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Located in the far western equatorial Pacific, the Western Pacific Warm Pool (WPWP) is a greater than 10 million km² area of the warmest water on the planet. The WPWP therefore facilitates intense atmospheric convection and participates in coupled ocean-atmosphere climate phenomena such as El Niño Southern Oscillation, regional monsoons, and the shifting Intertropical Convergence Zone. The WPWP is also a water mass crossroads where thermocline-depth western boundary currents (WBCs) such as the New Guinea Coastal Undercurrent (NGCUC) facilitate the transfer of mass, heat, and nutrients vertically, zonally, and meridionally in the ocean. In this dissertation I focus mostly on reconstructing WPWP upper ocean temperature, salinity, nutrient, and productivity dynamics via a suite of physical and geochemical paleoclimate proxies. I apply these proxies in bulk sediments and planktic foraminifera from International Ocean Discovery Program (IODP) Site U1486 over the Pleistocene (2580 ka to 11.7 ka) and Holocene (11.7 ka to present). Site U1486 is located at 2°22’S, 144°36’E in the Bismarck Sea north of New Guinea in the southern WPWP, and is ideally situated to track changes to the WPWP upper water column forced by the South Pacific. The presence of glacial-interglacial (G-IG) variability within WPWP records is particularly important for determining local versus high-latitude climatic influences on the WPWP – with climate shifts such as the mid-Pleistocene Transition (MPT; ~1250 – 700 ka) and mid-Brunhes Event (MBE; ~430 ka) of particular interest in the long-term records I present. In chapter 1, I explore the paleoceanography of the low-latitude Pacific via upper ocean nitrate dynamics. I present a new bulk sediment ẟ¹⁵N record from Site U1486 that spans from 1420 to 0.67 ka – over a million years longer than any nearby records. Via analysis of orbital variability and secular trends at Site U1486 and in records directly along the equator in the Pacific, I find that nitrate dynamics were largely unrelated in the two regions in the Middle and Late Pleistocene. Whereas ẟ¹⁵N at Site U1486 is in line with patterns of eastern Pacific denitrification, increasing ẟ¹⁵N after the MPT at sites located directly along the equator appears linked to increasing Southern Ocean nitrate utilization. Enhanced nitrate utilization is an indicator of a strengthened biological pump – a major contributor to the reduction of atmospheric 𝑝CO₂ during the last glacial. A post-MPT increase in nitrate utilization may therefore point to the Southern Ocean biological pump as a driver for the deeper and longer glacial periods of the 100-kyr world after the MPT. In Chapter 2, I investigate changes in the vertical temperature and salinity structure of the southern sector of the WPWP in relation to the upper ocean’s response to climate change. When combined with Mg/Ca paleotemperatures and δ¹⁸O_sw, my 670-kyr record of Δẟ¹⁸O between the surface-dwelling foraminifera Globigerinoides ruber (sensu stricto) and the thermocline-dwelling foraminifera Pulleniatina obliquiloculata and Globorotalia tumida suggests enhanced thermocline shoaling and a progressively increasing vertical salinity gradient commencing near 240 ka. This secular change in upper water column dynamics does not appear to be associated with previously documented changes in G-IG variability such as the MPT or MBE. Via comparison to other records, I identify widespread cooling of the thermocline in the equatorial Pacific after ~240 ka. After combining these reconstructions with ²³⁰Th-derived focusing factors I validate previous model results indicating obliquity-driven strengthening of low-latitude ocean currents and extend this to imply the periodic increased transport of high-salinity thermocline water masses. These results strengthen previous evidence that the structure of the WPWP thermocline is relatively independent from the drivers of climate at the surface and support that variability in WPWP thermocline circulation is substantially influenced by obliquity. Because of the nitrate dynamics in the Bismarck Sea, bulk sediment ẟ¹⁵N cannot be used to reconstruct productivity. However, chapter 3 constrains variability in productivity via the analysis of new ²³⁰Th-normalized records of preserved biogenic flux and its components at Site U1486 over the last 138 kyr. Here, I assess the drivers of variability in paleo-productivity by reconstructing paleo-stratification, as in the modern Bismarck Sea productivity is stimulated by the delivery of nutrients to the surface during increased upwelling (reduced stratification). Paleo-stratification is approximated by calculating upper ocean density gradients between the calcification depths of G. ruber, P. obliquiloculata, and G. tumida using Mg/Ca temperatures and δ¹⁸O_sw-estimated salinity. Decreased paleo-stratification (a reduced vertical density gradient) was associated with increased productivity and is generally in phase with maximum orbital precession. Paleo-productivity therefore appears to respond to monsoonal increases in coastal upwelling when the Intertropical Convergence Zone (ITCZ) was at its southernmost extent. This illustrates that the unique and more direct method of constraining stratification presented here, which is subject to greater uncertainty, yields results consistent with our current understanding of upper ocean dynamics. I also identify a period between 100 and 60 ka during a potential reorganization of the upper water column in which variability in productivity occurs at a higher frequency than that of precession. Finally, while also related to ITCZ shifts, a nearby record closer to the equator is phase-lagged from Site U1486 – emphasizing the fine-scale regional differences in the drivers of primary productivity in the WPWP.

The Upper Cretaceous Tropic Shale of southern Utah captures critical oceanographic changes that occurred during Oceanic Anoxic Event 2 (OAE 2) and the transgression of the Greenhorn Sea. We investigated the response of planktic and benthic foraminifera in a shallow (<100 >m) marine environment stressed by the onset of OAE 2 during the Cenomanian-Turonian boundary (CTB; 93.9 Ma) to determine the oceanographic mechanisms controlling the observed turnovers in the foraminiferal record. This study is based on high-resolution quantitative foraminifera counts and isotope paleoecology (d18O and d13C) from a 40-m outcrop. The OAE 2 interval is identified by a distinctive d13Corg signature and by correlation of bentonites and limestones across the seaway. Results of assemblage analyses indicate discrete intervals of environmental perturbations across the CTB interval. At the onset of OAE 2, surface waters were dominated by planktic Guembelitra cenomana with minor species of Heterohelix. Benthic abundances increase and were initially dominated by oxygen tolerant infaunal Neobulimina albertensis. Epifaunal Gavelinella dakotaensis briefly proliferated during the core of the OAE 2 and coinciding with the planktic “Heterohelix shift” and increasing accumulation of organic matter. The peak of OAE 2 at ~17 m is marked by a rapid shift to infaunal Neobulimina dominance. We suspect incursion of oxygen-poor Tethyan intermediate waters with peak transgression during the early Turonian, coupled with high productivity in surface waters resulted in the rapid depletion of benthic oxygen. The foraminiferal record reveals strong cyclicity in planktic/benthic ratio resembling parasequences that correlate to the GSSP in central Colorado.

Foraminifera of the Paleocene Aquia Formation outcropping near Hanover, Virginia were studied in terms of their taxonomy, stratigraphic distribution and abundance. A total of seventy-nine species were described, eight of which have never been reported in the Aquia. Twenty species of planktonic foraminifera were recovered. The basal seven feet of Aquia contains only long ranging Paleocene Foraminifera. In the next two feet of Aquia occurred Globigerina triloculinoides and Globorotalia acuta which overlap in the Middle Paleocene Globorotalia pusilla pusilla Zone and the Late Paleocene Globorotalia pseudomenardii Zone. The next section of Aquia, from nine feet above its base to six feet below the overlying Marlboro Clay, is referred to the Globorotalia pseudomenardii Zone based on the occurrence of Globorotalia aequa and Globigerina triloculinoides. The top six feet of the Aquia and basal one foot of Marlboro Clay contain Globorotalia subbotinae and Globorotalia occlusa placing this section in the Late Paleocene Globorotalia velascoensis Zone. The basal Aquia f oraminif eral fauna is characterized by low species diversity, high morphologic variability in dominant species and large populations suggesting an unstable, marginal marine environment. The upper sections of the Aquia Formation contain faunal associations with higher species diversity, lower dominance and smaller populations indicating a somewhat deeper water, more stable environment. The associated macrofossil communities and local lithologies support these conclusions. A cross-section through the study area reveals offsets in formational boundaries and unusual downdip thickening of the Tertiary section. Accompanying these anomalies are abrupt changes in the course of the Pamunkey River. These data suggests faulting in the study area analogous to the faulted Coastal Plain strata near Fredericksburg, Virginia (Mixon and Newell, 1978), / Master of Science

Recent concern over the effects of ocean acidification upon calcifying organisms in the modern ocean has highlighted the aragonitic shelled thecosomatous pteropods as being at a high risk. Laboratory studies have shown that increased pCO2, leading to decreased pH and low carbonate concentrations, has a negative impact on the ability of pteropods to calcify and maintain their shells. This study presents the micropalaeontological analysis of marine cores from the Caribbean Sea, Mediterranean Sea and Indian Ocean. Pteropods, heteropods and planktic foraminifera were picked from samples to provide palaeoenvironmental data for each core. Determination of pteropod calcification was made using the Limacina Dissolution Index (LDX) and the average shell size of Limacina inflata specimens. Pteropod calcification indices were compared to global ice volume and Vostok atmospheric CO2 concentrations to determine any associations between climate and calcification. Results show that changes in surface ocean carbonate concentrations throughout the Late Pleistocene did affect the calcification of thecosomatous pteropods. These effects can be detected in shells from marine sediments that are located well above the aragonite lysocline and have not undergone post-depositional dissolution. The results of this study confirm the findings of laboratory studies, showing a decrease in calcification during interglacial periods, when surface ocean carbonate concentrations were lower. During glacial periods, calcification was enhanced due to the increased availability of carbonate. This trend was found in all sediments studied, indicating that the response of pteropods to past climate change is of global significance. These results demonstrate that pteropods have been negatively affected by oceanic pH levels relatively higher and changing at a lesser rate than those predicted for the 21st Century. Results also establish the use of pteropods and heteropods in reconstructing surface ocean conditions. The LDX is a fast and appropriate way of determining variations in surface water carbonate saturation. Abundances of key species were also found to constrain palaeotemperatures better than planktic foraminifera, a use which could be further developed.

The work reported in this thesis applies a new isotope tracer, stable strontium isotopes (&delta;^88/86Sr), to address questions concerning changes in global climate that occur in response to continental weathering processes, and to constrain the modern marine geochemical Sr cycle. Stable Sr isotopes are a relatively new geochemical proxy, and as such their behavior needs to be understood in differing forms of marine calcium carbonate, the archives from which records of past stable Sr variability in the oceans can be constructed. Foraminifera, coccoliths and corals (both aragonite and high Mg calcite) acquire &delta;^88/86Sr values lighter than that of modern day seawater, (approximately 0.11, 0.05, 0.2 and 0.19 ‰ lighter than seawater at ~25°C respectively) providing a measureable offset which can be used to constrain the modern Sr outputs from the ocean and provide a better understanding of the modern Sr cycle. Using foraminifera as a sedimentary archive the first marine &delta;^88/86Sr record of seawater over the last two glacial cycles has been constructed, and used to investigate changing carbonate input and output over this 145 kyr period. Modelling of the large excursion of &delta;^88/86Sr to heavier values during Marine Isotope Stage (MIS) 3, reveals that this is more likely to be due to local changes in seawater or post-depositional alteration, rather then whole ocean changes. In the terrestrial environment &delta;&delta;88/86^Sr has been measured in the dissolved load of rivers from the Himalaya. It is found that, in general, rivers draining carbonate catchments possess lighter isotopic &delta;^88/86Sr values than those from rivers draining silicates. Covariations of either &delta;88/86Sr vs. &delta;30Si or &delta;^88/86Sr vs. 1/[Sr] can be used to distinguish between rivers draining different catchment areas.

Cinq carottes de la Méditerranée occidentale ont fait l’objet des approches multidisciplinaires basées essentiellement sur l'analyse des dinokystes, des foraminifères planctoniques et des isotopes afin d'identifier et préciser l'évolution climatique de ce bassin. L'ensemble de l'Holocène correspond au maximum de développement des dinokystes S. mirabilis et I. aculeatum et des foraminifères planctoniques G. inflata et G. ruber tandis que les épisodes froids sont caractérisés par la présence de Nematosphaeropsis labyrinthus et a un degré moindre de Spiniferites elongatus. Si dans la proximité du détroit de Gibraltar il est possible de distinguer les évènements de Heinrich du Maximum Glaciaire (LGM) cette distinction est moins évidente en se dirigeant vers l’Est. Au contraire le Younger Dryas s’exprime de façon identique sur l'ensemble du bassin occidental et se caractérise par le développement optimal de N. labyrinthus s’accompagnant d’après les fonctions de transfert dinos d’une baisse importante de la salinité. Cet épisode est marqué aussi par des concentrations maximales de dinokystes remarquablement corrélées à une augmentation du ?13C de G. bulloides. Cette augmentation de la productivité primaire au Dryas Récent est à relier à l’intensification des échanges Méditerranée-Atlantique. Par opposition, l'Holocène inférieur montre une baisse de la productivité primaire en Méditerranée occidentale contemporaine de la mise en place du sapropéle S1 dans le bassin oriental. Comme dans l'océan Atlantique, le refroidissement du "8.2 event" est clairement observée en Méditerranée occidentale ainsi que trois autres épisodes correspondant à ~9,3 ka; ~7 ka et ~2,7 ka cal. BP. / A multidisciplinary approach is occurred on five western Mediterranean cores based on dinocysts, planktonic foraminifera and isotopes to identify the climatic evolution of this region. The Holocene correspond to the maximal development of dinocysts S. mirabis and I. aculeatum and planktonic foraminifera G. inflata and G. ruber but the cold periods are characterised by the presence of N. labyrinthus and Spiniferites elongatus. The microfaunistic assemblages show that it's less easier to distinguish the LGM to Heinrich events (HE) when the study sites are far to strait of Gibraltar. The Younger Dryas is marked by the optimal development of N. labyrinthus on the entire basin in association to an important decrease of Sea Surface Salinity reconstructed on the basis of dinocyst transfer function. During this period, an intensification of Mediterranean-Atlantic water masses exchange is recorded by the increase of the ?13C of G. bulloides associated to the maximal dinocysts concentration. By contrast, the lower Holocene shows a decrease of primary productivity in western Mediterranean contemporaneous to the deposition of S1 sapropel in eastern basin. As in Atlantic Ocean, the 8.2 event is clearly observed in western Med with three other cold events at 9.3 ka, 7 ka and 2.7 ka cal. BP.

Análises sedimentológicas, geoquímicas e microfaunísticas realizadas em um testemunho coletado na plataforma interna de Cabo Frio, permitiram a compreensão das variações de produtividade nos últimos 9.300 anos. Quatro fases foram reconhecidas, influenciadas por flutuações do nível relativo do mar e mudanças climáticas que ocorreram na margem continental sudeste Brasileira, durante o Holoceno. Antes de 7,0 kanos cal A.P., os dados apontam para baixa produtividade, sob condições de nível relativo do mar mais baixo e clima úmido. Entre 7,0 e 5,8 kanos cal A.P., há aumento na produtividade oceânica, num cenário de nível do mar em ascensão e condições climáticas mais úmidas. Produtividade similar à fase anterior marca o período de 5,8 a 2,8 kanos cal A.P., em condições de descida do nível do mar e clima mais seco. De 2,8 kanos cal A.P. até o presente, aumento na produtividade oceânica e condições hidrodinâmicas intensas, associados ao estabelecimento do processo de ressurgência em Cabo Frio, quando condições climáticas atuais são estabelecidas. A partir de 2,5 kanos cal A.P., observa-se intensificação do processo de ressurgência, controlada pela ação conjunta de ventos de NE mais intensos (associados a eventos El-niño e/ou a posição da Zona de Convergência Intertropical - ZCIT), meandramento da Corrente do Brasil - CB - e configuração atual da linha de costa. / Sedimentological, geochemical and benthic foraminifera analyses carried out on a core sampled from the inner shelf of Cabo Frio, enabled us to identify different four productivity regimes related to sea-level fluctuations and/or climatic changes, that occurred in the southeastern Brazilian continental margin, during the last 9.3 kyr cal BP. Prior to 7.0 kyr cal BP, a lower productivity and less intense hydrodynamic regime occurred at lower sea levels and under drier climatic conditions. Between 7.0 and 5.8 kyr cal BP, relatively stronger local oceanic circulation and relatively high productivity were observed, in a scenario of rising sea levels and more humid conditions. From 5.8 to 2.8 kyr cal BP, bottom currents weakened and input of nutrients increased, with productivity levels similar to the previous phase at lower sea level and in a drier climate. From 2.8 kyr cal BP up to the present, stronger hydrodynamic conditions and a higher productivity regime linked to the establishment of the upwelling process in Cabo Frio. From 2.5 kyr cal BP to the present, upwelling enhancement has been recognized, resulting from the combined action of NE winds (related to El- Niño events and/or the Intertropical Convergence Zone - ITCZ - position), the meandering pattern of the Brazilian Current - BC - and present day coastline configuration.

Para o desenvolvimento deste estudo, foi utilizado um testemunho de alta resolução coletado no talude da Bacia de Santos, em que foram realizadas análises de foraminíferos planctônicos e isótopos de oxigênio. Os resultados foram complementados por dados de razões de Fe/Ca e Ti/Ca e permitiram a compreensão do cenário paleoceanográfico no setor oeste do Atlântico Sul nos últimos 15 mil anos. Condições mais frias foram encontradas no início do registro até aproximadamente 8 mil anos A.P., com predomínio da fauna fria (G. truncatulinoides, N. dutertrei, e G. inflata) e valores mais altos de ? 18O. Maior produtividade também é sugerida pela componente principal 2 (CP2), relacionada à camada de mistura e caracterizada pela assembléia G. ruber (white) e G. sacculifer. As razões de Fe/Ca e Ti/Ca indicam maior aporte de terrígenos pela pluma do Rio da Prata para o ambiente oceânico, provavelmente contribuindo para fertilização das águas superficiais. A partir de 8 mil anos A.P. observa-se aumento dos valores da curva paleoclimática e diminuição progressiva dos valores de ? 18O. A CP2 apresenta valores máximos entre 10 e 5 mil anos A.P., indicando uma coluna de água mais quente e altamente estratificada. Neste período, apresentam-se os mínimos de razões de Fe/Ca e Ti/Ca, indicando um período mais seco, relacionado ao mínimo de insolação de verão no hemisfério sul e posicionamento da ZCIT mais ao norte. A partir de 5 mil anos A.P. até o final do registro, observa-se novamente menores valores da CP2 e razões crescentes Fe/Ca e Ti/Ca, indicando condições mais úmidas e de maior produtividade no Holoceno superior. / For this study, faunal changes in foraminifer\'s assemblages and oxygen stable isotopes were carried out on a high- resolution core retrieved from the slope of Santos Basin. The results, complemented with Fe/Ca and Ti/Ca ratios enabled the understanding of paleoceanografic changes occurred in the last 15 Kyr. Cold conditions were recognized in the late deglaciation until 8 mil Kyr B.P., characterized by the cold assemblage (G. truncatulinoides, N. dutertrei, and G. inflata) and higher values of ? 18O. The low values of principal component 2 (PC 2), related to the mixed layer and dominated by the species G. ruber (white) and G. sacculifer suggest enhanced surface productivity. The Fe/Ca and Ti/Ca ratios on the sedimentary record indicate a high terrigenous input from the Plata Plume outflow in the oceanic environment, which probably contributed to the fertilization of superficial waters. From 8 Kyr B.P., an increase in the paleoclimatic curve values and gradual reduction in the ? 18O were observed in the data. The PC 2 yields maximum values between 10 and 5 Kyr B.P., indicating warm and highly stratified water-column conditions. In this period, low Fe/Ca and Ti/Ca ratios point out dryer conditions, related to the low peak austral summer insolation and the ITCZ located farther north. From 5 mil Kyr B.P. decreasing PC 2 values and increasing Fe/Ca and Ti/Ca ratios may be a sign of more productivity and humid conditions in the late Holocene.