The relationship between biodiversity and ecosystem functioning is important in maintaining agroecosystem sustainability. Plant-microbe symbioses, such as exists between the grass tall fescue (Schedonorus arundinaceum) and the asexual fungal endophyte Epichloë coenophiala, can be utilized to enhance agroecosystem functions, such as herbivore resistance. “Novel” E. coenophiala strains that vary in the production of mammal- and insect-toxic compounds have been identified, inserted into tall fescue cultivars, and are planted in pastures globally. Novel fungal endophyte-tall fescue associations may have divergent ecosystem function effects. This study assessed effects of different fescue-endophyte symbiotic combinations on pasture ecosystem function, including aboveground (fescue biomass, plant species richness, alkaloid synthesis, arthropod abundance) and belowground (soil microbial biomass, soil enzyme activity, trace gas fluxes) parameters. Results showed no significant effects of increasing symbiotic diversity within a fescue stand on aboveground measurements, bar arthropod abundance and alkaloid synthesis. Most soil parameters quantified had significant symbiotic diversity effects. For example, soil microbial biomass decreased whereas soil enzyme activity increased with increasing symbiotic diversity. Overall, our results suggested that increasing symbiotic diversity had weak to moderate effects on aboveground processes and stronger effects on certain belowground processes, indicating that symbiotic diversity can impact ecosystem functions and warrants further research.

O crescimento e o desenvolvimento de ecossistemas florestais são fortemente influenciados pelas flutuações do clima. Sendo assim, espera-se que florestas de eucalipto de rápido crescimento sejam amplamente afetadas pelas mudanças climáticas. A utilização de métodos que possibilitem a avaliação e comparação dos atributos funcionais do xilema das árvores sob a dinâmica dos ciclos biogeoquímicos são necessários, a fim de antecipar e mitigar as consequências das mudanças climáticas no funcionamento das plantações. A análise do crescimento, anatomia, microdensidade e propriedades hidráulicas do xilema podem trazer importantes conhecimentos sobre a fisiologia das árvores. A avaliação dessas propriedades, contudo, ocorre geralmente em algumas regiões do xilema do tronco, ou ramos, sendo sua avaliação ao longo de todo o histórico das árvores um desafio. Assim, a relação entre as propriedades e atributos funcionais das árvores com os ciclos da água e do carbono no nível do ecossistema ainda não está claro. Em março de 2008, instalou-se em área localizada próxima do município de Itatinga-SP, a torre de fluxo do Projeto EucFlux. O projeto tem como objetivo avaliar os fluxos de carbono e água (eddy covariance) ao longo do crescimento e desenvolvimento de árvores de eucalipto. Isso, permite avaliar as dinâmicas biogeoquímicas sobre o ecossistema florestal, buscando predizer sua produtividade sob diferentes condições climáticas. Em novembro de 2009, mudas de Eucalyptus grandis foram plantadas na área experimental de 90 ha, sendo avaliadas (diâmetro, altura, volume, etc.) até maio de 2018 (final da rotação). Com o corte das árvores, uma análise retrospectiva das propriedades e atributos funcionais do xilema do tronco de árvores de E. grandis foi realizada. Buscando compreender as relações dessas propriedades com as variações inter-intranuais das variáveis climáticas e ciclos do carbono e da água registrados pela torre de fluxo. Os métodos, resultados e avanços do presente estudo são descritos em dois capítulos. No Capítulo I, utilizou-se amostras do lenho de Eucalyptus grandis, Tectona grandis e Cedrela fissilis, para a descrição de um protocolo para obtenção de cortes histológicos longos e seus potenciais usos para avaliação de anéis de crescimento de árvores de eucalipto e espécies arbóreas tropicais, em uma abordagem conjunta de anatomia microscópica, perfis de microdensidade e anatomia quantitativa. Para o Capítulo II, avaliou-se árvores de E. grandis, seus anéis de crescimento (classes dominantes e codominantes), relacionando o crescimento radial e as propriedades do lenho do seu tronco (anatomia e microdensidade conforme capítulo I) com os ciclos biogeoquímicos (torre de fluxo, eddy covariance) em um período de 8 anos e em resolução inter-intranual. Como também a relação da formação do xilema com o crescimento em altura das árvores no mesmo período e resolução. Observou-se diferenças significativas entre o crescimento e as propriedades do lenho das três classes de dominância, onde as dominantes, seguidas pelas codominantes e dominadas, apresentaram maiores dimensões e densidade do lenho. As variáveis climáticas e fluxos de carbono e água apresentaram forte correlação com as propriedades e atributos funcionais do lenho, onde maior temperatura média e disponibilidade de água, resultaram em maior crescimento do tronco, menor densidade do lenho e vasos de maior diâmetro e, assim, maior condutividade potencial do xilema. A evapotranspiração do ecossistema apresentou correlação significativa com todas as variáveis estudadas, sendo forte indício das flutuações das variáveis climáticas e, assim, regulador da formação do xilema e funcionamento das árvores. Observou-se correlação entre os fluxos de carbono e crescimento, onde valores mais negativos de C (maior sequestro) resultaram em maior crescimento. O evento de estresse hídrico de 2014 teve forte efeito sobre os ciclos do carbono e da água, alterando assim, as propriedades do lenho das árvores. Ainda, o crescimento em altura teve forte correlação com as propriedades do lenho, onde maior altura resultou em vasos de maior dimensão e, assim, um sistema hidráulico com maior potencial de condução, contudo, com maior risco de cavitação e falha hidráulica. Os resultados integrados apontam o forte potencial da utilização de cortes histológicos longos para espécies tropicais, aprimorando a delimitação das camadas de crescimento anuais e permitindo a quantificação de variáveis anatômicas em conjunto com perfis de microdensidade, fundamentais para estudos fisiológicos das árvores. Assim, a relação das propriedades do lenho, com as flutuações das variáveis climáticas e ciclos do carbono e da água ao longo de todo o histórico de uma rotação de eucalipto em resolução inter-intranual tornou-se possível, indicando importantes novas possibilidades para os estudos de dendrocronologia e ciências florestais. / Growth and development of forest ecosystems are strongly influenced by climate fluctuations. Thus, fast-growing eucalyptus forests are expected to be largely affected by climate change. The use of methods that allow the evaluation and comparison of the functional traits of the tree xylem under the dynamics of the biogeochemical cycles are necessary in order to anticipate and mitigate the consequences of climate change on the functioning of plantations. The analysis of the growth, anatomy, microdensity and hydraulic properties of the xylem can bring important knowledge about the physiology of the trees. The evaluation of these properties, however, usually occurs in some regions of the trunk xylem, or branches, and their evaluation throughout the entire tree history is a challenge. Thus, the relationship between the properties and functional traits of trees with water and carbon cycles at the ecosystem level is still unclear. In March 2008, the flux tower of the EucFlux Project was installed in an area located near of Itatinga-SP. The project aims to evaluate the flux of carbon and water (eddy covariance) along the growth and development of eucalyptus trees. This allows to evaluate the biogeochemical dynamics on the forest ecosystem, seeking to predict its productivity under different climate conditions. In November 2009, seedlings of Eucalyptus grandis were planted in the experimental area of 90 ha, being evaluated (diameter, height, volume, etc.) until May 2018 (end of rotation). With the cut of the trees, a retrospective analysis of the properties and functional traits of the trunk xylem of E. grandis trees was performed. Seeking to understand the relationships of these properties with inter and intra annual variations of the climate variables and cycles of carbon and water, recorded by flux tower. The methods, results and advances of the present study are described in two chapters. In Chapter I, samples of Eucalyptus grandis, Tectona grandis and Cedrela fissilis wood, were used to describe a protocol for obtaining long histological sections and their potential uses for evaluation of growth rings of eucalyptus trees and tropical tree species, in a joint approach of microscopic anatomy, microdensity profiles and quantitative wood anatomy. For Chapter II, it was evaluated E. grandis trees, their growth rings (dominant and codominant classes), relating the radial growth and the wood properties of their trunk (anatomy and microdensity according to chapter I) to the biogeochemical cycles (flux tower, eddy covariance) over a period of 8 years in inter and intra annual resolution. As also, the relation of the xylem formation with the growth in height of the trees in the same period and resolution. Significant differences were observed between growth and wood properties of the three dominance classes, where dominant, followed by codominant and dominated, had larger wood dimensions and density. The climate variables and carbon and water fluxes showed a strong correlation with the properties and functional attributes of the wood, where higher mean temperature and water availability resulted in higher trunk growth, lower wood density and larger diameter vessels, greater potential conductivity of the xylem. The evapotranspiration of the ecosystem showed a significant correlation with all the studied variables, being a strong indication of the climate variables fluctuations and, therefore, regulator of xylem formation and tree functioning. There was a correlation between carbon fluxes and growth, where more negative values of C (higher sequestration) resulted in higher growth. The water stress event of 2014 had a strong effect on the carbon and water cycles, thus altering the wood properties of the trees. Also, the growth in height had a strong correlation with the properties of the wood, where higher height resulted in larger vessels and, thus, a hydraulic system with greater potential of conduction, however, with greater risk of cavitation and hydraulic failure. The integrated results point to the strong potential of using long histological sections for tropical species, improving the delimitation of the annual growth layers and allowing the quantification of anatomical variables together with microdensity profiles, fundamental for physiological studies of the trees. Thus, the relationship of wood properties with fluctuations in climate variables and cycles of carbon and water throughout the history of an inter-intranasal eucalyptus rotation became possible, indicating important new possibilities for the studies dendrochronology and forest sciences.

L’estuaire de la Gironde est affecté par une pollution polymétallique historique, dont la contamination persistante en cadmium (Cd) empêche une reprise complète et le développement de la conchyliculture girondine, avec un risque potentiel pour le 1er site ostréicole français (Marennes-Oléron). D’autre part, le suivi de l’état de la qualité chimique des masses d’eau, mis en place par la Directive Cadre sur l’Eau (DCE) a déclassé en 2009 la masse d’eau « Gironde centrale » à cause de niveaux élevés en tributylétain (TBT), hautement toxique et interdit depuis plusieurs décennies, détecté dans l’estuaire de la Gironde.Ce travail se base sur 12 campagnes océanographiques comprenant un suivi temporel mensuel pendant l’année 2015 aux sites de surveillance DCE (PK52 et PK86), à PK 30 et 3 profils longitudinaux sur l’ensemble du gradient salin depuis Bordeaux jusqu’à l’embouchure. Les mesures in-situ et les échantillons visaient à caractériser l’état actuel de la qualité des eaux girondines pour Cd et butyl-étains dans le contexte historique de décontamination et de résilience du système fluvio-estuarien. Les résultats ont montré les plus faibles additions en Cd dissous (Cdd) dans le gradient salin depuis 2002, pour des conditions hydriques contrastées. Le développement de plusieurs méthodes de calcul a permis de montrer une diminution des flux nets de Cdd au cours des 30 dernières années d’un facteur ~10. Les concentrations en Cd particulaire (Cdp) présentent des valeurs de l’ordre de 0,45 ± 0,07 mg/kg ces 10 dernières années. Cette valeur est supérieure au bruit de fond géochimique de l’estuaire salin (0,2 mg/kg) suggérant la persistance d’un potentiel de contamination de la zone côtière par désorption. Des mesures ADCP à l’embouchure de l’estuaire couplées à des analyses géochimiques ont permis d’estimer quantitativement les flux nets en matières en suspension (MES) et Cdp pour des conditions hydrologiques extrêmes. La prise en compte de l’ensemble de résultats scientifiques (mesures et modélisation hydrosédimentaire) antérieures et l’analyse des évènements de crue et des coefficients de marée depuis 1990 ont permis de proposer un modèle conceptuel d’export de MES et Cdp en zone côtière. Le suivi mensuel sur l’année 2015 montre que l’estuaire de la Gironde reste déclassé en TBT avec deux valeurs ponctuelles supérieures à la NQE-CMA et avec des moyennes annuelles supérieures à la NQE-MA pour les PK30, PK52 et PK86. Les enregistrements longitudinaux des butylétains (TBT, dibutylétain (DBT) et monobutylétain (MBT)) dans les compartiments eaux, MES et sédiments de l’ensemble de l’estuaire de la Gironde ont permis de mettre en évidence plusieurs sources potentielles actuelles localisées au niveau de Bordeaux, du Bec d’Ambès, mais surtout au niveau de la masse d’eau aval. / The Gironde Estuary is affected by historical multi-metal pollution. Persistent contamination by cadmium (Cd) prevents complete recovery of the Gironde oyster farming, and implies potential risks for the most important oyster farming areas in France (Marennes-Oléron). In addition, the water quality survey governed by the Water Framework Directive (WFD), has downgraded the "Central Gironde" water body in 2009 due to the presence of TBT, a highly toxic organo-metallic compound, on the list of priority substances and banned for several decades.This work relies on 12 oceanographic campaigns, including a monthly survey at the WFD monitoring sites (KP52 and KP86) in 2015 with additional sampling at KP30. Furthermore, 3 longitudinal profiles were carried out along the salinity gradient to characterize the current state of water quality in the Gironde Estuary for Cd and butyltin species, in a perspective of decontamination and resilience. The results showed the lowest dissolved Cd additions (Cdd) along the salinity gradient since 2002, for contrasting hydrological conditions. The development of several calculation methods has shown a decrease in net Cdd flows over the past 30 years by a factor of ~10. Particulate Cd (Cdp) concentrations were in the range of 0.45 ± 0.07 mg/kg during the past 10 years. This value is higher than the geochemical background of the saline Gironde Estuary (0.2 mg/kg) suggesting the persistence of potential contamination of the coastal zone by desorption. Physical and chemical measurements at the estuary mouth coupling ADCP with geochemical analyses have provided estimates of the suspended particulate matter (SPM) and Cdp fluxes, for extreme hydrological conditions. The set of previous scientific results (measurements and hydro-sedimentary modeling), the analysis of time-series of flood events and tidal coefficients since 1990, have been integrated into a conceptual model for the export of SPM and Cdp to the coastal zone. The 2015 monthly survey according to the WFD has produced two distinct values and annual average concentrations both exceeding the respective environmental quality thresholds showing that the Gironde Estuary remains downgraded with respect to TBT. Longitudinal records of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT)) in water, SPM and sediment of the entire Gironde Estuary have pointed to several potential sources including urban discharges (from Bordeaux), industrial releases (Bec d’Ambès) and estuarine dredging activities (from downstream harbours).

<p>The boreal forests represent 8 % of all forested areas on the earth and have a significant role in the control of greenhouse gases and an impact on global climate change. The main objective of this thesis is to increase the understanding of how evaporation and heat-flux processes in the boreal forest zone are affecting the regional and global climate.</p><p>A meteorological mesoscale model with an advanced land-surface parameterization has been utilized to study aggregation of fluxes of water vapour and heat. The model has been compared against four other methods for flux estimation in a southern boreal landscape. The results show that the mesoscale model is successfully reproducing 24-hour averages of fractionally weighted mast measurements of sensible and latent heat flux.</p><p>The model was also evaluated against in-situ observations of surface fluxes and other meteorological variables. The results reveal that a correct initialization of soil moisture is crucial to simulate a realistic partitioning of the sensible and latent heat fluxes. Significant differences in surface fluxes and friction velocities between two apparently similar forest sites indicate the need for careful assessment of areal representativity when comparing mesoscale model results with in-situ observations.</p><p>A parameterization for the absorption of solar radiation of high-latitude sparse forests was implemented and tested in the model that significantly improved the simulation of high wintertime midday sensible heat fluxes. A scheme for heat storage in vegetation was also implemented which improved the results, but the scheme needs further evaluation for high latitude forests.</p><p>Two commonly used strategies for the description of land-surface heterogeneity, the effective parameter approach and the mosaic approach, were tested in the mesoscale model against airborne observations of sensible and latent heat fluxes. The results show that the mosaic approach produces better results especially when small lakes are present in model grid-squares.</p> / <p>Norra halvklotets barrskogsbälte representerar 8 % av all skogsbeklädd mark på jorden och har stor betydelse för kontrollen av växthusgaser och påverkan på globala klimatförändringar. Syftet med denna avhandling är att öka förståelsen av hur avdunstning och värmeflöden i den boreala skogszonen påverkar klimatet regionalt och globalt.</p><p>En meteorologisk mesoskalemodell med en avancerad landyteparameterisering har använts för att studera aggregering av avdunstning och värmeflöden. Modellen jämfördes med fyra andra metoder för uppskattning av värmeflöden i den boreala skogszonens södra delar. Resultaten visade att mesoskalemodellen reproducerar 24-timmarsmedelvärden av sensibelt och latent värmeflöde från areellt viktade mastmätningar med bra resultat.</p><p>Modellen utvärderades även mot markbaserade mätningar av sensibelt och latent värme och andra meteorologiska variabler. Resultaten visar att en korrekt initialisering av markvatteninnehållet är avgörande för att simulera en realistisk uppdelning av de sensibla och latenta värmeflödena. Markanta skillnader i markyteflöden och friktionshastigheter mellan två liknande skogsmätstationer påvisar nödvändigheten av en noggrann bedömning av den areella representativiteten när man jämför resultat från mesoskalemodellen med markbaserade mätningar.</p><p>En parameterisering för absorption av solstrålning i glesa skogsbestånd på höga breddgrader infördes och testades i modellen vilket markant förbättrade simuleringen av de höga sensibla värmeflöden som observerats vid middagstid på vintern. Ett uttryck för att beskriva värmelagring i vegetationen infördes också vilket förbättrade resultaten, men uttrycket behöver vidare utvärdering för skogsbestånd på höga breddgrader.</p><p>Två ofta använda strategier för att beskriva markytans heterogenitet, effektiva parametermetoden och mosaikmetoden, testades i mesoskalemodellen mot flygburna observationer av sensibla och latenta värmeflöden. Resultaten visar att mosaikmetoden ger bättre resultat särskilt när mindre sjöar förekommer i modellrutorna.</p>

<p>Oceans cover about 70% of the earth’s surface. They are the largest source of the atmospheric water vapour and act as enormous heat reservoirs. Thus in order to predict the future weather and climate it is of great importance to understand the processes governing the exchange of water vapour and heat between the ocean and atmosphere. This exchange is to a large extent mediated by turbulent eddies. Current numerical climate and weather forecast models are unable to resolve the turbulence, which means that the turbulent exchange needs to be simplified by using parameterizations. </p><p>Tower based measurements at the Östergarnsholm Island in the Baltic Sea have been used to study the air-sea turbulent exchange of latent and sensible heat and the heat flux parameterizations. Although the measurements are made at an island, data obtained at this site is shown to represent open ocean conditions during most situations for winds coming from the east-south sector. It is found that during conditions with small air-sea temperature differences and wind speeds above 10 m s^-1, the structure of the turbulence is re-organized. Drier and colder air from aloft is transported to the surface by detached eddies, which considerably enhance the turbulent heat fluxes. The fluxes where observed to be much larger than predicted by current state-of-the-art parameterizations. The turbulence regime during these conditions is termed the Unstable Very Close to Neutral Regime, the UVCN-regime.</p><p>The global increase of the latent and sensible heat fluxes due to the UVCN-regime is calculated to 2.4 W m^-2 and 0.8 W m^-2 respectively. This is comparable to the current increase of the radiative forcing due to anthropogenic emissions of greenhouse gases, reported in Intergovernmental Panel on Climate Change fourth assessment report (IPCC AR4). Thus the UVCN-effect could have a significant influence when predicting the future weather and climate.</p>

The boreal forests represent 8 % of all forested areas on the earth and have a significant role in the control of greenhouse gases and an impact on global climate change. The main objective of this thesis is to increase the understanding of how evaporation and heat-flux processes in the boreal forest zone are affecting the regional and global climate. A meteorological mesoscale model with an advanced land-surface parameterization has been utilized to study aggregation of fluxes of water vapour and heat. The model has been compared against four other methods for flux estimation in a southern boreal landscape. The results show that the mesoscale model is successfully reproducing 24-hour averages of fractionally weighted mast measurements of sensible and latent heat flux. The model was also evaluated against in-situ observations of surface fluxes and other meteorological variables. The results reveal that a correct initialization of soil moisture is crucial to simulate a realistic partitioning of the sensible and latent heat fluxes. Significant differences in surface fluxes and friction velocities between two apparently similar forest sites indicate the need for careful assessment of areal representativity when comparing mesoscale model results with in-situ observations. A parameterization for the absorption of solar radiation of high-latitude sparse forests was implemented and tested in the model that significantly improved the simulation of high wintertime midday sensible heat fluxes. A scheme for heat storage in vegetation was also implemented which improved the results, but the scheme needs further evaluation for high latitude forests. Two commonly used strategies for the description of land-surface heterogeneity, the effective parameter approach and the mosaic approach, were tested in the mesoscale model against airborne observations of sensible and latent heat fluxes. The results show that the mosaic approach produces better results especially when small lakes are present in model grid-squares. / Norra halvklotets barrskogsbälte representerar 8 % av all skogsbeklädd mark på jorden och har stor betydelse för kontrollen av växthusgaser och påverkan på globala klimatförändringar. Syftet med denna avhandling är att öka förståelsen av hur avdunstning och värmeflöden i den boreala skogszonen påverkar klimatet regionalt och globalt. En meteorologisk mesoskalemodell med en avancerad landyteparameterisering har använts för att studera aggregering av avdunstning och värmeflöden. Modellen jämfördes med fyra andra metoder för uppskattning av värmeflöden i den boreala skogszonens södra delar. Resultaten visade att mesoskalemodellen reproducerar 24-timmarsmedelvärden av sensibelt och latent värmeflöde från areellt viktade mastmätningar med bra resultat. Modellen utvärderades även mot markbaserade mätningar av sensibelt och latent värme och andra meteorologiska variabler. Resultaten visar att en korrekt initialisering av markvatteninnehållet är avgörande för att simulera en realistisk uppdelning av de sensibla och latenta värmeflödena. Markanta skillnader i markyteflöden och friktionshastigheter mellan två liknande skogsmätstationer påvisar nödvändigheten av en noggrann bedömning av den areella representativiteten när man jämför resultat från mesoskalemodellen med markbaserade mätningar. En parameterisering för absorption av solstrålning i glesa skogsbestånd på höga breddgrader infördes och testades i modellen vilket markant förbättrade simuleringen av de höga sensibla värmeflöden som observerats vid middagstid på vintern. Ett uttryck för att beskriva värmelagring i vegetationen infördes också vilket förbättrade resultaten, men uttrycket behöver vidare utvärdering för skogsbestånd på höga breddgrader. Två ofta använda strategier för att beskriva markytans heterogenitet, effektiva parametermetoden och mosaikmetoden, testades i mesoskalemodellen mot flygburna observationer av sensibla och latenta värmeflöden. Resultaten visar att mosaikmetoden ger bättre resultat särskilt när mindre sjöar förekommer i modellrutorna.

Oceans cover about 70% of the earth’s surface. They are the largest source of the atmospheric water vapour and act as enormous heat reservoirs. Thus in order to predict the future weather and climate it is of great importance to understand the processes governing the exchange of water vapour and heat between the ocean and atmosphere. This exchange is to a large extent mediated by turbulent eddies. Current numerical climate and weather forecast models are unable to resolve the turbulence, which means that the turbulent exchange needs to be simplified by using parameterizations. Tower based measurements at the Östergarnsholm Island in the Baltic Sea have been used to study the air-sea turbulent exchange of latent and sensible heat and the heat flux parameterizations. Although the measurements are made at an island, data obtained at this site is shown to represent open ocean conditions during most situations for winds coming from the east-south sector. It is found that during conditions with small air-sea temperature differences and wind speeds above 10 m s-1, the structure of the turbulence is re-organized. Drier and colder air from aloft is transported to the surface by detached eddies, which considerably enhance the turbulent heat fluxes. The fluxes where observed to be much larger than predicted by current state-of-the-art parameterizations. The turbulence regime during these conditions is termed the Unstable Very Close to Neutral Regime, the UVCN-regime. The global increase of the latent and sensible heat fluxes due to the UVCN-regime is calculated to 2.4 W m-2 and 0.8 W m-2 respectively. This is comparable to the current increase of the radiative forcing due to anthropogenic emissions of greenhouse gases, reported in Intergovernmental Panel on Climate Change fourth assessment report (IPCC AR4). Thus the UVCN-effect could have a significant influence when predicting the future weather and climate.

Knowledge of the turbulent fluxes at the sea surface is important for understanding the interaction between atmosphere and ocean. With better knowledge, improvements in the estimation of the heat exchange coefficients can be made and hence models are able to predict the weather and future climate with higher accuracy. The exchange coefficients of latent and sensible heat during stable stratification vary in the literature. Therefore it is necessary to investigate the processes influencing the air-sea exchange of water vapour and heat in order to estimate these values. With measurements from a tower and a directional waverider buoy at the site Östergarnsholm in the Baltic Sea, data used in this study have been sampled from the years 2005-2007. This site represents open-ocean conditions during most situations when the wind comes from the south-east sector. The neutral exchange coefficients, CEN and CHN, have been calculated along with the non-dimensional profile functions for temperature and wind to study the dependence of stability and other parameters of relevance. It was found that CEN increased slightly with wind speed and reached a mean value of approximately 1.45×10-3. The highest values of CEN were observed during near neutral conditions and low wave ages. CHN attained a mean value of approximately 0.77×10-3 and did not show any relation to wind speed or to wave age. No significant dependence with wind or wave direction could be shown for either CEN or CHN in the sector 80-220°. The stability correction, performed to reduce the dependence on stratification for CEN and CHN, was well performed for stabilities higher than 0.15. The stability is represented by a relationship between the height and the Obukhov-length (z/L). Validity of the non-dimensional profile functions for temperature and wind showed that, for smaller stabilities, these functions gave higher values than the corresponding functions recommended by Högström (1996). The profile funtions for temperature was shown to have a larger scatter while the profile functions for wind was less scattered and deviated more from the functions given by Högström / Kunskap om turbulenta flöden i det marina gränsskiktet är viktigt för att förstå växelverkan mellan atmosfär och hav. Med bättre kunskap kan förbättringar i bestämningen av utbyteskoefficienterna för latent och sensibelt värme erhållas. Det medför att modeller kan prognostisera väder och framtida klimat med högre noggrannhet. Utbyteskoefficienterna för latent och sensibelt värme har för stabil skiktning olika värden i litteraturen. Detta gör det nödvändigt att undersöka de processer som påverkar utbytet av vattenånga och värme mellan luft och hav för att kunna bestämma dessa värden. Data som har använts i den här studien insamlades mellan år 2005 och 2007 från en boj och ett torn vid mätplatsen Östergarnsholm i Baltiska havet. För det flesta situationer, när vinden blåser från syd-ost, representerar mätplatsen ett förhållande likvärdigt det över öppet hav. De neutrala utbyteskoefficienterna, CEN och CHN, och de dimensionslösa profilfunktionera för temperatur och vind, och , har beräknats för att studera beroendet av stabilitet samt andra relevanta parametrar. Beräkningarna visade att CEN ökade något med vindhastighet och hamnade på ett medelvärde av ungefär 1.45×10-3. De högsta värdena på CEN observerades vid nära neutrala förhållanden och låga vågåldrar. CHN uppmättes till att ha ett medelvärde på ungefär 0.77×10-3 och uppvisade inget beroende med vindhastighet eller vågålder. Inget märkbart beroende med vind- eller vågriktning kunde visas för CEN eller CHN i sektorn 80-220°. Stabilitetskorrektionen, utförd för att reducera beroendet av atmosfärens skiktning för CEN och CHN, var bra för stabiliteter högre än 0.15. Stabiliteten representeras av förhållandet mellan höjden och Obukhov-längden (z/L). Utvärdering av de dimensionslösa funktionerna för temperatur och vind visade att dessa funktioner, för små stabiliteter, gav högre värden än motsvarande funktioner som rekommenderas av Högström (1996). Värdena på profilfunktionerna för temperatur hade större spridning än värdena på profilfunktionerna för vind och avvek mer från funktionerna givna av Högström.

Atmospheric convection is sensitive to the nature of the surface and its temperature. Both dry (without cloud) and moist (with cloud) convections depend on the surface temperature. Surface temperature is of critical importance in several practical applications like human comfort and crop cultivation. In the climate change scenario too, variations in the surface temperature take the center stage. Therefore, prediction of surface temperature is important. The evolution of the temperature is governed by the energy equation and the surface temperature by the surface energy balance. Important components of the surface energy balance are radiation (incoming solar radiation, reflected solar radiation, incoming and outgoing longwave radiation), sensible and latent heat fluxes and heat flux into the ground (called ground heat flux). A large number of individual and collective observations have been carried out in the past to understand the atmospheric boundary layer and the surface energy budgets. However a major share of the observations is from mid-latitudes. There have been few experiments carried out in India, for example, MONTBLEX, LASPEX, etc. One common drawback among these experiments is that the data time series is discontinuous and continuous measurements covering an entire season are lacking. Moreover these measurements were not comprehensive and hence did not allowed to calculate complete surface energy balance – in some cases radiation data is not available while in some humidity data. Therefore, continuous time series of sufficient duration and covering all variables needed to look at the seasonal energy balance based on measurements alone is missing in the Indian context. New programmes with the main objective of predicting convection are being planned in India. For example, PROWNAM (Prediction of Regional Weather with Observational Meso-Network and Atmospheric Modeling) is aimed at predicting the short term weather at SHAR and STORM (Severe Thunderstorms – Observations and Regional Modeling) aims to predict the occurrence of severe thunderstorms in the northeastern India. In both these programmes, measurement of all components of surface energy balance is one of the main objectives. However, the minimum configuration and data accuracy requirements for the flux towers, sensitivity of computed fluxes on data accuracy have not been carefully evaluated. This thesis is aimed at filling this gap. As a part of my work, a 10 m high micrometeorological tower was installed in an open area within the Indian Institute of Science (IISc) Air Field. Temperature, relative humidity and wind speed and direction instruments were mounted at two levels, 2 m and 8 m. All components of radiation were measured. Data, sampled every 5 s and averaged for 2 minutes were continuously stored, starting May 2006 onwards. Soil temperature was measured at 4 depths, 5 cm, 10 cm, 15 cm and 20 cm. In addition, a sonic anemometer capable of measuring 3 components of velocity and air temperature was installed at 2 m height, and data was collected for more than a month to enable the calculation of momentum and buoyancy fluxes using the Eddy correlation method (ECM). The present work evaluated the sensitivity of the fluxes for small calibration errors and quantified the minimum data accuracies and configuration needed for flux measurement with the Profile method (PM). After applying corrections, the comparison of fluxes from PM and ECM are in good agreement. The complete long-term surface energy balances is calculated in terms of source and sink. One aspect that emerges from the observation is that the seasonal variation in the sink term is relatively small (150-170 Wm-2) whereas the source term shows much larger variation from 180-250 Wm-2. A method has been implemented by which the ground surface temperature can be estimated by using the subsurface temperature timeseries by the method of Fourier decomposition and using the Fourier heat conduction equation. In addition we can compute the thermal diffusivity of the soil by using the amplitude and phase information of the sub-surface soil time series. The estimated temperatures from this method and one that estimated from radiation method are in good agreement with the maximum difference being less than 0º C.

I denna rapport undersöks hur mängden organiskt kol, TOC (Totalt organiskt kol), varierar i tid och rum i Mälarens avrinningsområde, samt vad det är som styr TOC-halten i Mälaren. Det är viktigt att förstå dynamiken hos TOC i Mälaren och i dess avrinningsområde eftersom ökat TOC i vattnet påverkar vattenkvaliteten och orsakar problem vid beredning av dricksvatten. TOC kan bland annat reagera med klor/UV-ljus och bilda cancerframkallande ämnen. Det kan också öka antal mikrober i vattnets distributionssystem. Arbetet omfattar analys av samband mellan elementen, transportberäkningar per ytenhet av elementen till Mälaren och en modelleringsansats för ett av avrinningsområdena. Rapporten innehåller även en jämförelse mellan de olika vattenföringsmodellerna samt uppmätt vattenföring för analys av eventuella systematiska skillnader mellan dessa som påverkar beräkningen av TOC och de andra elementens transport till Mälaren. Analysen av sambanden mellan variablerna TOC (mg/l), kaliumpermanganat förbrukning (KMnO4, mg/l), absorbans_F (F=filtrerad), järn (mg/l), mangan (mg/l) och SO4_IC (sulfat mätt med hjälp av jonkromatografi, mg/l), visade att vissa av dessa variabler är korrelerade med varandra. TOC mot KMnO4 och TOC mot absorbans_F hade de bästa anpassningarna med respektive R2- värden 0,65 och 0,59 och p-värden &lt;0,001. Årsnederbörd är positivt korrelerad med TOC per ytenhet för Kolbäcksån med R2-värde 0,63 och p-värde &lt;0,01, vilket innebär att sambandet är signifikant. Ökad årsnederbörd leder till ökad tillförsel av TOC till Mälaren. Det finns däremot inget signifikant samband mellan TOC-transport per ytenhet och årsmedeltemperatur. Arealflödesberäkningar tyder på att den största tillförseln av TOC- transport per ytenhet kommer från den nordöstra delen av Mälaren. Fyrisån står för den största tillförseln av TOC. Hydrologiska, kemiska och meteorologiska data inkluderades i modeller för att kunna skatta TOC-halten i Mälaren. Temperatur-, evapotranspirations- och nederbördsdata användes i en hydrologisk modell, HBV- modellen, för att simulera vattenföringen från avrinningsområdet. Sedan användes en processbaserad modell, INCA- C, som drivs av hydrologisk data och beräknade grundvattenbildning och markfuktighet för att simulera tidsmässiga mönster i TOC. Invariablerna till INCA-modellen, markfuktigheten och HER (grundvattenbildning), simulerades med hjälp av HBV- modellen. Dessa modeller tillämpades i Kolbäcksån (ett av Mälarens största avrinningsområden). Modelleringen av Kolbäcksåns TOC- halt resulterade i en modell som anpassade dynamiken mellan 1996 och 2009, men missar den mellan 2009 och juni 2010, med bäst anpassning mellan 2006 och 2008. R2- och NS värden som erhölls för modellen var 0,086 och -0,059. / In this report, it has been investigated how the amount of organic carbon, TOC, varies in time and space in the basin of Mälaren, and what controls the TOC content in the lake. It is important to understand the dynamics of the TOC in the lake and its catchment because increased TOC in the water affects water quality and causes problems in the preparation of drinking water. Particularly, it can react with chlorine / UV- light and form carcinogenic substances. It can also increase the number of microbes in water distribution systems. In addition the work includes analysis of the relation between water chemistry variables, annual fluxes calculations (g/m2/year) of element flows to the lake and a modeling approach to a watershed. Annual fluxes calculations (g/m2/year) indicate that the largest supply of TOC to the lake comes from the northeast of the lake. Fyrisån accounts for the largest input of TOC to the lake. The high TOC-flux is due to a small proportion of open water in the catchment. Hydrological, chemical and meteorological data have been included in models to estimate the TOC content in the Mälaren. Input data processing, especially precipitation data, has been an important part of the work as it affects the whole model. Temperature, evapotranspiration and precipitation data were used in a hydrological model, HBV model, to simulate the flow from the catchment area. Then a process-based model, INCA-C, operated by the hydrological data and soil moisture, has been used to simulate the temporal patterns in TOC. The input variables to INCA-C- model, soil moisture and HER (Hydrological effective rainfall), have been simulated using the HBV- model. Those models were applied in Kolbäcksån, one of the lake's largest catchments. The modeling of Kolbäcksån resulted in a model that captured the dynamics of a few periods of the whole time series. The modeling of Kolbäcksån TOC-concentration resulted in a model that captured the dynamics between 1996 and 2009, but misses it between 2009 and June 2010. R2 and NS values obtained for the model were 0.086 and -0.059, respectively.