Cette thèse propose une modélisation du bruit d'origine aérodynamique, avec une attention particulière aux mécanismes de transfert d'énergie entre l'écoulement et le milieu de propagation. Une première partie aborde le problème de la création et du transport de l'énergie acoustique en milieu aérodynamique. Trois grands courants de pensée sont identifiés : l'approche eulérienne linéarise les équations valables en cas de fluide parfait pour former une loi de conservation ; l'approche dissipative développe les équations de Navier-Stokes, fait intervenir les fluctuations de vorticité comment moteur du mouvement acoustique ou décompose la quantité de mouvement en une théorie potentielle ; l'approche lagrangienne décrit le déplacement lagrangien de la perturbation qui suit le passage de l'onde acoustique. La première est la plus naturelle. La deuxième est la plus complète et la seule à expliquer la création d'énergie par l'aérodynamique. Une théorie générale voyant l'acoustique comme le seul champ généralisé qui se trouve piégé par l'aérodynamique en découle. La dernière est la plus prometteuse pour l'avenir. Dans une deuxième partie, les moyens permettant le calcul du champ acoustique à partir d'une sollicitation surfacique sont présentés. Il s'agit de la méthode d'extrapolation des ondes de Kirchhoff basée sur la pression, la formulation de Ffowcs-Williams & Hawkings basée sur les débits, et l'intégrale de Rayleigh basée sur une vitesse vibratoire. Une troisième partie de la thèse utilise les formalismes d'excitation surfacique pour étudier la réaction du milieu acoustique à des excitations génériques sous formes de paquets d'onde, représentatives de l'aérodynamique instationnaire. La réponse acoustique est caractérisée par la direction d'émission privilégiée du rayonnement et son efficacité, défini comme le taux de transfert d'énergie entre l'excitation et son milieu. On montre notamment que l'introduction d'une dissymétrie amont-aval dans l'excitation augmente fortement son efficacité, de même que la prise en compte d'un milieu de propagation en mouvement uniforme. Dans une dernière partie, ces considérations sont étendues au rayonnement d'une couche de mélange et adaptées en se basant sur l'analogie de Liepmann. Cette approche peu répandue est une intégrale de Rayleigh dont l'excitation est la dérivée temporelle de l'épaisseur de déplacement. Les résultats sont comparés avec la base de données d'une simulation acoustique directe et des deux autres méthodes surfaciques. La directivité n'est pas retrouvée par la modélisation proposée. On montre que la prédiction des niveaux nécessite de modéliser une impédance de rayonnement. / This study proposes a model for the noise generated aerodynamically, while focusing on energy transfer mechanisms between the main flow and the propagating medium. Energy harvest in aerodynamic condition is therefore the subject of a first part. Three general trends may be identified ; the eulerian approach uses linearized Euler's equations for inviscid flows in a form of a conservation law ; the dissipating approach expands Navier-Stokes equations in series, relies on vorticity fluctuations to excite the medium or splits velocity or momentum vectors in a general potential theory ; the lagrangian approach describes the lagrangian displacement of the perturbation inherent to an acoustic wave. The first approach is the most commonly adopted. The second one is the most complete and provides aerodynamical mechanisms for energy generation. A general fashion follows where acoustics is a generalized field, trapped by a hydrodynamic impedance. The last one may be subject of close attention for future considerations. In a second part, computational models are presented with their ability to predict acoustic radiation from a surface excitation. These are the Kirchhoff formalism based on the pressure, the Ffowcs Williams & Hawkings formalism based on the mass flow rate and the Rayleigh integral based on the vibration velocity. These are applied in a third part of the study to investigate the response of the acoustic medium to a generique excitation in the form of a wavepacket, representative of unsteady aerodynamics. Such acoustic response is caracterised by its direction of maximum radiation and its efficiency, defined as the rate of energy transfer between the excitation and its surrounding medium. Introducing an upstream-downstream asymmetry in the excitation is showed to significantly enhance its efficiency, as well as a convection velocity in the propagating medium. Within these general considerations, the last part of this study models acoustic excitation in a mixing layer flow based on Liepmann's analogy. This relatively unexplored theory consists in a Rayleigh integral excited by the temporal derivative of the displacement thickness. Results are compared with direct noise computation database and two other methods of surface excitation. Directivity is likely to be found while pressure amplitude is correctly predicted by using a model for radiation impedance.

Cette thèse porte sur l'étude de trois systèmes de spins basse dimension par diffraction et diffusion inélastique de neutrons. Dans le composé DMACuCl3, les mesures macroscopiques semblent indiquer la coexistence de deux types de dimères : antiferromagnétique et ferromagnétique. Une étude par diffraction nous a permis de déterminer sa structure magnétique en champ nul qui prouve l'existence des deux dimères de manière irrévocable. Il a été montré que le composé de type Ising BaCo2V2O8 serait le premier système présentant un ordre magnétique incommensurable longitudinal (ICL) sous champ. Tout d'abord, nous avons déterminé la structure magnétique en champ nul. Ensuite, nous avons suivi l'évolution du vecteur de propagation en fonction du champ magnétique caractérisant ainsi l'entrée dans la phase ICL à Hc = 3.9 T. La détermination de l'ordre magnétique de la phase ICL confirme que BaCo2V2O8 est le premier composé présentant un ordre magnétique colinéaire à la direction du champ. Il a été montré que le composé organique DF5PNN est bien décrit à basse température par des chaînes de spins à couplages alternés. Or la structure cristallographique connue à température ambiante implique des couplages uniformes. Notre étude par diffraction montre l'existence d'une transition structurale à basse température (Tc = 450 mK) faisant passer du groupe d'espace C2/c à Pc, et expliquant la nature alternée des interactions. Nous avons également caractérisé une transition structurale induite sous champ (Hc = 1.1 T) faisant revenir le groupe d'espace à C2/c. Cette transition implique un retour à l'uniformité des échanges, ce que nous avons confirmé en étudiant les excitations magnétiques.

<p>This thesis addresses the investigation of doubly excited <i>2l´nl</i> states in helium atoms and double core excitations in solid lithium compounds.</p><p>Measurements on <i>He</i> are made in field free environments and under the influence of electric and magnetic fields, using synchrotron based inelastic photon scattering. Cross sections for scattering to singly excited final states are directly determined and compared to theoretical results and are found to be in excellent agreement. Radiative and spin-orbit effects are quantified and are shown to play an important role in the overall characterization of highly excited <i>He </i>states below the <i>N =2</i> threshold. A dramatic electric field dependence is also observed in the flourecence yield already for relatively weak fields. This signal increase, induced by electric as well as magnetic fields, is interpreted in terms of mixing with states of higher fluorescence branching ratios.</p><p>Double core excitations at the lithium site in solid lithium compounds are investigated using resonant inelastic x-ray scattering (RIXS). The lithium halides <i>LiF, LiCl, LiBr</i> and <i>LiI </i>are studied as well as the molecular compounds <i>Li</i><i>2</i><i>O, Li</i><i>2</i><i>CO</i><i>3</i> and <i>LiBF</i><i>4</i>. States with one, as well as both, of the excited electrons localized at the site of the bare lithium nucleus are identified, and transitions which involve additional band excitations are observed. A strong influence of the chemical surrounding is found, and it is discussed in terms of the ionic character of the chemical bond.</p>

<p>This thesis treats the mass range of charmonium states and excited gluonic fields in two experiments, BESII and PANDA, and outlines a phenomenological model that connects them.</p><p>In BESII, <i>e</i>⁺<i>e</i>^– form a charmonium initial state, which is utilised as a source for secondary particles. The analysed channels, <i>ψ</i>´→ <i>γK</i>⁺<i>K</i>^– and <i>ψ</i>´→ <i>γπ</i>⁺<i>π</i>^–, give access to intermediate scalar states such as the two glueball candidates: f₀(1500) and f₀(1710). The f₀(1710) is indeed observed in decay into both <i>π</i>⁺<i>π</i>^– and <i>K</i>⁺<i>K</i>^– and the f₀(1500) is accepted as a necessary part of the <i>π</i>⁺<i>π</i>^– signal at the moderate 5% level. In addition, we observe the two tensor states f₂(1270) (in both channels) and f₂´(1525) (in <i>K</i>⁺<i>K</i>^–), but the need for the f₂´(1525) is not firmly established. The region around 2 GeV/<i>c</i>² is fitted with an f₄(2050) and an f₀(2200) in <i>π</i>⁺<i>π</i>^–. This region is fairly flat in <i>K</i>⁺<i>K</i>^– with a slight peak at the f₀(2200). Branching ratios for all eight channels are given. A fit to the angular distribution of ψ´→ γ f₂(1270) → <i>γ π</i>⁺<i>π</i>^–gave two possible solutions for the relative importance of helicity projections zero, one and two.</p><p>The future <i>pp</i>bar experiment PANDA is still in the development phase; important physics goals have been defined and we are now taking on the laborious task of constructing a detector that is able to fulfil them. A simulation investigation of a theoretically preferred <i>J</i><i>PC</i>=1^–+ charmonium hybrid (<i>H</i><i>c</i>) is presented: <i>ppbar</i> → <i>H</i><i>c</i><i>π</i>⁰/<i>η</i>, <i>H</i><i>c</i> → <i>χ</i><i>c</i>₁ (<i>π</i>⁰<i>π</i>⁰)<i>S–wave</i>, <i>χ</i><i>c</i>₁ → <i>J</i>/<i>ψπ</i>⁰, with a final state of seven photons and a lepton pair. To detect this channel next to full coverage of CM phase space is needed and as little material as possible before the electromagnetic calorimeter. </p><p>A second simulation study of <i>pp</i>bar → <i>η</i><i>c</i> → <i>γγ</i> at PANDA, suggests that the channel should be possible to detect with a signal-to-background ratio of 5±1 and a detection efficiency of at least 10%. </p><p>By assuming a constant matrix element we obtain a relation between the decay width for <i>ψ</i> → <i>pp</i>bar+<i>m</i>, which has been measured at BES for several cases, and the cross section for <i>pp</i>bar charmonium production in association with the same light meson, <i>m</i> (at for example PANDA). Cross sections of ~300–3000 pb were predicted for J/ψ production and ~30 pb for <i>ψ</i>' production. Isoscalars seem to be preferred to isovectors in <i>J</i>/<i>ψ</i> production, this might however be an artefact of simplifications within the model. A comparison with the only measured cross section, <i>pp</i>bar → <i>J</i>/<i>ψπ</i>⁰, suggests that the model is useful as a first estimate.</p>

<p>The basic building blocks in molecular electronics often correspond to conjugated molecules. A compound class consisting of rigid rod-like staffane molecules with the heavier Group 14 elements Si, Ge, Sn and Pb at their bridgehead positions has now been investigated. Herein these oligomers are called heavy-core or Si-, Ge-, Sn- or Pb-core staffanes. These compounds benefit from interaction through their bicyclo[1.1.1]pentane monomer units. Quantum chemical calculations were performed to probe their geometries, stabilities and electronic properties associated with conjugation.</p><p>The stabilities of the bicyclo[<i>n.n.n</i>]alkane and [<i>n.n.n</i>]propellanes (1 ≤ <i>n</i> ≤ 3) with C, Si, Ge and Sn at the bridgehead positions were studied by calculation of homodesmotic ring strain energies. The bicyclic compounds with <i>n</i> = 1 and Si, Ge or Sn at bridgehead positions have lower strain than the all-carbon compound.</p><p>A gradually higher polarizability exaltation is found as the bridgehead element is changed from C to Si, Ge, Sn or Pb. The ratio between longitudinal and average polarizability also increases gradually as Group 14 is descended, consistent with enhanced conjugation in the heavier oligomers.</p><p>The localization of polarons in C-, Si- and Sn-core staffane radical cations was calculated along with internal reorganization energies. The polaron is less localized in Si- and Sn-core than in C-core staffane radical cation. The reorganization energies are also lower for the heavier staffanes, facilitating hole mobility when compared to the C-core staffanes.</p><p>The effect of the bicyclic structure on the low valence excitations in the UV-spectra of compounds with two connected disilyl segments was also investigated. MS-CASPT2 calculations of 1,4-disilyl- and 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.2.1]heptanes and 1,4-disilyl- and 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.1.1]hexanes revealed that although the bicyclic cage separates the two disilyl chromophores, there is a strong red-shift of the lowest valence excitations when compared to an isolated disilane.</p>

<p>In this Thesis studies of highly excited states in gas-phase atoms and molecules (He, Ne, N₂, O₂, N₂O and CO₂) using a variety of synchrotron-radiation based techniques are presented. The three techniques used most frequently are X-ray-emission-threshold-electron coincidence (XETECO), X-ray emission spectroscopy (XES) and X-ray photoelectron spectroscopy (XPS) and they are all given a brief introduction. </p><p>The fluorescence yield (FY) from doubly excited states in helium near the N=2 threshold(s) has been investigated in weak static external magnetic and electric fields, but also in a field free environment. The FY spectra in weak static magnetic fields show the importance of including the diamagnetic interaction in the theoretical models. The presence of weak static electric fields shows that even weak fields (as low as 44 V/cm) has a great impact on the observed FY spectra. Resonant XES spectra from some of the first doubly excited states in helium has been recorded in a field free environment, and compared to theory.</p><p>The XETECO technique is presented and the first XETECO results from Ne, N₂, O₂, CO₂ and N₂O are shown, together with interpretations of possible threshold dynamics. I show that XETECO can be interpreted as threshold photoelectron spectra free from post collision interaction, and can hence be compared to above threshold XPS measurements. The observed below-threshold structures in the XETECO spectra are discussed and given a tentative explanation. The results from the analysis of the N₂O XETECO spectrum lead to further investigations using XPS. Results showing the vibrational parameters and vibrationally resolved cross-sections and asymmetry parameters for N₂O are presented together with theoretical predictions.</p>

This thesis treats the mass range of charmonium states and excited gluonic fields in two experiments, BESII and PANDA, and outlines a phenomenological model that connects them. In BESII, e+e– form a charmonium initial state, which is utilised as a source for secondary particles. The analysed channels, ψ´→ γK+K– and ψ´→ γπ+π–, give access to intermediate scalar states such as the two glueball candidates: f0(1500) and f0(1710). The f0(1710) is indeed observed in decay into both π+π– and K+K– and the f0(1500) is accepted as a necessary part of the π+π– signal at the moderate 5% level. In addition, we observe the two tensor states f2(1270) (in both channels) and f2´(1525) (in K+K–), but the need for the f2´(1525) is not firmly established. The region around 2 GeV/c2 is fitted with an f4(2050) and an f0(2200) in π+π–. This region is fairly flat in K+K– with a slight peak at the f0(2200). Branching ratios for all eight channels are given. A fit to the angular distribution of ψ´→ γ f2(1270) → γ π+π–gave two possible solutions for the relative importance of helicity projections zero, one and two. The future ppbar experiment PANDA is still in the development phase; important physics goals have been defined and we are now taking on the laborious task of constructing a detector that is able to fulfil them. A simulation investigation of a theoretically preferred JPC=1–+ charmonium hybrid (Hc) is presented: ppbar → Hcπ0/η, Hc → χc1 (π0π0)S–wave, χc1 → J/ψπ0, with a final state of seven photons and a lepton pair. To detect this channel next to full coverage of CM phase space is needed and as little material as possible before the electromagnetic calorimeter. A second simulation study of ppbar → ηc → γγ at PANDA, suggests that the channel should be possible to detect with a signal-to-background ratio of 5±1 and a detection efficiency of at least 10%. By assuming a constant matrix element we obtain a relation between the decay width for ψ → ppbar+m, which has been measured at BES for several cases, and the cross section for ppbar charmonium production in association with the same light meson, m (at for example PANDA). Cross sections of ~300–3000 pb were predicted for J/ψ production and ~30 pb for ψ' production. Isoscalars seem to be preferred to isovectors in J/ψ production, this might however be an artefact of simplifications within the model. A comparison with the only measured cross section, ppbar → J/ψπ0, suggests that the model is useful as a first estimate.

In this Thesis studies of highly excited states in gas-phase atoms and molecules (He, Ne, N2, O2, N2O and CO2) using a variety of synchrotron-radiation based techniques are presented. The three techniques used most frequently are X-ray-emission-threshold-electron coincidence (XETECO), X-ray emission spectroscopy (XES) and X-ray photoelectron spectroscopy (XPS) and they are all given a brief introduction. The fluorescence yield (FY) from doubly excited states in helium near the N=2 threshold(s) has been investigated in weak static external magnetic and electric fields, but also in a field free environment. The FY spectra in weak static magnetic fields show the importance of including the diamagnetic interaction in the theoretical models. The presence of weak static electric fields shows that even weak fields (as low as 44 V/cm) has a great impact on the observed FY spectra. Resonant XES spectra from some of the first doubly excited states in helium has been recorded in a field free environment, and compared to theory. The XETECO technique is presented and the first XETECO results from Ne, N2, O2, CO2 and N2O are shown, together with interpretations of possible threshold dynamics. I show that XETECO can be interpreted as threshold photoelectron spectra free from post collision interaction, and can hence be compared to above threshold XPS measurements. The observed below-threshold structures in the XETECO spectra are discussed and given a tentative explanation. The results from the analysis of the N2O XETECO spectrum lead to further investigations using XPS. Results showing the vibrational parameters and vibrationally resolved cross-sections and asymmetry parameters for N2O are presented together with theoretical predictions.

The basic building blocks in molecular electronics often correspond to conjugated molecules. A compound class consisting of rigid rod-like staffane molecules with the heavier Group 14 elements Si, Ge, Sn and Pb at their bridgehead positions has now been investigated. Herein these oligomers are called heavy-core or Si-, Ge-, Sn- or Pb-core staffanes. These compounds benefit from interaction through their bicyclo[1.1.1]pentane monomer units. Quantum chemical calculations were performed to probe their geometries, stabilities and electronic properties associated with conjugation. The stabilities of the bicyclo[n.n.n]alkane and [n.n.n]propellanes (1 ≤ n ≤ 3) with C, Si, Ge and Sn at the bridgehead positions were studied by calculation of homodesmotic ring strain energies. The bicyclic compounds with n = 1 and Si, Ge or Sn at bridgehead positions have lower strain than the all-carbon compound. A gradually higher polarizability exaltation is found as the bridgehead element is changed from C to Si, Ge, Sn or Pb. The ratio between longitudinal and average polarizability also increases gradually as Group 14 is descended, consistent with enhanced conjugation in the heavier oligomers. The localization of polarons in C-, Si- and Sn-core staffane radical cations was calculated along with internal reorganization energies. The polaron is less localized in Si- and Sn-core than in C-core staffane radical cation. The reorganization energies are also lower for the heavier staffanes, facilitating hole mobility when compared to the C-core staffanes. The effect of the bicyclic structure on the low valence excitations in the UV-spectra of compounds with two connected disilyl segments was also investigated. MS-CASPT2 calculations of 1,4-disilyl- and 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.2.1]heptanes and 1,4-disilyl- and 1,4-bis(trimethylsilyl)-1,4-disilabicyclo[2.1.1]hexanes revealed that although the bicyclic cage separates the two disilyl chromophores, there is a strong red-shift of the lowest valence excitations when compared to an isolated disilane.

Simplified methods of analysis described in codes and specifications for seismically isolated structures are always used either directly in special cases or for checking the results of nonlinear response history analysis (RHA). Important predictions for seismically isolated structures by simplified methods are the maximum displacements and base shears of the isolation system. In this study, the maximum isolator displacements and base shears determined by nonlinear RHA are compared with those determined by the equivalent lateral force (ELF) procedure in order to assess the accuracy of the simplified method in the case of bi-directional excitations with near-field characteristics. However, although there are currently many methods for ground motion selection and scaling, little guidance is available to classify which method is more appropriate than the others in any applications. Features of this study are that the ground motions used in analysis are selected and scaled using contemporary concepts and that the ground excitation is considered biv directional. The variations in response of isolated structures due to application of ground motions uni-directionally and bi-directionally are also studied by employing a scaling procedure that is appropriate for the bi-directional analysis. The proposed new scaling methodology is an amplitude scaling method that is capable of preserving the horizontal orthogonal components and it is developed especially for dynamic analysis of isolated structures. Analyses are conducted for two different symmetric reinforced concrete isolated structure for two different soil conditions in structural analysis program SAP2000. Effect of asymmetry in superstructure on isolator displacement is also investigated with further analyses considering 5% mass eccentricity at each floor level. Furthermore, once the significance of the orthogonal horizontal component on the response of isolation system is shown, the biaxial interaction of hysteretic behavior of lead rubber bearings is implemented in OpenSees by developing a subroutine which was not readily available.