Interpreting and correlating epeiric sea sequences is key to understanding ancient marine environments. As a result, eNd, d13C and Sm/Nd profiles are developed as tools for interpreting epeiric sea carbonates. Previously, eNd and d13C profiles in epeiric sea carbonates have been used to study changes in the Nd isotope balance and C-cycle of adjacent ocean water. Instead, eNd, d13C and Sm/Nd profiles of Ordovician Midcontinent carbonates of North America demonstrate that fluctuations in sea level and depth are driving local changes in the eNd, d13C and Sm/Nd composition of epeiric seawater. <p> Dissolved Nd derived from the Transcontinental Arch, Taconic Highlands and the Iapetus Ocean determine the eNd composition of Midcontinent seawater. As sea level fluctuated, submergence of the Arch and an influx of Iapetus ocean waters adjusted the Nd isotope balance of epeiric seawater. As a result, eNd profiles can be used to track the submergence history of the Late Ordovician Midcontinent. Comparison of stratigraphic variations in carbonate Sm/Nd ratios with sea level curves, conodont paleoecology, and the eNd profiles also suggests that variations in Sm/Nd ratios are related to changes in depth. However, processes effecting Sm/Nd ratios in epeiric seas may be varied and require further investigation. <p> Sea level fluctuations and the waxing and waning of cool, nutrient rich, oxygen poor Iapetus waters onto the craton adjusted productivity and organic carbon burial rates on the Ordovician Midcontinent. Close to the Transcontinental Arch sea level rise caused an increase in organic carbon burial and productivity, while close to the Sebree Trough, and the influx of Iapetus waters, sea level rise caused a decrease in organic carbon burial and productivity. Differences in local C-cycling across a single epeiric sea encourage caution when using d13C profiles from epeiric sea carbonates to track changes in the C-cycle of adjacent oceans. <p> Because of their connection to sea level fluctuations, variations in the eNd, d13C and Sm/Nd profiles can also used to correlate Ordovician Midcontinent carbonates. However, the ability to correlate coeval strata using these profiles is limited by changes in depositional environment across the craton, which cause excursions to be absent, dampened, or magnified.

Interpreting and correlating epeiric sea sequences is key to understanding ancient marine environments. As a result, eNd, d13C and Sm/Nd profiles are developed as tools for interpreting epeiric sea carbonates. Previously, eNd and d13C profiles in epeiric sea carbonates have been used to study changes in the Nd isotope balance and C-cycle of adjacent ocean water. Instead, eNd, d13C and Sm/Nd profiles of Ordovician Midcontinent carbonates of North America demonstrate that fluctuations in sea level and depth are driving local changes in the eNd, d13C and Sm/Nd composition of epeiric seawater. <p> Dissolved Nd derived from the Transcontinental Arch, Taconic Highlands and the Iapetus Ocean determine the eNd composition of Midcontinent seawater. As sea level fluctuated, submergence of the Arch and an influx of Iapetus ocean waters adjusted the Nd isotope balance of epeiric seawater. As a result, eNd profiles can be used to track the submergence history of the Late Ordovician Midcontinent. Comparison of stratigraphic variations in carbonate Sm/Nd ratios with sea level curves, conodont paleoecology, and the eNd profiles also suggests that variations in Sm/Nd ratios are related to changes in depth. However, processes effecting Sm/Nd ratios in epeiric seas may be varied and require further investigation. <p> Sea level fluctuations and the waxing and waning of cool, nutrient rich, oxygen poor Iapetus waters onto the craton adjusted productivity and organic carbon burial rates on the Ordovician Midcontinent. Close to the Transcontinental Arch sea level rise caused an increase in organic carbon burial and productivity, while close to the Sebree Trough, and the influx of Iapetus waters, sea level rise caused a decrease in organic carbon burial and productivity. Differences in local C-cycling across a single epeiric sea encourage caution when using d13C profiles from epeiric sea carbonates to track changes in the C-cycle of adjacent oceans. <p> Because of their connection to sea level fluctuations, variations in the eNd, d13C and Sm/Nd profiles can also used to correlate Ordovician Midcontinent carbonates. However, the ability to correlate coeval strata using these profiles is limited by changes in depositional environment across the craton, which cause excursions to be absent, dampened, or magnified.

The Miocene Nullarbor Limestone is the most recent formation in the Cenozoic Eucla Group and was deposited in the Eucla Basin, southern Australia, at ~38°S paleolatitude during the early to middle Miocene. The rocks form the modern surface of the vast, karsted Nullarbor Plain. Older Eucla Group marine carbonates (Eocene-earliest Miocene) are cool-water in nature and dominated by bryozoans and echinoderms. The Nullarbor Limestone is subtropical in composition and rich in coralline algae (rhodoliths and articulated types), large and small benthic foraminifera and molluscs. Diverse zooxanthellate corals are also present but not numerous. Deposition is interpreted to have taken place in three main paleoenvironments: rhodolith gravels, seagrass banks, and open seafloors. The Southern Ocean extended inboard ~450 km from the shelf edge during Nullarbor Limestone deposition. Interpreted paleodepths ranged from the top to the base of the photic zone, implying a small slope over a wide shelf. The Miocene Eucla platform is therefore interpreted to have been epeiric in nature. Paleoenvironment distribution is explained using epeiric platform sedimentation patterns and comparisons with modern environments. Open seafloor environments, the deepest settings, are thought to have been below fair-weather wave base. Rhodolith gravels accumulated at intermediate depths, where waves frequently swept the seafloor. Seagrass banks developed in the shallowest waters farthest inboard, where wave energy had been largely dissipated. Diverse corals, large benthic foraminifera and micrite envelopes inboard and in the western part of the basin support the notion of paleotemperatures generally above 20°C, the upper limit of subtropical carbonate accumulation. Although deposition occurred during the Miocene Climatic Optimum, a simple overall temperature increase cannot completely account for the subtropical nature of these sediments at mid-latitudes. Tropical components decrease from west to east, implying a temperature gradient, probably due to the warm proto-Leeuwin Current. Thus, these subtropical carbonates were deposited at mid-latitudes and their presence did not simply reflect a change in global climate. / Thesis (Master, Geological Sciences & Geological Engineering) -- Queen's University, 2010-12-23 16:05:47.981

The Hirnantian mass extinction was the second largest of the Phanerozoic. A global sea level fall resulting from a glaciation on Gondwanaland caused significant changes in ocean circulation patterns and nutrient cycling that is recorded as a worldwide positive δ13C excursion.<p> In chapter 2, carbon and nitrogen isotope profiles were reconstructed from two North American carbonate platforms in Nevada and one in the Yukon with the purpose of gaining a better understanding of proximal to proximal gradients in δ13C values from Hirnantian epeiric seaway sediment. Positive δ13C excursions are recorded in bulk inorganic and organic carbon fractions from all three sections, and in graptolite periderms from one section. A larger positive excursion is recorded in the proximal sediment (7) compared to proximal sediment (3-4). This gradient appears to reflect differences in surface water dissolved inorganic carbon δ13C values across epeiric seas. These findings are consistent with the carbonate weathering hypothesis, that predicts larger positive δ13C shifts in proximal settings of tropical epeiric seas resulting from changes in the local carbon weathering flux caused by the exposure of vast areas of carbonate sediment during glacioeustatic sea level fall and restricted shelf circulation. A 2 positive excursion in δ15N is interpreted to result from increased ocean ventilation, greater partitioning of atmospheric oxygen into downwelling surface waters, oxygen minimum zone shrinkage, and declining denitrification rates. This allowed for upwelling of recycled nitrogen with high 15N values into the photic zone that forced exported organic matter from the photic zone to higher 15N values, consistent with the observed positive shift in 15N during the Hirnantian glaciation. This study presents a conceptual model to explain secular changes in δ13C and δ15N during the transition from a greenhouse to icehouse climate.<p> The second focus of this research, presented in chapter 3, was on improving the chemical and analytical methods for δ18O analysis of biogenic apatites. The technique applies cation exchange chromatography that allows for small sample sizes of apatite (200 µg) to be used for chemical conversion to Ag3PO4. The precision (0.15, 1) of δ18O analysis obtained using a Thermal Conversion Elemental Analyser Continuous Flow Isotope Ratio Mass Spectrometer (TC/EA CF-IRMS), and the ability to collect multipe isotopes (O, Ca, Sr, REE) using a cation exchange column, makes this technique valuable for high-resolution, multi-isotope studies of biogenic apatites.

The Hirnantian mass extinction was the second largest of the Phanerozoic. A global sea level fall resulting from a glaciation on Gondwanaland caused significant changes in ocean circulation patterns and nutrient cycling that is recorded as a worldwide positive δ13C excursion.<p> In chapter 2, carbon and nitrogen isotope profiles were reconstructed from two North American carbonate platforms in Nevada and one in the Yukon with the purpose of gaining a better understanding of proximal to proximal gradients in δ13C values from Hirnantian epeiric seaway sediment. Positive δ13C excursions are recorded in bulk inorganic and organic carbon fractions from all three sections, and in graptolite periderms from one section. A larger positive excursion is recorded in the proximal sediment (7) compared to proximal sediment (3-4). This gradient appears to reflect differences in surface water dissolved inorganic carbon δ13C values across epeiric seas. These findings are consistent with the carbonate weathering hypothesis, that predicts larger positive δ13C shifts in proximal settings of tropical epeiric seas resulting from changes in the local carbon weathering flux caused by the exposure of vast areas of carbonate sediment during glacioeustatic sea level fall and restricted shelf circulation. A 2 positive excursion in δ15N is interpreted to result from increased ocean ventilation, greater partitioning of atmospheric oxygen into downwelling surface waters, oxygen minimum zone shrinkage, and declining denitrification rates. This allowed for upwelling of recycled nitrogen with high 15N values into the photic zone that forced exported organic matter from the photic zone to higher 15N values, consistent with the observed positive shift in 15N during the Hirnantian glaciation. This study presents a conceptual model to explain secular changes in δ13C and δ15N during the transition from a greenhouse to icehouse climate.<p> The second focus of this research, presented in chapter 3, was on improving the chemical and analytical methods for δ18O analysis of biogenic apatites. The technique applies cation exchange chromatography that allows for small sample sizes of apatite (200 µg) to be used for chemical conversion to Ag3PO4. The precision (0.15, 1) of δ18O analysis obtained using a Thermal Conversion Elemental Analyser Continuous Flow Isotope Ratio Mass Spectrometer (TC/EA CF-IRMS), and the ability to collect multipe isotopes (O, Ca, Sr, REE) using a cation exchange column, makes this technique valuable for high-resolution, multi-isotope studies of biogenic apatites.

Previous studies have identified δ¹³C events in the Carboniferous that imply major shifts in the carbon cycle. However, inherent in this interpretation is the assumption that epicontinental seas are chemically representative of the global ocean. Our study uses stable isotope and trace element analyses of brachiopod shells to examine changes in climate and circulation of the North American epeiric sea. Formations were selected for study to provide shallow marine environments with geographic coverage of North America. These units include the Grove Church and Mattoon Formations (Illinois Basin), Glenshaw Formation (Appalachian Basin), Bird Spring Formation (Bird Spring Basin), and Oread Formation (US midcontinent). In all, 98 brachiopod shells were found to be well preserved based on screening with plane light and cathodoluminescence microscopy of thin-sections, and trace element analyses. Upper Chesterian Grove Church (Illinois Basin) samples have δ¹³C and δ¹⁸O averages of 1.1% and -3.1% respectively. These low values are interpreted as a local or regional effect caused by terrestrial runoff. Terrestrial influences are also suggested by the depositional environment: nearshore marine. Chesterian samples from the Bird Spring Formation at Arrow Canyon, Nevada average 3.7% and -1.4% for δ¹³C and δ¹⁸O respectively. The higher δ¹³C and δ¹⁸O values, compared with samples from the time equivalent Grove Church, likely reflect the freer exchange with the Panthalassa Ocean at this most western edge of North America, and best represent open-ocean conditions. Samples from the Virgilian Ames-Shumway-Plattsmouth cyclothem show a progression of δ¹³C and δ¹⁸O enrichment moving west from near the Appalachians (1.9% and -3.8%) to the Illinois Basin (3.2% and -2.4%) and finally to the US midcontinent (4.2% and -1.5%). This is interpreted as the transition from nearshore, terrestrial influence with enhanced organic matter oxidation and lower salinity to well-mixed conditions with normal salinities and potential for seafloor ventilation and upwelling. This is supported by published sediment ΣNd(t) values from the Appalachian Basin (ΣNd(t) = -9) that increase further westward (ΣNd(t) = -6) due to higher influence from the eastern Panthalassa Ocean. Mass balance calculations based on the δ¹⁸O of the brachiopod shells suggest salinities of 25 and 31 psu for the Appalachian and Illinois Basins, respectively, assuming salinities of 34.5 psu for the US midcontinent. Trace element analyses do not show a systematic east-west trend similar to stable isotopes. In both time slices, spiriferids from the intermediately-located Illinois Basin are enriched in Mg/Ca and Sr/Ca relative to those in other basins. This Mg and Sr enrichment in Illinois Basin brachiopods suggests delivery of Sr-rich fresh waters and restricted circulation in that basin.

Studies examining bioevents (e.g., mass extinctions, faunal turnovers, diversification events) usually only scrutinize a short interval prior to such events, however, understanding their actual paleobiological implications requires a thorough understanding of the background conditions. The objective of this study is to document the background biodiversity dynamics in a single lithofacies of the Upper Cretaceous Pierre Shale that was deposited in an offshore setting of the Western Interior Seaway (WIS) and to place these changes into an environmental context. To assess the background biodiversity dynamics, the concretionary faunas of the Baculites eliasi through B. clinolobatus biozones of the Pierre Shale in eastern Wyoming were examined to understand the structure of marine habitats in the WIS through an interval of ~2.5 Ma. Both changes in the taxonomic composition of assemblages and the relative abundance of the various species are interpreted to reflect ecological and environmental change through the study interval. The concretionary faunas are thought to represent relatively short-term, time-averaged accumulations of dead and living animals on the muddy sea floor of the WIS that were concentrated by storm or current activity. They are likely accurate representations of the original skeletonized fauna of the WIS. The samples with lower diversity and abundances show a relationship with intervals when water conditions were deepest and the paleoshoreline was furthest to the west, while higher diversity and abundances match periods when the paleoshoreline was the closest and shallow-water conditions prevailed in that part of the WIS. The decrease in diversity with depth can best be explained by the long-term presence of dysoxic/anoxic conditions that would have precluded benthic faunas. The distribution of taxa and diversity of the assemblages seen in the study interval most likely reflect migrating oxygen-controlled biofacies in the WIS that were responding to changes in depth and the proximity to the western shoreline that was in turn controlled by relative sea-level fluctuations. This analysis shows that significant changes in richness, abundance, and guild structure can arise in response to variations in sea level with no apparent changes in lithology. It is also shown that a lack of environmental context can significantly influence interpretations of paleobiological and paleoecological data and it is recommended that future lines of research should examine faunal, morphological, and ecological change in a time/environmental context.