<p>Förorenat dagvatten från Stena Gotthards metallåtervinningsanläggning i Eskilstuna har filtrerats genom kolonner innehållande två olika adsorbenter, torv och furubarksflis. Torv är en organisk jordart som främst används som bränsle och furubarksflis är en biprodukt från skogsindustrin. Båda filtermaterialen är relativt billiga och finns i stora kvantiteter i Sverige. Filtermaterialen har visat sig ha varierande kapacitet att adsorbera metaller i vatten på grund av själva materialet samt vattnets sammansättning. Resultatet från den här studien visar att av de två undersökta filtermaterialen så har furubarksflis störst kapacitet att reducera bly, koppar och zink från det specifika dag vattnet.</p> / <p>Polluted storm water from a metal recycling industry has been filtrated through columns that contained two different adsorbents, peat and pine bark. Peat is an organic soil, mainly used for energy production, and pine bark, a by-product from the forest industry. In Sweden, there are a lot of resources of peat as well as pine bark. Used as filter materials, they are relatively cheep and, like other kinds of filtermaterial used as adsorbents, they have varied capacity to adsorb metals in water. The capacity for the filter materials to adsorb metals depends on the physical structure and chemical contents of the peat and pine bark as well as the water metal composition. Results from this study show that pine bark had the highest adsorption capacity to reduce copper, lead and zinc from the specific storm water.</p>

<p>The filters used today to purify water are often expensive and the need to find new filter materials is substantial. Studies of pine bark have shown that this is a material that may be used as an alternative to conventional filter materials, such as activated carbon. However, the study of pine bark has shown that a leakage of phenolic compounds may occur when using the material for water purification. Therefore, the purpose of this report is to investigate the release of phenols from pine bark, in order to evaluate the use of pine bark as a filter material. Another assignment is to investigate the amount of metals adsorbed by the filter material. The studies were carried out through three leaching experiments. As leachates, double deionised water and storm water were used. The phenol concentration in the leachate was determined for both double deionised water and storm water. The degree of metal sorption was measured only for the storm water. The measured phenol concentration in the double deionised water was 4.40 mg/L and in the storm water 4.81 mg/L. These concentrations exceed the Canadian guideline value, of 4.0 μg/L, more than a 1000 times. No metal sorption occurred as the metal content of the storm water was too low. Instead a release of metals from the pine bark into the eluate of the storm water occurred. The leaching attempts also resulted in a decline of the pH-values of the two different waters. The pH-values for the double deionised water and the storm water decreased from 7.0 to 4.3 and from 6.0 to 4.2 respectively. A release of phenols was ascertained with a significant difference in concentrations between double deionised water and storm water. Therefore it is not advisable to use pine bark filters for purification of water with low concentrations of metals, as the filter material may release metals into the water under such conditions.</p><p>Keywords: pine bark, phenol, filter materials, leaching, metal sorption, toxicity</p><p>Nyckelord: furubarksflis, fenol, filtermaterial, lakning, metallsorption, toxicitet</p>

Förorenat dagvatten från Stena Gotthards metallåtervinningsanläggning i Eskilstuna har filtrerats genom kolonner innehållande två olika adsorbenter, torv och furubarksflis. Torv är en organisk jordart som främst används som bränsle och furubarksflis är en biprodukt från skogsindustrin. Båda filtermaterialen är relativt billiga och finns i stora kvantiteter i Sverige. Filtermaterialen har visat sig ha varierande kapacitet att adsorbera metaller i vatten på grund av själva materialet samt vattnets sammansättning. Resultatet från den här studien visar att av de två undersökta filtermaterialen så har furubarksflis störst kapacitet att reducera bly, koppar och zink från det specifika dag vattnet. / Polluted storm water from a metal recycling industry has been filtrated through columns that contained two different adsorbents, peat and pine bark. Peat is an organic soil, mainly used for energy production, and pine bark, a by-product from the forest industry. In Sweden, there are a lot of resources of peat as well as pine bark. Used as filter materials, they are relatively cheep and, like other kinds of filtermaterial used as adsorbents, they have varied capacity to adsorb metals in water. The capacity for the filter materials to adsorb metals depends on the physical structure and chemical contents of the peat and pine bark as well as the water metal composition. Results from this study show that pine bark had the highest adsorption capacity to reduce copper, lead and zinc from the specific storm water.

The filters used today to purify water are often expensive and the need to find new filter materials is substantial. Studies of pine bark have shown that this is a material that may be used as an alternative to conventional filter materials, such as activated carbon. However, the study of pine bark has shown that a leakage of phenolic compounds may occur when using the material for water purification. Therefore, the purpose of this report is to investigate the release of phenols from pine bark, in order to evaluate the use of pine bark as a filter material. Another assignment is to investigate the amount of metals adsorbed by the filter material. The studies were carried out through three leaching experiments. As leachates, double deionised water and storm water were used. The phenol concentration in the leachate was determined for both double deionised water and storm water. The degree of metal sorption was measured only for the storm water. The measured phenol concentration in the double deionised water was 4.40 mg/L and in the storm water 4.81 mg/L. These concentrations exceed the Canadian guideline value, of 4.0 μg/L, more than a 1000 times. No metal sorption occurred as the metal content of the storm water was too low. Instead a release of metals from the pine bark into the eluate of the storm water occurred. The leaching attempts also resulted in a decline of the pH-values of the two different waters. The pH-values for the double deionised water and the storm water decreased from 7.0 to 4.3 and from 6.0 to 4.2 respectively. A release of phenols was ascertained with a significant difference in concentrations between double deionised water and storm water. Therefore it is not advisable to use pine bark filters for purification of water with low concentrations of metals, as the filter material may release metals into the water under such conditions. Keywords: pine bark, phenol, filter materials, leaching, metal sorption, toxicity Nyckelord: furubarksflis, fenol, filtermaterial, lakning, metallsorption, toxicitet