not indicate progressive accumulation of damage, suggesting that for the chosen parameters there is no the concrete around the dowel bar will not fail. Models with bars placed higher in the slab and bars with angular misalignment exhibited more damage than the non-misaligned models without reaching the damage criteria used in this study. The models did not exhibit the amount of damage reported in the studies on dowel bar misalignment having used pull-out tests. It was found that no significant difference existed between uncoated and coated dowel bars models results with regards to concrete damage at the joint. However, a high coefficient of friction between the dowel and the concrete, simulating dowel bar corrosion, proved to be the most detrimental to joint integrity. All of the models performed very well with respect to joint load transfer efficiency, suggesting that the plastic strains in the concrete around the dowel did not have a significant impact on joint performance for the realistic range of parameters investigated.

Nanoindentation has been widely used for measuring mechanical behavior of nanocrystalline (nc) metals that cannot be measured by tensile and compressive test. The hardness and elastic modulus are usually obtained by Oliver and Pharr method. However, this may not be true for materials showing viscoelastic characteristics. This study aims at clarifying the effect of testing parameters, especially loading rate and holding time, on the hardness and elastic modulus of a nanocrystalline Fe-51Ni coating obtained in nanoindentation tests as the material exhibits anelastic and creep characteristics. An analytical method based on the correspondence principle for linear viscoelasticity was developed. The holding displacement-time data obtained in indentation creep tests at a high loading rate of 20 mN/s were analyzed and material parameters related to the elastic, anelastic and creep characteristic were derived using a model containing one Maxwell unit and two Kelvin units. The anelastic deformation thus contains at least two relaxation processes having relaxation times of 0.37 s and 6.8 s, respectively and the creep deformation is described by a viscosity value of 4.2x104 GPa.s for the alloy in an as-deposited state. Moreover, electrodeposited (ED) Ni was analyzed by electron backscatter diffraction. Results indicated that the ED Ni exhibits a bimodal distribution of grain size. The grains having sizes larger than 2 £gm shows a strong fiber texture of <100>//ND, whereas the small grains (<2 £gm) are mainly randomly oriented.

The aims of this thesis to investigate the two step loading of Ti/APC-2 hybrid nanocomposite laminates and their notched effect. Ti/APC-2 laminates were composed of three layers of titanium sheets and two layers of APC-2. Nanoparticles SiO2 were dispersed uniformly on the interfaces of APC-2 with the optimal amount of 1 wt %. Then, APC-2 was stacked according to cross-ply [0/90]s and quasi-isotropic [0/45/90/-45] sequences. The modified diaphragm curing process was adopted to fabricate the hybrid panels for minimal impact of production. The panels were cur into samples and drilled an diameter hole in the center with diameters of 4 or 6 mm. Both tension and fatigue tests were carried out with MTS 810 universal testing machine at room temperature. Also, two-step loading tests include high¡÷low and low¡÷high tests, were conducted. 0.9£mnom is denoted as high load and 0.7£mnom low load for two-step loading spectrum. In both high¡÷low and low¡÷high step loadings the first step is to do cyclic tests at a half life of the corresponding load, and then finish it due to last step load. From the received results, some conclusions were made. First, the ultimate load of notched cross-ply samples was reduced about 50% and the notched quasi-isotropic samples reduced about 30% compared to their unnotched counterparts. Second, the S-N curves are very close for both centrally notched samples of diameters 4 mm and 6 mm in cross-ply and quasi-isotropic samples. Third, quasi-isotropic samples had higher average values of cumulative damage than cross-ply samples. Because of notched effect centrally notched samples of diameters 4 mm had higher average values of cumulative damage than centrally notched samples of diameters 6 mm.

Dredge cutting forces produced by the movement of the cutterhead through the sediment have been measured with the laboratory dredge carriage located at the Haynes Coastal Engineering Laboratory. The sediment bed that was used for the dredging test was considered to be relatively smooth and the sediment used was sand with a d50=0.27 mm. Forces on the dredge carriage were measured using five 13.3 kN (3000 lb) one directional load cells placed on the dredge ladder in various places so the transmitted cutting forces could be obtained. The objectives for this study are to determine the vertical, horizontal, and axial forces that are produced by the cutterhead while testing. So, to find these cutter forces, a static analysis was performed on the carriage by applying static loads to the cutterhead in the vertical, horizontal, and axial directions, and for each load that was applied, readings were recorded for all five of the load cells. Then, static equilibrium equations were developed for the dredge carriage ladder to determine loads in the five load cells. Also, equilibrium equations can be applied to a dredging test to find the cutterhead forces by taking the measured data from the five load cells and applying the known forces to the equations, and the cutterhead forces can be determined. These static equilibrium equations have been confirmed by using a program called SolidWorks, which is modeling software that can be used to do static finite element analysis of structural systems to determine stresses, displacement, and pin and bolt forces. Data that were gathered from the experimental procedure and the theoretical calculations show that the force on the dredge cutterhead can be determined. However, the results from the static equilibrium calculations and the results from the SolidWorks program were compared to the experiment procedure results, and from the comparison the procedure results show irregularities when a force of approximately 0.889 kN (200 lb) or above is applied to the cutterhead in a north, south, west, or east orientation. The SolidWorks program was used to determine the results for displacements of the dredge carriage ladder system, which showed that large displacements were occurring at the location of the cutterhead, and when the cutterhead displaces it means that the carriage ladder is also moving, which causes false readings in the five load cells. From this analysis it was determined that a sixth force transducer was needed to produce more resistance on the ladder; and the cell #1 location needed to be redesigned to make the ladder system as rigid as possible and able to produce good testing results. The SolidWorks program was used to determine the best location where the sixth force transducer would give the best results, and this location was determined to be on the lower south-west corner oriented in the direction east to west. The static equilibrium equations were rewritten to include the new redesigned cell #1 location and the new location of the sixth load cell. From the new system of equations, forces on the cutterhead can be determined for future dredging studies conducted with the dredge carriage. Finally, the forces on the laboratory cuttersuction dredge model cutterhead were scaled up to the prototype 61 cm (24 in) cuttersuction dredge. These scaled up cutting forces on the dredge cutterhead can be utilized in the design of the swing winches, swing cable size, ladder supports, and ladder.

Mechanical loading is an integral component to maintaining bone mass during periods of disuse (i.e. bedrest or casting) or reduced weightbearing activity. Recent data has shown a direct relation between the sympathetic nervous system (SNS) and bone metabolism, however the underlying mechanisms responsible for this relationship are unknown. Furthermore, the role that beta adrenergic stimulation during disuse has on cancellous bone mass and microarchitecture have yet to be defined. The central hypothesis of this research is that resistance exercise and beta-1 adrenergic (Adrb1) receptor agonist administration attenuate disuse-associated reductions in metaphyseal bone during 28 days of rodent hindlimb unloading (HU). Study one determined whether an eccentric- (ECC) or combined isometric+eccentric- (ISO+ECC) based contraction paradigm, engaged during hindlimb unloading (HU), mitigates losses in musculoskeletal mass and strength. Both simulated resistance training (SRT) protocols inhibited reductions in disuse-sensitive cancellous bone mass and maintained plantarflexor muscle strength. Study two determined whether combining the anabolic effects of SRT with the anti-resorptive effects of alendronate (ALEN) during HU positively impacts cancellous bone in an additive or synergistic fashion. ALEN significantly inhibited the anabolic response of cancellous bone to SRT during HU. Study three determined whether an Adrb1 receptor agonist (dobutamine; DOB) mitigates disuse-associated losses in bone mass and formation rate (BFR) during HU. DOB administration significantly blunted reductions in bone mineral density (vBMD) by maintaining cancellous BFR. Study four determined if Adrb1 receptor agonist administration during HU results in an attenuation of osteocyte apoptosis within cancellous bone and whether this relates to a decrease in Bax/Bcl-2 mRNA content ratio (pro- and anti-apoptotic proteins). HU significantly increased cancellous bone osteocyte apoptosis and Bax/Bcl-2 mRNA content ratio, which was reduced by the administration of DOB. Collectively, these are the first studies to assess the role of beta-1 adrenergic signaling and resistance exercise in mitigating disuse-induced loss of cancellous bone mass in rodents. The long term goals of this research are to understand the exact molecular mechanisms by which both Adrb1 signaling and high intensity resistance exercise provide beneficial bone effects during prolonged periods of disuse and to apply these findings to current osteoporosis research.

名古屋大学博士学位論文 学位の種類 : 医学博士(論文) 学位授与年月日:平成4年7月20日 宮口和彦氏の博士論文として提出された

ABSTRACT In the present study, it is emphasized that mixed-type finite element formulation, which is different from the conventional displacement-type formulation, has both displacements and stresses as its primary variables. Therefore, stress, as well as displacement boundary conditions, can be imposed easily and exactly. Except around the outer edge where support is placed, stresses obtained by both displacement and mixed formulation are close to each other when the circular plate is subject to transverse uniform loading. However, large discrepancies exist around the locations of constraints, where the stresses are always significant and critical. Since mixed formulation of the present study can completely satisfy the stress and displacement boundary conditions, it can theoretically provide more accurate stress analysis and should be considered as a more appropriate analysis tool.