Groundwater recharge is an essential metric for understanding and protecting groundwater resources. Quantifying this parameter remains extremely challenging due to the uncertainties associated with the extent to which the vadose zone affects groundwater movement and the highly heterogeneous nature of the aquifer systems being monitored. The difficulty surrounding recharge quantification is compounded when considering a fractured rock aquifer system, where classification and modeling is complicated by highly complex structural geology. However, the ability to distinguish the character and geometry of fractured rock aquifers is indispensable for quantifying recharge to evaluate sustainable yields, as well as for implementing protective measures to manage these systems. The primary intention of this study is to assess the hydrogeologic properties that have led the unique recharge signals within the fractured crystalline-rock aquifer system near Ploemeur, France. Infiltration and groundwater movement are characterized via time-series hydraulic head and precipitation data collected at daily, monthly, yearly, and at decadal intervals. In spite of the nearly one million cubic meters of groundwater extraction, measured drawdowns are marginal, suggesting that local and regional recharge plays a significant role in moderating water-level declines and raising questions as to the origins of the substantial inflow required to sustain this complex system. A roughly two-month lag has been observed between seasonal water level and monthly precipitation at Ploemeur, which has previously been attributed solely to slow vertical migration of water through the low-permeability micaschist layer to the fractured contact zone and interconnected fault. However, results from this study suggest that a significant portion of the observed lag can be attributed to vadose-zone processes, particularly the thickness of the vadose zone. This investigation also reveals a recharge signal that continues throughout the calendar year, departing from the traditional simplified concept that recharge quantity is essentially equivalent to the value of evapotranspiration subtracted from infiltration. / Master of Science / Groundwater recharge is the amount of water added to underground water sources, called aquifers. This occurs as precipitation falls to the ground, moves downward through the unsaturated subsurface, and accumulates at the top of the saturated zone, deemed the water table. The saturated zone is so named because all pore spaces between sediment grains or crevices in rocks are fully filled with water. Understanding groundwater recharge is important to the protection of groundwater resources, but is hard to estimate due to the lack of knowledge about water movement in the unsaturated zone and the uncertainties related to the systems being studied. Aquifers forming within fractured rocks are even more challenging to investigate, because the complex geological structures are difficult to replicate with computer modeling. However, fractured rock aquifers are an important groundwater resource, and understanding them is the first step in estimating recharge within the system. Recharge estimates are used to calculate how much water can be safely removed from the aquifer for years to come, so that the resource can remain protected. The aim of this investigation is to assess the aquifer properties that lead to the unique recharge signal in a fractured crystalline-rock aquifer in Ploemeur, France, where nearly 1 million cubic meters of water have been removed each year since 1991 but water table levels have not fallen significantly. This behavior raises questions about the water returned to the system as recharge that is sustaining such a highly productive resource. This site also shows a roughly two-month lag between seasonal precipitation falling and the reflection of that precipitation recorded in the water level of the aquifer. It was previously thought that the lag occurred because water travelled slowly through the mica-schist layer, which has little pore space for water to move, and into the contact zone and interconnected fault. However, this study shows instead that a majority of the lag is associated with the unsaturated zone properties and processes, particularly thickness. This investigation also shows recharge entering the aquifer system throughout the calendar year, a departure from earlier studies conceptualizations.

A study was carried out in a sedimentary fractured rock site located in south central Wisconsin, US, which was impacted by DNAPL releases estimated to occur in the 1950’s and 1960’s. The majority of the DNAPL has accumulated in the upper portion of the Lone Rock Formation at a depth between 140 and 180 ft bgs referred as Layer 5 in this study. A groundwater VOC plume of more than 3km long has formed in this Layer. The DNAPL is mainly composed of 1,1,1-TCA, PCE, TCE and BTEX, while large amounts of biodegradation products such as cis-DCE and 1,1-DCA are present in the plume. Long term VOC data have been collected at the site and diverse geological and hydrogeological techniques have been applied to have a better understanding of the DNAPL history and behavior of the VOC plume. Evidence of biodegradation was also documented near the DNAPL source in these studies. The thesis objectives of the present study aimed first to have a better understanding of the long term contaminant distribution and degradation history at the site. This objective was accomplished reviewing the VOC historical concentration data collected from 1992 to 2006 in the wells tapping the most contaminated. hydrogeological unit in the bedrock (Layer 5) and in the overburden aquifer (referred as Layer 2). The second objective aimed to evaluate the current degree or extent of biodegradation of chlorinated compounds, which was accomplished evaluating the current groundwater redox conditions and using a combined analysis of VOC concentration and carbon isotope data collected in groundwater in September 2007. The historical data collected between1992 to 2006 showed the degradation of the VOC plume in Layer 5 was controlled by the availability of electron acceptors and redox conditions in the fracture bedrock aquifer. This pattern and the extension of the VOC plume were linked to different DNALP pumping events in the source zone and the operation of a Hydraulic Barrier System. The current geochemical and isotope study showed a different pattern of biodegradation of chlorinated compounds in different parts of the plume. The cis-DCE tend to accumulate in the area from the source to the middle of the plume and around 80 % of biodegradation of 1,1,1-TCA to 1,1-DCA was observed in this area. The fringes of the plume were characterized by a dominant presence of TCE and 1,1,1 TCA. These patterns were linked to different redox conditions and amount of electron acceptors. The cis-DCE dominated area is characterized by anaerobic conditions and the presence of relative high amount of BTEX. The TCE-dominated area is under aerobic condition and no BTEX was found in this area. The operation of the Hydraulic Barrier System seems to have change redox condition which influenced the extent of degradation in the plume, especially in the area between the extraction wells. The formation of large amounts of VC in Layer 2 and the more reducing (at least sulfate reducing and maybe methanogenic conditions) of the groundwater in this Layer compared to Layer 5 confirmed the extent of VOC biodegradation is linked to the availability of electron donors. This study provides information about the current degree of the biodegradation of chlorinated compounds at a fracture rock site. This information is very valuable for the evaluation of natural attenuation as strategy for long term plume management or for future remediation strategies such as biostimulation or bioaugmentation at the site. This study also shows the present and long term behavior of the chlorinated compounds (degradation history) in the most contaminated hydrogeologic unit (Layer 5), has mainly been controlled by plume management strategies including DNAPL pumping in the source and the creation of a Hydraulic Barrier System. The ketones and BTEX, that acted as electron donors and carbon substrate for the microbial community responsible for the dechlorination of chlorinated compounds were shown to have controlled the past and current redox conditions and thus the degree and potential of biodegradation of chlorinated ethenes and chlorinated ethanes at the study site.

A study was carried out in a sedimentary fractured rock site located in south central Wisconsin, US, which was impacted by DNAPL releases estimated to occur in the 1950’s and 1960’s. The majority of the DNAPL has accumulated in the upper portion of the Lone Rock Formation at a depth between 140 and 180 ft bgs referred as Layer 5 in this study. A groundwater VOC plume of more than 3km long has formed in this Layer. The DNAPL is mainly composed of 1,1,1-TCA, PCE, TCE and BTEX, while large amounts of biodegradation products such as cis-DCE and 1,1-DCA are present in the plume. Long term VOC data have been collected at the site and diverse geological and hydrogeological techniques have been applied to have a better understanding of the DNAPL history and behavior of the VOC plume. Evidence of biodegradation was also documented near the DNAPL source in these studies. The thesis objectives of the present study aimed first to have a better understanding of the long term contaminant distribution and degradation history at the site. This objective was accomplished reviewing the VOC historical concentration data collected from 1992 to 2006 in the wells tapping the most contaminated. hydrogeological unit in the bedrock (Layer 5) and in the overburden aquifer (referred as Layer 2). The second objective aimed to evaluate the current degree or extent of biodegradation of chlorinated compounds, which was accomplished evaluating the current groundwater redox conditions and using a combined analysis of VOC concentration and carbon isotope data collected in groundwater in September 2007. The historical data collected between1992 to 2006 showed the degradation of the VOC plume in Layer 5 was controlled by the availability of electron acceptors and redox conditions in the fracture bedrock aquifer. This pattern and the extension of the VOC plume were linked to different DNALP pumping events in the source zone and the operation of a Hydraulic Barrier System. The current geochemical and isotope study showed a different pattern of biodegradation of chlorinated compounds in different parts of the plume. The cis-DCE tend to accumulate in the area from the source to the middle of the plume and around 80 % of biodegradation of 1,1,1-TCA to 1,1-DCA was observed in this area. The fringes of the plume were characterized by a dominant presence of TCE and 1,1,1 TCA. These patterns were linked to different redox conditions and amount of electron acceptors. The cis-DCE dominated area is characterized by anaerobic conditions and the presence of relative high amount of BTEX. The TCE-dominated area is under aerobic condition and no BTEX was found in this area. The operation of the Hydraulic Barrier System seems to have change redox condition which influenced the extent of degradation in the plume, especially in the area between the extraction wells. The formation of large amounts of VC in Layer 2 and the more reducing (at least sulfate reducing and maybe methanogenic conditions) of the groundwater in this Layer compared to Layer 5 confirmed the extent of VOC biodegradation is linked to the availability of electron donors. This study provides information about the current degree of the biodegradation of chlorinated compounds at a fracture rock site. This information is very valuable for the evaluation of natural attenuation as strategy for long term plume management or for future remediation strategies such as biostimulation or bioaugmentation at the site. This study also shows the present and long term behavior of the chlorinated compounds (degradation history) in the most contaminated hydrogeologic unit (Layer 5), has mainly been controlled by plume management strategies including DNAPL pumping in the source and the creation of a Hydraulic Barrier System. The ketones and BTEX, that acted as electron donors and carbon substrate for the microbial community responsible for the dechlorination of chlorinated compounds were shown to have controlled the past and current redox conditions and thus the degree and potential of biodegradation of chlorinated ethenes and chlorinated ethanes at the study site.

Philosophiae Doctor - PhD / The Table Mountain Group (TMG) Aquifer is a huge aquifer system which may provide large bulk water supplies for local municipalities and irrigation water for agriculture in the Western Cape and Eastern Cape Provinces in South Africa. In many locations, water pressure in an aquifer may force groundwater out of ground surface so that the borehole drilled into the aquifer would produce overflow without a pump. Appropriate testing and evaluation of such artesian aquifers is very critical for sound evaluation and sustainable utilization of groundwater resources in the TMG area. However, study on this aspect of hydrogeology in TMG is limited. Although the flow and storage of TMG aquifer was conceptualised in previous studies, no specific study on artesian aquifer in TMG was made available. There are dozens of flowing artesian boreholes in TMG in which the pressure heads in the boreholes are above ground surface locally. A common approach to estimate hydraulic properties of the aquifers underneath is to make use of free-flowing and recovery tests conducted on a flowing artesian borehole. However, such testing approach was seldom carried out in TMG due to lack of an appropriate device readily available for data collection. A special hydraulic test device was developed for data collection in this context. The test device was successfully tested at a flowing artesian borehole in TMG. The device can not only be used to measure simultaneous flow rate and pressure head at the test borehole, but also be portable and flexible for capturing the data during aquifer tests in similar conditions like artesian holes in Karoo, dolomite or other sites in which pressure head is above ground surface. The straight-line method proposed by Jacob-Lohman is often adopted for data interpretation. However, the approach may not be able to analyse the test data from flowing artesian holes in TMG. The reason is that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale, which implies that some assumptions of infinite aquifer required for the straight-line method cannot be fulfilled. Boundary conditions based on the Jacob-Lohman method need to be considered during the simulation. In addition, the diagnostic plot analysis method using reciprocal rate derivative is adapted to cross-check the results from the straight-line method. The approach could help identify the flow regimes and discern the boundary conditions, of which results further provide useful information to conceptualize the aquifer and facilitate an appropriate analytical method to evaluate the aquifer properties. Two case studies in TMG were selected to evaluate the hydraulic properties of artesian aquifers using the above methods. The transmissivities of the artesian aquifer in TMG range from 0.6 to 46.7 m2/d based on calculations with recovery test data. Storativities range from 10-4 to 10-3 derived from free-flowing test data analysis. For the aquifer at each specific site, the transmissivity value of the artesian aquifer in Rawsonville is estimated to be 7.5–23 m2/d, with storativity value ranging from 2.0×10-4 to 5.5×10-4. The transmissivity value of the artesian aquifer in Oudtshoorn is approximately 37 m2/d, with S value of 1.16×10-3. The simulation results by straight-line and diagnostic plot analysis methods, not only imply the existence of negative skin zone in the vicinity of the test boreholes, but also highlight the fact that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale. With the storativity values of artesian aquifers derived from data interpretation, total groundwater storage capacity of aquifers at two case studies was calculated. The figures will provide valuable information for decision-makers to plan and develop sustainable groundwater utilization of artesian aquifers in local or intermediate scales. With the hydraulic test device readily available for data collection, more aquifer tests can be carried out in other overflow artesian boreholes in TMG. It becomes feasible to determine the hydraulic properties of artesian aquifers for the entire TMG. Thereof quantification of groundwater resources of artesian aquifers in TMG at a mega-scale becomes achievable. This would also contribute towards global research initiative for quantification of groundwater resources at a mega-scale.

The Karoo has been receiving considerable attention since the early 1970’s when uranium mining was at its peak, with numerous research studies being instigated to look at all aspects of uranium mining. It has recently been observed that there seems to be resurgence in uranium exploration in and around the town of Beaufort West. A study on the transport mechanisms of uranium and thorium in fractured-rock aquifers, initiated in the hope of understanding the actual processes controlling radionuclide mobilisation, is reported here. Hydrochemical investigations of the various boreholes were sampled for water quality in June, 2009. The hydrochemical description is typical of shallow fresh groundwater, changing composition to a more sulphate hydrochemical facies along the flow path. While the geochemistry of groundwater in the study area seems to have minimal effects on uranium concentrations, the low levels of uranium in boreholes sampled suggest the importance of hydrological and lithological variability on the measured concentrations. Nevertheless, the uranium concentration is within the recommended levels as specified in the US-EPA, WHO and SA water quality guidelines and thus poses no immediate threat to the general public. Analysis of pumping and tracer tests, reveals that the fractured-rock aquifer can be highly transmissive and that transport can take place via multiple flow paths having different hydraulic properties. Tracer diffusing into stagnant water zones within fracture asperities and the rock matrix are seen as an important retardation mechanism, that has implications for remediation should the aquifer be contaminated by radionuclides. In terms of conceptualising flow at a local scale, aperture sizes ranging from (563-828ìm) along with high flow velocities (1.90E-03m/s), points to the importance of bedding-plane fractures as conduits of groundwater flow. The groundwater flow has been influenced by dolerite dykes creating compartments isolated from each other, suggesting a highly complex aquifer system. Based on the conceptual model, it is shown that these structures can create unique, site specific flow conditions. The integration of all available data into the conceptual model provides an effective research tool that can be built upon as a basis for further research. / Dissertation (MSc)--University of Pretoria, 2010. / Geology / unrestricted

>Magister Scientiae - MSc / Deformation of the western part of the Table Mountain Group rocks during the Cape Orogeny created a series of folds and associated fractures. The subsequent continental break-up of Gondwana led to the development of large fault systems. These exert a major influence on deep and shallow groundwater flow. There are 3 main types of structures that are investigated. The geological contacts between hydraulically different lithologies, the primary characteristics of the sediments comprising the main geological units and the secondary structures developed from the tectonic events. These inter-alia include lithological boundaries, bedding and conjugate joints and large faults. Compartmentalisation of the aquifers by lithological and fault boundaries are the main regional level controls on flow in the study area. Joints are important for local control of flow, but cumulatively exert a regional effect as well. These controls exert a strong 3 dimensional impact on flow patterns within the area. Geological cross sections and detailed fieldwork combined with the conceptual models proposed are used to determine groundwater flow and the extent of the flow constraints. There is heterogeneity in the fault characteristics whilst there is consistence in the impermeable aquitards. These effect boundaries at the base of the aquifer, divide the aquifer into upper and lower units and cap the top of the aquifer. Using water level data, EC and pH an attempt is made to establish patterns created by structures, mainly faults. There appears to be some control of these shown by patterns seen on contour plots of the data. Understanding of the structures can significantly alter the way the available data could be interpreted. The integration of all available data into the conceptual model provides an effective research tool, which opens up further avenues for new approaches and methods for continued research in this area.