Installed photovoltaic nameplate power have been growing rapidly around the worldin the last few years. But how much energy is returned to society (i.e. net energy) by this technology, and which factors contribute the most to the amount of energy returned? The objective of this thesis was to examine the importance of certain inputs and outputs along the solar panel production chain and their effect on the energy return on (energy) investment (EROI) for crystalline wafer-based photovoltaics. A process-chain model was built using publicly available life-cycle inventory (LCI) datasets. This model has been kept simple in order to ensure transparency. Univariate sensitivity analysis for processes and multivariate case studies was then applied to the model. The results show that photovoltaic EROI values are very sensitive to assumptions regarding location and efficiency. The ability of solar panels to deliver net energy in northern regions of the earth is questionable. Solar cell wafer thickness have a large impact on EROI, with thinner wafers requiring less silicon material. Finding an alternative route for production of solar-grade silicon is also found to be of great importance, as is introduction of kerf loss recycling. Equal system sizes have been found to yield an primary EROI between approximately 5.5-19 depending on location and assumptions. This indicates that a generalized absolute EROI for photovoltaics may be of little use for decision-makers. Using the net energy cliff concept in relation to primary EROI found in this thesis shows that primary EROI rarely decreases to less than the threshold of 8:1 in univariate cases. Crystalline photovoltaics under similar system boundaries as those in the thesis model does not necessarily constrain economic growth on an energetic basis.

This thesis examines the energy return on investment (EROI) of a model 3 MW hybrid gas-geothermal plant on the Texas Gulf Coast. The model plant uses a design similar to the DOE Pleasant Bayou No. 2 test geothermal plant, and uses a gas engine to harness entrained methane and an Organic Rankine Cycle turbine to harness thermal energy from hot brines. The indirect energy cost was calculated using the Carnegie Mellon University Economic Input-Output Life Environmental Life Cycle Analysis (EIO-LCA) model. The EROI of the plant using the 1997 EIO-LCA energy data is 12.40, and the EROI of the plant using 2002 EIO-LCA energy data is 14.18. Sensitivity analysis was run to determine how the plant parameters affect the EROI. A literature review of the EROI of different power sources shows that the EROI of the hybrid geothermal plant is greater than the EROI of flash steam geothermal and solar, but is lower than the EROI of dry steam geothermal, wind power, nuclear, coal, gas, and hydroelectric plants. An analysis of the EROI to financial return on investment (FROI) shows that the FROI for a hybrid geothermal plant could be competitive with wind and solar as a viable renewable resource in the Texas electricity market. / text

The aspiration for producing algal biofuel is motivated by the desire to replace conventional petroleum fuels, produce fuels domestically, and reduce greenhouse gas emissions. Although, in theory, algae have the potential to produce a large amount of petroleum fuel substitutes and capture carbon emissions, in practice, profitable algal biofuel production has proven quite challenging. This dissertation characterizes the production pathways for producing petroleum fuel substitutes from algae and evaluates constraints on algal biofuel production. Chapter 8 provides a summary of the entire dissertation. The first chapter provides a framework for reporting the production of renewable diesel from algae in a consistent way by using data that are specific and by presenting information with relevant metrics. The second chapter presents a review of analytical tools (i.e., microscopy, spectroscopy, and chromatography) that can be used to analyze the structure and composition of intermediate products in an algal biofuel production pathway. In chapters 3 through 6, the energy return on investment, water intensity, and financial return on investment are presented for three cases: 1) an Experimental Case in which data were measured during five batches of algal biocrude production with a combined processed volume of about 7600 L, 2) a hypothetical Reduced Case that assumes the same energy output as the Experimental Case, with reduced energy and material inputs, and 3) a Highly Productive Case that assumes higher energy outputs than the Experimental Case, with reduced energy and material inputs, similar to the Reduced Case. For all three cases, the second-order energy return on investment was determined to be significantly less than 1, which means that all three cases are energy negative. The water intensity (consumption and withdrawal) for all cases was determined to be much greater than that of conventional petroleum fuels and biofuels produced from non-irrigated crops. The financial return on investment was also found to be significantly less than 1 for all cases, indicating production would be unprofitable. Additionally, it was determined that large-scale algal biofuel production would be constrained by the availability of critical energy and material inputs (e.g., nitrogen and carbon dioxide). The final part of this dissertation presents a first-principles thermodynamic analysis that represents an initial attempt at characterizing the thermodynamic limits for algal biofuel production. In that analysis, the energy, entropy, and exergy is calculated for each intermediate product in the algal biofuel production pathway considered here. Based on the results presented in this body of work, game-changing technology and biotechnology developments are needed for sustainable and profitable algal biofuel production. / text

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Tandis que les bénéfices physiologiques de chaussures de référence dans le milieu de la course à pied d’endurance sont montrés dans la littérature scientifique, les effets spécifiques et contrôlés de certaines propriétés mécaniques des chaussures demeurent peu connus. L’objectif général de ce travail de thèse était d’étudier les effets du retour d’énergie des semelles intermédiaire des chaussures et de la raideur en flexion des chaussures sur la performance physiologique et biomécanique en course à pied d'endurance. Que ce soit à court-terme ou lors d’une course à pied prolongée, le coût énergétique métabolique (critère utilisé pour évaluer la performance en course à pied) n’était pas significativement modifié par les propriétés mécaniques testées en moyenne parmi le groupe complet de participants. En revanche, les réponses spécifiques aux participants, à la fois à court-terme et lors d’une course à pied prolongée, ont permis de mettre en évidence des combinaisons de réponses biomécaniques et de caractéristiques intrinsèques aux participants expliquant les variations du coût énergétique métabolique en fonction des propriétés mécaniques chaussantes. Une nouvelle stratégie a notamment été mise en évidence chez les participants bénéficiant de la raideur en flexion des chaussures qui se traduisait par une redistribution descendante des activations musculaires des articulations de la hanche et du genou vers l’articulation de la cheville avec la durée de course. Ce travail de thèse soulignait l’importance de considérer une offre de conception de chaussures adaptées à des groupes de coureurs aux réponses biomécaniques et/ou aux caractéristiques intrinsèques similaires. / While physiological benefits of baseline running racing shoes are shown in the scientific literature, the specific and controlled effects of some shoe mechanical features remain not well known. The main purpose of this work was to study the effects of the midsole energy return and the shoe longitudinal bending stiffness on the physiological and biomechanical performance during endurance running. In both short-term and prolonged running duration, the metabolic energetic cost (criteria used to evaluate the endurance running performance) was not significantly altered by the tested mechanical features in average over the group of participants. The main finding was that the shoe mechanical features induced different effects on the metabolic energetic cost depending on the participants. Taking into account the participant-specific responses (in both short-term and during a prolonged running duration) enabled to highlight combinations of biomechanical responses and intrinsic participant characteristics explaining the variations of the metabolic energetic cost as a function of shoe mechanical features. A novel strategy has been highlighted in participants benefiting from the shoe longitudinal bending stiffness resulting in descendant redistribution of the muscular coordination from the hip and knee joints to the ankle joint with the running duration. This work showed the importance of considering a footwear design offer suitable to groups of runners with similar biomechanical responses and/or intrinsic characteristics.

O desenvolvimento sustentável e a própria sobrevivência da humanidade dependem da compatibilização da demanda por recursos energéticos com as limitações ambientais e necessidades humanas. Dessa maneira, torna-se fundamental compreender e mensurar a sustentabilidade energética. Para tanto, esse trabalho vale-se de princípios da economia ecológica e do planejamento integrado de recursos para identificar e analisar os fatores que afetam a sustentabilidade energética de um dado sistema. A partir desses fatores são definidos indicadores de sustentabilidade, os quais compõem uma metodologia concebida para avaliar o grau de sustentabilidade da produção de energia. Tal metodologia é testada em um estudo de caso da matriz elétrica paulista, a qual mostrou um nível próximo da sustentabilidade, mas com a necessidade de aprimoramentos. Por fim, são feitas reflexões sobre a robustez, a flexibilidade e as limitações da metodologia proposta, assim como recomendações para ajustes da composição da matriz estudada com o propósito de torná-la mais sustentável. / Sustainable development and the very survival of humanity depends on the compatibility of the demand for energy resources with environmental constraints and human needs. Thus, it is essential to understand and define metrics for energy sustainability. For that reason, this work draws on principles of ecological economics and integrated resource planning to identify and analyze the factors affecting energy sustainability of a given system. From these factors are defined sustainability indicators, which are the foundations for a methodology designed to assess the degree of sustainability of energy production. The methodology is tested on a case study of the electricity matrix of the State of Sao Paulo, which is close to a sustainable level even though requiring improvements in some aspects. Finally, reflections on the sturdiness, flexibility and limitations of the proposed methodology, as well as recommendations for adjustments in the composition of the case study matrix in order to make it more sustainable are made.

O desenvolvimento sustentável e a própria sobrevivência da humanidade dependem da compatibilização da demanda por recursos energéticos com as limitações ambientais e necessidades humanas. Dessa maneira, torna-se fundamental compreender e mensurar a sustentabilidade energética. Para tanto, esse trabalho vale-se de princípios da economia ecológica e do planejamento integrado de recursos para identificar e analisar os fatores que afetam a sustentabilidade energética de um dado sistema. A partir desses fatores são definidos indicadores de sustentabilidade, os quais compõem uma metodologia concebida para avaliar o grau de sustentabilidade da produção de energia. Tal metodologia é testada em um estudo de caso da matriz elétrica paulista, a qual mostrou um nível próximo da sustentabilidade, mas com a necessidade de aprimoramentos. Por fim, são feitas reflexões sobre a robustez, a flexibilidade e as limitações da metodologia proposta, assim como recomendações para ajustes da composição da matriz estudada com o propósito de torná-la mais sustentável. / Sustainable development and the very survival of humanity depends on the compatibility of the demand for energy resources with environmental constraints and human needs. Thus, it is essential to understand and define metrics for energy sustainability. For that reason, this work draws on principles of ecological economics and integrated resource planning to identify and analyze the factors affecting energy sustainability of a given system. From these factors are defined sustainability indicators, which are the foundations for a methodology designed to assess the degree of sustainability of energy production. The methodology is tested on a case study of the electricity matrix of the State of Sao Paulo, which is close to a sustainable level even though requiring improvements in some aspects. Finally, reflections on the sturdiness, flexibility and limitations of the proposed methodology, as well as recommendations for adjustments in the composition of the case study matrix in order to make it more sustainable are made.

The aim of this thesis is to evaluate ORC systems and technologies from an energy and economic perspective. ORC systems are a growing renewable electricity generation technology, but New Zealand has limited local skills and expertise for identifying ORC resource opportunities and subsequently developing suitable technologies at low cost. For this reason, this thesis researches ORC technology, resource types, and international development, with the aim to determine guidelines for how to cost-effectively develop ORC systems, and to make recommendations applicable to furthering their development within a New Zealand context. This thesis first uses two surveys, one of commercial ORC installations, and a second of economic evaluations of ORC systems in literature, to determine what resources and economic scenarios are supportive of commercial development. It is found that geothermal resources provide the largest share of ORC capacity, with biomass and waste-heat recovery (WHR) being developed more recently. The surveys also found that countries with high electricity prices or policy interventions have developed a wider range of resources using ORC systems. This thesis then undertakes an EROI evaluation of ORC electricity generation systems using a combination of top-down and process based methodologies. Various heat sources; geothermal, biomass, solar, and waste heat are evaluated in order to determine how the utilised resource can affect energy profitability. A wide range of EROIstnd values, from 3.4 – 22.7 are found, with solar resources offering the lowest EROIs, and geothermal systems the highest. Higher still EROI values are found to be obtainable with longer system lifetimes, especially for WHR systems. Specific engineering aspects of ORC design and technology such as high-side pressure, heat storage, modularity, superheating, pinch-point temperature difference, and turbine efficiency are evaluated in terms of economic performance, and a variety of general conclusions are made about each. It is found that total system thermo-economic optimisation may not lead to the highest possible EROI, depending on the objective function. Lastly, the effects of past and potential future changes to the markets and economies surrounding ORCs are explored, including the New Zealand electricity spot price, steel and aluminium prices, subsidies, and climate policy. Of the subsidy types explored, it is found that directly subsidising ORC system capital has the greatest effect on the economic performance of ORC systems, as measured by common metrics. In conclusion, this thesis finds that ORC systems have a limited applicability to New Zealand’s electricity market under current economic conditions outside of geothermal and off-grid generation, but changes to these conditions could potentially make their development more viable. The author recommends that favourable resources should be developed using systems that provide high efficiencies, beyond what might provide the best economic performance, in order to increase EROI, and reduce the future need for costly investments into increasingly less favourable resources.

The aim of this thesis is to evaluate ORC systems and technologies from an energy and economic perspective. ORC systems are a growing renewable electricity generation technology, but New Zealand has limited local skills and expertise for identifying ORC resource opportunities and subsequently developing suitable technologies at low cost. For this reason, this thesis researches ORC technology, resource types, and international development, with the aim to determine guidelines for how to cost-effectively develop ORC systems, and to make recommendations applicable to furthering their development within a New Zealand context. This thesis first uses two surveys, one of commercial ORC installations, and a second of economic evaluations of ORC systems in literature, to determine what resources and economic scenarios are supportive of commercial development. It is found that geothermal resources provide the largest share of ORC capacity, with biomass and waste-heat recovery (WHR) being developed more recently. The surveys also found that countries with high electricity prices or policy interventions have developed a wider range of resources using ORC systems. This thesis then undertakes an EROI evaluation of ORC electricity generation systems using a combination of top-down and process based methodologies. Various heat sources; geothermal, biomass, solar, and waste heat are evaluated in order to determine how the utilised resource can affect energy profitability. A wide range of EROIstnd values, from 3.4 – 22.7 are found, with solar resources offering the lowest EROIs, and geothermal systems the highest. Higher still EROI values are found to be obtainable with longer system lifetimes, especially for WHR systems. Specific engineering aspects of ORC design and technology such as high-side pressure, heat storage, modularity, superheating, pinch-point temperature difference, and turbine efficiency are evaluated in terms of economic performance, and a variety of general conclusions are made about each. It is found that total system thermo-economic optimisation may not lead to the highest possible EROI, depending on the objective function. Lastly, the effects of past and potential future changes to the markets and economies surrounding ORCs are explored, including the New Zealand electricity spot price, steel and aluminium prices, subsidies, and climate policy. Of the subsidy types explored, it is found that directly subsidising ORC system capital has the greatest effect on the economic performance of ORC systems, as measured by common metrics. In conclusion, this thesis finds that ORC systems have a limited applicability to New Zealand’s electricity market under current economic conditions outside of geothermal and off-grid generation, but changes to these conditions could potentially make their development more viable. The author recommends that favourable resources should be developed using systems that provide high efficiencies, beyond what might provide the best economic performance, in order to increase EROI, and reduce the future need for costly investments into increasingly less favourable resources.

Brown macroalgae or brown seaweed is a promising source of ethanol that may avoid the challenges of arable land use, water use, lignin content, and the food vs. fuel debate associated with first generation and cellulosic ethanol sources; however, this promise is challenged by seaweed’s high water content, high ash content, and natural composition fluctuations. Notably, lifecycle studies of seaweed ethanol are lacking in the literature. To address this gap, a well-to-wheel model of ethanol production from farmed brown seaweed was constructed and applied to the case of Saccharina latissima farming in British Columbia (BC), Canada, to determine energy return on energy invested (EROI), carbon intensity (CI), and near shore seaweed farming production potential for seaweed ethanol and to examine the production cost of seaweed ethanol. Seaweed farming and ethanol production were modeled based on current BC farming methods and the dry grind corn ethanol production process; animal feed was included as an ethanol co-product, and co-product credits were considered. A seaweed ethanol yield calculation tool that accounts for seaweed composition was proposed, and a sensitivity study was done to examine case study data assumptions. In the case study, seaweed ethanol had lower CI than sugarcane, wheat, and corn ethanol at 10.1 gCO2e/MJ, and it had an EROI comparable to corn ethanol at 1.78. Seaweed ethanol was potentially profitable due to significant revenue from animal feed sales; however, the market for seaweed animal feed was limited by the feed’s high sodium content. Near shore seaweed farming could meet the current demand for ethanol in BC, but world near shore ethanol potential is likely an order of magnitude lower than world ethanol production and two orders of magnitude lower than world gasoline production. Composition variation and a limited harvest season make solar thermal or geothermal seaweed drying and storage necessary for ethanol production in BC. Varying seaweed composition, solar thermal drying performance, co-product credits, the type of animal feed produced, transport distances, and seaweed farming performance in the sensitivity study gave an EROI of over 200 and a CI of -42 gCO2e/MJ in the best case and an EROI of 0.64 and CI of 33 gCO2e/MJ in the worst case. Co-product credits and the type of animal feed produced had the most significant effect overall, and the worst cases of seaweed composition and solar thermal seaweed drying system performance resulted in EROI of 0.64 and 1.0 respectively. Brown seaweed is concluded to be a potentially profitable source of ethanol with climate benefits that surpass current ethanol sources; however, additional research into seaweed animal feed value, co-product credits, large scale seaweed conversion, and the feasibility of solar thermal or geothermal seaweed drying is required to confirm this conclusion. / Graduate