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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Pressure Effects on Electric Field Spectra of Molecular Rydberg States

Altenloh, Daniel Dean 12 1900 (has links)
Electric field studies, electrochromism, were used to obtain excited-state data for analogous divalent sulfur compounds. The sulfides investigated were dimethyl sulfide and small cyclic sulfides including the three to six member ring compounds. The excited-state dipole moments and polarizabilities are reported for the first s, p, and d Rydberg absorption bands which occur in the near vacuum ultraviolet region from 230 to 170 nm. The excited-state data are interpreted in terms of the particular excited-state (s, p, or d) for the molecules and the bending differences due to the presence of the ring and the number of atoms in the ring. The next section describes the use of electrochromism to investigate the pressure effect of argon, carbon tetrafluoride and sulfur hexafluoride on the spectra for molecular Rydberg states.

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