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Understanding and controlling the forces between colloidal particles in solution, along with the resulting stability of a dispersion of such particles, continues to be at topic of great interest. Although most laboratory studies focus on model systems in which the number of system species is kept to a minimum, real colloidal systems can be much more complex, consisting of multiple components that can vary greatly in size, charge, shape, etc. This dissertation focused on a topic that has received very little prior study, namely synergistic effects that can arise in mixed colloidal systems in which the resulting force and stability of the system cannot be predicted using results obtained in more idealized systems consisting of fewer components. Two specific systems were studied. The first was a ternary system of particles in which micron-sized particles were in a dispersion containing both nanoparticles and submicron particles. It was shown through both computation modeling and direct force measurements that the nanoparticles can create attractive forces between the micron and submicron particles such that a halo of submicron particles is formed. This halo results in long range forces between the microparticles that cannot be predicted from measurements in systems containing only nanoparticles or only submicron particles. In addition, the forces can be large enough to alter the stability of a dispersion of these microparticles. The second system consisted of microparticles in a solution containing nanoparticles and a polyelectrolyte, specifically poly(acrylic) acid. Again, through modeling and experimentation, it was found that complexation of the nanoparticles and polyelectrolyte molecules led to depletion and structural forces between the microparticles that were substantially greater than the sum of the forces measured in systems of only nanoparticles or only polyelectrolyte. It was also found that these greater forces could lead to destabilization of a dispersion of microparticles that was stable when only nanoparticles or only polyelectrolyte was present. While these results clearly demonstrate the difficulty associated with predicting forces and stability in mixed colloidal systems, they also indicate that such systems offer new and interesting opportunities for controlling stability that clearly warrant additional study. / Ph. D.

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本文旨在以鑽石體系探討台灣晶圓代工產業在發展了30年後，之所以具有國際競爭力各項條件，並在五力模型的分析下，進一步探討台灣晶圓代工產業未來的威脅及具有的優勢。本研究認為，台灣晶圓代工產業具備有鑽石體系中的各項生產因素、需求條件、相關與支援產業以及同業競爭與企業策略等條件，且台灣在發展晶圓代工產業的初期，政府扮演相當重要的要角，是推動這30年來晶圓代工產業蓬勃發展的重要原因。而這台灣獨創的專業晶圓代工模式也因為在國際分工需求下，產生其效益，並帶給台灣半導體上下游產業的垂直分工發展並使半導體產業聚落形成。 另一方面，在以五力模型中的各項威脅因素分析時，發現在同業競爭、供應商以及顧客的各項因素中，其威脅屬於中等程度，並沒有特別具有威脅的一項；而在潛在競爭者的威脅這一部分則更弱了，因為其成本太高以及經營模式和一般整合元件廠商（Integrated Device Manufacturer, IDM）以及記憶體廠商的經營方式不同，使得進入障礙提高；在替代產業的威脅上則是最低的，目前幾乎沒有可以取代晶圓代工產業的產品。故短期間內台灣的晶圓代工產業在國際上具有相當大的優勢。 本研究也針對以上結果綜合提出四個命題。第一、在晶圓代工產業發展初期，政府對鑽石體系中生產因素的策略性協助越多，越容易使其成功；第二、整合性服務與誠信這兩方面表現越佳者，未來越具有競爭力；第三、在供應商、晶圓代工業以及客戶的關係裡，位居買方之產業其轉換成本高；第四、未來唯有資本雄厚的整合元件製造廠（IDM）有能力進入該產業。 / The research shows that Taiwan semiconductor pure foundry industry composes of four well-proven completed environment conditions in Porter’s Diamond Model: Factor Conditions, Demand Conditions, Related and Supporting Industries, and Firm Strategy, Structure, and Rivalry. In addition, the Role of Government, defined as the fifth condition in the model, plays an important role in the early stage. The pure foundry model created by Taiwan also contributes the development of vertical de-integration and the formation of semiconductor cluster. Meanwhile, Five-Force Model is used to analyze the threats of Taiwan semiconductor pure foundry industry, which shows the threat from rivalry among existing competitors, suppliers and buyers is moderate. The threat of new entrants is low, and the threat of substitute products or services is insignificant. In summary, Taiwan semiconductor pure foundry industry still has strong competitive adventages in the near future. The research also provides four propositions. First, the more the government provides assistance to the factor conditions in the early stage, the easier the foundry industry will be successful. Second, the better the integrated services and the higher integrity a company could offer, the more competitive the company will be. Third, in the relationship of supplier, foundry and customer, the roles of buyer have higher switching cost. Fourth, the Integrated Device Manufacturer (IDM) companies with sufficient capital are the only type of companies could enter this industry in the future.

Turning is one of the most widely used processes in machining and is characterized by a cutting tool moving along the axis of a rotating workpiece as it removes material. A detrimental phenomenon to productivity in turning operations is unstable cutting or chatter. This can reduce the life of tooling, dimensional accuracy, and the quality of a part's surface finish because of severe levels of vibration. Ideally, cutting conditions are chosen such that material removal is performed in a stable manner. However, it is sometimes unavoidable because of the geometry of the cutting tool or workpiece. This work seeks to develop a dynamic cutting force model that can be used to predict both the point of chatter instability as well as its amplitude growth over time. Previous chatter models fail to capture the physics of the process from a first-principles point of view because they are oversimplified and rely on various "cutting force coefficients" that must be tuned in order to get a desired correlation with experimental results. The proposed approach models the process in a geometrically rigorous fashion, also giving treatment to the strain, strain rate, and temperature effects encountered in machining. It derives the forces encountered during a turning operation from two sources: forces due to chip formation and forces due to plowing and flank interference. This study consists of a detailed derivation of two new cutting force models. One relies on careful approximations in order to obtain a closed-form solution; the other is more explicit and obtains a solution through numerical methods. The models are validated experimentally by comparing their prediction of the point of instability, the magnitude of vibration in the time and frequency domains, as well as the machined surface topography during chatter.

Classical orthogonal and oblique cutting are the fundamental material removal or machining processes to which other practical machining processes can be related in the study and modelling of the machining processes. In the last century, a large amount of research and development work has been done to study and understand the various machining processes with a view to improving the processes for further economic (cost and productivity) gains. However, many aspects of the cutting processes and cutting performance remains to be fully understood in order to increase the cutting capability and optimize the cutting processes; in particular, there is little study to understand the effects of the inevitable tool wear on the machining processes. This thesis includes an extensive literature review on the mechanics of cutting analysis. Considerable work has been carried out in past decades on the fundamental analysis of 'sharp' tool cutting. Although some work has been reported on the effects of tool flank wear on the cutting performance, there is a general lack of the fundamental study of the effects of the flank wear on the basic cutting or chip formation process. It has been well documented that tool flank wear results in an increase in the cutting forces. However, it was not known if this force increase is a result of the change in the chip formation process, and/or the rubbing or ploughing forces between the tool flank and the workpiece. In work carried out since the early 1980s, the effects of the so-called edge forces have been considered when the tool is not absolutely sharp. Little has been reported to further develop fundamental cutting theories to understand applications to more relevant the practical situation, i.e. to consider the tool wear effects. Based on the findings of the literature review, an experimental investigation is presented in the first part of the thesis to study the effects of tool flank wear on the basic cutting or chip formation process by examining the basic cutting variables and performance in the orthogonal cutting process with tool flank wear. The effects of tool flank wear on the basic cutting variables are discussed by a comprehensive analysis of the experimental data. It has been found that tool flank wear does not affect the basic cutting variables (i.e. shear angle, friction angle and shear stress). It is therefore deduced that the flank wear does not affect the basic chip formation process in the shear zone and in the tool-chip interface. The study also finds that tool flank wear causes an increase in the total cutting forces, as can be expected and such an increase is entirely a result of the rubbing or ploughing forces on the tool wearland. The significance of this finding is that the well-developed machining theories for 'sharp' tools can be used in modelling the machining processes when tool flank wear is present, rather than study the machining process and develop machining theories from scratch. The ploughing forces can be modelled for incorporation into the overall cutting force prediction. The experimental study also allows for the forces on the wearland (or wearland force) and edge forces to be separated from the total measured forces. The wearland force and edge force models are developed in empirical form for force prediction purpose. In addition, a database for the basic cutting variables or quantities is established for use in modelling the cutting forces. The orthogonal cutting force model allowing for the effects of flank wear is developed and verified by the experimental data. A comprehensive analysis of the mechanics of cutting in the oblique cutting process is then carried out. Based on this analysis, predictive cutting force models for oblique cutting allowing for the effects of flank wear are proposed. The wearland force and edge force are re-considered by analysing the oblique cutting process and the geometrical relation. The predictive force models are qualitatively and quantitatively assessed by oblique cutting tests. It shows that the model predictions are in excellent agreement with the experimental data. The modelling approach is then used to develop the cutting force models for a more general machining process, turning operation. By using the concept of an equivalent cutting edge, the tool nose radius is allowed for under both orthogonal and oblique cutting conditions. The wearland forces and edge forces are taken into consideration by the integration of elemental forces on the tool flank and the cutting edge, respectively. The cutting forces in turning operations are successfully predicted by using the basic cutting quantity database established in the orthogonal cutting analysis. The models are verified by turning operation tests. It shows that the model predictions are in excellent agreement with the experimental results both qualitatively and quantitatively. The major findings, research impacts and practical implications of the research are finally highlighted in the conclusion. The modelling approach considering the flank wear effects in the classical orthogonal and oblique cutting and turning operations can be readily extended to other machining operations, such as drilling and milling.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第24220号 / 工博第5048号 / 新制||工||1788(附属図書館) / 京都大学大学院工学研究科都市社会工学専攻 / (主査)教授 五十嵐 晃, 教授 杉浦 邦征, 教授 KIM Chul-Woo / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Doctor of Philosophy / Department of Industrial & Manufacturing Systems Engineering / Zhijian Pei / Titanium alloy is one of the most important materials used in major segments of industries such as aerospace, automobile, sporting goods, medical and chemical. Market survey has stated that the titanium shipment in the USA has increased significantly in last two decades, indicating its increased usage. Industries are always under tremendous pressure to meet the ever-increasing demand to lower cost and improve quality of the products manufactured from titanium alloy. Similar to titanium alloys, silicon carbide and dental ceramics are two important materials used in many applications. Rotary ultrasonic machining (RUM) is a non-traditional machining process that combines the material removal mechanisms of diamond grinding and ultrasonic machining. It comprises of a tool mounted on a rotary spindle attached to a piezo-electric transducer to produce the rotary and ultrasonic motion. No study has been reported on RUM of titanium alloy, silicon carbide and dental ceramics. The goal of this research was to provide new knowledge of machining these hard-to-machine materials with RUM for further improvements in the machining cost and surface quality. A thorough research has been conducted based on the feasibility study, effects of tool variables, effects of machining variables and wheel wear mechanisms while RUM of titanium alloy. The effects of machining variables (such as spindle speed, feed rate, ultrasonic vibration power) and tool variables (grit size, diamond grain concentration, bond type) have been studied on the output variables (such as cutting force, material removal rate, surface roughness, chipping size) and the wheel wear mechanisms for titanium alloy. Feasibility of machining silicon carbide and dental ceramics is also conducted along with a designed experimental study.

Autonomous driving requires tactical decision-making while navigating in a dynamic shared space environment. The complexity and uncertainty in this process arise due to unknown and tightly-coupled interaction among traffic users. This thesis work formulates an unknown navigation problem as a Markov decision process (MDP), supported by models of traffic participants and userspace. Instead of modeling a traditional MDP, this work formulates a Multi-policy decision making (MPDM) in a shared space scenario with pedestrians and vehicles. The employed model enables a unified and robust self-driving of the ego vehicle by selecting a desired policy along the pre-planned path. Obstacle avoidance is coupled within the navigation module performing a detour off the planned path and obtaining a reward on task completion and penalizing for collision with others. In addition to this, the thesis work is further extended by analyzing the real-time constraints of the proposed model. The performance of the implemented framework is evaluated in a simulation environment on a typical construction (quarry) scenario. The effectiveness and efficiency of the elected policy verify the desired behavior of the autonomous vehicle.

Nowadays, the need for three-dimensional miniaturized components is increasing in many areas, such as electronics, biomedics, aerospace and defence, etc. To support the demands, various micro-scale fabrication techniques have been further introduced and developed over the last decades, including micro-electric-mechanical technologies (MEMS and LIGA), laser ablation, and miniature machine tools (mMTs). Each of these techniques has its own benefits, however miniature machine tools are superior to any others in enabling three-dimensional complex geometry with high relative accuracy, and the capability of dealing with a wide range of mechanical materials. Thus, mMTs are emerging as a promising fabrication process. In this work, various researches have been carried out based on the mMTs. The thesis presents micro-machining, in particular, micro-milling force model and three relevant subsystems for miniature machine tools (mMTs), to enhance machining productivity/efficiency and dimensional accuracy of machined parts. The comprehensive force model that predicts micro-endmilling dynamics has been developed. Unlike conventional macro-machining, the cutting mechanism in micro-machining is complex with high level of non-linearity due to the combined effects of edge radius, size, and minimum chip thickness effect, etc., resulting in no chip formation when the chip thickness is below the minimum chip forming thickness. Instead, part of the work material deforms plastically under the edge of a tool and the rest of the material recovers elastically. The developed force model for micro-endmilling is effective to understand the micro-machining process. As a result, the micro-endmilling force model is helpful to improve the quality of machined parts. In addition, three relevant subsystems which deliver maximum machining productivity and efficiency are also introduced. Firstly, ultrasonic atomization-based cutting fluid application system is introduced. During machining, cutting fluid is required at the cutting zone for cooling and lubricating the cutting tool against the workpiece. Improper cutting fluid application leads to significantly increased tool wear, and which results in overall poor machined parts quality. For the micro-machining, conventional cooling methods using high pressure cutting fluid is not viable due to the potential damage and deflection of weak micro-cutting tools. The new atomization-based cutting fluids application technique has been proven to be quite effective in machinability due to its high level of cooling and lubricating. Secondly, an acoustic emission (AE)-based tool tip positioning method is introduced. Tool tip setting is one of the most important factors to be considered in the CNC machine tool. Since several tools with different geometries are employed during machining, overall dimensional accuracy of the machined parts are determined by accurate coordinates of each tool tip. In particular, tool setting is more important due to micro-scale involved in micro-machining. The newly developed system for tool tip positioning determines the accurate coordinates of the tool tip through simple and easy manipulation. At last, with the advance of the 3D micro-fabrication technologies, the machinable miniaturized components are getting complex in geometry, leading to increased demand on dimensional quality control. However, the system development for micro-scale parts is slow and difficult due to complicated detection devices, algorithm, and fabrication of a micro-probe. Consequently, the entire dimensional probing system tends to become bulky and expensive. A new AE-based probing system with a wire-based probe was developed to address this issue with reduced cost and size, and ease of application. / Graduate