Synthetic gas, syngas, is a popular alternative fuel for the gas turbine industry, but the composition of syngas can contain different types and amounts of contaminants, such as carbon dioxide, methane, moisture, and nitrogen, depending on the industrial process involved in its manufacturing. The presence of steam in syngas blends is of particular interest from a thermo-chemical perspective as there is limited information available in the literature. This study investigates the effect of moisture content (0 ? 15% by volume), temperature (323 ? 423 K), and pressure (1 ? 10 atm) on syngas mixtures by measuring the laminar flame speed in a newly developed constant-volume, heated experimental facility. This heated vessel also broadens the experimental field of study in the authors? laboratory to low vapor pressure fuels and other vaporized liquids. The new facility is capable of performing flame speed experiments at an initial pressure as high as 30 atm and an initial temperature up to 600 K. Several validation experiments were performed to demonstrate the complete functionality of the flame speed facility. Additionally, a design-of-experiments methodology was used to study the mentioned syngas conditions that are relevant to the gas turbine industry. The design-of-experiments methodology provided the capability to identify the most influential factor on the laminar flame speed of the conditions studied. The experimental flame speed data are compared to the most up-to-date C4 mechanism developed through collaboration between Texas A&M and the National University of Ireland Galway. Along with good model agreement shown with all presented data, a rigorous uncertainty analysis of the flame speed has been performed showing an extensive range of values from 4.0 cm/s to 16.7 cm/s. The amount of carbon monoxide dilution in the fuel was shown to be the most influential factor on the laminar flame speed from fuel lean to fuel rich. This is verified by comparing the laminar flame speed of the atmospheric mixtures. Also, the measured Markstein lengths of the atmospheric mixtures are compared and do not demonstrate a strong impact from any one factor but the ratio of hydrogen and carbon monoxide plays a key role. Mixtures with high levels of CO appear to stabilize the flame structure of thermal-diffusive instability. The increase of steam dilution has only a small effect on the laminar flame speed of high-CO mixtures, while more hydrogen-dominated mixtures demonstrate a much larger and negative effect of increasing water content on the laminar flame speed.

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This thesis is concerned with the experimental determination of the fundamental flame characteristics in a dust-air mixture and the influence of turbulence on flame propagation. Experiments were carried out in a tube having a 0.19 meter inside diameter and a length of 0.93 meter, and 1.86 meter with both ends closed. A dispersion system was developed giving a good quality uniform dust suspension. A comparative method for the estimation of dust flame characteristics, based on well defined methane-air flame characteristics, was developed and employed to estimate the characteristics of a flame propagating in a cornstarch dust-air mixture. A systematic study of the influence of dispersion-induced turbulence on the dust flame propagation was carried out. The influence of obstacles on flame propagation also was investigated. Some mechanisms of flame propagation in a cornstarch dust-air mixture have been proposed and discussed. In the conclusion, general remarks concerning the dust flame characteristics and the influence of turbulence on flame propagation are made. The future direction of research is also indicated.

A turbulent diffusion flame that is typically used in a thermal spray coating system was analyzed in this study, as part of a diagnostic and development program undertaken by a research group at Queen’s University. Contributions made by this researcher were to numerically and experimentally investigate velocity and turbulent fields of the gaseous phase of the jet. Numerical and experimental analyses have been further developed upon previous research, with improved numerical methods and advanced experimental instrumentation. Numerous numerical simulations were performed in both two dimensional axisymmetric and three dimensional wedge geometries, while testing the dependence of the final solution on various physical models. Numerical analyses revealed the requirement for simulating this problem in three dimensions and improved turbulence modeling to account for relatively high levels of anisotropy. Velocity and turbulent measurements of non-reacting and combusting jets were made with a laser Doppler anemometer to validate numerical models. Excellent agreement was found between predicted and measured velocity and turbulent quantities for cold flow cases. However, numerical predictions did not agree quite as well with experiments of the flame due to limitations in modeling techniques and flow tracking abilities of tracer particles used in experimentation. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2007-09-28 13:05:54.365

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